Aryl diazonium salts: new coupling agents in polymer and surface science
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| Other Authors: | |
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| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2012
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XXI, 335 S. Ill., graph. Darst. |
| ISBN: | 9783527329984 9783527650446 |
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| 245 | 1 | 0 | |a Aryl diazonium salts |b new coupling agents in polymer and surface science |c ed. by Mohamed Mehdi Chehimi |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2012 | |
| 300 | |a XXI, 335 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 4 | |a Diazo compounds | |
| 650 | 4 | |a Arylation | |
| 650 | 4 | |a Surface chemistry | |
| 650 | 0 | 7 | |a Kupplungsreaktion |0 (DE-588)4166199-0 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Aromatische Verbindungen |0 (DE-588)4129374-5 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Grenzflächenaktiver Stoff |0 (DE-588)4158138-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Diazoniumverbindungen |0 (DE-588)4192798-9 |2 gnd |9 rswk-swf |
| 689 | 0 | 0 | |a Diazoniumverbindungen |0 (DE-588)4192798-9 |D s |
| 689 | 0 | 1 | |a Aromatische Verbindungen |0 (DE-588)4129374-5 |D s |
| 689 | 0 | 2 | |a Grenzflächenaktiver Stoff |0 (DE-588)4158138-6 |D s |
| 689 | 0 | 3 | |a Kupplungsreaktion |0 (DE-588)4166199-0 |D s |
| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Chehimi, Mohamed Mehdi |0 (DE-588)1023408317 |4 edt | |
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| _version_ | 1804149275649638400 |
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| adam_text | IMAGE 1
CONTENTS
PREFACE X V
LIST O F CONTRIBUTORS X V I I
1 ATTACHMENT O F ORGANIC LAYERS T O MATERIALS SURFACES
BY REDUCTION O F DIAZONIUM SALTS 1
JEAN PINSON
1.1 A B R I E F SURVEY O F T H E C H E M I S T R Y A N D
ELECTROCHEMISTRY
O F D I A Z O N I U M SALTS 1
1.2 T H E DIFFERENT M E T H O D S T H A T P E R M I T GRAFTING O F D I A
Z O N I U M SALTS 3
1.2.1 ELECTROCHEMISTRY 3
1.2.2 R E D U C I N G SUBSTRATE, HOMOLYTIC DEDIAZONATION, REACTION W I T
H T H E SUBSTRATE 4
1.2.3 R E D U C I N G REAGENT 5
1.2.4 NEUTRAL A N D BASIC MEDIA 6
1.2.5 ULTRASONICATION 6
1.2.6 H E A T I N G A N D MICROWAVE 6
1.2.7 MECHANICAL GRAFTING 7
1.2.8 P H O T O C H E M I S T R Y 7
1.3 T H E DIFFERENT SUBSTRATES, D I A Z O N I U M SALTS, A N D SOLVENTS
T H A T C A N BE U S E D 7
1.3.1 SUBSTRATES 7
1.3.2 D I A Z O N I U M SALTS 9
1.3.3 SOLVENTS 10
1.4 EVIDENCE FOR T H E P R E S E N C E O F A B O N D B E T W E E N T H E
SUBSTRATE
A N D T H E O R G A N I C LAYER 11
1.4.1 STABILITY O F T H E LAYER 11
1.4.2 SPECTROSCOPIC EVIDENCE FOR A B O N D 12
1.5 F R O M MONOLAYERS TO MULTILAYERS 13
1.5.1 MONOLAYERS 14
