Dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
2012
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| Schlagworte: | |
| Online-Zugang: | kostenfrei https://nbn-resolving.org/urn:nbn:de:bvb:355-epub-255068 Inhaltsverzeichnis |
| Beschreibung: | III, 159 S. graph. Darst. |
Internformat
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| 264 | 1 | |c 2012 | |
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Datensatz im Suchindex
| _version_ | 1804149413320327168 |
|---|---|
| adam_text | IMAGE 1
CONTENTS
INTRODUCTION 1
1 THEORETICAL BACKGROUND 5
1.1 BASICS OF ELECTRODYNAMICS 5
1.1.1 MAXWELL AND CONSTITUTIVE EQUATIONS 5
1.1.2 THE ELECTRIC DISPLACEMENT FIELD 6
1.1.3 WAVE EQUATIONS 7
1.2 DIELECTRIC RELAXATION 9
1.2.1 POLARIZATION ; 9
1.2.2 RESPONSE FUNCTIONS OF THE ORIENTATIONAL POLARIZATION 10
1.3 EMPIRICAL DESCRIPTION OF DIELECTRIC RELAXATION 11
1.3.1 DEBYE EQUATION 11
1.3.2 RELAXATION TIME DISTRIBUTIONS 12
1.3.3 DAMPED HARMONIC OSCILLATOR 13
1.3.4 COMBINATION OF MODELS 14
1.4 MICROSCOPIC MODELS OF DIELECTRIC RELAXATION 14
1.4.1 ONSAGER EQUATION 14
1.4.2 KIRKWOOD-FROHLICH EQUATION 15
1.4.3 CAVELL EQUATION 15
1.4.4 DEBYE MODEL OF ROTATIONAL DIFFUSION 16
1.4.5 MICROSCOPIC AND MACROSCOPIC RELAXATION TIMES 17
1.5 ION ASSOCIATION 18
1.6 TEMPERATURE DEPENDENCE OF RELAXATION TIMES 19
1.6.1 ARRHENIUS EQUATION 19
1.6.2 EYRING EQUATION 19
2 EXPERIMENTAL 21
2.1 SAMPLE PREPARATION 21
2.2 MEASUREMENT OF DIELECTRIC PROPERTIES 22
2.2.1 FREQUENCY-DOMAIN REFLECTOMETRY 22
2.2.2 INTERFEROMETRY 24
2.2.3 DATA PROCESSING 27
2.3 SUPPORTING MEASUREMENTS 29
I
HTTP://D-NB.INFO/1028945930
IMAGE 2
CONTENTS
2.3.1 DENSIMETRY 29
2.3.2 CONDUCTIVITY 29
2.3.3 QUANTUM MECHANICAL CALCULATIONS 30
3 SMALL ALKYLCARBOXYLATES 31
3.1 AQUEOUS SOLUTIONS OF SODIUM FORMATE AND SODIUM ACETATE . 31
3.1.1 CHOICE OF FIT MODEL AND ASSIGNMENT OF RELAXATION MODES . . . . . .
. . 32
3.1.2 RELAXATION AMPLITUDES 42
3.1.3 QUANTITATIVE DESCRIPTION OF ION PAIRING 44
3.1.4 ION HYDRATION 47
3.1.5 TEMPERATURE DEPENDENCE OF ION HYDRATION IN NAOAC(AQ) 51
3.1.6 BULK WATER DYNAMICS 52
3.2 AQUEOUS SOLUTIONS OF SODIUM TRIFLUOROACETATE 56
3.2.1 CHOICE OF FIT MODEL AND ASSIGNMENT OF RELAXATION MODES 56
3.2.2 WATER RELAXATIONS AND ION HYDRATION 60
3.2.3 ION ASSOCIATION 63
4 AMPHIPHILIC CARBOXYLATES 67
4.1 AQUEOUS SOLUTIONS OF SODIUM PROPANOATE, BUTANOATE AND PENTANOATE . .
. . 67 4.1.1 CHOICE OF FIT MODEL 68
4.1.2 . RELAXATION MODES AND RELAXATION TIMES 76
4.1.3 SOLUTE RELAXATION AND ION ASSOCIATION 81
4.1.4 WATER-RELAXATION AMPLITUDES 86
4.1.5 ION HYDRATION 87
4.2 AQUEOUS SOLUTIONS OF SODIUM BENZOATE 92
4.2.1 CHOICE OF FIT MODEL 92
4.2.2 RELAXATION TIMES AND ASSIGNMENT OF RELAXATION MODES 97
4.2.3 SOLUTE RELAXATION AMPLITUDE 98
4.2.4 WATER RELAXATIONS AND ION HYDRATION 100
5 METHYLSULFATE AND METHANESULFONATE 103
5.1 CHOICE OF FIT MODEL AND ASSIGNMENT OF RELAXATION MODES 103
5.2 WATER RELAXATIONS AND ION HYDRATION I L L
5.3 ION ASSOCIATION 117
SUMMARY AND CONCLUSIONS 121
APPENDIX 125
A.L DIELECTRIC DATA OF AQUEOUS SODIUM CHLORIDE 125
A.2 DRS OF AQUEOUS SOLUTIONS OF RUBIDIUM FLUORIDE 129
A.3 DRS OF NON-AQUEOUS ELECTROLYTE SOLUTIONS 139
BIBLIOGRAPHY 149
|
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| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| indexdate | 2024-07-10T00:22:38Z |
