Metal-fluorocarbon based energetic materials:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2012
|
| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | XVIII, 342 S. Ill., graph. Darst. 24 mm x 17 mm |
| ISBN: | 352732920X 9783527329205 9783527644186 |
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| 100 | 1 | |a Koch, Ernst-Christian |d 1968- |e Verfasser |0 (DE-588)1019695714 |4 aut | |
| 245 | 1 | 0 | |a Metal-fluorocarbon based energetic materials |c Ernst-Christian Koch |
| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2012 | |
| 300 | |a XVIII, 342 S. |b Ill., graph. Darst. |c 24 mm x 17 mm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 650 | 0 | 7 | |a Energetisches Material |0 (DE-588)7643045-5 |2 gnd |9 rswk-swf |
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| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe, PDF |z 978-3-527-64420-9 |
| 856 | 4 | 2 | |m X:MVB |q text/html |u http://deposit.dnb.de/cgi-bin/dokserv?id=3870445&prov=M&dok_var=1&dok_ext=htm |3 Inhaltstext |
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| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-024795741 | |
Record in the Search Index
| _version_ | 1805146241211826176 |
|---|---|
| adam_text |
IMAGE 1
VII
CONTENTS
FOREWORD XIII PREFACE XV ACKNOWLEDGMENT XVII
1 INTRODUCTION TO PYROLANTS 1
REFERENCES 3
2 HISTORY 6
2.1 ORGANOMETALLIC BEGINNING 6
2.2 EXPLOSIVE & OBSCURANT PROPERTIES 8 2.3 RISE OF FLUOROCARBONS 10
2.4 ROCKETS FIRED AGAINST AIRCRAFT 13 2.5 METAL/FLUOROCARBON PYROLANTS
15 REFERENCES 17 FURTHER READING 19
3 PROPERTIES OF FLUOROCARBONS 20
3.1 POLYTETRAFLUOROETHYLENE (PTFE) 20 3.2 POLYCHLOROTRIFLUOROETHYLENE
(PCTFE) 22 3.3 POLYVINYLIDENE FLUORIDE (PVDF) 24 3.4 POLYCARBON
MONOFLUORIDE (PMF) 25
3.5 VINYLIDENE FLUORIDE-HEXAFLUOROPROPENE COPOLYMER 27 3.5.1 LFC-1 28
3.6 VINYLIDENE FLUORIDE-CHLORORRIFLUOROETHYLENE COPOLYMER 28 3.7
COPOLYMER OF TFE AND VDF 30
3.8 TERPOLYMERS OF TFE, HFP AND VDF 31 3.9 SUMMARY OF CHEMICAL AND
PHYSICAL PROPERTIES OF COMMON FLUOROPOLYMERS 33 REFERENCES 33
4 THERMOCHEMICAL AND PHYSICAL PROPERTIES OF METALS AND THEIR FLUORIDES
36 REFERENCES 41
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1014518083
DIGITALISIERT DURCH
IMAGE 2
VIII CONTENTS
5
5.1 5.2 5.3 5.4 5.5 5.6
5.7 5.8 5.9 5.10 5.11 5.12
5.13 5.14
6 6.1 6.2
7
8 8.1 8.1.1 8.1.2
8.2 8.3 8.4
8.4.1 8.4.2 8.4.2.1 8.4.2.2
8.4.3 8.4.4 8.4.5 8.4.6
8.4.7 8.4.8
REACTIVITY AND THERMOCHEMISTRY OF SELECTED METAL/FLUOROCARBON SYSTEMS 42
LITHIUM 42 MAGNESIUM 45 TITANIUM 47
ZIRCONIUM 52 HAFNIUM 53 NIOB 53 TANTALUM 54
ZINC 55 CADMIUM 56 BORON 57 ALUMINIUM 59
SILICON 63 CALCIUM SILICIDE 64 TIN 65
REFERENCES 66
IGNITION AND COMBUSTION MECHANISM OF MTV 68 IGNITION AND PRE-IGNITION OF