1.5.2 LAYERS O F M E D I U M T H I C K N E S S 16
1.5.2.1 T H I C K LAYERS 19
1.6 STRUCTURE A N D F O R M A T I O N O F MULTILAYERS 21
HTTP://D-NB.INFO/101777496X
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V I I I C O N T E N T S
1.6.1 C H E M I C A L STRUCTURE 21
1.6.2 T H E SPATIAL STRUCTURE O F T H E LAYERS 2 2
1.6.3 C O M P A C T N E S S O F T H E LAYERS 23
1.6.4 SWELLING O F T H E LAYER 2 4
1.6.5 ELECTRON T R A N S F E R T H R O U G H T H E LAYERS 2 4
1.6.6 T H E F O R M A T I O N M E C H A N I S M O F MULTILAYERS 2 5
1.7 C O N C L U S I O N 2 7
REFERENCES 2 7
2 ARYL-SURFACE BONDING: A DENSITY FUNCTIONAL THEORY
(DFT) SIMULATION APPROACH 3 7 N A N SHAO, SHENG DAI, A N D DE-EN JIANG
2.1 I N T R O D U C T I O N 3 7
2.2 DENSITY FUNCTIONAL THEORY 3 8
2.3 B O N D I N G B E T W E E N ARYL A N D VARIOUS SUBSTRATES 3 8
2.3.1 O N G R A P H I T E / G R A P H E N E 39
2.3.1.1 O N T H E BASAL P L A N E 3 9
2.3.1.2 O N T H E EDGES O F G R A P H E N E 4 2
2.3.2 O N C A R B O N N A N O T U B E S 4 4
2.3.3 O N METAL SURFACES 4 5
2.4 S U M M A R Y A N D O U T L O O K 4 8
A C K N O W L E D G M E N T S 49 REFERENCES 5 0
3 PATTERNED MOLECULAR LAYERS O N SURFACES 5 3
ALISON J. DOWNARD, ANDREW J. GROSS, A N D BRADLEY M. SIMONS 3.1 M E T H
O D S BASED O N S C A N N I N G P R O B E LITHOGRAPHY 5 3
3.1.1 A F M 5 4
3.1.2 SECM 5 4
3.1.3 SPOTTING 5 6
3.2 M E T H O D S BASED O N SOFT LITHOGRAPHY 5 7
3.2.1 P R I N T I N G 5 7
3.2.2 MOLDS 5 9
3.2.3 N A N O S P H E R E LITHOGRAPHY 5 9
3.3 M E T H O D S BASED O N LITHOGRAPHY 6 0
3.4 M E T H O D S BASED O N SURFACE-DIRECTED P A T T E R N I N G 62
3.4.1 MODIFICATION O F SI SURFACES 63
3.4.2 MODIFIED ELECTRODE ARRAYS 64
3.5 S U M M A R Y A N D CONCLUSIONS 66
REFERENCES 68
4 ANALYTICAL M E T H O D S FOR T H E CHARACTERIZATION O F ARYL LAYERS 71
KARSTEN HINRICHS, KATY ROODENKO, JORG RAPPICH, M O H A M E D M. CHEHIMI,
A N D JEAN PINSON 4.1 I N T R O D U C T I O N 71
4.2 S C A N N I N G PROBE MICROSCOPIES 71
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4.3 U V - V I S SPECTROSCOPY: T R A N S M I S S I O N , REFLECTION,
A N D ELLIPSOMETRY 72
4.4 IR SPECTROSCOPY 72
4.4.1 T R A N S M I S S I O N SPECTROSCOPY 73
4.4.2 REFLECTION SPECTROSCOPY 74
4.4.3 INFRARED SPECTROSCOPIC ELLIPSOMETRY (IRSE) 7 5
4.4.4 IRSE SURFACE CHARACTERIZATION 7 7
4.4.5 I N S I T U IR SPECTROSCOPY: ATR A N D IRSE 79
4.5 R A M A N SPECTROSCOPY A N D SURFACE-ENHANCED R A M A N
SCATTERING (SERS) 83 4.6 X-RAY PHOTOELECTRON SPECTROSCOPY (XPS) 84
4.7 X-RAY S T A N D I N G WAVES (XSW) 91
4.8 RUTHERFORD BACKSCATTERING 93
4.9 T I M E O F FLIGHT SECONDARY I O N MASS SPECTROSCOPY 93
4.10 ELECTROCHEMISTRY 94
4.11 CONTACT ANGLE M E A S U R E M E N T S 96
4.12 CONCLUSION 96
REFERENCES 9 8
5 MODIFICATION O F NANO-OBJECTS BY ARYL
DIAZONIUM SALTS 103 DAO-JUN CUO A N D FAKHRADIN MIRKHALAF 5.1
