Palladium complexes for cross-coupling reactions in aqueous media:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2011
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | 282 S. 210 mm x 148 mm, 373 g |
| ISBN: | 9783868539646 3868539646 |
Internformat
MARC
| LEADER | 00000nam a2200000 c 4500 | ||
|---|---|---|---|
| 001 | BV039127498 | ||
| 003 | DE-604 | ||
| 005 | 20120224 | ||
| 007 | t | ||
| 008 | 110708s2011 m||| 00||| eng d | ||
| 015 | |a 11,N28 |2 dnb | ||
| 016 | 7 | |a 1013303415 |2 DE-101 | |
| 020 | |a 9783868539646 |c Pb. : EUR 51.00 (DE) |9 978-3-86853-964-6 | ||
| 020 | |a 3868539646 |9 3-86853-964-6 | ||
| 024 | 3 | |a 9783868539646 | |
| 035 | |a (OCoLC)825095151 | ||
| 035 | |a (DE-599)DNB1013303415 | ||
| 040 | |a DE-604 |b ger |e rakddb | ||
| 041 | 0 | |a eng | |
| 049 | |a DE-12 |a DE-91 |a DE-19 |a DE-29T | ||
| 082 | 0 | |a 546.63625 |2 22/ger | |
| 084 | |a CHE 376d |2 stub | ||
| 084 | |a 540 |2 sdnb | ||
| 084 | |a CHE 334d |2 stub | ||
| 084 | |a CHE 327d |2 stub | ||
| 100 | 1 | |a Marziale, Alexander Nicandro |d 1982- |e Verfasser |0 (DE-588)1013372182 |4 aut | |
| 245 | 1 | 0 | |a Palladium complexes for cross-coupling reactions in aqueous media |c Alexander Marziale |
| 250 | |a 1. Aufl. | ||
| 264 | 1 | |a München |b Verl. Dr. Hut |c 2011 | |
| 300 | |a 282 S. |c 210 mm x 148 mm, 373 g | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Anorganische Chemie | |
| 502 | |a Zugl.: München, Techn. Univ., Diss., 2011 | ||
| 650 | 0 | 7 | |a Wässrige Lösung |0 (DE-588)4124928-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Katalysator |0 (DE-588)4029919-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Palladiumkomplexe |0 (DE-588)4223138-3 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Kupplungsreaktion |0 (DE-588)4166199-0 |2 gnd |9 rswk-swf |
| 655 | 7 | |0 (DE-588)4113937-9 |a Hochschulschrift |2 gnd-content | |
| 689 | 0 | 0 | |a Palladiumkomplexe |0 (DE-588)4223138-3 |D s |
| 689 | 0 | 1 | |a Katalysator |0 (DE-588)4029919-3 |D s |
| 689 | 0 | 2 | |a Kupplungsreaktion |0 (DE-588)4166199-0 |D s |
| 689 | 0 | 3 | |a Wässrige Lösung |0 (DE-588)4124928-8 |D s |
| 689 | 0 | |5 DE-604 | |
| 856 | 4 | 2 | |m X:MVB |q text/html |u http://deposit.dnb.de/cgi-bin/dokserv?id=3849791&prov=M&dok_var=1&dok_ext=htm |3 Inhaltstext |
| 856 | 4 | 2 | |m DNB Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024145922&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 943 | 1 | |a oai:aleph.bib-bvb.de:BVB01-024145922 | |
Datensatz im Suchindex
| _version_ | 1809403809540079616 |
|---|---|
| adam_text |
IMAGE 1
TABLE OF CONTENTS
TABLE OF CONTENTS
A. INTRODUCTION 17
1. PALLADIUM-CATALYZED COUPLING REACTIONS 18
1.1. THE HISTORY OF PALLADIUM CATALYZED CROSS-COUPLING REACTIONS 21
1.2. THE MECHANISM OF PALLADIUM-CATALYZED COUPLING REACTIONS 22
1.3. THE SUZUKI-MIYAURA REACTION 24
1.4. THE SONOGASHIRA REACTION 26
1.5. ALLYLIC ALKYLATIONS - THE TSUJI-TROST REACTION 29
1.6. CROSS-COUPLING REACTIONS IN AQUEOUS MEDIA 31
1.7. ORGANIC SYNTHESIS IN WATERAND SOLVENT EFFECTS 34
2. GREEN CHEMISTRY 37
3. ASYMMETRIC CATALYSIS 42
3 . 1. ENANTIOSELECTIVE HOMOGENOUS CATALYSIS 42
3.2. ENZYMATIC CATALYSIS 44
3.3. ENZYMATIC AND HOMOGENOUS CATALYSIS 44
4. O R G A N O M E T A L L I C - E N Z Y M E - H Y B R I DS (OMEHS) 46
4 . 1. SUPRAMOLECULAR ANCHORING 49
4.2. DATIVE ANCHORING 49
4 . 3. COVALENT ANCHORING 50
5. AMIDO COMPLEXES OF LATE TRANSITION-METALS 51
5 . 1. LIGAND-METAL INTERACTIONS 51
5.2. REACTIVITY 52
5 . 3. PALLADIUM AMIDO COMPLEXES IN CATALYSIS 54
6. SCOPE OF THE THESIS 55
