Introduction to polymer rheology:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Hoboken, NJ
Wiley
2012
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 395 S. Ill., graph. Darst. |
| ISBN: | 9780470388440 |
Internformat
MARC
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| 100 | 1 | |a Shaw, Montgomery T. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Introduction to polymer rheology |c Montgomery T. Shaw |
| 264 | 1 | |a Hoboken, NJ |b Wiley |c 2012 | |
| 300 | |a XIV, 395 S. |b Ill., graph. Darst. | ||
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Datensatz im Suchindex
| _version_ | 1804148486598295552 |
|---|---|
| adam_text | Titel: Introduction to polymer rheology
Autor: Shaw, Montgomery T
Jahr: 2012
Contents
1. INTRODUCTION..........................................................................................1
A. Polymers and the importance of rheology..................................................1
B. Rheology in its simplest form.....................................................................9
Problems........................................................................................................12
Suggested references, with commentary.......................................................13
2. STRESS........................................................................................................15
A. Stress and pressure....................................................................................16
B. Organization of the stress components.....................................................30
C. Coping with subscripts..............................................................................31
D. Typical stress tensors................................................................................32
Appendix 2-1: Compilation of equations of motion (ssc).............................38
Appendix 2-2: Equations of motion-curvilinear quick list (ssc).................40
Problems........................................................................................................40
References......................................................................................................44
3. VELOCITY, VELOCITY GRADIENT AND RATE OF
DEFORMATION.........................................................................................45
A. Why velocity is simpler than location-Speedometers vs. GPS..............45
B. Velocity gradients.....................................................................................46
C Rate of deformation..................................................................................48
Appendix 3-1: Components of the rate-of-deformation tensor.....................52
Appendix 3-2: Components of the continuity equation.................................53
Appendix 3-3: Nomenclature and sign conventions used in
popular rheology texts.............................................................................53
XI
xii CONTENTS
54
Problems.......................................................................................................
57
DpfpfPTlPf*^ ..................••.................................................••• *J
4. RELATIONSHIP BETWEEN STRESS AND RATE OF
DEFORMATION: THE NEWTONIAN FLUID........................................59
A Material idealizations in rheology............................................................59
B. The Newtonian fluid................................................................................63
Problems.......................................................................................................68
References..................................................................................................... 0
5. GENERALIZED NEWTONIAN FLUIDS-
A SMALL BUT IMPORTANT STEP TOWARD
A DESCRIPTION OF REAL BEHAVIOR FOR POLYMERS.................71
A. Reasons for inventing generalized Newtonian fluids-
behavior of polymer melts......................................................................72
C. Generalizing the GNF to three dimensions..............................................77
D. Inventing relationships for viscosity vs. shear rate..................................82
E. Short primer on finding GNF parameters from data................................86
F. Summary of GNF characteristics.............................................................90
Appendix 5-1: Fitting data with Excel®........................................................90
Problems..................................................................•.....................................92
References.....................................................................................................96
6. NORMAL STRESSES-ORDINARY BEHAVIOR FOR POLYMERS... 97
A. Introduction..............................................................................................97
B. What are normal stresses?........................................................................98
C. Origin of normal stresses in simple shear................................................99
D. The second normal-stress difference......................................................102
E. Normal-stress coefficients and empirical findings.................................103
F. Transient rheological functions..............................................................107
D. Temperature effects and superposition of steady-flow data..................109
Problems.....................................................................................................116
References...................................................................................................122
7. EXPERIMENTAL METHODS.................................. .....ZZ ZZ Z . 125
A. Measurement of viscosity......................................................................126
B. Normal stresses from shearing flows.....................................................149
C. Extensional rheology...................................................................... 155
D. Specialized geometries.............................................................. 162
E. Flow visualization and other rheo-optical methods...............................165
F. Micro and nano rheology.................................................. 171
Appendix 7-1: Numerical derivatives.........................................................174
Appendix 7-2: Velocity-profile correction for non-Newtonian fluids........176
CONTENTS xiii
Appendix 7-3: Incorporation of slip into the velocity-profile correction-
the Mooney correction.............................................................................179
Appendix 7-4: Normal stresses using the cone-and-plate geometry...........180
Appendix 7-5: Desktop rheo-optical experiment.........................................184
Problems......................................................................................................186
References....................................................................................................193
8. STRAIN, SMALL AND LARGE..............................................................197
A. Displacement...........................................................................................197
B. Infinitesimal strain..................................................................................201