INTRODUCTION 103
5.2 ELECTROCHEMICAL MODIFICATION O F NANO-OBJECTS
BY REDUCTION O F D I A Z O N I U M SALTS 105 5.2.1 SURFACE MODIFICATION
O F C A R B O N NANO-OBJECTS VIA ELECTROCHEMICAL
REDUCTION O F ARYL D I A Z O N I U M CATIONS 105 5.2.2 SURFACE
MODIFICATION O F METAL A N D METAL OXIDE NANO-OBJECTS VIA
ELECTROCHEMICAL REDUCTION O F ARYL D I A Z O N I U M CATIONS 111 5.3 C H
E M I C A L MODIFICATION O F NANO-OBJECTS B Y REDUCTION
O F D I A Z O N I U M SALTS 112
5.3.1 SURFACE MODIFICATION O F C A R B O N NANO-OBJECTS VIA C H E M I C
A L R E D U C T I O N
O F ARYL D I A Z O N I U M CATIONS 112 5.3.2 SURFACE MODIFICATION O F
METAL A N D METAL OXIDE NANO-OBJECTS VIA C H E M I C A L REDUCTION O F
ARYL D I A Z O N I U M CATIONS 116
5.4 S U M M A R Y A N D CONCLUSIONS 119
A C K N O W L E D G M E N T S 120 REFERENCES 120
6 POLYMER CRAFTING T O ARYL DIAZONIUM-MODIFIED MATERIALS:
M E T H O D S A N D APPLICATIONS 125 SARRA GAM-DEROUICH, SAMIA
MAHOUEHE-CHERGUI, H A T E M BEN ROMDHANE, AND M O H A M E D M. CHEHIMI
6.1 INTRODUCTION 125
6.2 M E T H O D S FOR GRAFTING C O U P L I N G AGENTS F R O M ARYL D I A
Z O N I U M
C O M P O U N D S 127
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6.3 GRAFTING MACROMOLECULES TO SURFACES T H R O U G H ARYL LAYERS 130
6.3.1 B I N D I N G MACROMOLECULES TO SURFACES BY A GRAFTING
F R O M STRATEGY 130
6.3.1.1 SURFACE-INITIATED A T O M T R A N S F E R RADICAL POLYMERIZATION
(SI-ATRP) 130
6.3.1.2 SURFACE-INITIATED REVERSIBLE A D D I T I O N - F R A G M E N T A
T I O N C H A I N T R A N S F E R (SI-RAFT) 142 6.3.1.3
SURFACE-INITIATED PHOTOPOLYMERIZATION 143 6.3.1.4 ALTERNATIVE M E T H O
D S 146
6.3.2 A T T A C H M E N T O F MACROMOLECULES T H R O U G H GRAFTING
O N T O STRATEGIES 147
6.3.2.1 PHOTOCHEMICAL A T T A C H M E N T 147
6.3.2.2 R I N G O P E N I N G 148
6.3.2.3 ACYLATION 149
6.3.2.4 CLICK C H E M I S T R Y 149
6.3.2.5 DIAZOTATION O F SUBSTRATES A N D MACROMOLECULES 150 6.4 A D H E
S I O N O F POLYMERS TO SURFACES T H R O U G H ARYL LAYERS 151
6.5 C O N C L U S I O N 153
REFERENCES 153
7 CRAFTING POLYMER FILMS O N T O MATERIAL SURFACES:
T H E ONE-STEP REDOX PROCESSES 159 GUY DENIAU, SERGE PALACIN, ALICE
MESNAGE, A N D LORRAINE TESSIER 7.1 CATHODIC ELECTROGRAFTING (CE) I N A
N O R G A N I C M E D I U M 160
7.1.1 DIRECT CATHODIC ELECTROGRAFTING O F VINYLIC POLYMERS 160
7.1.2 INDIRECT CATHODIC ELECTROGRAFTING 162
7.2 SURFACE ELECTROINITIATED E M U L S I O N POLYMERIZATION (SEEP) 164
7.2.1 CHARACTERIZATION O F POLY(BUTYL METHACRYLATE) FILMS 166 7.2.2 D E
T E R M I N A T I O N O F T H E F I L M STRUCTURE 167
7.2.3 R E D U C T I O N O F PROTONS A N D T H E ROLE O F H Y D R O G E N
RADICALS 169
7.2.4 M E C H A N I S M O F SEEP 170
7.3 C H E M I C A L GRAFTING VIA C H E M I C A L REDOX ACTIVATION
(GRAFTFAST*) 171
