Terpyridine-based materials: for catalytic, optoelectronic and life science applications
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| Main Authors: | , , |
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| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2011
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIX, 522 S. Ill., graph. Darst. |
| ISBN: | 9783527330386 9783527639649 9783527639632 9783527639656 9783527639625 |
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Record in the Search Index
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| adam_text | IMAGE 1
CONTENTS
PREFACE IX LIST OF ABBREVIATIONS XI
1 INTRODUCTION 1
2 SYNTHESIS, PROPERTIES, AND APPLICATIONS OF FUNCTIONALIZED
2,2 :6 ,2 -TERPYRIDINES 13 2.1 INTRODUCTION 13
2.2 BASIC SYNTHETIC STRATEGIES 13
2.2.1 RING-ASSEMBLY METHODOLOGIES 14 2.2.2 CROSS-COUPLING PROCEDURES 18
2.3 SYNTHESIS AND PROPERTIES OF 2,2 :6 ,2 -TERPYRIDINE DERIVATIVES 19
2.3.1 4 -SUBSTIRUTED 2,2 :6 ,2 -TERPYRIDINOXY DERIVATIVES 19 2.3.2
MISCELLANEOUS 4 -SUBSTITUTED 2,2 :6 ,2 -TERPYRIDINE DERIVATIVES 24 2.4
2,2 :6 ,2 -TERPYRIDINES SYMMETRICALLY SUBSTITUTED ON THE OUTER
PYRIDINE RINGS 28
2.5 ZIESSEL-TYPE 2,2 :6 ,2 -TERPYRIDINES 31 2.6 KROEHNKE-TYPE
2,2 :6 ,2 -TERPYRIDINES 38 2.7 MISCELLANEOUS TERPYRIDINE-ANALOGOUS
COMPOUNDS 49 2.7.1 RIGID U- AND S-SHAPED TERPYRIDINES 49 2.7.2
FIVE-MEMBERED N-HETEROCYDES REPLACING THE OUTER PYRIDINE RINGS 51 2.7.3
THE SWEDISH CONCEPT: EXPANDED BITE ANGLES IN TRIDENTATE
LIGANDS 53
3 CHEMISTRY AND PROPERTIES OF TERPYRIDINE TRANSITION METAL ION COMPLEXES
65 3.1 INTRODUCTION 65
3.2 BASIC SYNTHETIC STRATEGIES AND CHARACTERIZATION TOOLS 66 3.3 RU AND
OS COMPLEXES 73
TERPYRIDINE-BASED MATERIALS: FOR CATALYTIC, OPTOELECTRONIC AND LIFE
SCIENCE APPLICATIONS, FIRST EDITION. ULRICH S. SCHUBERT, ANDREAS WINTER,
AND GEORGE R. NEWKOME. 2011 WILEY-VCH VERLAG GMBH & CO. KGAA,
WEINHEIM. PUBLISHED 2011 BY WILEY-VCH VERLAG GMBH & CO. KGAA
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1011200724
DIGITALISIERT DURCH
IMAGE 2
VI I CONTENTS
3.3.1 SYNTHESIS OF RU AND OS BIS(TERPYRIDINE) COMPLEXES 73
3.3.2 RU 11 IONS AND TERPYRIDINE LIGANDS - A HAPPY MARRIAGE? 75 3.3.2.1
PHOTOPHYSICAL PROPERTIES 75 3.3.2.2 MONONUDEAR RU 11 BIS(TERPYRIDINE)
COMPLEXES 76 3.3.2.3 OLIGONUDEAR COMPLEXES CONTAINING RU N /OS
BIS (TERPYRIDINE) UNITS 89 3.3.2.4 DENDRITIC AND STAR-SHAPED SYSTEMS
CONTAINING RU 11 BIS(TERPYRIDINE) UNITS 102
3.4 IRIDIUM(III) COMPLEXES WITH TERPYRIDINE LIGANDS 107 3.5 PLATINUM(II)
MONO(TERPYRIDINE) COMPLEXES 115
4 METALLO-SUPRAMOLECULAR ARCHITECTURES BASED ON TERPYRIDINE COMPLEXES
129 4.1 INTRODUCTION 129
4.2 TERPYRIDINE-CONTAINING METALLO-MACROCYDES 230 4.3 THE HETTAP CONCEPT
148
4.4 RACKS AND GRIDS 154
4.5 HELICATES 171
4.6 ROTAXANES AND CATENANES 177
4.7 MISCELLANEOUS STRUCTURES 182 4.7.1 CYCLODEXTRIN DERIVATIVES 182
4.7.2 OTHER ASSEMBLIES 185
5 ^-CONJUGATED POLYMERS INCORPORATING TERPYRIDINE METAL COMPLEXES 199