| institution | BVB |
| language | English |
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| physical | III, 159 S. graph. Darst. |
| psigel | ebook |
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| spelling | Abd ur-Rahman, Muhammad Verfasser aut Dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules vorgelegt von Hafiz Muhammad Abd ur Rahman 2012 III, 159 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Regensburg, Univ., Diss., 2012 Relaxationsspektroskopie (DE-588)4177696-3 gnd rswk-swf Ionenwolke (DE-588)4498254-9 gnd rswk-swf Dielektrische Relaxation (DE-588)4149721-1 gnd rswk-swf Biomolekül (DE-588)4135124-1 gnd rswk-swf Hydratation (DE-588)4193125-7 gnd rswk-swf Anion (DE-588)4130938-8 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Biomolekül (DE-588)4135124-1 s Ionenwolke (DE-588)4498254-9 s Dielektrische Relaxation (DE-588)4149721-1 s Relaxationsspektroskopie (DE-588)4177696-3 s DE-604 Anion (DE-588)4130938-8 s Hydratation (DE-588)4193125-7 s Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:355-epub-255068 http://epub.uni-regensburg.de/25506/ Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:355-epub-255068 Resolving-System DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025221539&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Abd ur-Rahman, Muhammad Dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules Relaxationsspektroskopie (DE-588)4177696-3 gnd Ionenwolke (DE-588)4498254-9 gnd Dielektrische Relaxation (DE-588)4149721-1 gnd Biomolekül (DE-588)4135124-1 gnd Hydratation (DE-588)4193125-7 gnd Anion (DE-588)4130938-8 gnd |
| subject_GND | (DE-588)4177696-3 (DE-588)4498254-9 (DE-588)4149721-1 (DE-588)4135124-1 (DE-588)4193125-7 (DE-588)4130938-8 (DE-588)4113937-9 |
| title | Dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules |
| title_auth | Dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules |
| title_exact_search | Dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules |
| title_full | Dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules vorgelegt von Hafiz Muhammad Abd ur Rahman |
| title_fullStr | Dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules vorgelegt von Hafiz Muhammad Abd ur Rahman |
| title_full_unstemmed | Dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules vorgelegt von Hafiz Muhammad Abd ur Rahman |
| title_short | Dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules |
| title_sort | dielectric spectroscopy of the hydration of organic anions as models for anionic residues of biomolecules |
| topic | Relaxationsspektroskopie (DE-588)4177696-3 gnd Ionenwolke (DE-588)4498254-9 gnd Dielektrische Relaxation (DE-588)4149721-1 gnd Biomolekül (DE-588)4135124-1 gnd Hydratation (DE-588)4193125-7 gnd Anion (DE-588)4130938-8 gnd |
| topic_facet | Relaxationsspektroskopie Ionenwolke Dielektrische Relaxation Biomolekül Hydratation Anion Hochschulschrift |
| url | http://epub.uni-regensburg.de/25506/ https://nbn-resolving.org/urn:nbn:de:bvb:355-epub-255068 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025221539&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT abdurrahmanmuhammad dielectricspectroscopyofthehydrationoforganicanionsasmodelsforanionicresiduesofbiomolecules |