High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes: a study of molecular and electronic structure
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| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
Berlin [u.a.]
Springer
2012
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| Series: | Springer Theses
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVIII, 132 S. Ill., graph. Darst. 235 mm x 155 mm |
| ISBN: | 9783642272530 |
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MARC
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Record in the Search Index
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| adam_text | IMAGE 1
CONTENTS
1 INTRODUCTION TO TRIPODAL N-HETEROCYCLIC CAR BENE IRON COMPLEXES 1
1.1 CARBENES 1
1.2 HISTORY O F N-HETEROCYCLIC CARBENES (NHC) AND THEIR APPLICATION 3
1.3 NHC LIGANDS FOR THE STABILIZATION OF LOW AND HIGH OXIDATION STATE
TRANSITION METALS 5
1.4 TYPES OF TRIPODAL LIGAND ENVIRONMENTS 6
1.4.1 OVERVIEW O F TRIPODAL LIGANDS 6
1.4.2 TRIPODAL N-HETEROCYCLIC CARBENE LIGANDS 8
1.5 HIGH-VALENT IRON SPECIES: INTERMEDIATES IN ENZYMATIC REACTIONS AND
THE HABER-BOSCH PROCESS 9
1.6 OBJECTIVES 10
1.7 SUMMARY AND ACKNOWLEDGEMENTS 12
REFERENCES 14
2 TIMEN MES : AN IRON NITRIDE COMPLEX 19
2.1 INTRODUCTION 19
2.2 RESULTS AND DISCUSSION 20
2.2.1 GENERAL SYNTHETIC PROCEDURE FOR THE PRECURSORS O F THE T I M E N R
SYSTEM 20
2.2.2 THE TIMEN MCS LIGAND AND ITS COORDINATION TO IRON: SYNTHESIS
TOWARDS AN ELUSIVE IRON NITRIDE COMPLEX. . . . 21 2.3 CONCLUSION 4 0
2.4 EXPERIMENTAL 41
2.4.1 METHODS, PROCEDURES, AND STARTING MATERIALS 41
2.4.2 COMPUTATIONAL DETAILS 4 2
2.4.3 SYNTHETIC DETAILS 43
2.4.4 X-RAY CRYSTAL STRUCTURE DETERMINATION DETAILS 45
REFERENCES 50
X I
HTTP://D-NB.INFO/1017314551
IMAGE 2
X I I C O N T E N T S
3 TIMEN TOL/3 SXYL : UNEXPECTED REACTIVITY RESULTING FROM
MODIFICATIONS O F THE LIGAND PERIPHERY 53
3.1 INTRODUCTION 53
3.2 RESULTS AND DISCUSSION 55
3.3 THEORETICAL CONSIDERATIONS 69
3.4 CONCLUSION 71
3.5 EXPERIMENTAL 74
3.5.1 METHODS, PROCEDURES, AND STARTING MATERIALS 74
3.5.2 COMPUTATIONAL DETAILS 75
3.5.3 SYNTHETIC DETAILS 75
3.5.4 X-RAY CRYSTAL STRUCTURE DETERMINATION DETAILS 81
REFERENCES 82
4 TIMEN 3 5CF3 : HYBRID SYSTEM CAPABLE O F CYCLOMETALLATION AND
NITRIDE INSERTION 85
4.1 INTRODUCTION 85
4.2 RESULTS AND DISCUSSION 86
4.3 CONCLUSION 92
4.4 EXPERIMENTAL 93
4.4.1 METHODS, PROCEDURES, AND STARTING MATERIALS 93
4.4.2 SYNTHETIC DETAILS 9 4
4.4.3 X-RAY CRYSTAL STRUCTURE DETERMINATION DETAILS 9 6
REFERENCES 100
5 PHB( BU IM)7: SYNTHESIS, STRUCTURE, AND REACTIVITY OF AN IRON (V)
NITRIDE 101
5.1 INTRODUCTION 101
5.2 RESULTS AND DISCUSSION 102
5.3 CONCLUSION 112
5.4 EXPERIMENTAL 112
5.4.1 METHODS, PROCEDURES, AND STARTING MATERIALS 112
5.4.2 COMPUTATIONAL DETAILS 113
5.4.3 SYNTHETIC DETAILS 113
5.4.4 X-RAY CRYSTAL STRUCTURE DETERMINATION DETAILS 115
REFERENCES 117
6 PHB( MES IM)J: SPIN CROSSOVER IN A FOUR-COORDINATE IRON(II) COMPLEX
119
6.1 INTRODUCTION 119
6.2 RESULTS AND DISCUSSION 120
6.3 CONCLUSION 125
IMAGE 3
C O N T E N T S X I I I
6.4 EXPERIMENTAL 126
6.4.1 METHODS, PROCEDURES, AND STARTING MATERIALS 126
6.4.2 SYNTHETIC DETAILS 127
6.4.3 MAGNETIC SUSCEPTIBILITY MEASUREMENTS 128
6.4.4 COMPUTATIONAL DETAILS 129
6.4.5 X-RAY CRYSTAL STRUCTURE DETERMINATION DETAILS 130
REFERENCES 132
|
| any_adam_object | 1 |