5.1 INTRODUCTION 199
5.2 METALLO-SUPRAMOLECULAR POLYMERIZATION 200 5.3 METALLOPOLYMERS BASED
ON 7C-CONJUGATED BIS (TERPYRIDINE)S 204 5.3.1 POLYMERIZATION BY
TRANSITION METAL ION COORDINATION 204
5.3.2 SELF-ASSEMBLY OF METALLOPOLYMERS 212 5.3.3 CHIRAL METALLOPOLYMERS
219 5.3.4 NON-CLASSICAL METALLOPOLYMERS 220 5.3.5 POLYMERIZATION USING
THE COMPLEX FIRST METHOD 224 5.4 MAIN-CHAIN METALLOPOLYMERS BASED ON
TERPYRIDINE-FUNCTIONALIZED K-CONJUGATED POLYMERS 229
6 FUNCTIONAL POLYMERS INCORPORATING TERPYRIDINE-METAL COMPLEXES 241 6.1
INTRODUCTION 241
6.2 POLYMERS WITH TERPYRIDINE UNITS IN THE SIDE-CHAIN 242 6.2.1
MATERIALS BASED ON FLEXIBLE ORGANIC POLYMERS 242 6.2.2 MATERIALS BASED
ON JT-CONJUGATED POLYMERS 257
IMAGE 3
CONTENTS VII
6.3 POLYMERS WITH TERPYRIDINES WITHIN THE POLYMER BACKBONE 262
6.3.1 POLYMERS FROM ORGANIC SMALL-MOLECULE BUILDING BLOCKS 263 6.3.2
CHAIN-EXTENDED POLYMERS FROM POLYMERIC BUILDING BLOCKS 269 6.3.3
MONOTOPIC MACROLIGANDS BY END-GROUP FUNCTIONALIZATION 272 6.3.4
FUNCTIONAL TERPYRIDINE-CONTAINING INITIATORS 277 6.3.4.1 INITIATION OF
IONIC POLYMERIZATION REACTIONS 277 6.3.4.2 INITIATION OF CONTROLLED
RADICAL POLYMERIZATION REACTIONS 281 6.3.4.3 POST-POLYMERIZATION
FUNCTIONALIZATION 288 6.3.5 MONONUCLEAR METALLO-SUPRAMOLECULAR POLYMERS
291 6.3.5.1 SUPRAMOLECULAR A-[M]-A HOMOPOLYMERS 291 6.3.5.2
SUPRAMOLECULAR BLOCK COPOLYMERS 294 6.3.6 OLIGONUCLEAR
METALLO-SUPRAMOLECULAR COPOLYMERS 308
7 TERPYRIDINE METAL COMPLEXES AND THEIR BIOMEDICAL RELEVANCE 319 7.1
INTRODUCTION 319
7.2 TERPYRIDINE METAL COMPLEXES WITH BIOLOGICAL ACTIVITY 320 7.2.1
INTERCALATION AND CYTOTOXICITY 320 7.2.1.1 TERPYRIDINE COMPLEXES WITH D
8 LATE TRANSITION METAL IONS 320 7.2.1.2 TERPYRIDINE COMPLEXES WITH
HEAVY D 6 TRANSITION METAL IONS 350
7.2.1.3 TERPYRIDINE COMPLEXES WITH MISCELLANEOUS TRANSITION METAL IONS
364 7.2.2 BIOLABELING 376
8 TERPYRIDINES AND NANOSTRUCTURES 399 8.1 INTRODUCTION 399
8.2 TERPYRIDINES AND SURFACE CHEMISTRY 401 8.3 TERPYRIDINES AND
INORGANIC NANOMATERIALS 420 8.4 TERPYRIDINES AND NANO-STRUCTURED TIO 2 :
PHOTOVOLTAIC APPLICATIONS 431
8.5 ORGANOPOLYMERIC RESINS, BEADS, AND NANOPARTICLES 447
9 CATALYTIC APPLICATIONS OF TERPYRIDINES AND THEIR TRANSITION METAL
COMPLEXES 459 9.1 INTRODUCTION 459
9.2 (ASYMMETRIC) CATALYSTS IN ORGANIC REACTIONS 460 9.3 ELECTROCATALYTIC
OXIDATION AND REDUCTION PROCESSES 476 9.4 PHOTOCATALYTIC PROCESSES 480
9.4.1 LIGHT-DRIVEN HYDROGEN FORMATION 483 9.4.2 MOLECULAR
TERPYRIDINE-BASED CATALYSTS FOR WATER OXIDATION 488
10 CONCLUDING REMARKS 507
INDEX 509
|
| any_adam_object | 1 |
| author | Schubert, Ulrich Sigmar 1969- Winter, Andreas 1972- Newkome, George R. 1938- |
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| author_facet | Schubert, Ulrich Sigmar 1969- Winter, Andreas 1972- Newkome, George R. 1938- |
| author_role | aut aut aut |
| author_sort | Schubert, Ulrich Sigmar 1969- |
| author_variant | u s s us uss a w aw g r n gr grn |