METAL/FLUOROCARBON PYROLANTS 68 MAGNESIUM-GRIGNARD HYPOTHESIS 68
REFERENCES 77
IGNITION OF MTV 80 REFERENCES 85
COMBUSTION 87 MAGNESIUM/TEFLON/VITON 87 PRESSURE EFFECTS ON THE BURN
RATE 87 PARTICLE SIZE DISTRIBUTION AND SURFACE AREA EFFECTS ON THE BURN
RATE 88
POROSITY 95 BURN RATE DESCRIPTION 96 COMBUSTION OF METAL-FLUOROCARBON
PYROLANTS WITH FUELS OTHER THAN MAGNESIUM 97 MAGNESIUM HYDRIDE 97 ALKALI
AND ALKALINE EARTH METAL 98
LITHIUM 98 MAGNESIUM-ALUMINIUM ALLOY 99 TITAN 99 ZIRCONIUM 102
ZINC 103 BORON 104 MAGNESIUM BORIDE, MGB 2 105 ALUMINIUM 105
IMAGE 3
CONTENTS IIX
8.4.9 SILICON 108
8.4.10 SILICIDES 110
8.4.10.1 DIMAGNESIUM SUICIDE, MG 2 SI 110 8.4.10.2 CALCIUM DISILICIDE
111 8.4.10.3 ZIRCONIUM DISILICIDE 113 8.4.11 TUNGSTEN-ZIRCONIUM ALLOY
113 8.5 UNDERWATER COMBUSTION 1 14
REFERENCES 115
9 SPECTROSCOPY 119
9.1 INTRODUCTION 119
9.2 UV-VIS SPECTRA 120
9.2.1 POLYTETRAFLUOROETHYLENE COMBUSTION 121 9.2.2
MAGNESIUM/FLUOROCARBON PYROLANTS 122 9.2.3 MGH 2 , MGB 2 , MG 3 N 2 , MG
2 SI/MG 3 AL 2 /FLUOROCARBON BASED PYROLANTS 128
9.2.4 SILICON/PTFE BASED PYROLANTS 133 9.2.5 BORON/PTFE/VITON BASED
PYROLANTS 134 9.3 MWIR SPECTRA 135
9.3.1 POLYTETRAFLUOROETHYLENE COMBUSTION 136 9.3.2
MAGNESIUM/FLUOROCARBON COMBUSTION 136 9.3.3 MGH 2 , MGB 2 , MG 3 N 2 ,
MG 2 SI/FLUOROCARBON BASED PYROLANTS 139 9.3.4 SI/FLUOROCARBON BASED
PYROLANTS 140
9.3.5 BORON/PTFE/VITON BASED PYROLANTS 141 9.4 TEMPERATURE DETERMINATION
141 9.4.1 CONDENSED-PHASE TEMPERATURE 142 9.4.2 GAS-PHASE TEMPERATURE
144
REFERENCES 148
10 INFRARED EMITTERS 151
10.1 DECOY FLARES 151
10.2 NONEXPENDABLE FLARES 153 10.2.1 TARGET AUGMENTATION 153 10.2.2
MISSILE TRACKING FLARES 156 10.3 METAL-FLUOROCARBON FLARE COMBUSTION
FLAMES AS SOURCES OF
RADIATION 158
10.3.1 FLAME STRUCTURE AND MORPHOLOGY 160 10.3.2 RADIATION OF MTV 162
10.4 INFRARED COMPOSITIONS 165 10.4.1 INHERENT EFFECTS 166 10.4.1.1
INFLUENCE OF STOICHIOMETRY 166 10.4.2 SPECTRAL FLARE COMPOSITIONS 180
10.4.3 PARTICLE SIZE ISSUES 181 10.4.4 GEOMETRICAL ASPECTS 181 10.5
OPERATIONAL EFFECTS 184
IMAGE 4
X CONTENTS
10.5.1 ALTITUDE EFFECTS 184
10.5.2 WINDSPEED EFFECTS 186 10.6 OUTLOOK 191
REFERENCES 193
11 OBSCURANTS 197
11.1 INTRODUCTION 197
11.2 METAL-FLUOROCARBON REACTIONS IN AEROSOL GENERATION 199 11.2.1
METAL-FLUOROCARBON REACTIONS AS AN EXCLUSIVE AEROSOL SOURCE 200 11.2.2
METAL-FLUOROCARBON REACTIONS TO TRIGGER AEROSOL RELEASE 201 11.2.2.1
METAL-FLUOROCARBON REACTIONS TO TRIGGER SOOT FORMATION 201 11.2.2.2
METAL-FLUOROCARBON REACTIONS TO TRIGGER PHOSPHORUS
VAPORISATION 204 REFERENCES 208
12 IGNITERS 210
REFERENCES 214
13 INCENDIARIES, AGENT DEFEAT, REACTIVE FRAGMENTS AND DETONATION
PHENOMENA 216 13.1 INCENDIARIES 216