B R E S U L TS A ND D I S C U S S I ON 56
1. PUBLISHED RESEARCH ARTICLES 57
1.1. FACILE PALLADIUM CATALYZED SUZUKI-MIYAURA COUPLING IN AIR AND WATER
AT AMBIENT
TEMPERATUREE 57
1.2. AN EFFICIENT PROTOCOL FOR THE PALLADIUM-CATALYSED SUZUKI-MIYAURA
CROSS-COUPLING. 70
1.3. AN EFFICIENT PROTOCOL FOR COPPER-FREE PALLADIUM-CATALYSED
SONOGASHIRA CROSS-COUPLING
IN AQUEOUS MEDIA AT LOW TEMPERATURES 97
1.4. PALLADIUM PNP-DIALKYLAMIDES: SYNTHESIS, STRUCTURAL CHARACTERIZATION
AND REACTIVITY.
112
2. UNPUBLISHED RESULTS 141
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1013303415
DIGITALISIERT DURCH
IMAGE 2
10
2.1. SYNTHESIS OF PHOSPHINITE PALLADACYCLES 141
2 . 2. SYNTHESIS OF FUNCTIONALIZED PALLADIUM COMPOUNDS 1 46
2.3. SYNTHESIS OF METALLA-AFFINITY LABELS 157
2 . 4. ORGANOMETALLIC-ENZYME-HYBRIDS DERIVED FROM CYSTEINE PROTEASES 1
76
2 . 5. ORGANOMETALLIC-ENZYME-HYBRIDS DERIVED FROM SERINE PROTEASES 1 91
C EXPERIMENTAI. 194
1. GENERAL 195
1.1. SCHLENK TECHNIQUE 1 95
1.2. GLOVE-BOX TECHNIQUE 195
1.3. SOLVENT PREPARATION 195
2. ANALYTICAL METHODS 195
3. SYNTHETIC PROCEDURES 198
3.1. SYNTHESIS OF PHOSPHINITE PALLADACYCLES 198
3 . 2. SYNTHESIS OF FUNCTIONALIZED BISPYRIDYL PALLADIUM COMPLEXES 2 05
3 . 3. SYNTHESIS OF FUNCTIONALIZED BISPOSPHANE PALLADIUM COMPLEXES 2 10
3 . 4. SYNTHESIS OF METALLA-AFFINITY LABELS 2 18
3.5. CHARACTERIZATION OF ORGANOMETALLIC-ENZYME-HYBRIDS 233
3.6. CATALYTIC PROTOCOLS FOR THE TESTING OF PALLADIUM COMPLEXES,
PALLADIUM AFFINITY LABELS
AND PALLADIUM BASED O M E HS 2 34
3 . 7. CRYSTALLOGRAPHIC DATA 2 37
D. SUMMARY 2 44
1. PALLADIUM-CATALYZED CROSS-COUPLING REACTIONS IN WATER 245
1.1. THE SUZUKI-MIYAURA REACTION IN AQUEOUS MEDIA 245
1.2. THE SONOGASHIRA REACTION IN AQUEOUS MEDIA 2 48
2. SYNTHESIS OF ORGANOMETALLIC-ENZYME-HYBRIDS VIA
METALLA-AFFINITY-LABELS 249
2 . 1. SYNTHESIS OF FUNCTIONALIZED PALLADIUM COMPLEXES 2 50
2.2. SYNTHESIS OF METALLA-AFFINTIY-LABELS 250
2 . 3. SYNTHESIS FOR ORGANOMETALLIC-ENZYME-HYBRIDS 2 52
2 . 4. ORGANOMETALLIC-ENZYME-HYBRIDS AS CATALYSTS FOR THE TSUJI-TROST
REACTION IN WATER 2 53
3. SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF PALLADIUM
PNP-DIALKYLAMIDES 2 54
E ZUSAMMENFASSUNG 258
1. PALLADIUM-KATALYSIERTE KREUZKUPPLUNGSREAKTIONEN IN WASSER 2 59
1.1. DIE SUZUKI-MIYAURA REAKTION IM WAESSRIGEN MEDIUM 259
1.2. DIE SONOGASHIRA REAKTION IM WAESSRIGEN MEDIUM 2 63
IMAGE 3
TABLE OF CONTENTS 11
2. SYNTHESE VON O R G A N O M E T A L L - E N Z Y M H Y B R I D EN
MITTELS M E T A L L A - A F F I N I T AE T S M A R K E RN 2 64
2.1. SYNTHESE FUNKTIONALISIERTER PALLADIUMKOMPLEXE 265
2.2. SYNTHESE DER METALLA-AFFINITAETSMARKER 266
2 . 3. SYNTHESE VON ORGANOMETALL-ENZYMHYBRIDEN 2 68
2.4. ORGANOMETALLISCHE-ENZYMHYBRIDE ALS KATALYSATOREN FUER DIE
TSUJI-TROST REAKTION IN
WASSER 269
3. SYNTHESE UND STRUKTURELLE CHARAKTERISIERUNG VON PALLADIUM
PNP-DIALKYLAMIDEN 2 71
E PUBLICATIONS 2 76
1. JOURNAL CONTRIBUTIONS 277
2. POSTER PRESENTATIONS AND CONFERENCE CONTRBUTIONS 2 78
3. BOOK CONTRIBUTIONS 2 79
FI CURRICULUM VITAE 2 80 |
| any_adam_object | 1 |
| author | Marziale, Alexander Nicandro 1982- |
| author_GND | (DE-588)1013372182 |
| author_facet | Marziale, Alexander Nicandro 1982- |
| author_role | aut |
| author_sort | Marziale, Alexander Nicandro 1982- |
| author_variant | a n m an anm |
| building | Verbundindex |
| bvnumber | BV039127498 |
| classification_tum | CHE 376d CHE 334d CHE 327d |
| ctrlnum | (OCoLC)825095151 (DE-599)DNB1013303415 |
| dewey-full | 546.63625 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546.63625 |
| dewey-search | 546.63625 |
