Chalcogenides: metastability and phase change phenomena
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Berlin [u.a.]
Springer
2012
|
| Series: | Springer series in materials science
164 |
| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | XVI, 284 S. Ill., graph. Darst. 235 mm x 155 mm |
| ISBN: | 3642287042 9783642287046 |
Staff View
MARC
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Record in the Search Index
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IMAGE 1
CONTENTS
PART I AMORPHOUS SEMICONDUCTORS
1 FUNDAMENTALS OF AMORPHOUS SEMICONDUCTORS 3
1.1 DEFINITIONS 3
1.2 GLASS TRANSITION 4
1.2.1 PHENOMENOLOGY OF GLASS TRANSITION 4
1.2.2 GLASS-FORMATION CRITERIA 5
1.2.3 REVERSIBLE AMORPHOUS-TO-CRYSTAL TRANSITION 7
1.3 ATOMIC STRUCTURE 11
1.3.1 LONG-RANGE ORDER 11
1.3.2 SHORT-RANGE ORDER 12
1.3.3 MEDIUM-RANGE ORDER 14
1.3.4 MELTING OF SEMICONDUCTORS 14
1.4 STRUCTURE OF PROTOTYPICAL CHALCOGENIDES 15
1.4.1 ELEMENTAL CHALCOGENS 15
1.4.2 CHALCOGENIDE GLASSES 17
1.4.3 PHASE-CHANGE MATERIALS 18
1.5 DEFECTS 19
1.5.1 IDEAL GLASS AND THE "8-N" RULE 19
1.5.2 TOPOLOGICAL DEFECTS 20
1.5.3 SOFT CONFIGURATIONS 23
1.6 ELECTRONIC STRUCTURE 24
1.6.1 ORIGIN OF THE BANDGAP 24
1.6.2 ANDERSON LOCALISATION 25
1.6.3 PERCOLATION 27
1.7 FABRICATION OF AMORPHOUS SEMICONDUCTORS 27
1.7.1 MELT QUENCHING 27
1.7.2 VAPOUR DEPOSITION 28
1.7.3 SPIN COATING 31
1.7.4 ION IMPLANTATION 32
REFERENCES 32
XI
HTTP://D-NB.INFO/1019655348
IMAGE 2
XII CONTENTS
2 PROPERTIES OF AMORPHOUS CHALCOGENIDES 35
2.1 ELECTRICAL PROPERTIES 35
2.1.1 PINNING OF THE FERMI LEVEL 35
2.1.2 P-TYPE CONDUCTIVITY 35
2.1.3 HALL EFFECT ANOMALY 36
2.1.4 PHASE-CHANGE MATERIALS 36
2.1.5 CHALCOGENIDES" AS TOPOLOGICAL INSULATORS 38
2.1.6 LIQUID CHALCOGENIDES 39
2.2 OPTICAL ABSORPTION 40
2.2.1 INTERBAND ABSORPTION 40
2.2.2 ABSORPTION EDGE (THE URBACH RULE) 41
2.2.3 PHASE-CHANGE MATERIALS 42
2.3 PHOTOEXCITATION AND RECOMBINATION 43
2.3.1 PHOTOLUMINESCENCE 43
2.3.2 PHOTO-INDUCED METASTABILITY 45
REFERENCES 46
3 METHODS OF STRUCTURE ANALYSIS 49
3.1 EXPERIMENTAL METHODS FOR INVESTIGATING ATOMIC STRUCTURE. . . . 49
3.1.1 BRAGG DIFFRACTION AND ITS LIMITATIONS 49
3.1.2 PAIR-DISTRIBUTION-FUNCTION ANALYSIS 51
3.1.3 X-RAY ABSORPTION FINE STRUCTURE SPECTROSCOPY 52
3.1.4 NANOBEAM ELECTRON DIFFRACTION 55
3.2 ELECTRONIC STRUCTURE 56
3.2.1 BAND STRUCTURE 56
3.2.2 DEFECT SPECTROSCOPY 58
3.3 STRUCTURAL MODELLING 60
3.3.1 REVERSE MONTE CARLO MODELLING 60
3.3.2 RING STATISTICS 61
3.3.3 AB-INITIO DENSITY-FUNCTIONAL THEORY SIMULATIONS. . . . 61
REFERENCES 62
PART II CHALCOGENIDE GLASSES
4 REVERSIBLE PHOTOSTRUCTURAL CHANGES 67
4.1 PHOTODARKENING 67
4.1.1 REVERSIBLE AND IRREVERSIBLE PHOTODARKENING 67
4.1.2 RECOVERY OF INITIAL PARAMETERS 71
4.2 REVERSIBLE STRUCTURAL CHANGES 72
4.2.1 MANIFESTATIONS OF STRUCTURAL CHANGES 72
4.2.2 PHENOMENOLOGICAL DESCRIPTION: CONFIGURATION-COORDINATE MODEL 74
IMAGE 3
CONTENTS XIII