7.3.1 PROCESS W I T H O U T VINYLIC M O N O M E R 172
7.3.2 PROCESS W I T H VINYLIC M O N O M E R 174
7.3.2.1 TYPE O F MATERIALS 174
7.3.2.2 P A R A M E T E R S CONTROLLED I N T H E PROCESS 174
7.4 S U M M A R Y A N D CONCLUSIONS 177
REFERENCES 178
8 ELECTROGRAFTING O F CONDUCTIVE OLIGOMERS
A N D POLYMERS 181
JEAN CHRISTOPHE LACROIX, JALAL CHILANE, LUIS SANTOS, CAELLE
TRIPPE-ALLARD, PASCAL MARTIN, A N D HYACINTHE RANDRIAMAHAZAKA 8.1 I N T
R O D U C T I O N 181
8.2 C O N J U G A T E D O L I G O M E R S A N D POLYMERS 181
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8.3 SURFACE GRAFTING BASED O N ELECTROREDUCTION
O F D I A Z O N I U M SALTS 184
8.4 POLYPHENYLENE A N D OLIGOPHENYLENE-TETHERED SURFACE P R E P A R E D
B Y T H E D I A Z O N I U M R E D U C T I O N O F ANILINE O R
4-SUBSTITUTED ANILINE 187 8.5 N - D O P I N G A N D C O N D U C T A N C
E SWITCHING O F G R A F T E D BIPHENYL, T E R P H E N Y L ,
NITRO-BIPHENYL A N D 4-NITROAZOBENZENE MONO- A N D MULTILAYERS 187 8.6
P-DOPING A N D C O N D U C T A N C E SWITCHING O F GRAFTED OLIGO-
P H E N Y L T H I O P H E N E O R O L I G O T H I O P H E N E MONO- A N
D MULTILAYERS 190 8.7 P-DOPING A N D C O N D U C T A N C E SWITCHING O F
G R A F T E D OLIGOANILINE
MONO- A N D MULTILAYERS 192 8.8 C O N C L U S I O N A N D OUTLOOK 193
REFERENCES 195
9 T H E U S E O F ARYL DIAZONIUM SALTS IN T H E FABRICATION O F
BIOSENSORS
A N D CHEMICAL S E N S O R S 197
J. JUSTIN GOODING, CUOZHEN LIU, A N D ALICIA L. CUI 9.1 I N T R O D U C
T I O N 197
9.1.1 SENSORS A N D INTERFACIAL D E S I G N 197
9.1.2 MOLECULAR LEVEL CONTROL OVER T H E FABRICATION
O F S E N S I N G INTERFACES 198
9.2 T H E I M P O R T A N T FEATURES O F ARYL D I A Z O N I U M SALTS
W I T H REGARD TO S E N S I N G 200
9.3 S E N S O R S A N D BIOSENSORS FABRICATED U S I N G ARYL
D I A Z O N I U M SALTS 201
9.3.1 C H E M I C A L S E N S O R S - S E N S O R S FABRICATED VIA T H E
I M M O B I L I Z A T I O N
O F C H E M I C A L RECOGNITION SPECIES 201 9.3.2 BIOSENSORS 205
9.3.2.1 E N Z Y M E BIOSENSORS 206
9.3.2.2 I M M U N O B I O S E N S O R S 208
9.3.2.3 DNA-BASED BIOSENSORS 210
9.3.2.4 CELL-BASED BIOSENSORS 213
9.4 CONCLUSIONS 213
REFERENCES 214
10 DIAZONIUM C O M P O U N D S IN MOLECULAR ELECTRONICS 219
RICHARD MCCREERY A N D A D A M JOHAN BERGREN 10.1 I N T R O D U C T I O
N 219
10.2 FABRICATION O F MOLECULAR JUNCTIONS U S I N G D I A Z O N I U M
REAGENTS 2 2 2
10.2.1 SUBSTRATES FOR DIAZONIUM-DERIVED MOLECULAR JUNCTIONS 2 2 2 10.2.2
SURFACE MODIFICATION U S I N G D I A Z O N I U M C H E M I S T R Y 223
10.2.3 APPLICATION O F T O P CONTACTS 225
10.3 ELECTRONIC P E R F O R M A N C E O F DIAZONIUM-DERIVED MOLECULAR
JUNCTIONS 226 10.3.1 SURFACE DIFFUSION MEDIATED DEPOSITION (SDMD) 2 2 7
10.3.2 STRUCTURAL CONTROL O F MOLECULAR J U N C T I O N BEHAVIOR 230
