Synthetic polymer-polymer composites:
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| Format: | Book |
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| Language: | English |
| Published: |
Cincinnati, Ohio ; München
Hanser
2012
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturangaben |
| Physical Description: | XXIX, 797 S. Ill., graph. Darst. 25 cm |
| ISBN: | 9781569905104 156990510X 9781569905258 |
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| 245 | 1 | 0 | |a Synthetic polymer-polymer composites |c Debes Bhattacharyya ; Stoyko Fakirov |
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| adam_text | IMAGE 1
CONTENTS
PART I INTRODUCTION CHAPTER 1 MANUFACTURING AND PROCESSING OF POLYMER
COMPOSITES J. SCHUSTER, M. DUHOVIC, D. BHATTACHARYYA
1.1. INTRODUCTION 3
1.2. AUTOCLAVE-PROCESSING 5
1.2.1. INTRODUCTION 5
1.2.2. EQUIPMENT 5
1.2.3. LAMINATE ASSEMBLY 5
1.2.4. PROCESS DESCRIPTION 6
1.2.5. FURTHER DEVELOPMENTS 7
1.3. PULTRUSION 7
1.3.1. INTRODUCTION 7
1.3.2. EQUIPMENT 7
1.3.3. PROCESS DESCRIPTION 8
1.4. FILAMENT WINDING A N D PLACEMENT TECHNIQUES 10
1.4.1. FILAMENT WINDING 10
1.4.2. TAPE-LAYING 15
1.5. LIQUID COMPOSITE MOLDING 18
1.5.1. INTRODUCTION 18
1.5.2. LCM PROCESSES WITH SINGLE SIDED TOOLS 19
1.5.3. DOUBLE SIDED TOOL LCM PROCESSES 23
1.6. THERMOFORMING OF SEMIFINISHED THERMOPLASTIC COMPOSITE SHEETS 26
1.6.1. DOUBLE BELT PRESS FORMING 26
1.6.2. CONTINUOUS COMPRESSION MOLDING 26
1.6.3. ROLL FORMING 27
1.7. COMBINED FORMING PROCESSES 29
1.7.1. THERMOFORMING A N D INJECTION/COMPRESSION MOLDING 29
1.7.2. PULTRUSION/IMPREGNATION A N D ROLL FORMING 29
1.8. POST PROCESSING OF COMPOSITES 30
1.8.1. WELDING OF THERMOPLASTICS 31
1.9. CONCLUSIONS A N D OUTLOOK 32
REFERENCES: 32
HTTP://D-NB.INFO/1024138348
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VIII
CONTENTS
CHAPTER 2 MELTING OF POLYMER-POLYMER COMPOSITES BY PARTICULATE HEATING
PROMOTERS AND ELECTROMAGNETIC RADIATION T. BAYERL, A. BENEDITO BORRAS,
J.-I. ANDRES GALLEGO,
B. GALINDO GALIANA, P. MITSCHANG
2.1. INTRODUCTION 39
2.2. STATE OF THE A R T 40
2.2.1. INDUCTION HEATING 41
2.2.2. MICROWAVE HEATING 43
2.3. SELECTIVE MELTING USING PARTICULATE FILLERS 48
2.3.1. SELECTIVE MELTING BY INDUCTION 49
2.4. SELECTIVE MELTING BY MICROWAVE RADIATION 57
2.4.1. EFFECT OF DIFFERENT SUSCEPTOR MATERIALS 57
2.4.2. INFLUENCE OF DISPERSION QUALITY 60
2.5. CONCEPTS FOR AN INDUSTRIAL APPLICATION 61
2.6. CONCLUSIONS A N D OUTLOOK 62
ACKNOWLEDGEMENTS 63
REFERENCES 63
FURTHER READING 64
CHAPTER 3 INTER-PARTICLE DISTANCE AND TOUGHENING MECHANISMS IN
PARTICULATE THERMOSETTING COMPOSITES H. S. KIM
3.1. INTRODUCTION 65
3.2. VARIOUS CONDITIONS FOR FRACTURE SURFACE MORPHOLOGY 66
3.3. INTER-PARTICLE/VOID DISTANCE A N D TOUGHENING MECHANISM 67
3.3.1. THEORETICAL INTER-PARTICLE DISTANCE 68
