NMR in organometallic chemistry:
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2012
|
| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | XIV, 392 S. Ill., graph. Darst. |
| ISBN: | 9783527330133 3527330135 |
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MARC
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Record in the Search Index
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| adam_text |
IMAGE 1
V I I
CONTENTS
PREFACE X I
ABBREVIATIONS X I I I
1 INTRODUCTION 1
REFERENCES 5
2 ROUTINE MEASURING A N D RELAXATION 7
2.1 GETTING STARTED 7
2.2 RELAXATION 9
2.2.1 D I P O L E - D I P O L E RELAXATION 12
2.2.2 CHEMICAL SHIFT ANISOTROPY 15
2.2.3 P A S S I N G C O M M E N T S 16
2.2.4 USEFUL TIPS 16
REFERENCES 17
3 COSY A N D H M Q C 2-D SEQUENCES 19
3.1 TACTICS 19
3.2 COSY 20
3.3 H M Q C A N D H M B C 21
3.3.1 M E T H O D S 21
3.3.2 O N E - B O N D 2-D 1 3 C , ' H CORRELATIONS 22
3.3.3 O N E - B O N D 2-D 15N,1 H CORRELATIONS 2 5
3.3.4 TWO A N D T H R E E LONG-RANGE B O N D 1 3 C , 1 H CORRELATIONS 26
3.3.5 X, 1 H CORRELATIONS 31
REFERENCES 36
4 O V E R H A U S E R EFFECTS A N D 2-D NOESY 3 9
4.1 BACKGROUND 39
4.2 A S S I G N I N G SIGNALS VIA NOES A N D G E N E R A L APPLICATIONS
4 0
4.3 X / H O V E R H A U S E R EFFECTS 41
4.4 2-D NOESY 43
4.5 HOESY 5 0
HTTP://D-NB.INFO/1016558546
IMAGE 2
VIII C O N T E N T S
4.6 METAL COMPLEXES A N D NOES. ROESY VS NOESY 51
REFERENCES 54
5 DIFFUSION CONSTANTS VIA NMR M E A S U R E M E N T S 5 5
REFERENCES 60
6 CHEMICAL SHIFTS 63
6.1 ' H N M R 64
6.1.1 ANISOTROPIC EFFECTS 6 4
6.1.2 HYDRIDES 6 7
6.1.3 MOLECULAR H 2 A N D R | 2 - X - H - M COMPLEXES W I T H X = C, SI,
A N D H 72
6.1.4 A - B O U N D ALKYL G R O U P S 73
6.1.5 _ R| 2, RI4-01EFIN, A N D RI6-ARENE PROTON CHEMICAL SHIFTS 74
6.1.6 ALLYL A N D C P A N I O N S 79
6.1.7 C A R B E N E LIGANDS 83
6.2 I N T R O D U C T I O N TO HEAVY A T O M N M R 84
6.3 13C 8 7
6.3.1 ER-BOUND ALKYL, ARYL, A N D ALKYNYL COMPLEXES 8 9
6.3.2 IT-BOUND OLEFIN COMPLEXES 99
6.3.3 ACETYLENE COMPLEXES 109
6.3.4 ALLYL A N D C P COMPLEXES 111
6.3.5 CARBONYL COMPLEXES 119
6.3.6 CARBENES, CARBYNES, A N D RELATED COMPLEXES 125
6.3.7 N-HETEROCYCLIC C A R B E N E S (NHCS) 130
6.4 1 5 N N M R 134
6.5 1 9 F N M R 146
6.6 3 1 P N M R 155
6.7 TRANSITION METALS 179
REFERENCES 196 F U R T H E R READING 206
7 COUPLING C O N S T A N T S 207
7.1 BACKGROUND 207
7.2 ONE-BOND .INTERACTIONS 208
7.3 A SHORT 1 9 F EXCURSION 216
1.4 APPLICATIONS INVOLVING 1 J 219
7.5 \ / ( H , D ) A N D MOLECULAR H Y D R O G E N COMPLEXES 220
7.6 \ / ( C , H ) I N /? 2-C-H-* M COMPLEXES: AGOSTIC INTERACTIONS 2 2 2
U R E M O T E AGOSTIC BONDS 226
7.8 V(SI,H) I N ; 2-SI-H- * M COMPLEXES 226
7.9 T R A N S INFLUENCE A N D XJ 230
7.10 TWO- A N D THREE-BOND / - V A L U E S 238
7.10.1 ROUTINE 1 H C O U P L I N G C O N S T A N T S 242
7.10.2 T W O A N D THREE-BOND 3 1 P COUPLING C O N S T A N T S W I T H :
H 246
