Solvent extraction: classical and novel approaches
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Amsterdam [u.a.]
Elsevier
2012
|
| Edition: | 1. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XV, 555 S. Ill., graph. Darst. |
| ISBN: | 9780444537782 |
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MARC
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| 100 | 1 | |a Kislik, Vladimir S. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Solvent extraction |b classical and novel approaches |c Vladimir S. Kislik |
| 250 | |a 1. ed. | ||
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 2012 | |
| 300 | |a XV, 555 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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| 650 | 4 | |a Solvent extraction | |
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Record in the Search Index
| _version_ | 1804149108129136640 |
|---|---|
| adam_text | Contents
Preface
xi
Introduction
xiii
Part
I
Conventional (Classical) Principles and Practice
of Solvent Extraction
1.
Modern (Classical) Fundamental Principles
of Solvent Extraction
3
1.
Introduction
5
2.
Solvent Extraction By Solvation
5
3.
Solvent Extraction with Chemical Reactions
(By Complexation)
12
4.
Driving Forces of Solvent Extraction
1 5
5.
Influence of Kinetics Factors
1 7
6.
Selectivity
34
7.
Factors Affecting Extraction Process
36
8.
Module Design Considerations
49
9.
Experimental Determination of Distribution Ratios
55
10.
Summarizing Remarks
58
References
63
2.
Principles of Solvent Extraction of Organic
and Mineral Acids
69
1.
Introduction
69
2.
Extraction of Acids by Carbon-Bonded Oxygen-Donor
Extradants
and Substituted Hydrocarbon Solvents
71
3.
Phosphorus-Bonded Oxygen Donor
Extractante
85
4.
Aliphatic
Amine
Extradants
89
5.
Extraction of Strong (Inorganic) Acids
98
6.
Summarizing Remarks
102
References
108
3.
Chemistry of Metal Solvent Extraction
113
1.
Introduction
114
2.
Metal Extradion by Cation Exchangers (Acidic
Extradants)
114
3.
Metal Extraction by
Anion
Exchangers (Ion Pair Formation)
127
Contents
4.
Extraction
Through Formation of
Н
-Bonding
and
Solvating Complexes
135
5.
Extraction Through Mixed Complex Formation
144
6.
Extractable Complexation of
Monovalent
Metals
150
7.
Extraction with Aqueous Biphasic Systems
1 51
References
153
4.
Engineering Development of Solvent Extraction
Processes
157
1.
Introduction
157
2.
Extraction Stage
159
3.
Stripping Organic Solutions
169
4.
Extraction Efficiency
170
5.
Equipment Design for Continuous
Extraction-Stripping Processes
1 73
6.
Solvent Losses
182
7.
Economical Considerations
183
8.
Problems with Scale-Up to Industrial Systems
183
References
184
5.
Examples of Application of Solvent Extraction
Techniques in Chemical, Radiochemical, Biochemical,
Pharmaceutical, Analytical Separations, and
Wastewater Treatment 1
85
1.
Introduction
188
2.
Extraction in Hydrometallurgy (Metals Extraction)
1 89
3.
Solvent Extraction in Nuclear Chemistry and Technology
218
4.
Solvent Extraction in Analytical Chemistry
239
5.
Application of Solvent Extraction in Biochemical and
Pharmaceutical Separations
273
6.
Application of Solvent Extraction in Organic and Biofuels
Separation
278
7.
Solvent Extraction in Recovery
oí
Waste and Wastewater
Treatment
284
References
297
Part II
Novel Competitive Complexation/Solvation Theory
(CCST) of Solvent Extraction: Principles and Practice
6.
Backgrounds of the Competitive Complexation/
Solvation Theory of Solvent Extraction
317
1.
Introduction
317
Contents
2. Complexation
Through the
H-Bonding
and
Proton Transfer
31 7
3.
Distribution Isotherm
319
4.
Modified Competitive Preferential Solvation Theory
323
5.
Electronic Acid-Base Theory and Amphoterity
327
6.
Aggregation
328
References
329
7.
Competitive Complexation/Solvation Theory of
Solvent Extraction: General Mechanisms
and Kinetics
335
1.
Basic Statements
335
2.
Extraction Systems with Low Solute Concentrations
in Organic Phase
336
3.
Systems with Medium Concentrations of the Solute
345
4.
Systems with High Solute Concentrations
348
5.
Comparison of Conventional and Presented Theories
Description
350
6.
Summarizing Remarks for the CCST
351
References
352
8.
CCST in Engineering Design, Procedures,
and Calculations
355
1.
Introduction
355
2.