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10.3.3 REDOX REACTIONS I N MOLECULAR JUNCTIONS 2 3 2
10.3.4 MICROFABRICATED MOLECULAR DEVICES M A D E W I T H D I A Z O N I U
M C H E M I S T R Y 233 10.4 S U M M A R Y A N D OUTLOOK 235
A C K N O W L E D G M E N T S 236 REFERENCES 236
11 ELECTRONIC PROPERTIES O F SI SURFACES MODIFIED
BY ARYL DIAZONIUM C O M P O U N D S 241
JORG RAPPICH, XIN ZHANG, A N D KARSTEN HINRICHS 11.1 I N T R O D U C T I
O N 241
11.2 EXPERIMENTAL T E C H N I Q U E S TO CHARACTERIZE ELECTRONIC
PROPERTIES O F SI SURFACES I N SOLUTIONS 242
11.2.1 I N SITU P H O T O L U M I N E S C E N C E A N D PHOTO VOLTAGE M
E A S U R E M E N T S 2 4 2
11.2.2 I N SITU PL A N D PV M E A S U R E M E N T S D U R I N G
ELECTROCHEMICAL GRAFTING 244
11.2.3 REACTION S C H E M E O F T H E ELECTROCHEMICAL GRAFTING VIA D I A
Z O N I U M IONS 245
11.2.4 C H A N G E I N I PL A N D UPV D U R I N G ELECTROCHEMICAL
GRAFTING
O N T O SI SURFACES 246
11.2.5 C H A N G E I N B A N D B E N D I N G A N D W O R K F U N C T I O
N AFTER
ELECTROCHEMICAL GRAFTING O N T O SI SURFACES 248 11.2.6 P H D E P E N D
E N C E A N D E N H A N C E D SURFACE PASSIVATION 249
11.3 CONCLUSION A N D OUTLOOK 251
A C K N O W L E D G M E N T S 2 5 2 REFERENCES 252
12 NON-DIAZONIUM ORGANIC A N D ORGANOMETALLIC COUPLING AGENTS FOR
SURFACE MODIFICATION 2 5 5 FETAH I. PODVORICA
12.1 A M I N E S 255
12.1.1 CHARACTERIZATION O F T H E GRAFTED LAYER 2 5 7
12.1.1.1 ELECTROCHEMICAL M E T H O D S 2 5 7
12.1.1.2 SURFACE ANALYSIS T E C H N I Q U E S 258 12.1.2 C H E M I C A L
GRAFTING 259
12.1.3 LOCALIZED ELECTROGRAFTING 2 6 0
12.1.4 GRAFTING M E C H A N I S M 261
12.1.5 APPLICATIONS 262
12.2 ARYLHYDRAZINES 2 6 4
12.3 ARYLTRIAZENES 2 6 6
12.4 ALCOHOLS 2 6 7
12.4.1 OBSERVATION A N D CHARACTERIZATION O F T H E FILM 268
12.4.2 APPLICATIONS 2 6 9
12.5 G R I G N A R D REAGENTS 270
12.5.1 CHARACTERIZATION O F T H E LAYERS 271
12.5.2 GRAFTING M E C H A N I S M 2 7 2
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12.6 O N I U M SALTS 272
12.6.1 I O D O N I U M SALTS 2 7 2
12.6.2 S U L F O N I U M SALTS 273
12.6.3 A M M O N I U M SALTS 273
12.7 ALKYL HALIDES 274
12.8 C O N C L U S I O N 2 7 5
REFERENCES 276
13 VARIOUS ELECTROCHEMICAL STRATEGIES FOR CRAFTING ELECTRONIC FUNCTIONAL
MOLECULES T O SILICON 283 DINESH K. ASWAL, SHANKAR PRASAD KOIRY, A N D
SHIV KUMAR GUPTA
13.1 I N T R O D U C T I O N 283
13.2 ARCHITECTURE O F H Y B R I D DEVICES 284
13.2.1 MOLECULAR DIELECTRICS A N D W I R E S 285
13.2.2 MOLECULAR DIODES 286
13.2.3 R E S O N A N T T U N N E L DIODES 2 8 6
13.2.4 MOLECULAR TRANSISTORS 286
13.3 ELECTROGRAFTING O F MONOLAYERS TO SI 2 8 7
13.3.1 ESSENTIAL R E Q U I R E M E N T S 2 8 7
13.3.2 EXPERIMENTAL PROCESS O F ELECTROGRAFTING 2 8 7
13.4 NEGATIVE DIFFERENTIAL RESISTANCE EFFECT I N A MONOLAYER
ELECTROGRAFTED U S I N G A D I A Z O N I U M C O M P L E X 2 8 8 13.4.1