7.10.3 A N EXCURSION INVOLVING 3 1 P A N D 13C J-VALUES 249
IMAGE 3
CONTENTS IX
7.10.4 SECOND-ORDER EFFECTS I N 13C SPECTRA O F B I S P H O S P H I N E
COMPLEXES 251
7.10.5 . T H E GEOMETRIC D E P E N D E N C E O F ^ ( L ' - M - L 2 ) 254
7.10.6 ( 31P-M-1 H ) 255
7.10.7 ^ ( X ^ H ) 256
7.10.8 2/(31P,31P) 258
7.10.9 2J(31P,13C) 264
7.10.10 2/(31P,19F) 266
7.10.10.1 2/(31 P,X) 2 6 7
REFERENCES 273
F U R T H E R READING 2 7 7
8 DYNAMICS 279
8.1 VARIABLE T E M P E R A T U R E 2 8 0
8.2 LINE SHAPE ANALYSIS 284
8.3 MAGNETIZATION T R A N S F E R 291
8.4 TWO-DIMENSIONAL N M R A N D CHEMICAL EXCHANGE 296
REFERENCES 308
9 PREFACE T O T H E PROBLEMS 311
10 ORGANOMETALLIC INTRODUCTION 313
10.1 OXIDATIVE ADDITION 313
10.2 MIGRATORY INSERTION (OR INTRAMOLECULAR NUCLEOPHILIC ATTACK) 314
10.3 EXTERNAL NUCLEOPHILIC ATTACK 314
10.4 BETA-HYDROGEN ELIMINATION 315
10.5 REDUCTIVE ELIMINATION 3 1 5
10.6 SYNTHESIS O F T R A N S I T I O N M E T A L - H Y D R I D E
COMPLEXES 316
10.7 SYNTHESIS O F T R A N S I T I O N METAL ALKYL COMPLEXES 316
10.8 SYNTHESIS O F T R A N S I T I O N METAL CARBONYL COMPLEXES 317
10.9 SYNTHESIS O F TRANSITION METAL OLEFIN COMPLEXES 317
10.10 SYNTHESIS O F TRANSITION METAL C A R B E N E COMPLEXES 318
11 NMR PROBLEMS 319
11.1 T H R E E S A M P L E P R O B L E M S 319
11.2 N M R P R O B L E M S 323
12 SOLUTIONS T O T H E PROBLEMS A N D C O M M E N T S 361
INDEX 389 |
| any_adam_object | 1 |
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| spelling | Pregosin, Paul S. Verfasser aut NMR in organometallic chemistry Paul S. Pregosin Weinheim Wiley-VCH 2012 XIV, 392 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier NMR-Spektroskopie (DE-588)4075421-2 gnd rswk-swf Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Metallorganische Verbindungen (DE-588)4038906-6 s NMR-Spektroskopie (DE-588)4075421-2 s DE-604 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3902526&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024965193&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Pregosin, Paul S. NMR in organometallic chemistry NMR-Spektroskopie (DE-588)4075421-2 gnd Metallorganische Verbindungen (DE-588)4038906-6 gnd |
| subject_GND | (DE-588)4075421-2 (DE-588)4038906-6 |
| title | NMR in organometallic chemistry |
| title_auth | NMR in organometallic chemistry |
| title_exact_search | NMR in organometallic chemistry |
| title_full | NMR in organometallic chemistry Paul S. Pregosin |
| title_fullStr | NMR in organometallic chemistry Paul S. Pregosin |
| title_full_unstemmed | NMR in organometallic chemistry Paul S. Pregosin |
| title_short | NMR in organometallic chemistry |
| title_sort | nmr in organometallic chemistry |
| topic | NMR-Spektroskopie (DE-588)4075421-2 gnd Metallorganische Verbindungen (DE-588)4038906-6 gnd |
| topic_facet | NMR-Spektroskopie Metallorganische Verbindungen |
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