3.3.2. METHOD FOR INTER-PARTICLE DISTANCE MEASUREMENT 69
3.3.3. STATISTICAL PROPERTIES OF INTER-PARTICLE DISTANCE 74
3.3.4. EXPERIMENTAL INTER-VOID DISTANCE AND TOUGHNESS 81
3.4. TOUGHENING MECHANISMS IN T H E PRESENCE OF COMPRESSIVE STRESS
AROUND PARTICLES/VOIDS 89
3.4.1. NECESSARY CONDITIONS FOR CAVITATION 89
3.4.2. GRAPHICAL UNDERSTANDING OF COMPRESSIVE STRESS AROUND PARTICLES 90
3.4.3. CREATING COMPRESSIVE STRESS AROUND MODIFIER PARTICLES AS A
TOUGHENING METHOD 91
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CONTENTS
IX
3.4.4. PRODUCTION OF MECHANICAL TESTING SPECIMENS 92
3.4.5. MECHANICAL PROPERTIES OF TOUGHENED EPOXIES 93
3.4.6. FRACTURE SURFACE MORPHOLOGY EXAMINATION 93
3.4.7. STRESS INTENSITY FACTOR INFLUENCED BY COMPRESSIVE RESIDUAL STRESS
97
3.4.8. MOHR CIRCLE ANALYSIS FOR FRACTURE SURFACE MORPHOLOGY 100
3.4.9. INTERACTION OF TOUGHENING MECHANISMS 106
3.5. CONCLUSIONS I L L
REFERENCES 112
PART II POLYMER-POLYMER COMPOSITES WITH
PREMADE FIBROUS REINFORCEMENT
CHAPTER 4 FRACTURE BEHAVIOR OF SHORT CARBON FIBER REINFORCED POLYMER
COMPOSITES S. P. BAO, G. D. LIANG, S. C. TJONG
4.1. INTRODUCTION 119
4.2. DEFORMATION OF SCF-REINFORCED COMPOSITES 120
4.2.1. CARBON FIBER-POLYMER MATRIX INTERFACE 120
4.2.2. FIBER LENGTH 124
4.2.3. MATRIX MICROSTRUCTURE 126
4.2.4. FIBER ORIENTATION 128
4.3. FIBER HYBRIDIZATION 130
4.4. FRACTURE TOUGHNESS OF SCF-REINFORCED COMPOSITES 132
4.5. FATIGUE FAILURE * , 138
4.6. CONCLUSIONS AND OUTLOOK 141
REFERENCES 141
CHAPTER 5 POLYMER-CARBON NANOTUBE COMPOSITES: MELT PROCESSING,
PROPERTIES AND APPLICATIONS S. PEGEL, T. VILLMOW. G. KASALIWAL, P.
POTSCHKE
5.1. INTRODUCTION 145
5.2. MICROSCOPY BASED CHARACTERIZATION OF DISPERSION, DISTRIBUTION, AND
ALIGNMENT OF NANOTUBES IN POLYMER MATRICES 148
5.2.1. LIGHT MICROSCOPY 148
5.2.2. TRANSMISSION ELECTRON MICROSCOPY 149
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X CONTENTS
5.3. DISPERSION OF NANOTUBES BY MELT MIXING 150
5.3.1. THEORETICAL CONSIDERATIONS 150
5.3.2. SMALL-SCALE BATCH COMPOUNDING 153
5.3.3. TWIN-SCREW EXTFRUSION 162
5.4. MORPHOLOGY DEVELOPMENT DURING SHAPING 164
5.4.1. COMPRESSION MOLDING 165
5.4.2. INJECTION MOLDING 167
5.4.3. FIBER SPINNING 169
5.5. PROPERTIES AND APPLICATIONS 170
5.5.1. MECHANICAL REINFORCEMENT 170
5.5.2. ELECTRICAL CONDUCTIVITY 173
5.5.3. RESISTIVITY CHANGES DUE T O EXTERNAL STIMULI 179
5.5.4. FIRE RETARDANCY 181
5.6. CONCLUSIONS A N D OUTLOOK 182
ACKNOWLEDGMENTS 183
APPENDIX 183
REFERENCES 187
CHAPTER 6 MANUFACTURING AND ELECTRICAL PROPERTIES OF CARBON NANOTUBE
REINFORCED POLYMER COMPOSITES G. D. LIANG, S. C. TJONG
6.1. INTRODUCTION 193
6.2. FUNCTIONALIZATION OF CARBON NANOTUBES 194
6.3. MANUFACTURING CARBON NANOTUBE/POLYMER COMPOSITES 196
6.3.1. SOLUTION MIXING 196
6.3.2. I N SITU POLYMERIZATION 199
6.3.3. MELT MIXING 200