ELECTROGRAFTING O F D H T T 2 8 8
13.4.2 N D R EFFECT I N D H T T MONOLAYERS 2 9 0
13.5 DIELECTRIC MONOLAYERS ELECTROGRAFTED U S I N G SILANES 293
13.5.1 M E C H A N I S M O F ELECTROGRAFTING 2 9 3
13.5.2 ELECTRICAL CHARACTERIZATION 294
13.6 MOLECULAR DIODES BASED O N C 60/PORPHYRIN-DERIVATIVE BILAYERS 2 9 5
13.6.1 FABRICATION PROCESS 296
13.6.1.1 ELECTROGRAFTING O F ACCEPTOR C 60 LAYER O N SI 296 13.6.1.2
SELF-ASSEMBLY O F D O N O R PORPHYRIN DERIVATIVE LAYER O N C6O/SI 2 9 7
13.6.2 RECTIFICATION CHARACTERISTICS O F D - A BILAYERS 2 9 8
13.7 M E M O R Y EFFECT I N TPP-C11 MONOLAYERS ELECTROGRAFTED U S I N G
A C=C LINKER 301
13.7.1 ELECTROGRAFTING O F TPP-C11 MONOLAYER 301 13.7.2 ELECTRICAL
BISTABILITY A N D M E M O R Y EFFECT 303
13.8 S U M M A R Y 3 0 5
REFERENCES 3 0 5
14 PATENTS A N D INDUSTRIAL APPLICATIONS O F ARYL DIAZONIUM SALTS
A N D O T H E R COUPLING AGENTS 3 0 9
J A M E S A. BELMONT, CHRISTOPHE BUREAU, M O H A M E D M. CHEHIMI, SARRA
CAM-DEROUICH, A N D JEAN PINSON 14.1 INTRODUCTION 309
14.2 PATENTS 3 0 9
14.2.1 T H E SURFACE C H E M I S T R Y O F D I A Z O N I U M SALTS 309
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14.2.2 T H E SURFACE C H E M I S T R Y O F O T H E R C O U P L I N G
AGENTS 3 1 0
14.2.3 POST-MODIFICATION O F T H E GRAFTED LAYERS 3 1 0
14.2.4 C O M P O S I T E MATERIALS 3 1 0
14.2.5 T H E SURFACE MODIFICATION O F NANO-OBJECTS 3 1 2
14.2.6 MICROELECTRONICS 3 1 2
14.2.7 BIOMEDICAL APPLICATIONS 3 1 2
14.2.8 SENSORS, BIOSENSORS, SURFACES FOR BIOLOGICAL APPLICATIONS 3 1 2
14.2.9 ENERGY CONVERSION 313
14.3 INDUSTRIAL APPLICATIONS 313
14.3.1 T H E D E V E L O P M E N T O F MODIFIED C A R B O N BLACKS 313
14.3.2 INDUSTRIAL APPLICATIONS O F T H E ELECTROPOLYMERIZATION O F
VINYLICS: A L C H I M E R A N D ALCHIMEDICS 3 1 4 14.3.2.1 F R O M
RESEARCH TO D E V E L O P M E N T 3 1 4
14.3.2.2 APPLICATION O F E G * TO DRUG-ELUTING STENTS: ALCHIMEDICS 3 1 5
14.3.2.3 APPLICATION O F E G * TO C O P P E R INTERCONNECTS: A L C H I M
E R 3 1 7
14.4 C O N C L U S I O N 319
REFERENCES 319
INDEX 323
|
| any_adam_object | 1 |
| author2 | Chehimi, Mohamed Mehdi |
| author2_role | edt |
| author2_variant | m m c mm mmc |
| author_GND | (DE-588)1023408317 |
| author_facet | Chehimi, Mohamed Mehdi |
| building | Verbundindex |
| bvnumber | BV040270564 |
| classification_rvk | VK 7400 |
| ctrlnum | (OCoLC)796918590 (DE-599)BVBBV040270564 |
| dewey-full | 547.040453 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.040453 |
| dewey-search | 547.040453 |
| dewey-sort | 3547.040453 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV040270564 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:20:27Z |
| institution | BVB |
| isbn | 9783527329984 9783527650446 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-025126137 |
