Materials thermodynamics: with emphasis on chemical approach
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
New Jersey [u.a.]
World Scientific
2012
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis Klappentext |
| Beschreibung: | Frühere Ausg. u.d.T.: Lee, Hae-Geon: Chemical thermodynamics for metals and materials |
| Beschreibung: | XI, 461 S. graph. Darst. CD-ROM (12 cm) |
| ISBN: | 9814368059 9789814368056 |
Internformat
MARC
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Datensatz im Suchindex
| _version_ | 1804149056705921024 |
|---|---|
| adam_text | Contents
Preface
vii
1.
Introduction
1
1.1
Energy
2
1.2
Heat and Work
4
2.
The First Law of Thermodynamics
7
2.1
The First Law of Thermodynamics
7
2.2
Enthalpy and heat Capacity
15
2.3
Enthalpy Change
23
3.
The Second Law of Thermodynamics
27
3.1
Grades of Energy
27
3.2
Heat Engines and Entropy
32
3.3
Energy Dispersion and Entropy
53
3.4
Equilibrium Criterion and Entropy
62
3.5
Entropy Changes and Entropy Productions
73
3.6
Statements of the Second Law of Thermodynamics
94
4.
Free Energy Functions
97
4.1
Energy Functions
97
4.2
Helmholtz Energy
99
4.3
Gibbs Energy
101
4.4
Effect of Pressure on Gibbs Energy Change
104
4.5
Effect of Temperature on Gibbs Energy Change
106
4.6
Some Useful Equations
107
5.
The Third Law of Thermodynamics 111
5.1
Statements of the Third Law 111
5.2
Corollaries to the Third Law
112
5.3
Absolute Entropies
115
χ
Materials
Thermodynamics with Emphasis on Chemical Approach
5.4
Molecular Interpretation
116
6.
Enthalpy and Gibbs Energy Changes
119
6.1
Standard States
119
6.2
Heat of Formation
120
6.3
Heat of Reaction
122
6.4
Adiabatic Flame Temperature
127
6.5
Gibbs Energy Changes
129
7.
Behavior of Gases
133
7.1
Ideal Gases
133
7.2
Real Gases and
Fugacity
136
8.
Thermodynamic Functions of Mixing
141
8.1
Activity
141
8.2
Partial Properties
148
9.
Behavior of Solutions
157
9.1
Ideal Solutions
157
9.2
Non-ideal Solutions and Excess Properties
161
9.3
Dilute Solutions
167
9.4
Gibbs-Duhem Equation
171
9.5
Solution Models
175
10.
Reaction Equilibria
185
10.1
Equilibrium Constants
185
10.2
Criteria of Reaction Equilibrium
190
10.3
Effect of Temperature on Equilibrium Constant
201
10.4
Effect of Pressure on Equilibrium Constant
203
10.5
Le
Chatelier s Principle
205
10.6
Alternative Standard States
207
10.7
Interaction Coefficients
215
10.8
Ellingham Diagram
218
10.9
Adsorption Equilibria
227
11.
Phase Equilibria
239
11.1
Phase rule
239
11.2
Phase Transformations
248
11.3
Phase Equilibria and Gibbs Energies
255
11.4
Influence of Interfaces on Equilibrium
271
12.
Phase Diagrams
287
12.1
One Component (Unary) Systems
287
12.2
Binary Systems
297
12.3
Thermodynamic Models
326
Contents
12.4
Ternary
Systems 335
12.5
Predominance Diagrams
363
13.
Electrochemistry
367
13.1
Basic Electrochemical Concepts
367
13.2
Electrochemical Cell Thermodynamics
370
13.3
Electrochemical Cells and Electrodes
378
13.4
Concentration Cells
390
13.5
Activities in Aqueous Solutions
403
13.6
Solubility Products
411
13.7
Pourbaix Diagrams
416
Appendices
427
Appendix I Heats of formation, standard entropies and heat capacities
429
Appendix II Standard Gibbs energies of formation
436
Appendix III Properties of selected elements
449
Appendix IV Standard half-cell potentials in aqueous solutions
452
Index
455
4ATE
RIA
THERMODYNAMICS
With Emphasis on Chemical Approach
lis
book is the expanded edition of the first
book entitled Chemical Thermodynamics for
Metals and Materials. This new version presents
thermodynamics of materials with emphasis on
the chemical approach, and is thus suitable for
students in materials science and metallurgical
engineering, as well as related fields such as
chemical engineering and physical chemistry.
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| id | DE-604.BV040104725 |
| illustrated | Illustrated |
| indexdate | 2024-07-10T00:16:58Z |
| institution | BVB |
| isbn | 9814368059 9789814368056 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-024961196 |
| oclc_num | 796205021 |
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| owner_facet | DE-703 DE-91G DE-BY-TUM |
| physical | XI, 461 S. graph. Darst. CD-ROM (12 cm) |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | World Scientific |
| record_format | marc |
| spelling | Lee, Hae-Geon Verfasser aut Materials thermodynamics with emphasis on chemical approach Hae-Geon Lee New Jersey [u.a.] World Scientific 2012 XI, 461 S. graph. Darst. CD-ROM (12 cm) txt rdacontent n rdamedia nc rdacarrier Frühere Ausg. u.d.T.: Lee, Hae-Geon: Chemical thermodynamics for metals and materials Thermochemie (DE-588)4078260-8 gnd rswk-swf Thermodynamik (DE-588)4059827-5 gnd rswk-swf Thermochemie (DE-588)4078260-8 s DE-604 Thermodynamik (DE-588)4059827-5 s Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024961196&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024961196&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Lee, Hae-Geon Materials thermodynamics with emphasis on chemical approach Thermochemie (DE-588)4078260-8 gnd Thermodynamik (DE-588)4059827-5 gnd |
| subject_GND | (DE-588)4078260-8 (DE-588)4059827-5 |
| title | Materials thermodynamics with emphasis on chemical approach |
| title_auth | Materials thermodynamics with emphasis on chemical approach |
| title_exact_search | Materials thermodynamics with emphasis on chemical approach |
| title_full | Materials thermodynamics with emphasis on chemical approach Hae-Geon Lee |
| title_fullStr | Materials thermodynamics with emphasis on chemical approach Hae-Geon Lee |
| title_full_unstemmed | Materials thermodynamics with emphasis on chemical approach Hae-Geon Lee |
| title_short | Materials thermodynamics |
| title_sort | materials thermodynamics with emphasis on chemical approach |
| title_sub | with emphasis on chemical approach |
| topic | Thermochemie (DE-588)4078260-8 gnd Thermodynamik (DE-588)4059827-5 gnd |
| topic_facet | Thermochemie Thermodynamik |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024961196&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024961196&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
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