6.3.5. ALIGNED CARBON NANOTUBE/POLYMER COMPOSITES 202
6.4. ELECTRICAL PROPERTIES OF POLYMER/CNT COMPOSITES 204
6.4.1. PERCOLATION THRESHOLD 204
6.4.2. CNT/THERMOPLASTIC NANOCOMPOSITES 205
6.4.3. CNT/ELASTOMER NANOCOMPOSITES 215
6.4.4. ALIGNED CNT/POLYMER COMPOSITES 216
6.5. CONCLUSION A N D OUTLOOK 219
REFERENCES 219
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CONTENTS XI
CHAPTER 7 FABRICATION, MORPHOLOGIES AND MECHANICAL PROPERTIES OF CARBON
NANOTUBE BASED POLYMER NANOCOMPOSITES T. X. LIU, D. CHEN, W . W. TJIU
7.1. INTRODUCTION 225
7.2. CARBON NANOTUBES 226
7.2.1. W H A T IS CARBON NANOTUBE? 226
7.2.2. MECHANICAL PROPERTIES OF CARBON NANOTUBES 226
7.2.3. FUNCTIONALIZATION A N D ALIGNMENT OF CARBON NANOTUBES 227
7.3. FABRICATION OF POLYMER/CARBON NANOTUBE COMPOSITES 229
7.3.1. MELT COMPOUNDING 229
7.3.2. SOLUTION BLENDING 230
7.3.3. I N SITU POLYMERIZATION 230
7.3.4. OTHER FABRICATION METHODS 230
7.4. MECHANICAL PROPERTIES OF POLYMER/CARBON NANOTUBE COMPOSITES 231
7.4.1. SIMULATION RESULTS 231
7.4.2. EXPERIMENTAL RESULTS 231
7.5. CONCLUSIONS A N D OUTLOOK 241
ACKNOWLEDGEMENTS 243
REFERENCES 243
CHAPTER 8 MANUFACTURING AND PROPERTIES OF ARAMID REINFORCED COMPOSITES
Z. DENCHEV, N. DENCHEVA
8.1. INTRODUCTION 251
8.2. ARAMID TYPES A N D MANUFACTURERS 252
8.3. SYNTHESIS OF ARAMIDS 253
8.4. COMMERCIAL FORMS OF ARAMIDS AND THEIR PHYSICAL PROPERTIES 255
8.5. STRUCTURE A N D PROPERTIES OF P-ARAMID FIBERS 258
8.6. PROPERTIES OF P- ARAMID FIBER REINFORCED POLYMER COMPOSITES 263
8.6.1. P- ARAMID F R P S WITH THERMOSET MATRICES 263
8.6.2. P-ARAMID F R P S WITH THERMOPLASTIC MATRICES 271
8.7. CONCLUDING REMARKS 274
ACKNOWLEDGEMENTS 275
REFERENCES 275
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XII CONTENTS
CHAPTER 9 MOLECULAR LIQUID CRYSTALLINE POLYMERS REINFORCED POLYMER
COMPOSITES: THE CONCEPT OF HAIRY RODS C. FAKIROV
9.1. INTRODUCTION 281
9.1.1. RAPID PREPARATION TECHNOLOGIES TO EXCLUDE PHASE SEPARATION 282
9.1.2. ADVANCED SYNTHESIS TO OBTAIN A HOMOGENEOUS BLEND 283
9.1.3. HOMOGENEOUS MIXTURES BY INCREASED ENTHALPY: STRONG DIPOLE-DIPOLE
INTERACTION, HYDROGEN BONDING AND IONIC INTERACTIONS 284
9.1.4. ADVANCED MOLECULAR STRUCTURE, CONSISTING OF RIGID AND FLEXIBLE
SEGMENTS ... 284 9.1.5. ADVANCED MOLECULE STRUCTURE: RIGID STAR
MOLECULES OR MULTIPODES 286 9.2. MOLECULAR COMPOSITES FROM HAIRY-ROD
MOLECULES PREPARED VIA THE LANGMUIR-BLODGETT TECHNIQUE 286
9.2.1. SYNTHESIS OF HAIRY-ROD MOLECULES 287
9.2.2. PREPARATION OF CONSTRUCTS OF INTERNAL NANOSCALE ARCHITECTURE
USING THE LANGMUIR-BLODGETT TECHNIQUE 288
9.2.3. SOME PROPERTIES OF MULTILAYERS OF HAIRY-ROD MACROMOLECULES 290
9.2.4. CONSTRUCTION OF NANOSCALED DEVICES AND FUNCTIONAL MATERIALS 292
9.3. CONCLUSIONS AND OUTLOOK 294
REFERENCES 294
CHAPTER 10 ELECTROSPUN COMPOSITE NANOFIBERS AND POLYMER COMPOSITES K.