| oclc_num | 796918590 |
| open_access_boolean | |
| owner | DE-11 DE-703 |
| owner_facet | DE-11 DE-703 |
| physical | XXI, 335 S. Ill., graph. Darst. |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Aryl diazonium salts new coupling agents in polymer and surface science ed. by Mohamed Mehdi Chehimi Weinheim Wiley-VCH 2012 XXI, 335 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Diazo compounds Arylation Surface chemistry Kupplungsreaktion (DE-588)4166199-0 gnd rswk-swf Aromatische Verbindungen (DE-588)4129374-5 gnd rswk-swf Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd rswk-swf Diazoniumverbindungen (DE-588)4192798-9 gnd rswk-swf Diazoniumverbindungen (DE-588)4192798-9 s Aromatische Verbindungen (DE-588)4129374-5 s Grenzflächenaktiver Stoff (DE-588)4158138-6 s Kupplungsreaktion (DE-588)4166199-0 s DE-604 Chehimi, Mohamed Mehdi (DE-588)1023408317 edt DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025126137&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Aryl diazonium salts new coupling agents in polymer and surface science Diazo compounds Arylation Surface chemistry Kupplungsreaktion (DE-588)4166199-0 gnd Aromatische Verbindungen (DE-588)4129374-5 gnd Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd Diazoniumverbindungen (DE-588)4192798-9 gnd |
| subject_GND | (DE-588)4166199-0 (DE-588)4129374-5 (DE-588)4158138-6 (DE-588)4192798-9 |
| title | Aryl diazonium salts new coupling agents in polymer and surface science |
| title_auth | Aryl diazonium salts new coupling agents in polymer and surface science |
| title_exact_search | Aryl diazonium salts new coupling agents in polymer and surface science |
| title_full | Aryl diazonium salts new coupling agents in polymer and surface science ed. by Mohamed Mehdi Chehimi |
| title_fullStr | Aryl diazonium salts new coupling agents in polymer and surface science ed. by Mohamed Mehdi Chehimi |
| title_full_unstemmed | Aryl diazonium salts new coupling agents in polymer and surface science ed. by Mohamed Mehdi Chehimi |
| title_short | Aryl diazonium salts |
| title_sort | aryl diazonium salts new coupling agents in polymer and surface science |
| title_sub | new coupling agents in polymer and surface science |
| topic | Diazo compounds Arylation Surface chemistry Kupplungsreaktion (DE-588)4166199-0 gnd Aromatische Verbindungen (DE-588)4129374-5 gnd Grenzflächenaktiver Stoff (DE-588)4158138-6 gnd Diazoniumverbindungen (DE-588)4192798-9 gnd |
| topic_facet | Diazo compounds Arylation Surface chemistry Kupplungsreaktion Aromatische Verbindungen Grenzflächenaktiver Stoff Diazoniumverbindungen |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=025126137&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT chehimimohamedmehdi aryldiazoniumsaltsnewcouplingagentsinpolymerandsurfacescience |