C. Hookean solids........................................................................................208
D. Finite strain.............................................................................................210
E. The Lodge elastic fluid and variants.......................................................214
F. The Cauchy strain measure.....................................................................219
G. Fixing up integral equations based on C and CT1...................................222
Appendix 8-1: The relaxation function........................................................226
Appendix 8-2: Constant-rate extension of the LEF.....................................227
Problems......................................................................................................233
References....................................................................................................238
9. MOLECULAR ORIGINS OF RHEOLOGICAL BEHAVIOR.................239
A. Description of polymer molecules..........................................................239
B. The Rouse chain-a limited description of polymer behavior...............241
C. Other chain-like models..........................................................................242
D. Dealing with entanglements....................................................................248
E. Summary of predictions of molecular theory.........................................255
Problems......................................................................................................256
References....................................................................................................259
10.ELEMENTARY POLYMER PROCESSING CONCEPTS......................261
A. Simple laboratory processing methods...................................................261
B. Elementary extrusion concepts...............................................................271
C. A downstream process-spinning..........................................................281
D. Summary.................................................................................................284
Appendix 10-1: Densities of melts at elevated temperatures......................284
Problems......................................................................................................286
References....................................................................................................290
11. QUALITY-CONTROL RHEOLOGY.......................................................291
A. Examples of methods used by various industries...................................292
B. Test precision..........................................................................................297
Appendix 11-1: ASTM tests methods for rheological characterization......302
Problems......................................................................................................305
References....................................................................................................308
xiv CONTENTS
12.FL0W OF MODIFIED POLYMERS AND POLYMERS WITH
SUPERMOLECULAR STRUCTURE......................................................311
A. Polymers filled with particulates............................................................311
B. Liquid crystallinity and rheology...........................................................321
C. Polymers with microphase separation in melts or solutions..................323
D. Covalent crosslinking of polymers........................................................327
Appendix 12-1: Van tHoff equation applied to gelation..........................329
Problems.....................................................................................................330
References...................................................................................................335
ANSWERS TO SELECTED PROBLEMS....................................................337
Chapter 1.....................................................................................................337
Chapter 2.....................................................................................................339
Chapter 3.....................................................................................................342
Chapter 4.....................................................................................................345
Chapter 5.....................................................................................................350
Chapter 6.....................................................................................................352
Chapter 7.....................................................................................................357
Chapter 8.....................................................................................................362
Chapter 9.....................................................................................................371
Chapter 10...................................................................................................372
Chapter 11...................................................................................................375
Chapter 12...................................................................................................377
NOMENCLATURE........................................................................................381
Greek Symbols:...........................................................................................382
AUTHOR INDEX......................................................................... .. . ZZZ.3S5
SUBJECT INDEX................................................................................ . . . .! . . 391
|
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| discipline | Physik Werkstoffwissenschaften / Fertigungstechnik |
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| language | English |
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| spelling | Shaw, Montgomery T. Verfasser aut Introduction to polymer rheology Montgomery T. Shaw Hoboken, NJ Wiley 2012 XIV, 395 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Polymers / Rheology Polymerlösung (DE-588)4175242-9 gnd rswk-swf Rheologie (DE-588)4049828-1 gnd rswk-swf Polymerlösung (DE-588)4175242-9 s Rheologie (DE-588)4049828-1 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024484653&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Shaw, Montgomery T. Introduction to polymer rheology Polymers / Rheology Polymerlösung (DE-588)4175242-9 gnd Rheologie (DE-588)4049828-1 gnd |
| subject_GND | (DE-588)4175242-9 (DE-588)4049828-1 |
| title | Introduction to polymer rheology |
| title_auth | Introduction to polymer rheology |
| title_exact_search | Introduction to polymer rheology |
| title_full | Introduction to polymer rheology Montgomery T. Shaw |
| title_fullStr | Introduction to polymer rheology Montgomery T. Shaw |
| title_full_unstemmed | Introduction to polymer rheology Montgomery T. Shaw |
| title_short | Introduction to polymer rheology |
| title_sort | introduction to polymer rheology |
| topic | Polymers / Rheology Polymerlösung (DE-588)4175242-9 gnd Rheologie (DE-588)4049828-1 gnd |
| topic_facet | Polymers / Rheology Polymerlösung Rheologie |
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