MOLNAR, L. M. VAS
10.1. INTRODUCTION 301
10.2. ELECTROSPINNING OF NANOFIBERS 303
10.2.1. PRINCIPLES OF ELECTROSPINNING 305
10.2.2. PROCESS OPTIMIZATION FOR GAINING ULTRAFINE NANOFIBERS 311
10.3. INDUSTRIALIZATION A T T E M P T S FOR PRODUCING ELECTROSPUN
MATERIALS IN A HIGH VOLUME 312
10.3.1. MODIFIED SPINNERETS FOR HIGHER OUTPUTS 312
10.3.2. MODIFIED COLLECTOR SYSTEMS FOR PRODUCING SPECIAL ELECTROSPUN
STRUCTURES .... 316
10.4. COMPOSITE NANOFIBERS . 321
10.4.1. TESTING AND MODELING THE MECHANICAL BEHAVIOR OF NANOFIBERS FOR
COMPOSITE APPLICATIONS 321
10.4.2. COMPOSITE NANOFIBERS INCORPORATED WITH SMALLER NANOPARTICLES 324
10.4.3. CORE-SHELL NANOFIBERS PREPARED BY COAXIAL ELECTROSPINNING 327
10.5. SYNTHETIC POLYMER-POLYMER COMPOSITES CONTAINING OR BASED ON
ELECTROSPUN NANOFIBERS 330
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CONTENTS
XIII
10.5.1. NANOFIBERS AS INTERLAMINAR REINFORCEMENT OF COMPOSITES 330
10.5.2. ELECTROSPUN NANOFIBERS AND THEIR MODIFICATIONS AS POTENTIAL
REINFORCEMENT OF POLYMER-POLYMER COMPOSITES 334
10.6. CONCLUSIONS AND OUTLOOK 341
ACKNOWLEDGEMENTS 341
REFERENCES 342
PART III I N S I T U NANO- AND MICROFIBRILLAR
POLYMER-POLYMER COMPOSITES
CHAPTER 11 THE CONCEPT OF MICRO- OR NANOFIBRILS REINFORCED
POLYMER-POLYMER COMPOSITES S. FAKIROV
11.1. INTRODUCTION: A BRIEF HISTORICAL OVERVIEW 353
11.2. PREPARATION OF M F C 357
11.2.1. MISCIBILITY A N D COMPATIBILITY IN POLYMER BLENDS 357
11.3. MECHANISM OF MICROFIBRILS FORMATION IN POLYMER BLENDS A N D EFFECT
OF THE COMPATIBILIZERS ON THIS PROCESS 363
11.4. MICROFIBRILLAR COMPOSITES FROM BLENDS OF CONDENSATION POLYMERS 367
11.4.1. PECULIARITIES OF MFCS PREPARED FROM BLENDS OF CONDENSATION
POLYMERS 368 11.4.2. MECHANICAL PROPERTIES OF MFCS PREPARED FROM BLENDS
OF CONDENSATION POLYMERS 369
11.5. MICROFIBRILLAR COMPOSITES FROM BLENDS OF CONDENSATION POLYMERS
WITH POLYOLEFINS 371
11.6. NANOFIBRILS REINFORCED COMPOSITES FROM POLYMER BLENDS 376
11.6.1. PECULIARITIES OF POLYMER NANOCOMPOSITES 376
11.6.2. MANUFACTURING OF NANOFIBRILLAR POLYMER-POLYMER COMPOSITES 377
11.6.4. MECHANICAL PROPERTIES OF NFCS 379
11.7. EFFECT OF FIBRILS ORIENTATION ON T H E MECHANICAL PERFORMANCE OF
MFCS A N D N F C S 381
11.8. OPPORTUNITIES ARISING FROM THE MFC CONCEPT 387
11.8.1. COMMERCIAL POTENTIALS OF T H E M F C CONCEPT IN THE AUTOMOTIVE
INDUSTRY .... 388 11.8.2. COMMERCIAL POTENTIALS OF THE M F C CONCEPT FOR
COMMODITY PURPOSES 388 11.8.3. POTENTIAL OF THE M F C CONCEPT FOR
BIOMEDICAL APPLICATIONS 390
11.9. CONCLUSIONS AND OUTLOOK 393
ACKNOWLEDGMENTS 394
REFERENCES 394
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XIV CONTENTS
CHAPTER 12 MICROFIBRIL REINFORCED POLYMER-POLYMER COMPOSITES V I A HOT
STRETCHING: PREPARATION, STRUCTURE AND PROPERTIES Y. H. CHEN, G. J.
ZHONG, Z. M. LI
12.1. INTRODUCTION 401
12.2. FABRICATION OF MICROFIBRIL REINFORCED POLYMER-POLYMER COMPOSITES
402
12.2.1. RHEOLOGICAL FUNDAMENTAL FOR DEFORMATION OF DISPERSED PHASE 402
12.2.2. PREPARATION OF MICROFIBRIL REINFORCED POLYMER-POLYMER COMPOSITES
403
12.3. THREE PRIMARY FACTORS AFFECTING I N SITU FIBRILLATION 406
12.3.1. COMPOSITION 407
12.3.2. HOT STRETCH RATIO 409
12.3.3. VISCOSITY RATIO 410
12.4. MECHANICAL PROPERTIES OF MICROFIBRIL REINFORCED POLYMER-POLYMER
COMPOSITES 411
12.5. RHEOLOGICAL PROPERTIES OF MICROFIBRIL REINFORCED POLYMER-POLYMER
COMPOSITES 415
12.5.1. RHEOLOGY-COMPOSITION RELATIONSHIP OF MICROFIBRIL REINFORCED
POLYMER-POLYMER COMPOSITES 415
12.5.2. RHEOLOGY-MORPHOLOGY RELATIONSHIP OF MICROFIBRIL REINFORCED
POLYMER-POLYMER COMPOSITES .-. 418
12.6. CRYSTALLIZATION PROPERTY AND CRYSTAL STRUCTURE OF MICROFIBRIL
REINFORCED POLYMER-POLYMER COMPOSITES 419
12.6.1. CRYSTALLIZATION KINETICS OF MICROFIBRIL REINFORCED
POLYMER-POLYMER COMPOSITES 419
12.6.2. CRYSTAL STRUCTURES OF MICROFIBRIL REINFORCED POLYMER-POLYMER
COMPOSITES 421
12.6.3. CRYSTALLINE MORPHOLOGY A N D AGGREGATES OF MICROFIBRIL
REINFORCED POLYMER-POLYMER COMPOSITES 423
12.7. APPLICATION OF MICROFIBRIL REINFORCED POLYMER-POLYMER COMPOSITES
CONCEPT 426 12.7.1. RECYCLING OF THERMOPLASTIC BLENDS 426
12.7.2. SUPPRESSION OF SKIN-CORE STRUCTURE IN INJECTION MOLDED POLYMER
PARTS VIA I N SITU MICROFIBRILS 430
12.8. CONCLUSIONS 432
ACKNOWLEDGEMENTS 433
REFERENCES 433
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CONTENTS
X V
CHAPTER 13 MICROFIBRIL REINFORCED POLYMER-POLYMER COMPOSITE V I A HOT
STRETCHING: ELECTRICALLY CONDUCTIVE FUNCTIONALIZATION Y. C. ZHANG, Z. M.