| dewey-sort | 3546.63625 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| edition | 1. Aufl. |
| format | Thesis Book |
| fullrecord | <?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>00000nam a2200000 c 4500</leader><controlfield tag="001">BV039127498</controlfield><controlfield tag="003">DE-604</controlfield><controlfield tag="005">20120224</controlfield><controlfield tag="007">t</controlfield><controlfield tag="008">110708s2011 m||| 00||| eng d</controlfield><datafield tag="015" ind1=" " ind2=" "><subfield code="a">11,N28</subfield><subfield code="2">dnb</subfield></datafield><datafield tag="016" ind1="7" ind2=" "><subfield code="a">1013303415</subfield><subfield code="2">DE-101</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">9783868539646</subfield><subfield code="c">Pb. : EUR 51.00 (DE)</subfield><subfield code="9">978-3-86853-964-6</subfield></datafield><datafield tag="020" ind1=" " ind2=" "><subfield code="a">3868539646</subfield><subfield code="9">3-86853-964-6</subfield></datafield><datafield tag="024" ind1="3" ind2=" "><subfield code="a">9783868539646</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(OCoLC)825095151</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)DNB1013303415</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-604</subfield><subfield code="b">ger</subfield><subfield code="e">rakddb</subfield></datafield><datafield tag="041" ind1="0" ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="049" ind1=" " ind2=" "><subfield code="a">DE-12</subfield><subfield code="a">DE-91</subfield><subfield code="a">DE-19</subfield><subfield code="a">DE-29T</subfield></datafield><datafield tag="082" ind1="0" ind2=" "><subfield code="a">546.63625</subfield><subfield code="2">22/ger</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 376d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">540</subfield><subfield code="2">sdnb</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 334d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">CHE 327d</subfield><subfield code="2">stub</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Marziale, Alexander Nicandro</subfield><subfield code="d">1982-</subfield><subfield code="e">Verfasser</subfield><subfield code="0">(DE-588)1013372182</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Palladium complexes for cross-coupling reactions in aqueous media</subfield><subfield code="c">Alexander Marziale</subfield></datafield><datafield tag="250" ind1=" " ind2=" "><subfield code="a">1. Aufl.</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">München</subfield><subfield code="b">Verl. Dr. Hut</subfield><subfield code="c">2011</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">282 S.</subfield><subfield code="c">210 mm x 148 mm, 373 g</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="490" ind1="0" ind2=" "><subfield code="a">Anorganische Chemie</subfield></datafield><datafield tag="502" ind1=" " ind2=" "><subfield code="a">Zugl.: München, Techn. Univ., Diss., 2011</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Wässrige Lösung</subfield><subfield code="0">(DE-588)4124928-8</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Katalysator</subfield><subfield code="0">(DE-588)4029919-3</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Palladiumkomplexe</subfield><subfield code="0">(DE-588)4223138-3</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="650" ind1="0" ind2="7"><subfield code="a">Kupplungsreaktion</subfield><subfield code="0">(DE-588)4166199-0</subfield><subfield