4.2.3 MICROSCOPIC NATURE OF PHOTOSTRUCTURAL CHANGES 78
4.2.4 IN SITU STUDIES OF REVERSIBLE PHOTOSTRUCTURAL CHANGES 81
4.2.5 WHY PHOTOSTRUCTURAL CHANGES ARE RESTRICTED TO VITREOUS
CHALCOGENIDE SEMICONDUCTORS 84
4.3 PHOTO-INDUCED DEFECT CREATION AND MODIFICATION 86
4.3.1 PHOTO-INDUCED ELECTRON SPIN RESONANCE 86
4.3.2 PHOTO-INDUCED MIDGAP ABSORPTION 91
4.3.3 PHOTOLUMINESCENCE FATIGUE 91
4.3.4 PHOTO-INDUCED CHANGE IN AC-CONDUCTIVITY 91
4.4 RELATIONSHIP BETWEEN PHOTO-INDUCED ESR AND REVERSIBLE
PHOTOSTRUCTURAL CHANGE (PHOTODARKENING) . . . . 92 4.5 PHOTO-INDUCED
PHENOMENA IN LIQUID CHALCOGENS 95
4.5.1 LIQUID SULPHUR 95
4.5.2 LIQUID SELENIUM 98
4.6 PHOTO-INDUCED SITE-SELECTIVE OXIDATION 99
REFERENCES 99
5 PHOTO-INDUCED ANISOTROPY 103
5.1 OPTICAL LINEAR DICHROISM AND BIREFRINGENCE 103
5.1.1 PHOTO-INDUCED OPTICAL ANISOTROPY 103
5.1.2 OPTICAL REVERSIBILITY OF INDUCED ANISOTROPY 103
5.1.3 DEPENDENCE OF PHOTO-INDUCED ANISOTROPY ON EXPOSURE PARAMETERS 104
5.1.4 ANISOTROPY VERSUS PHOTODARKENING 107
5.1.5 ANISOTROPY INDUCED BY NON-POLARISED AND CIRCULARLY POLARISED LIGHT
108
5.2 PHOTO-INDUCED ANISOTROPY OF OTHER PROPERTIES I L L
5.2.1 ANISOTROPIC PHOTOLUMINESCENCE I L L
5.2.2 ANISOTROPY OF PHOTOCONDUCTIVITY I L L
5.2.3 POLARISED PHOTODOPING I L L
5.2.4 ANISOTROPIC OPTOMECHANICAL EFFECT I L L
5.2.5 ANISOTROPIC MASS FLOW 112
5.2.6 MACROSCOPIC ANISOTROPIC DEFORMATIONS 112
5.2.7 ANISOTROPIC PHOTOCRYSTALLISATION 112
5.3 STRUCTURAL STUDIES 114
5.4 MODELS OF PHOTOANISOTROPY 116
REFERENCES 120
6 PHOTO-INDUCED CHANGE OF THE PHASE STATE 123
6.1 PHOTOCRYSTALLISATION 123
6.1.1 PHOTOCRYSTALLISATION OF SELENIUM 123
6.1.2 CRYSTALLISATION OF PHASE-CHANGE MATERIALS THROUGH THE USE OF
COHERENT PHONONS 124
IMAGE 4
XIV CONTENTS
6.2 PHOTO-INDUCED LOSS OF LONG-RANGE ORDER 126
6.2.1 ATHERMAL PHOTOAMORPHISATION 126
6.2.2 PHOTO-INDUCED VISCOSITY/FLUIDITY 128
6.2.3 PHOTOMELTING OF SELENIUM 129
REFERENCES 130
7 PHOTO-INDUCED PHENOMENA IN CHALCOGENIDE-METAL STRUCTURES . . . 133 7.1
PHOTODOPING 133
7.1.1 PHOTODISSOLUTION 133
7.1.2 LATERAL DIFFUSION 134
7.1.3 DIFFUSION MECHANISM 136
7.1.4 REACTION PRODUCTS AND THEIR PROPERTIES 138
7.2 PHOTODEPOSITION OF SILVER 139
7.2.1 LIGHT INTENSITY, PHOTON ENERGY AND TEMPERATURE DEPENDENCIES 140
7.2.2 REVERSIBILITY 141
7.2.3 MECHANISM OF PHOTOSURFACE DEPOSITION 141
7.2.4 PROGRAMMABLE METALLISATION CELL 143
REFERENCES 144
PART III PHASE-CHANGE MATERIALS
8 STRUCTURE OF THE CRYSTALLINE PHASE 149
8.1 STRUCTURE OF THE STABLE PHASE 149
8.1.1 BINARY GETE 149
8.1.2 GE 2 SB 2 TE 5 AND RELATED MATERIALS 152
8.2 STRUCTURE OF THE METASTABLE PHASE 155
8.2.1 LONG-RANGE ORDER (GLOBAL STRUCTURE) 155
8.2.2 SHORT-RANGE ORDER (LOCAL STRUCTURE) 162
8.2.3 RESONANCE BONDING 164
8.2.4 POINT DEFECTS, VACANCIES AND DISTORTIONS 168
8.3 ENGINEERED STRUCTURES 172
8.3.1 GETE-SB2TE3 LAYERED STRUCTURES 172
8.3.2 EPITAXIAL GROWTH OF PHASE-CHANGE MATERIALS 173
REFERENCES 177
9 STRUCTURE OF THE AMORPHOUS PHASE 181
