Type selective functionalization of single-walled carbon nanotubes:
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| Main Author: | |
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| Format: | Thesis Book |
| Language: | English |
| Published: |
2012
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| Subjects: | |
| Online Access: | Volltext https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-33213 http://d-nb.info/1025182677/34 Inhaltsverzeichnis |
| Physical Description: | VIII, 241 S. Ill., zahlr. graph. Darst. |
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Record in the Search Index
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| adam_text | IMAGE 1
TABLE OF CONTENTS
1. INTRODUCTION
1.1. STRUCTURE, PROPERTIES AND PRODUCTION OF CARBON NANOTUBES 1
1.1.1. ELECTRONIC PROPERTIES 4
1.1.2. MECHANICAL PROPERTIES 10
1.1.3. PRODUCTION OF CARBON NANOTUBES 11
1.2. REACTIVITY OF CARBON NANOTUBES 12
1.3. FUNCTIONALIZATION OF CARBON NANOTUBES 15
1.3.1. ENDOHEDRAL FUNCTIONALIZATION 17
1.3.2. NON-COVATENT FUNCTIONALIZATION . 17
1.3.3. DEFECT FUNCTIONALIZATION 18
1.3.4. COVAIENT SIDEWALL FUNCTIONALIZATION 20
1.4. CHARACTERIZATION OF FUNCTIONALIZED CARBON NANOTUBES 24
1.4.1. TRANSMISSION ELECTRON MICROSCOPY 24
1.4.2. ATOMIC FORCE MICROSCOPY 26
1.4.3. EMISSION SPECTROSCOPY 27
1.4.4. ABSORPTION SPECTROSCOPY 28
1.4.5. X-RAY PHOTOELECTRON SPECTROSCOPY 30
1.4.6. THERMOGRAVIMETRIC ANALYSIS COUPLED WITH MASS SPECTROMETRY 31
1.4.7. RAMAN SPECTROSCOPY 33
1.5. APPLICATIONS OF FUNCTIONALIZED CARBON NANOTUBES 39
2. PROPOSAL
3. RESULTS AND DISCUSSION
3.1. PURIFICATION OF SINGLE-WALLED CARBON NANOTUBES 43
3.2. NUCLEOPHILIC ADDITION OF ORGANOMETALLIC COMPOUNDS 46
3.2.1. STRUCTURE DEPENDENT REACTIVITY OF THE NUCLEOPHILIC ADDITION 46
3.2.2. NUCLEOPHILIC ADDITION OF LITHIUM ALKYNES 62
3.2.3. NUCLEOPHILIC ADDITION OF LITHIUM DIALKYNES 77
3.3. FLEFRO-FUNCTIONALIZATION OF SINGLE-WALLED CARBON NANOTUBES 83
3.4. DOUBLE FUNCTIONALIZATION OF SINGLE-WALLED CARBON NANOTUBES 88
3.5. DOUBLE FUNCTIONALIZATION SEQUENCE BASED ON THE
FLEFRO-FUNCTIONALIZATION APPROACH INCLUDING A TUNABLE DEGREE OF
SELECTIVITY 96
3.6. REDUCTIVE FUNCTIONALIZATION OF CARBON NANOTUBES 114
3.6.1. REDUCTIVE FUNCTIONALIZATION WITH CARBONYL COMPOUNDS 115
3.6.2. TYPE SELECTIVE CARBOXYLATION OF CARBON NANOTUBES 125
3.6.3. POSTFUNCTIONALIZATION OF POIYCARBOXYTATED SWCNTS. 148
V I I
HTTP://D-NB.INFO/1026544912
IMAGE 2
3.6.4. FUNCTIONAL GROUP CONVERSION 152
3.6.5. SELECTIVITY EVALUATION IN DEPENDENCY OF THE REDOX POTENTIAL 157
3.6.6. CONCENTRATION DEPENDENT SELECTIVITY OF THE REDUCTIVE
FUNCTIONAIIZATION 162
3.7. REDUCTIVE HYDROGENATION OF SWCNTS 171
3.8. REOXIDATION OF CHARGED SWCNT INTERMEDIATES 176
3.8.1. REDUCTIVE OXIDATION OF SWCNT INTERMEDIATES 176
3.8.2. REOXIDATION OF BUN-SWCNV INTERMEDIATES 182
4. SUMMARY
4. ZUSAMMENFASSUNG
5. EXPERIMENTAL SECTION
5.1. INSTRUMENTS AND METHODS 196
5.2. CHEMICALS 198
5.3. EXPERIMENTAL DETAILS 198
6. REFERENCES
7. APPENDIX
7.1. ADDITIONAL SPECTRA 233
7.2. COMPOUNDS 238
7.3. INDEX OF PUBLICATIONS 241
V I I I
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| discipline | Chemie / Pharmazie |
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| spelling | Gebhardt, Benjamin Verfasser aut Type selective functionalization of single-walled carbon nanotubes von Benjamin Gebhardt 2012 VIII, 241 S. Ill., zahlr. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Erlangen-Nürnberg, Univ., Diss., 2012 Funktionalisierung Chemie (DE-588)4279323-3 gnd rswk-swf Nanoröhre (DE-588)4844582-4 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Nanoröhre (DE-588)4844582-4 s Funktionalisierung Chemie (DE-588)4279323-3 s DE-604 Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:29-opus-33213 https://open.fau.de/handle/openfau/2321 Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-33213 Resolving-System http://d-nb.info/1025182677/34 Langzeitarchivierung Nationalbibliothek DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025302980&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gebhardt, Benjamin Type selective functionalization of single-walled carbon nanotubes Funktionalisierung Chemie (DE-588)4279323-3 gnd Nanoröhre (DE-588)4844582-4 gnd |
| subject_GND | (DE-588)4279323-3 (DE-588)4844582-4 (DE-588)4113937-9 |
| title | Type selective functionalization of single-walled carbon nanotubes |
| title_auth | Type selective functionalization of single-walled carbon nanotubes |
| title_exact_search | Type selective functionalization of single-walled carbon nanotubes |
| title_full | Type selective functionalization of single-walled carbon nanotubes von Benjamin Gebhardt |
| title_fullStr | Type selective functionalization of single-walled carbon nanotubes von Benjamin Gebhardt |
| title_full_unstemmed | Type selective functionalization of single-walled carbon nanotubes von Benjamin Gebhardt |
| title_short | Type selective functionalization of single-walled carbon nanotubes |
| title_sort | type selective functionalization of single walled carbon nanotubes |
| topic | Funktionalisierung Chemie (DE-588)4279323-3 gnd Nanoröhre (DE-588)4844582-4 gnd |
| topic_facet | Funktionalisierung Chemie Nanoröhre Hochschulschrift |
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