Silicon containing mesogen building blocks: synthesis, characterization and application in silane and siloxane self-assembly
Saved in:
| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
2012
|
| Subjects: | |
| Online Access: | Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120516-1095880-1-6 Inhaltsverzeichnis |
| Physical Description: | III, 217 S. Ill., graph. Darst. |
Staff View
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV040553209 | ||
| 003 | DE-604 | ||
| 005 | 20140724 | ||
| 007 | t | ||
| 008 | 121120s2012 ad|| m||| 00||| eng d | ||
| 035 | |a (OCoLC)820417783 | ||
| 035 | |a (DE-599)BVBBV040553209 | ||
| 040 | |a DE-604 |b ger |e rakwb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-384 |a DE-473 |a DE-703 |a DE-1051 |a DE-824 |a DE-29 |a DE-12 |a DE-91 |a DE-19 |a DE-1049 |a DE-92 |a DE-739 |a DE-898 |a DE-355 |a DE-706 |a DE-20 |a DE-1102 | ||
| 082 | 0 | |a 546.6832 |2 22//ger | |
| 084 | |a CHE 365d |2 stub | ||
| 084 | |a CHE 617d |2 stub | ||
| 100 | 1 | |a Heinz, Paul |e Verfasser |0 (DE-588)1034264222 |4 aut | |
| 245 | 1 | 0 | |a Silicon containing mesogen building blocks |b synthesis, characterization and application in silane and siloxane self-assembly |c Paul Heinz |
| 264 | 1 | |c 2012 | |
| 300 | |a III, 217 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a München, Techn. Univ., Diss., 2012 | ||
| 650 | 0 | 7 | |a Mesogen |0 (DE-588)4336645-4 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Silane |0 (DE-588)4181296-7 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Siloxane |0 (DE-588)4181431-9 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Silane |0 (DE-588)4181296-7 |D s |
| 689 | 0 | 1 | |a Siloxane |0 (DE-588)4181431-9 |D s |
| 689 | 0 | 2 | |a Mesogen |0 (DE-588)4336645-4 |D s |
| 689 | 0 | |5 DE-604 | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |o urn:nbn:de:bvb:91-diss-20120516-1095880-1-6 |
| 856 | 4 | 1 | |u http://mediatum.ub.tum.de/node?id=1095880 |x Verlag |z kostenfrei |3 Volltext |
| 856 | 4 | |u https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120516-1095880-1-6 |x Resolving-System | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025398954&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 912 | |a ebook | ||
| 999 | |a oai:aleph.bib-bvb.de:BVB01-025398954 | ||
Record in the Search Index
| _version_ | 1804149647584788480 |
|---|---|
| adam_text | IMAGE 1
TABLE OF CONTENTS
1 INTRODUCTION 1
2 THEORETICAL BACKGROUND 7
2.1 SUPRAMOLECULAR CHEMISTRY AND SELF-ASSEMBLY PHENOMENA 7
2.1.1 DIFFERENT FORMS O F SINGLE MOLECULE SELF-ASSEMBLY 11
2.2 SILICON CONTAINING OLIGOMERS AND POLYMERS 15
2.2.1 BASIC MATERIALS 15
2.2.2 POLYSILOXANES 17
2.2.3 THREE DIMENSIONAL SILOXANE STRUCTURES 21
2.2.4 POLYSILANES 25
2.2.5 POLYSILANE NETWORKS 31
2.2.6 DEFINED SI-BASED POLYHEDRA 33
3 OBJECTIVES 37
4 MESOGEN LIBRARY 4 3
4.1 INTRODUCTION 43
4.2 SYNTHESIS STRATEGY 45
4.2.1 METALATED MESOGENS FOR THE NUCLEOPHILIC SUBSTITUTION ON
CHLOROSILANES.. 46
4.2.2 MESOGENS WITH UNSATURATED FUNCTIONAL GROUPS 48
4.3 SUMMARY 54
HTTP://D-NB.INFO/1034264257
IMAGE 2
5 BI AND TETRAMESOGENS WITH SILICON CONTAINING LINKERS 57
5.1 INTRODUCTION 57
5.2 SYNTHESIS 59
5.2.1 BIMESOGENS 59
5.2.2 TETRAMESOGENS 62
5.3 PROPERTIES O F BULK MATERIALS 64
5.3.1 THERMAL PROPERTIES AND FORMATION O F MESOPHASES 64
5.3.2 STRUCTURES O F BULK MATERIALS 75
5.4 MORPHOLOGIES AND STRUCTURES O F THIN FILMS 80
5.4.1 SURFACE STRUCTURES VISUALIZED BY AFM 80
5.4.2 DETERMINATION O F THIN FILM CHARACTERISTICS 83
5.5 SUMMARY 87
6 SILICON BASED POLYMERS 91
6.1 INTRODUCTION 91
6.2 SYNTHESIS O F MONOMERS 9 3
6.2.2 STYRENE-BASED MONOMERS 9 5
6.3 TVURTZ-TYPE REDUCTIVE POLYMERIZATIONS 104
6.4 DETERMINATION O F POLYMER CHARACTERISTICS 110
6.4.1 POLYMERS FROM SATURATED MONOMERS 110
6.4.2 POLYMERS FROM UNSATURATED MONOMERS 114
6.5 SELF-ASSEMBLY ON SURFACES 126
6.6 EFFECT O F PYROLYSIS ON NANOSTRUCTURES 135
6.7 HOMOGENEOUSLY NANOSTRUCTURED FILMS BY PLASMA TREATMENT 140
6.8 SUMMARY 147
7 SUMMARY 151
8 ZUSAMMENFASSUNG 1SS
IMAGE 3
TABLE O F CONTENTS III
9 EXPERIMENTAL PART 161
9.1 METHODS 161
9.1.1 THIN FILM PREPARATION 161
9.1.2 PLASMA TREATMENT O F POLYMER THIN FILMS 161