LI
13.1. INTRODUCTION 437
13.2. ISOTROPICALLY CONDUCTIVE POLYMER COMPOSITE 438
13.2.1. ISOTROPIC I - C B / P E T / P E 438
13.2.2. ISOTROPIC O - C B / P E T / P E 447
13.3. ANISOTROPICALLY CONDUCTIVE POLYMER COMPOSITE 451
13.3.1. PREPARATION AND TYPICAL MORPHOLOGY 451
13.3.2. T H E PERCOLATION BEHAVIOR 452
13.3.3. T H E RESISTIVITY-TEMPERATURE BEHAVIOR 454
13.4. CONCLUSIONS 460
ACKNOWLEDGMENTS 460
REFERENCES 461
CHAPTER 14 PREPARATION, MECHANICAL PROPERTIES AND STRUCTURAL
CHARACTERIZATION OF MICROFIBRILLAR COMPOSITES BASED ON
POLYETHYLENE/POLYAMIDE BLENDS Z. DENCHEV, N. DENCHEVA
14.1. INTRODUCTION 465
14.2. PREPARATION AND MORPHOLOGY OF MICROFIBRILLAR COMPOSITES 468
14.3. MECHANICAL CHARACTERIZATION OF P E / P A MICROFIBRILLAR COMPOSITES
472
14.3.1. TENSILE TESTS WITH H D P E / P A 6 SYSTEMS 472
14.3.2. T H E FLEXURAL TESTS 479
14.3.3. T H E IMPACT TESTS 482
14.3.4. A COMPARISON BETWEEN THE MECHANICAL PROPERTIES OF PA6 A N D PA12
MFCS 484
14.4. STRUCTURE-PROPERTIES RELATION IN MICROFIBRILLAR COMPOSITES 486
14.4.1. MICROSCOPY STUDIES OF H D P E / P A 6 A N D H D P E / P A 1 2
SYSTEMS 490
14.4.2. SYNCHROTRON X-RAY STUDIES OF H D P E / P A 6 A N D H D P E / P A
1 2 M F C 499
14.5. CONCLUSIONS A N D OUTLOOK 517
ACKNOWLEDGEMENTS 518
REFERENCES 519
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XVI CONTENTS
CHAPTER 15 MICROFIBRILS REINFORCED COMPOSITES BASED ON PP AND PET:
EFFECT OF DRAW RATIO ON MORPHOLOGY, STATIC AND DYNAMIC MECHANICAL
PROPERTIES, CRYSTALLIZATION AND RHEOLOGY
K. JAYANARAYANAN, K. JOSEPH, S. THOMAS
15.1. INTRODUCTION 525
15.2. EXPERIMENTAL DETAILS: MATERIALS AND PROCEDURES 528
15.3. SAMPLE CHARACTERIZATION 532
15.3.1. MORPHOLOGY DEVELOPMENT 532
15.3.2. STATIC MECHANICAL PROPERTIES 537
15.3.3. DYNAMIC MECHANICAL ANALYSIS 539
15.3.4. CRYSTALLIZATION 545
15.3.5. DYNAMIC RHEOLOGY 551
15.4. CONCLUSIONS A N D OUTLOOK 555
REFERENCES 557
CHAPTER 16 STRUCTURAL AND MECHANICAL CHARACTERIZATION OF THE
REINFORCEMENT AND PRECURSORS OF MICRO- AND NANOFIBRILS REINFORCED
POLYMER-POLYMER COMPOSITES N. STRIBECK, D. BHATTACHARYYA, S. FAKIROV
16.1. INTRODUCTION 563
16.1.1. MONITORING STRUCTURE VARIATION IN POLYMER-POLYMER COMPOSITES 563
16.1.2. PROGRESS IN X-RAY SCATTERING 564
16.1.3. PROGRESS IN METHODS FOR THE ANALYSIS OF SCATTERING D A T A 565