13.2 CURABLE FLUOROCARBON RESIN-BASED COMPOSITIONS 217 13.3 DOCUMENT
DESTRUCTION 218
13.4 AGENT DEFEAT 221
13.5 REACTIVE FRAGMENTS 223
13.6 SHOCKWAVE LOADING OF METAL-FLUOROCARBONS AND DETONATION-LIKE
PHENOMENA 229 REFERENCES 232 FURTHER READING 234
14 MISCELLANEOUS APPLICATIONS 235
14.1 SUBMERGED APPLICATIONS 235 14.1.1 UNDERWATER EXPLOSIVES 235 14.1.2
UNDERWATER FLARES 235 14.1.3 UNDERWATER CUTTING TORCH 236 14.2
MINE-DISPOSAL TORCH 238
14.3 STORED CHEMICAL ENERGY 240 14.3.1 HEATING DEVICE 240 14.3.2 STORED
CHEMICAL ENERGY PROPULSION 240
14.4 TRACERS 240
14.5 PROPELLANTS 241
REFERENCES 244
15 SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS 247 15.1 INTRODUCTION 247
IMAGE 5
CONTENTS XI
15.2 MAGNESIUM 249
15.3 SILICON AND SUICIDES 252
REFERENCES 256
16 VAPOUR-DEPOSITED MATERIALS 258 REFERENCES 262
17
18 18.1 18.2 18.3 18.3.1
18.3.1.1 18.3.1.2 18.3.2
18.3.3 18.3.4 18.3.5 18.3.6 18.3.6.1 18.4 18.5 18.6
18.7 18.8 18.8.1 18.8.2
18.8.3 18.8.4
19 19.1 19.2 19.2.1 19.2.2 19.2.3 19.2.4 19.3
19.3.1 19.4 19.4.1
AGEING 264 REFERENCES 270
MANUFACTURE 271 INTRODUCTION 271 TREATMENT OF METAL POWDER 271 MIXING
273 SHOCK GEL PROCESS 273 PROCEDURE A 273
PROCEDURE B 275 CONVENTIONAL MIXING 276 EXPERIMENTAL SUPER SHOCK GEL
PROCESS 276 EXPERIMENTAL DRY MIXING TECHNIQUE 280 EXPERIMENTAL CRYO-N 2
PROCESS 282
EXTRUSION 282 TWIN SCREW EXTRUSION 282 PRESSING 286 CUTTING 289
PRIMING 289 MISCELLANEOUS 289 ACCIDENTS AND PROCESS SAFETY 290 MIXING
290
PRESSING 293 PROCESS ANALYSIS 294 PERSONAL PROTECTION EQUIPMENT (PPE)
294 REFERENCES 296
SENSITIVITY 299 INTRODUCTION 299 IMPACT SENSITIVITY 300 MTV 300
TITANIUM/PTFE/VITON AND ZIRCONIUM/PTFE/VITON 300 METAL-FLUOROCARBON
SOLVENTS 301 VITON AS BINDER IN MG/NANO 3 301 FRICTION AND SHEAR
SENSITIVITY 301
METAL/FLUOROCARBON 303 THERMAL SENSITIVITY 304 MTV 304
IMAGE 6
XII CONTENTS
19.5 ESD SENSITIVITY 305
19.6 INSENSITIVE MUNITIONS TESTING 310 19.6.1 INTRODUCTION 310
19.6.2 COOKOFF 314
19.6.3 BULLET IMPACT 316 19.6.4 SYMPATHETIC REACTION 319 19.6.5 IM
SIGNATURE SUMMARY 320 19.7 HAZARDS POSED BY LOOSE IN-PROCESS MTV CRUMB
AND TNT
EQUIVALENT 321 REFERENCES 323
20 20.1 20.2 20.3
20.3.1 20.3.2 20.3.3
21
TOXIC COMBUSTION PRODUCTS 326 MTV FLARE COMPOSITION 326 OBSCURANT
FORMULATIONS 330 FLUORINE COMPOUNDS 331
HYDROGEN FLUORIDE 331 ALUMINIUM FLUORIDE 331 MAGNESIUM FLUORIDE 332
REFERENCES 332
OUTLOOK 334 REFERENCES 335
INDEX 337 |
| any_adam_object | 1 |
| author | Koch, Ernst-Christian 1968- |
| author_GND | (DE-588)1019695714 |
| author_facet | Koch, Ernst-Christian 1968- |
| author_role | aut |
| author_sort | Koch, Ernst-Christian 1968- |
| author_variant | e c k eck |
| building | Verbundindex |
| bvnumber | BV039937620 |
| classification_rvk | VN 5480 |
