Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts: = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren
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| Format: | Thesis Book |
| Language: | English |
| Published: |
2011
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| Subjects: | |
| Online Access: | Volltext https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-28925 Inhaltsverzeichnis |
| Physical Description: | X, 151 S. Ill., graph. Darst. 21 cm |
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MARC
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| 035 | |a (DE-599)DNB1017333610 | ||
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| 100 | 1 | |a Loekman, Soebiakto |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts |b = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren |c vorgelegt von Soebiakto Loekman |
| 246 | 1 | 1 | |a Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren |
| 264 | 1 | |c 2011 | |
| 300 | |a X, 151 S. |b Ill., graph. Darst. |c 21 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 502 | |a Erlangen, Nürnberg, Univ., Diss., 2011 | ||
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 776 | 0 | 8 | |i Erscheint auch als |n Online-Ausgabe |o urn:nbn:de:bvb:29-opus-28925 |
| 856 | 4 | |u https://open.fau.de/handle/openfau/1940 |x Verlag |z kostenfrei |3 Volltext | |
| 856 | 4 | |u https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-28925 |x Resolvingsystem | |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024583565&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 912 | |a ebook | ||
| 999 | |a oai:aleph.bib-bvb.de:BVB01-024583565 | ||
Record in the Search Index
| _version_ | 1804148620395544576 |
|---|---|
| adam_text | CONTENTS
ACKNOWLEDGMENT
.......................................................................................................................
V
KURZFASSUNG
.............................................................................................................................
VII
ABSTRACT
.....................................................................................................................................
IX
1
INTRODUCTION
.....................................................................................................................
1
2
THEORY
...........................................................................................................................
3
2.1
PROPENE
.........................................................................................................................
3
2.2
METATHESIS
.....................................................................................................................
7
2.2.1
OVERVIEW........................................................................................................................
7
2.2.2
HETEROGENEOUS
METATHESIS
CATALYSTS
............................................................................
8
2.2.3
HOMOGENEOUS
METATHESIS
CATALYSTS
..............................................................................
9
2.2.4
METATHESIS
MECHANISM
...............................................................................................
12
2.2.5
CATALYST
DEACTIVATION
MECHANISMS
..............................................................................
14
2.2.6
THERMODYNAMIC
ASPECTS
OF
METATHESIS
......................................................................
18
2.2.7
IMMOBILIZATION
OF
HOMOGENEOUS
METATHESIS
CATALYSTS
................................................
22
2.2.7.1
AQUEOUS
MULTIPHASE
SYSTEMS
.....................................................................................
22
2.2.7.2
IONIC
LIQUID
MULTIPHASE
SYSTEMS
..................................................................................
24
2.2.7.3
SOLID
SUPPORTS
..............................................................................................................
28
2.3
SUPPORTED
IONIC
LIQUID
PHASE
(SILP)
TECHNOLOGY
.......................................................
35
2.3.1
CONCEPT
AND
APPLICATIONS
............................................................................................
35
2.3.2
SILP
METATHESIS...........................................................................................................
37
3.
EXPERIMENTAL................................................................................................................
39
3.1
.
SILP
CATALYST
PREPARATION
............................................................................................
39
3.2
BATCH
AUTOCLAVE
EXPERIMENTS
......................................................................................
40
3.3
CONTINUOUS
GAS-PHASE
EXPERIMENTS
...........................................................................
41
3.4
THERMOGRAVIMETRY
.......................................................................................................
49
4.
RESULTS
AND
DISCUSSION
...............................................................................................
50
4.1
BATCH
AUTOCLAVE
EXPERIMENTS
......................................................................................
50
4.2
CONTINUOUS
FIXED-BED
GAS-PHASE
EXPERIMENTS
WITH
SILP
CATALYST
...............................
55
4.2.1
REPRODUCIBILITY
..............................................................................................................
55
4.2.2
INFLUENCE
OF
AIR
AND
MOISTURE
........................................................................................
56
4.2.3
INFLUENCE
OF
FEEDSTOCK
PURITY
........................................................................................
57
4.2.4
ACTIVITY
OF
NON-SUPPORTED
CATALYST
................................................................................
58
4.2.5
TEMPERATURE
VARIATION
..................................................................................................
59
4.2.6
SUPPORT
MATERIAL
VARIATION
............................................................................................
63
4.2.7
VARIATION
OF
CATALYST
PRECURSOR
......................................................................................
66
4.2.8
VARIATION
OF
IONIC
LIQUID
.................................................................................................
70
4.2.8.1
ANION
INFLUENCE
............................................................................................................
70
4.2.8.2
CATION
INFLUENCE
...........................................................................................................
73
4.2.8.3
VARIATION
OF
IONIC
LIQUID
LOADING
.....................................................................................
80
4.2.8.4
ISOMERIZATION
BEHAVIOUR
OF
GRUBBS
CATALYSTS
...............................................................
84
4.3
CONTINUOUS
PHYSISORBED
RU-GRUBBS
CATALYST
EXPERIMENTS
.........................................
89
4.3.1
SCREENING
OF
CATALYST
PRECURSORS
.................................................................................
89
4.3.2
VARIATION
OF
SUPPORT
MATERIAL
........................................................................................
92
4.3.3
VARIATION
OF
PROPENE
PARTIAL
PRESSURE
..........................................................................
93
4.3.4
VARIATION
OF
RESIDENCE
TIME
...........................................................................................
96
4.4
CATALYST
CONDITIONING
STUDIES
........................................................................................