16.2. PRACTICE OF EXPERIMENT AND D A T A ANALYSIS 565
16.3. WAXD FIBER MAPPING 566
16.3.1. MOTIVATION AND METHOD DESIGN 566
16.3.2. ACTIONS REQUIRED BY THE USER 566
16.3.3. AUTOMATED MAPPING 568
16.3.4. APPLICATION 568
16.4. X-RAY SCATTERING FIBER TOMOGRAPHY 569
16.4.1. MOTIVATION 569
16.4.2. INTRODUCTION OF T H E METHOD 571
16.4.3. APPLICATIONS 574
16.5. SAXS MONITORING OF MECHANICAL TESTS 576
16.5.1. MOTIVATION AND METHOD DEVELOPMENT 576
16.5.2. RESULTS 576
IMAGE 11
CONTENTS XVII
16.6. COMBINING TIME RESOLUTION A N D SPATIAL RESOLUTION 582
16.7. CONCLUSIONS A N D OUTLOOK 583
ACKNOWLEDGMENT 584
REFERENCES 584
CHAPTER 17 APPLICATION OPPORTUNITIES OF THE MICROFIBRIL REINFORCED
COMPOSITE CONCEPT R. J. SHIELDS, D. BHATTACHARYYA, S. FAKIROV
17.1. INTRODUCTION 589
17.2. BARRIER PROPERTIES OF POLYMER BLENDS A N D COMPOSITES 592
17.2.1. THEORETICAL ASPECTS OF PERMEABILITY 593
17.2.2. HOW CRYSTALLINITY AFFECTS PERMEABILITY 594
17.3. M F C APPLICATION OPPORTUNITIES AS PACKAGING WITH IMPROVED BARRIER
PROPERTIES 595
17.4. M F C PERMEATION EXPERIMENTS 596
17.4.1. EXPERIMENTAL SETUP 596
17.4.2. PRELIMINARY PERMEATION EXPERIMENTS 596
17.4.3. M F C PERMEABILITY INVESTIGATION 598
17.4.4. MECHANICAL PROPERTIES 604
17.5. M F C PERMEABILITY MODELING 604
17.6. APPLICATION OPPORTUNITIES IN VEHICLE MANUFACTURING 609
17.7. APPLICATIONS FOR BIOMEDICAL PURPOSES 611
17.8. OTHER APPLICATIONS OF T H E M F C CONCEPT 620
17.8.1. RECYCLING OF BLENDED PLASTIC WASTE STREAMS 620
17.8.2. ELECTROCONDUCTIVE MATERIALS 621
17.9. CONCLUSIONS A N D OUTLOOK 622
ACKNOWLEDGEMENTS 623
REFERENCES 623
CHAPTER 18 POLYLACTIDE BASED BIO-RESORBABLE BONE NAILS: IMPROVEMENTS OF
STRENGTH AND STIFFNESS BY MICROFIBRILLAR REINFORCEMENT K. FRIEDRICH, J.
HOFFMANN, A. A. ALMAJID, M. EVSTATIEV
18.1. INTRODUCTION 627
18.2. MATERIALS, PREPARATION, A N D CHARACTERIZATION 629
18.2.1. MATERIALS USED 629
18.2.2. SPECIMEN CHARACTERIZATION 630
18.2.3. M F C PREPARATION 630
IMAGE 12
XVIII
CONTENTS
18.3. MORPHOLOGY AND MECHANICAL PROPERTIES 635
18.3.1. MORPHOLOGY OF THE SAMPLES 635
18.3.2. MECHANICAL PROPERTIES 637
18.4. CONCLUSIONS 640
ACKNOWLEDGEMENTS 640
REFERENCES 640
PART IV SINGLE POLYMER COMPOSITES
CHAPTER 19 MICRO- AND NANOFIBRILLAR SINGLE POLYMER COMPOSITES M.