9.1 EXPERIMENTAL STUDIES 182
9.1.1 BINARY GETE 182
9.1.2 QUASIBINARY GETE-SB2TE3 ALLOYS 183
9.1.3 DIFFERENTLY PREPARED AMORPHOUS PHASES: POLYMORPHISM 189
IMAGE 5
CONTENTS X V
9.2 COMPUTER SIMULATIONS 192
9.2.1 AROUND THE UMBRELLA-FLIP MODEL 192
9.2.2 MELT-QUENCHED AMORPHOUS PHASE 195
9.2.3 AB INITIO XANES STUDIES 203
9.2.4 AG-IN-SB-TE ALLOYS 208
9.3 LIQUID PHASE 209
9-.3.1 EXPERIMENTAL STUDIES 209
9.3.2 COMPUTER SIMULATIONS 211
REFERENCES 213
10 PRESSURE-INDUCED TRANSFORMATIONS 217
10.1 GE-SB-TE ALLOYS 217
10.1.1 PRESSURE-INDUCED AMORPHISATION 217
10.1.2 HIGH-PRESSURE BCC PHASE AND INITIAL STRUCTURE MEMORY 221
10.2 PRESSURE-INDUCED CHANGES IN GE-FREE PHASE-CHANGE ALLOYS. . . 225
10.2.1 BINARY SB 2 TE 225
10.2.2 AG-IN-SB-TE ALLOY 225
10.3 AB INITIO STUDIES OF PRESSURE-INDUCED CHANGES 226
10.3.1 PRESSURE-INDUCED AMORPHISATION 226
10.3.2 HIGH-PRESSURE BCC PHASE 229
10.3.3 AMORPHISATION UPON DECOMPRESSION 229
REFERENCES 230
11 MECHANISM OF THE PHASE-CHANGE PROCESS 231
11.1 MICROSCOPIC MODELS OF PHASE CHANGE 231
11.1.1 UMBRELLA-FLIP OF GE ATOMS 231
11.1.2 FOUR-MEMBERED RINGS REARRANGEMENT 232
11.1.3 RESONANCE BONDING 232
11.1.4 PHOTO-ASSISTED AMORPHISATION OF GE2SB2TE5 236 11.2
PRESSURE-INDUCED AMORPHISATION 239
11.2.1 AMORPHISATION UPON COMPRESSION 239
11.2.2 AMORPHISATION UPON DECOMPRESSION 241
11.3 AMORPHISATION OF AG-IN-SB-TE: BOND-INTERCHANGE MODEL . . . . 241
11.4 ORIGIN OF OPTICAL AND ELECTRICAL CONTRAST 242
11.4.1 COORDINATION CHANGE 242
11.4.2 RESONANT BONDING 243
REFERENCES 246
IMAGE 6
XVI CONTENTS
PART IV APPLICATIONS
12 MEMORY DEVICES 251
12.1 OPTICAL MEMORIES 251
12.1.1 COMPACT DISC AND DIGITAL VERSATILE DISC FAMILIES . . . 252 12.1.2
RECORDABLE DISCS (CD-R AND DVD-R) 256
12.1.3 ERASABLE DISCS (CD-RW, DVD-RW AND DVD-RAM) 257
12.1.4 SUPER-RENS DISCS 259
12.2 NON-VOLATILE ELECTRONIC MEMORIES 265
12.2.1 PHASE-CHANGE RANDOM ACCESS MEMORY 265
12.2.2 PHASE-CHANGE MEMORY FOR THE FUTURE 268
REFERENCES 274
INDEX 277 |
| any_adam_object | 1 |
| author | Kolobov, Alexander V. Tominaga, Junji 1959- |
| author_GND | (DE-588)124809421 |
| author_facet | Kolobov, Alexander V. Tominaga, Junji 1959- |
| author_role | aut aut |
| author_sort | Kolobov, Alexander V. |
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| building | Verbundindex |
| bvnumber | BV040439684 |
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| ctrlnum | (OCoLC)835273469 (DE-599)DNB1019655348 |
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| dewey-ones | 530 - Physics |
| dewey-raw | 530.414 |
| dewey-search | 530.414 |
| dewey-sort | 3530.414 |
| dewey-tens | 530 - Physics |
| discipline | Maschinenbau / Maschinenwesen Physik |
| format | Book |
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| id | DE-604.BV040439684 |
| illustrated | Illustrated |
| indexdate | 2024-08-21T00:11:56Z |
| institution | BVB |