Engineering Considerations in Experimental Investigation
of CCST
356
3.
Experimental Techniques for the Presented Theory
358
4.
Determination of Extraction Constant and its Comparison
with CCST Affinity Constant Ratios
361
5.
Analytical Methods Used for the CCST Verification
363
6.
Transferability of the Values of Affinity Constant Ratios
364
References
364
9.
The CCST in Solvent Extraction of Acids
by Amine-Based Extractants
367
1.
Introduction
367
2.
Acid-Amine Systems in the CCST Interpretation
372
3.
The Systems with Active Solvent as an Additive
381
4.
Experimental Application of the CCST in Carboxylic
Acids Extraction
384
5.
Summarizing Remarks
395
References
397
Contents
10.
Competitive
Complexation/Solvation
Theory
in
Metal
Solvent
Extraction
399
1.
Introduction
399
2.
CCST Basic Statements
400
3.
Mathematical Supplement for the CCST in Metal
Extraction
415
4.
Experimental Verification of the CCST Approach
423
5.
Summarizing Remarks
427
References
428
11.
Final Remarks on the Competitive Complexation/
Solvation Theory of Solvent Extraction
and its Application
433
Part III
Modern and Future Trends in Fundamentals
and Applications of Solvent Extraction
12.
Modern and Future Trends in Fundamentals
of Solvent Extraction
439
1.
Introduction
439
2.
Novel Molecular Models Theoretical Approach
440
3.
Low Energy Reactions Measurement
442
4.
Expected Advances in Kinetics Studies
442
5.
Supramolecular
(SUPRAS)
Theoretical Approach
443
References
449
13.
Advances in Development of Solvents
for Liquid-Liquid Extraction
451
1.
Introduction
452
2.
Organic Solvents
453
3.
Water as a Solvent
457
4.
Renewable Water-Based Solvents
458
5.
Ionic Liquids as Solvents for Extraction
465
6.
Amphiphilic Compounds (Supramolecules) as Solvents
in Solvent Extraction
467
7.
Extraction by
Microemulsion 471
8.
Recovery of Reagents
474
9.
Future Trends in the Development of New Solvents
475
10.
Concluding Remarks
477
References
478
Contents
14.
Recent
Advances in Solvent Extraction Processes
and Techniques
483
1.
Introduction
484
2.
Equipment Design and Scale-Up Considerations
485
3.
Supercritical Fluid Extraction
486
4.
Subcriticai
Water Extraction
493
5.
Aqueous Two-Phase Systems
498
6.
Extraction Processes with Ionic Liquids
499
7.
Liquid Membrane and
Nondispersive,
Membrane-Based
Solvent Extraction Techniques
501
8.
Supramolecular-Based Extraction Techniques
504
9.
Solid-Liquid Extraction Systems
511
10.
Assisted Solvent Extraction
513
11.
Extraction of Gas in Analytical Applications
514
References
515
Appendix
525
Index
539
|
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| indexdate | 2024-07-10T00:17:47Z |
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| language | English |
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| physical | XV, 555 S. Ill., graph. Darst. |
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| spelling | Kislik, Vladimir S. Verfasser aut Solvent extraction classical and novel approaches Vladimir S. Kislik 1. ed. Amsterdam [u.a.] Elsevier 2012 XV, 555 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Solvent extraction Flüssig-Flüssig-Extraktion (DE-588)4113583-0 gnd rswk-swf Flüssig-Flüssig-Extraktion (DE-588)4113583-0 s DE-604 Digitalisierung UB Bayreuth - ADAM Catalogue Enrichment application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024996945&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Kislik, Vladimir S. Solvent extraction classical and novel approaches Solvent extraction Flüssig-Flüssig-Extraktion (DE-588)4113583-0 gnd |
| subject_GND | (DE-588)4113583-0 |
| title | Solvent extraction classical and novel approaches |
| title_auth | Solvent extraction classical and novel approaches |
| title_exact_search | Solvent extraction classical and novel approaches |
| title_full | Solvent extraction classical and novel approaches Vladimir S. Kislik |
| title_fullStr | Solvent extraction classical and novel approaches Vladimir S. Kislik |
| title_full_unstemmed | Solvent extraction classical and novel approaches Vladimir S. Kislik |
| title_short | Solvent extraction |
| title_sort | solvent extraction classical and novel approaches |
| title_sub | classical and novel approaches |
| topic | Solvent extraction Flüssig-Flüssig-Extraktion (DE-588)4113583-0 gnd |
| topic_facet | Solvent extraction Flüssig-Flüssig-Extraktion |
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