DUHOVIC, S. FAKIROV, R. HOLSCHUH, P. MITSCHANG, D. BHATTACHARYYA
19.1. INTRODUCTION 643
19.2. PRODUCING POLYMERIC MICRO- AND NANOFIBERS 644
19.2.1. MELT BLOWING 645
19.2.2. ELECTROSPINNING 646
19.2.3. BICOMPONENT MELT SPINNING . 647
19.3. MECHANICAL PROPERTIES OF POLYMER MICRO- A N D NANOFIBERS 649
19.3.1. CHARACTERIZATION AND MODELING OF THE MECHANICAL PROPERTIES 649
19.4. MANUFACTURING ROUTES FOR MICRO- A N D NANO-SPC MATERIALS 650
19.4.1. I N SITU CREATION OF POLYMER MICRO- A N D NANOFIBRILS 651
19.4.2. REACTIVE PROCESS I N SITU COPOLYMERIZATION METHOD 653
19.4.3. HOT-COMPACTION METHOD 655
19.4.4. FILM STACKING METHOD 656
19.4.5. RESIN INFUSION METHOD 656
19.4.6. OVERHEATING METHOD 656
19.4.7. CO-EXTRUSION METHOD 656
19.5. COMMERCIALLY AVAILABLE SPC MATERIALS 657
19.5.1. CURV 657
19.5.2. PURE 659
19.5.3. PARA-LITE P P 659
19.5.4. ARMORDON 659
19.5.5. KAYPLA 660
19.5.6. COMFIL SPCS AND INJECTION MOLDABLE SPC PELLETS (ESPRI PROJECT)
660
19.6. CASE STUDIES 661
19.6.1. SPCS BY I N SITU CREATION OF NANOFIBRILS AND H O T COMPACTION
661
19.6.2. SPCS BY MELT SPINNING AND I N SITU COPOLYMERIZATION 665
19.7. SUMMARY AND OUTLOOK 667
REFERENCES 667
IMAGE 13
CONTENTS X I X
CHAPTER 20 POLYMORPHISM- AND STEREOREGULARITY-BASED SINGLE POLYMER
COMPOSITES J. KARGER-KOCSIS, S. FAKIROV
20.1. INTRODUCTION 673
20.1.1. DEFINITIONS 674
20.1.2. PREPARATION OF SINGLE POLYMER COMPOSITES 675
20.2. STEREOREGULARITY, CRYSTALLIZATION AND POLYMORPHISM IN POLYMERS 677
20.2.1. STEREOREGULARITY OF MACROMOLECULES 678
20.2.2. CRYSTALLIZATION OF POLYMERS 679
20.2.3. POLYMORPHISM IN POLYMERS 680
20.3. AMORPHOUS MATRIX WITH AMORPHOUS REINFORCEMENT 682
20.3.1. SINGLE POLYMER MICROCOMPOSITES 682
20.3.2. SINGLE POLYMER NANOCOMPOSITES 683
20.4. AMORPHOUS MATRIX WITH SEMICRYSTALLINE REINFORCEMENT 683
20.4.1. SINGLE POLYMER MICROCOMPOSITES 684
20.4.2. SINGLE POLYMER NANOCOMPOSITES 684
20.5. SEMICRYSTALLINE MATRIX WITH SEMICRYSTALLINE REINFORCEMENT 685
20.5.1. SINGLE POLYMER MICROCOMPOSITES 685
20.5.2. SINGLE POLYMER NANOCOMPOSITES 691
20.6. APPLICATIONS OF SPCS 694
20.7. OUTLOOK A N D FUTURE TRENDS 694
ACKNOWLEDGEMENTS 695
REFERENCES 695
CHAPTER 21 LAYERED POLYMER-POLYMER COMPOSITE WITH NANOCOMPOSITE AS
REINFORCEMENT W. H. RUAN, T. CZIGANY, T. BARANY, M. Z. RONG, M. Q. ZHANG
21.1. INTRODUCTION . 699
21.2. GRAFT POLYMERIZATION ONTO NANOPARTICLES 700
21.3. ORIENTED P P REINFORCEMENTS FILLED WITH NANO-SI0 2 702
21.4. MANUFACTURING A N D CHARACTERIZATION OF P P HOMOPOLYMER-PP
COPOLYMER COMPOSITE WITH NANOCOMPOSITE AS REINFORCEMENT 711
21.5. CONCLUSIONS 715
ACKNOWLEDGEMENT 716
REFERENCES 716
IMAGE 14
X X
CONTENTS
CHAPTER 22 MANUFACTURING OF SELF-REINFORCED ALL-PP COMPOSITES
A. BLEDZKI, H.-P. HEIM, D. PABMANN, A. RIES
22.1. INTRODUCTION 719
22.2. SELF-REINFORCED THERMOPLASTIC FIBER COMPOSITE MATERIALS 719
22.3. MANUFACTURING CONCEPT A N D COMPOSITE STRUCTURE 721
22.3.1. PRIMARY SHAPING 721
22.3.2. SEMIFINISHED PRODUCT MANUFACTURING 722
22.3.3. COMPACTION A N D MOLDING 723
22.3.4. COMPOSITE STRUCTURE 723
22.4. T H E PROCESSING TECHNOLOGY OF HOT-COMPACTION 724
22.4.1. PREHEATING 724
22.4.2. COMPACTION 724
22.4.3. COOLING 726
22.5. MOLDING STRATEGIES 726
22.5.1. THERMOFORMING HOT-COMPACTED SEMIFINISHED PLATE PRODUCTS 727
22.5.2. COMPRESSION MOLDING IN COMBINATION WITH T H E HOT-COMPACTION OF
SEMIFINISHED TEXTILE PRODUCTS 728
22.6. PROPERTY SPECTRUM OF S R - P P COMPOSITES 729
22.7. FIELDS OF APPLICATION FOR SELF-REINFORCED ORGANIC SHEETS MADE OF P
P 732
22.8. CONCLUSIONS AND OUTLOOK 734
ACKNOWLEDGEMENT 734
REFERENCES 734
CHAPTER 23 SINGLE POLYMER COMPOSITES V I A SHEAR CONTROLLED ORIENTATION
INJECTION MOLDING (SCORIM) OR OSCILLATING PACKING INJECTION MOLDING
(OPIM) TECHNIQUES
J. LEI, Z.-M. LI
23.1. INTRODUCTION 739
23.2. SELF-REINFORCED POLYETHYLENE BY SCORIM TECHNIQUES 743