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| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.593 |
| dewey-search | 547.593 |
| dewey-sort | 3547.593 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| format | Book |
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| indexdate | 2024-07-10T00:08:31Z |
| institution | BVB |
| isbn | 9783527330386 9783527639649 9783527639632 9783527639656 9783527639625 |
| language | English |
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| spelling | Schubert, Ulrich Sigmar 1969- Verfasser (DE-588)113792077 aut Terpyridine-based materials for catalytic, optoelectronic and life science applications Ulrich S. Schubert ; Andreas Winter, and George R. Newkome Weinheim Wiley-VCH 2011 XIX, 522 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Terpyridinderivate 2,2':6',2''- (DE-588)4667950-9 gnd rswk-swf Supramolekulare Chemie (DE-588)4306141-2 gnd rswk-swf Terpyridinderivate 2,2':6',2''- (DE-588)4667950-9 s Supramolekulare Chemie (DE-588)4306141-2 s DE-604 Winter, Andreas 1972- Verfasser (DE-588)1016244169 aut Newkome, George R. 1938- Verfasser (DE-588)1234616327 aut DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024511059&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Schubert, Ulrich Sigmar 1969- Winter, Andreas 1972- Newkome, George R. 1938- Terpyridine-based materials for catalytic, optoelectronic and life science applications Terpyridinderivate 2,2':6',2''- (DE-588)4667950-9 gnd Supramolekulare Chemie (DE-588)4306141-2 gnd |
| subject_GND | (DE-588)4667950-9 (DE-588)4306141-2 |
| title | Terpyridine-based materials for catalytic, optoelectronic and life science applications |
| title_auth | Terpyridine-based materials for catalytic, optoelectronic and life science applications |
| title_exact_search | Terpyridine-based materials for catalytic, optoelectronic and life science applications |
| title_full | Terpyridine-based materials for catalytic, optoelectronic and life science applications Ulrich S. Schubert ; Andreas Winter, and George R. Newkome |
| title_fullStr | Terpyridine-based materials for catalytic, optoelectronic and life science applications Ulrich S. Schubert ; Andreas Winter, and George R. Newkome |
| title_full_unstemmed | Terpyridine-based materials for catalytic, optoelectronic and life science applications Ulrich S. Schubert ; Andreas Winter, and George R. Newkome |
| title_short | Terpyridine-based materials |
| title_sort | terpyridine based materials for catalytic optoelectronic and life science applications |
| title_sub | for catalytic, optoelectronic and life science applications |
| topic | Terpyridinderivate 2,2':6',2''- (DE-588)4667950-9 gnd Supramolekulare Chemie (DE-588)4306141-2 gnd |
| topic_facet | Terpyridinderivate 2,2':6',2''- Supramolekulare Chemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024511059&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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