98
4.4.1
CATALYST
WITHOUT
IONIC
LIQUID
FILM
....................................................................................
98
4.4.1.1
NITROGEN
TREATMENT
PRIOR
TO
REACTION
.............................................................................
98
4.4.1.2
VACUUM
TREATMENT
DURING
REACTION
..............................................................................
99
4.4.2
CATALYST
WITH
IONIC
LIQUID
CONTENT
................................................................................
100
4.4.2.1
NITROGEN
TREATMENT
PRIOR
TO
REACTION
...........................................................................
100
4.4.2.2
NITROGEN
TREATMENT
DURING
REACTION
............................................................................
101
4.4.2.3
VACUUM
TREATMENT
DURING
REACTION
............................................................................
102
4.4.2.4
ETHENE
TREATMENT
PRIOR
TO
REACTION
..............................................................................
103
4.4.2.5
ETHENE
TREATMENT
DURING
REACTION
...............................................................................
107
II
4.4.3
THERMAL
STABILITY
OF
THE
SILP
SYSTEM
.........................................................................
108
4.4.4
CATALYST
WITH
ORGANIC
LIQUID
........................................................................................
111
5.
CONCLUSION
AND
OUTLOOK
.............................................................................................
113
6.
REFERENCES
................................................................................................................
117
7.
APPENDIX
....................................................................................................................
120
7.1
THERMODYNAMIC
ASPECTS
OF
METATHESIS
....................................................................
120
7.2
CONTINUOUS
GAS-PHASE
REACTOR
SETUP
.........................................................................
125
7.3
OVERVIEW
OF
MFC
CORRECTION
FACTORS
..........................................................................
129
7.4
PRESSURE
DROP
CALCULATION
..........................................................................................
138
7.5
SYNTHESIS
OF
VINYL-FUNCTIONALIZED
IONIC
LIQUIDS
...........................................................
139
7.5.1
SYNTHESIS
OF
[BVIM][BF
4
]
...........................................................................................
140
7.5.2
SYNTHESIS
OF
[BVIM][NTF
2
]
..........................................................................................
143
7.5.3
VISCOSITY
MEASUREMENTS
OF
[BVIM][BF
4
]
AND
[BVIM][NTF
2
]
.......................................
146
7.5.4
DIFFERENTIAL
SCANNING
CALORIMETRY
OF
[BVIM][NTF
2
]
......................................................
148
LIST
OF
ABBREVIATIONS
..............................................................................................................
149
III
|
| any_adam_object | 1 |
| author | Loekman, Soebiakto |
| author_facet | Loekman, Soebiakto |
| author_role | aut |
| author_sort | Loekman, Soebiakto |
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| ctrlnum | (OCoLC)772867353 (DE-599)DNB1017333610 |
| format | Thesis Book |
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| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV039735778 |
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| indexdate | 2024-07-10T00:10:02Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-024583565 |
| oclc_num | 772867353 |
| open_access_boolean | 1 |
| owner | DE-384 DE-473 DE-BY-UBG DE-703 DE-1051 DE-824 DE-29 DE-12 DE-91 DE-BY-TUM DE-19 DE-BY-UBM DE-1049 DE-92 DE-739 DE-898 DE-BY-UBR DE-355 DE-BY-UBR DE-706 DE-20 DE-1102 DE-29T |
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| physical | X, 151 S. Ill., graph. Darst. 21 cm |
| psigel | ebook |
| publishDate | 2011 |
| publishDateSearch | 2011 |
| publishDateSort | 2011 |
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| spelling | Loekman, Soebiakto Verfasser aut Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren vorgelegt von Soebiakto Loekman Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren 2011 X, 151 S. Ill., graph. Darst. 21 cm txt rdacontent n rdamedia nc rdacarrier Erlangen, Nürnberg, Univ., Diss., 2011 (DE-588)4113937-9 Hochschulschrift gnd-content Erscheint auch als Online-Ausgabe urn:nbn:de:bvb:29-opus-28925 https://open.fau.de/handle/openfau/1940 Verlag kostenfrei Volltext https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-28925 Resolvingsystem DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024583565&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Loekman, Soebiakto Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren |
| subject_GND | (DE-588)4113937-9 |
| title | Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren |
| title_alt | Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren |
| title_auth | Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren |
| title_exact_search | Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren |
| title_full | Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren vorgelegt von Soebiakto Loekman |
| title_fullStr | Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren vorgelegt von Soebiakto Loekman |
| title_full_unstemmed | Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren vorgelegt von Soebiakto Loekman |
| title_short | Cross-metathesis of propene using supported ionic liquid phase (SILP) catalysts |
| title_sort | cross metathesis of propene using supported ionic liquid phase silp catalysts kreuzmetathese von propen mittels supported ionic liquid phase silp katalysatoren |
| title_sub | = Kreuzmetathese von Propen mittels Supported-ionic-liquid-phase-(SILP)-Katalysatoren |
| topic_facet | Hochschulschrift |
| url | https://open.fau.de/handle/openfau/1940 https://nbn-resolving.org/urn:nbn:de:bvb:29-opus-28925 http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024583565&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT loekmansoebiakto crossmetathesisofpropeneusingsupportedionicliquidphasesilpcatalystskreuzmetathesevonpropenmittelssupportedionicliquidphasesilpkatalysatoren AT loekmansoebiakto kreuzmetathesevonpropenmittelssupportedionicliquidphasesilpkatalysatoren |