| ctrlnum | (OCoLC)779625413 (DE-599)DNB1014518083 |
| dewey-full | 662.2 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 662 - Explosives, fuels & related products |
| dewey-raw | 662.2 |
| dewey-search | 662.2 |
| dewey-sort | 3662.2 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie |
| format | Book |
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| id | DE-604.BV039937620 |
| illustrated | Illustrated |
| indexdate | 2024-07-21T00:26:45Z |
| institution | BVB |
| isbn | 352732920X 9783527329205 9783527644186 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-024795741 |
| oclc_num | 779625413 |
| open_access_boolean | |
| owner | DE-11 DE-19 DE-BY-UBM DE-703 |
| owner_facet | DE-11 DE-19 DE-BY-UBM DE-703 |
| physical | XVIII, 342 S. Ill., graph. Darst. 24 mm x 17 mm |
| publishDate | 2012 |
| publishDateSearch | 2012 |
| publishDateSort | 2012 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Koch, Ernst-Christian 1968- Verfasser (DE-588)1019695714 aut Metal-fluorocarbon based energetic materials Ernst-Christian Koch Weinheim Wiley-VCH 2012 XVIII, 342 S. Ill., graph. Darst. 24 mm x 17 mm txt rdacontent n rdamedia nc rdacarrier Energetisches Material (DE-588)7643045-5 gnd rswk-swf Energetisches Material (DE-588)7643045-5 s DE-604 Erscheint auch als Online-Ausgabe, EPUB 978-3-527-64419-3 Erscheint auch als Online-Ausgabe, MOBI 978-3-527-64421-6 Erscheint auch als Online-Ausgabe, PDF 978-3-527-64420-9 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3870445&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024795741&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Koch, Ernst-Christian 1968- Metal-fluorocarbon based energetic materials Energetisches Material (DE-588)7643045-5 gnd |
| subject_GND | (DE-588)7643045-5 |
| title | Metal-fluorocarbon based energetic materials |
| title_auth | Metal-fluorocarbon based energetic materials |
| title_exact_search | Metal-fluorocarbon based energetic materials |
| title_full | Metal-fluorocarbon based energetic materials Ernst-Christian Koch |
| title_fullStr | Metal-fluorocarbon based energetic materials Ernst-Christian Koch |
| title_full_unstemmed | Metal-fluorocarbon based energetic materials Ernst-Christian Koch |
| title_short | Metal-fluorocarbon based energetic materials |
| title_sort | metal fluorocarbon based energetic materials |
| topic | Energetisches Material (DE-588)7643045-5 gnd |
| topic_facet | Energetisches Material |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3870445&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024795741&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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