9.1.3 POLYMER ANALYSIS 163
9.1.4 IMAGING TECHNIQUES 164
9.1.5 STRUCTURE ANALYSIS 165
9.2 SYNTHESES 170
9.2.1 REAGENTS AND METHODS 170
9.2.2 COMPOUNDS FOR THE MESOGEN LIBRARY 171
9.2.3 BI AND TETRAMESOGENS WITH SILICON CONTAINING LINKERS 185
9.2.4 CHLOROSILANE-BASED MONOMERS 196
9.2.5 SILICON BASED POLYMERS 204
10 APPENDIX 207
10.1 LIST O F PUBLICATIONS 207
11 REFERENCES 209
|
| any_adam_object | 1 |
| author | Heinz, Paul |
| author_GND | (DE-588)1034264222 |
| author_facet | Heinz, Paul |
| author_role | aut |
| author_sort | Heinz, Paul |
| author_variant | p h ph |
| building | Verbundindex |
| bvnumber | BV040553209 |
| classification_tum | CHE 365d CHE 617d |
| collection | ebook |
| ctrlnum | (OCoLC)820417783 (DE-599)BVBBV040553209 |
| dewey-full | 546.6832 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546.6832 |
| dewey-search | 546.6832 |
| dewey-sort | 3546.6832 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| format | Thesis Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01974nam a2200445 c 4500</leader><controlfield tag="001">BV040553209</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20140724 </controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">121120s2012 ad|| m||| 00||| eng d</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)820417783</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)BVBBV040553209</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-384</subfield><subfield code="a">DE-473</subfield><subfield code="a">DE-703</subfield><subfield code="a">DE-1051</subfield><subfield code="a">DE-824</subfield><subfield code="a">DE-29</subfield><subfield code="a">DE-12</subfield><subfield code="a">DE-91</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-1049</subfield><subfield code="a">DE-92</subfield><subfield code="a">DE-739</subfield><subfield code="a">DE-898</subfield><subfield code="a">DE-355</subfield><subfield code="a">DE-706</subfield><subfield code="a">DE-20</subfield><subfield code="a">DE-1102</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">546.6832</subfield><subfield code="2">22//ger</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 365d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 617d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Heinz, Paul</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)1034264222</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Silicon containing mesogen building blocks</subfield><subfield code="b">synthesis, characterization and application in silane and siloxane self-assembly</subfield><subfield code="c">Paul Heinz</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2012</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">III, 217 S.</subfield><subfield code="b">Ill., graph. Darst.</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="502" ind1=" " ind2=" "><subfield code="a">München, Techn. Univ., Diss., 2012</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Mesogen</subfield><subfield code="0">(DE-588)4336645-4</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Silane</subfield><subfield code="0">(DE-588)4181296-7</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Siloxane</subfield><subfield code="0">(DE-588)4181431-9</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="0">(DE-588)4113937-9</subfield><subfield code="a">Hochschulschrift</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Silane</subfield><subfield code="0">(DE-588)4181296-7</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Siloxane</subfield><subfield code="0">(DE-588)4181431-9</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="2"><subfield code="a">Mesogen</subfield><subfield code="0">(DE-588)4336645-4</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="776" ind1="0" ind2="8"><subfield code="i">Erscheint auch als</subfield><subfield code="n">Online-Ausgabe</subfield><subfield code="o">urn:nbn:de:bvb:91-diss-20120516-1095880-1-6</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://mediatum.ub.tum.de/node?id=1095880</subfield><subfield code="x">Verlag</subfield><subfield code="z">kostenfrei</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2=" "><subfield code="u">https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120516-1095880-1-6</subfield><subfield code="x">Resolving-System</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">DNB Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025398954&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ebook</subfield></datafield><datafield tag="999" ind1=" " ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-025398954</subfield></datafield></record></collection> |
| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV040553209 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:26:21Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025398954 |
| oclc_num | 820417783 |
| open_access_boolean | 1 |
| owner | DE-384 DE-473 DE-BY-UBG DE-703 DE-1051 DE-824 DE-29 DE-12 DE-91 DE-BY-TUM DE-19 DE-BY-UBM DE-1049 DE-92 DE-739 DE-898 DE-BY-UBR DE-355 DE-BY-UBR DE-706 DE-20 DE-1102 |
| owner_facet | DE-384 DE-473 DE-BY-UBG DE-703 DE-1051 DE-824 DE-29 DE-12 DE-91 DE-BY-TUM DE-19 DE-BY-UBM DE-1049 DE-92 DE-739 DE-898 DE-BY-UBR DE-355 DE-BY-UBR DE-706 DE-20 DE-1102 |
| physical | III, 217 S. Ill., graph. Darst. |
| psigel | ebook |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| record_format | marc |
| spelling | Heinz, Paul Verfasser (DE-588)1034264222 aut Silicon containing mesogen building blocks synthesis, characterization and application in silane and siloxane self-assembly Paul Heinz 2012 III, 217 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier München, Techn. Univ., Diss., 2012 Mesogen (DE-588)4336645-4 gnd rswk-swf Silane (DE-588)4181296-7 gnd rswk-swf Siloxane (DE-588)4181431-9 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Silane (DE-588)4181296-7 s Siloxane (DE-588)4181431-9 s Mesogen (DE-588)4336645-4 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:91-diss-20120516-1095880-1-6 http://mediatum.ub.tum.de/node?id=1095880 Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120516-1095880-1-6 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025398954&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Heinz, Paul Silicon containing mesogen building blocks synthesis, characterization and application in silane and siloxane self-assembly Mesogen (DE-588)4336645-4 gnd Silane (DE-588)4181296-7 gnd Siloxane (DE-588)4181431-9 gnd |
| subject_GND | (DE-588)4336645-4 (DE-588)4181296-7 (DE-588)4181431-9 (DE-588)4113937-9 |
| title | Silicon containing mesogen building blocks synthesis, characterization and application in silane and siloxane self-assembly |
| title_auth | Silicon containing mesogen building blocks synthesis, characterization and application in silane and siloxane self-assembly |
| title_exact_search | Silicon containing mesogen building blocks synthesis, characterization and application in silane and siloxane self-assembly |
| title_full | Silicon containing mesogen building blocks synthesis, characterization and application in silane and siloxane self-assembly Paul Heinz |
| title_fullStr | Silicon containing mesogen building blocks synthesis, characterization and application in silane and siloxane self-assembly Paul Heinz |
| title_full_unstemmed | Silicon containing mesogen building blocks synthesis, characterization and application in silane and siloxane self-assembly Paul Heinz |
| title_short | Silicon containing mesogen building blocks |
| title_sort | silicon containing mesogen building blocks synthesis characterization and application in silane and siloxane self assembly |
| title_sub | synthesis, characterization and application in silane and siloxane self-assembly |
| topic | Mesogen (DE-588)4336645-4 gnd Silane (DE-588)4181296-7 gnd Siloxane (DE-588)4181431-9 gnd |
| topic_facet | Mesogen Silane Siloxane Hochschulschrift |
| url | http://mediatum.ub.tum.de/node?id=1095880 https://nbn-resolving.org/urn:nbn:de:bvb:91-diss-20120516-1095880-1-6 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025398954&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT heinzpaul siliconcontainingmesogenbuildingblockssynthesischaracterizationandapplicationinsilaneandsiloxaneselfassembly |