23.3. SELF-REINFORCED POLYPROPYLENE BY SCORIM TECHNIQUES 755
23.4. OTHER POLYMER COMPOSITES REINFORCED BY SCORIM TECHNIQUES 764
23.5. CONCLUSIONS AND OUTLOOK 765
REFERENCES 765
LIST OF ACKNOWLEDGEMENTS 769
AUTHOR INDEX 781
SUBJECT INDEX 785
|
| any_adam_object | 1 |
| author_GND | (DE-588)115146210 |
| building | Verbundindex |
| bvnumber | BV040373139 |
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| dewey-raw | 668.494 |
| dewey-search | 668.494 |
| dewey-sort | 3668.494 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Maschinenbau / Maschinenwesen Werkstoffwissenschaften Werkstoffwissenschaften / Fertigungstechnik |
| format | Book |
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| id | DE-604.BV040373139 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:22:45Z |
| institution | BVB |
| isbn | 9781569905104 156990510X 9781569905258 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025226712 |
| oclc_num | 808723967 |
| open_access_boolean | |
| owner | DE-92 DE-12 DE-91G DE-BY-TUM DE-210 DE-83 DE-29T DE-573 |
| owner_facet | DE-92 DE-12 DE-91G DE-BY-TUM DE-210 DE-83 DE-29T DE-573 |
| physical | XXIX, 797 S. Ill., graph. Darst. 25 cm |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | Hanser |
| record_format | marc |
| spelling | Synthetic polymer-polymer composites Debes Bhattacharyya ; Stoyko Fakirov Cincinnati, Ohio ; München Hanser 2012 XXIX, 797 S. Ill., graph. Darst. 25 cm txt rdacontent n rdamedia nc rdacarrier Literaturangaben Kohlenstoff-Nanoröhre (DE-588)4581365-6 gnd rswk-swf Chemiefaser (DE-588)4069934-1 gnd rswk-swf Chemiefaserverstärkter Kunststoff (DE-588)4147617-7 gnd rswk-swf Mikrofaser (DE-588)4568602-6 gnd rswk-swf Nanokomposit (DE-588)4768127-5 gnd rswk-swf Kohlenstofffaser (DE-588)4128150-0 gnd rswk-swf Chemiefaserverstärkter Kunststoff (DE-588)4147617-7 s Kohlenstofffaser (DE-588)4128150-0 s Chemiefaser (DE-588)4069934-1 s Nanokomposit (DE-588)4768127-5 s Kohlenstoff-Nanoröhre (DE-588)4581365-6 s Mikrofaser (DE-588)4568602-6 s DE-604 Bhattacharyya, Debes Sonstige oth Fakirov, Stoyko 1936- Sonstige (DE-588)115146210 oth DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025226712&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Synthetic polymer-polymer composites Kohlenstoff-Nanoröhre (DE-588)4581365-6 gnd Chemiefaser (DE-588)4069934-1 gnd Chemiefaserverstärkter Kunststoff (DE-588)4147617-7 gnd Mikrofaser (DE-588)4568602-6 gnd Nanokomposit (DE-588)4768127-5 gnd Kohlenstofffaser (DE-588)4128150-0 gnd |
| subject_GND | (DE-588)4581365-6 (DE-588)4069934-1 (DE-588)4147617-7 (DE-588)4568602-6 (DE-588)4768127-5 (DE-588)4128150-0 |
| title | Synthetic polymer-polymer composites |
| title_auth | Synthetic polymer-polymer composites |
| title_exact_search | Synthetic polymer-polymer composites |
| title_full | Synthetic polymer-polymer composites Debes Bhattacharyya ; Stoyko Fakirov |
| title_fullStr | Synthetic polymer-polymer composites Debes Bhattacharyya ; Stoyko Fakirov |
| title_full_unstemmed | Synthetic polymer-polymer composites Debes Bhattacharyya ; Stoyko Fakirov |
| title_short | Synthetic polymer-polymer composites |
| title_sort | synthetic polymer polymer composites |
| topic | Kohlenstoff-Nanoröhre (DE-588)4581365-6 gnd Chemiefaser (DE-588)4069934-1 gnd Chemiefaserverstärkter Kunststoff (DE-588)4147617-7 gnd Mikrofaser (DE-588)4568602-6 gnd Nanokomposit (DE-588)4768127-5 gnd Kohlenstofffaser (DE-588)4128150-0 gnd |
| topic_facet | Kohlenstoff-Nanoröhre Chemiefaser Chemiefaserverstärkter Kunststoff Mikrofaser Nanokomposit Kohlenstofffaser |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025226712&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT bhattacharyyadebes syntheticpolymerpolymercomposites AT fakirovstoyko syntheticpolymerpolymercomposites |