| isbn | 3642287042 9783642287046 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025287541 |
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| owner_facet | DE-11 DE-703 |
| physical | XVI, 284 S. Ill., graph. Darst. 235 mm x 155 mm |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | Springer |
| record_format | marc |
| series | Springer series in materials science |
| series2 | Springer series in materials science |
| spelling | Kolobov, Alexander V. Verfasser aut Chalcogenides metastability and phase change phenomena Alexander Kolobov ; Junji Tominaga Berlin [u.a.] Springer 2012 XVI, 284 S. Ill., graph. Darst. 235 mm x 155 mm txt rdacontent n rdamedia nc rdacarrier Springer series in materials science 164 Phasenwechselspeicher (DE-588)7627893-1 gnd rswk-swf Amorpher Halbleiter (DE-588)4001756-4 gnd rswk-swf Chalkogenide (DE-588)4147541-0 gnd rswk-swf Chalkogenide (DE-588)4147541-0 s Amorpher Halbleiter (DE-588)4001756-4 s Phasenwechselspeicher (DE-588)7627893-1 s DE-604 Tominaga, Junji 1959- Verfasser (DE-588)124809421 aut Erscheint auch als Online-Ausgabe 978-3-642-28705-3 Springer series in materials science 164 (DE-604)BV000683335 164 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3976368&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025287541&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kolobov, Alexander V. Tominaga, Junji 1959- Chalcogenides metastability and phase change phenomena Springer series in materials science Phasenwechselspeicher (DE-588)7627893-1 gnd Amorpher Halbleiter (DE-588)4001756-4 gnd Chalkogenide (DE-588)4147541-0 gnd |
| subject_GND | (DE-588)7627893-1 (DE-588)4001756-4 (DE-588)4147541-0 |
| title | Chalcogenides metastability and phase change phenomena |
| title_auth | Chalcogenides metastability and phase change phenomena |
| title_exact_search | Chalcogenides metastability and phase change phenomena |
| title_full | Chalcogenides metastability and phase change phenomena Alexander Kolobov ; Junji Tominaga |
| title_fullStr | Chalcogenides metastability and phase change phenomena Alexander Kolobov ; Junji Tominaga |
| title_full_unstemmed | Chalcogenides metastability and phase change phenomena Alexander Kolobov ; Junji Tominaga |
| title_short | Chalcogenides |
| title_sort | chalcogenides metastability and phase change phenomena |
| title_sub | metastability and phase change phenomena |
| topic | Phasenwechselspeicher (DE-588)7627893-1 gnd Amorpher Halbleiter (DE-588)4001756-4 gnd Chalkogenide (DE-588)4147541-0 gnd |
| topic_facet | Phasenwechselspeicher Amorpher Halbleiter Chalkogenide |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3976368&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025287541&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV000683335 |
| work_keys_str_mv | AT kolobovalexanderv chalcogenidesmetastabilityandphasechangephenomena AT tominagajunji chalcogenidesmetastabilityandphasechangephenomena |