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| dewey-ones | 547 - Organic chemistry |
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| dewey-search | 547.05621 |
| dewey-sort | 3547.05621 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Thesis Book |
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| illustrated | Illustrated |
| indexdate | 2024-07-10T00:14:51Z |
| institution | BVB |
| isbn | 9783642272530 |
| language | English |
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| physical | XVIII, 132 S. Ill., graph. Darst. 235 mm x 155 mm |
| publishDate | 2012 |
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| spelling | Vogel, Carola Stefanie 1981- Verfasser (DE-588)1014591430 aut High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes a study of molecular and electronic structure Carola S. Vogel Berlin [u.a.] Springer 2012 XVIII, 132 S. Ill., graph. Darst. 235 mm x 155 mm txt rdacontent n rdamedia nc rdacarrier Springer Theses Zugl.: Erlangen-Nürnberg, Univ., Diss., 2011 m.d.T.: Molecular and electronic structure of high- and low-valent tris-N-heterocyclic carbene iron complexes Tripodligand (DE-588)4599922-3 gnd rswk-swf Eisenorganische Verbindungen (DE-588)4151587-0 gnd rswk-swf Heterocyclische Carbene -N (DE-588)7652572-7 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Eisenorganische Verbindungen (DE-588)4151587-0 s Heterocyclische Carbene -N (DE-588)7652572-7 s Tripodligand (DE-588)4599922-3 s DE-604 Erscheint auch als Online-Ausgabe 978-3-642-27254-7 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024810181&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Vogel, Carola Stefanie 1981- High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes a study of molecular and electronic structure Tripodligand (DE-588)4599922-3 gnd Eisenorganische Verbindungen (DE-588)4151587-0 gnd Heterocyclische Carbene -N (DE-588)7652572-7 gnd |
| subject_GND | (DE-588)4599922-3 (DE-588)4151587-0 (DE-588)7652572-7 (DE-588)4113937-9 |
| title | High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes a study of molecular and electronic structure |
| title_auth | High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes a study of molecular and electronic structure |
| title_exact_search | High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes a study of molecular and electronic structure |
| title_full | High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes a study of molecular and electronic structure Carola S. Vogel |
| title_fullStr | High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes a study of molecular and electronic structure Carola S. Vogel |
| title_full_unstemmed | High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes a study of molecular and electronic structure Carola S. Vogel |
| title_short | High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes |
| title_sort | high and low valent tris n heterocyclic carbene iron complexes a study of molecular and electronic structure |
| title_sub | a study of molecular and electronic structure |
| topic | Tripodligand (DE-588)4599922-3 gnd Eisenorganische Verbindungen (DE-588)4151587-0 gnd Heterocyclische Carbene -N (DE-588)7652572-7 gnd |
| topic_facet | Tripodligand Eisenorganische Verbindungen Heterocyclische Carbene -N Hochschulschrift |
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