code="2">gnd</subfield><subfield code="9">rswk-swf</subfield></datafield><datafield tag="655" ind1=" " ind2="7"><subfield code="0">(DE-588)4113937-9</subfield><subfield code="a">Hochschulschrift</subfield><subfield code="2">gnd-content</subfield></datafield><datafield tag="689" ind1="0" ind2="0"><subfield code="a">Palladiumkomplexe</subfield><subfield code="0">(DE-588)4223138-3</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="1"><subfield code="a">Katalysator</subfield><subfield code="0">(DE-588)4029919-3</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="2"><subfield code="a">Kupplungsreaktion</subfield><subfield code="0">(DE-588)4166199-0</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2="3"><subfield code="a">Wässrige Lösung</subfield><subfield code="0">(DE-588)4124928-8</subfield><subfield code="D">s</subfield></datafield><datafield tag="689" ind1="0" ind2=" "><subfield code="5">DE-604</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">X:MVB</subfield><subfield code="q">text/html</subfield><subfield code="u">http://deposit.dnb.de/cgi-bin/dokserv?id=3849791&prov=M&dok_var=1&dok_ext=htm</subfield><subfield code="3">Inhaltstext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="m">DNB Datenaustausch</subfield><subfield code="q">application/pdf</subfield><subfield code="u">http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024145922&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA</subfield><subfield code="3">Inhaltsverzeichnis</subfield></datafield><datafield tag="943" ind1="1" ind2=" "><subfield code="a">oai:aleph.bib-bvb.de:BVB01-024145922</subfield></datafield></record></collection> |
| genre | (DE-588)4113937-9 Hochschulschrift gnd-content |
| genre_facet | Hochschulschrift |
| id | DE-604.BV039127498 |
| illustrated | Not Illustrated |
| indexdate | 2024-09-06T00:19:00Z |
| institution | BVB |
| isbn | 9783868539646 3868539646 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-024145922 |
| oclc_num | 825095151 |
| open_access_boolean | |
| owner | DE-12 DE-91 DE-BY-TUM DE-19 DE-BY-UBM DE-29T |
| owner_facet | DE-12 DE-91 DE-BY-TUM DE-19 DE-BY-UBM DE-29T |
| physical | 282 S. 210 mm x 148 mm, 373 g |
| publishDate | 2011 |
| publishDateSearch | 2011 |
| publishDateSort | 2011 |
| publisher | Verl. Dr. Hut |
| record_format | marc |
| series2 | Anorganische Chemie |
| spelling | Marziale, Alexander Nicandro 1982- Verfasser (DE-588)1013372182 aut Palladium complexes for cross-coupling reactions in aqueous media Alexander Marziale 1. Aufl. München Verl. Dr. Hut 2011 282 S. 210 mm x 148 mm, 373 g txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2011 Wässrige Lösung (DE-588)4124928-8 gnd rswk-swf Katalysator (DE-588)4029919-3 gnd rswk-swf Palladiumkomplexe (DE-588)4223138-3 gnd rswk-swf Kupplungsreaktion (DE-588)4166199-0 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Palladiumkomplexe (DE-588)4223138-3 s Katalysator (DE-588)4029919-3 s Kupplungsreaktion (DE-588)4166199-0 s Wässrige Lösung (DE-588)4124928-8 s DE-604 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3849791&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024145922&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Marziale, Alexander Nicandro 1982- Palladium complexes for cross-coupling reactions in aqueous media Wässrige Lösung (DE-588)4124928-8 gnd Katalysator (DE-588)4029919-3 gnd Palladiumkomplexe (DE-588)4223138-3 gnd Kupplungsreaktion (DE-588)4166199-0 gnd |
| subject_GND | (DE-588)4124928-8 (DE-588)4029919-3 (DE-588)4223138-3 (DE-588)4166199-0 (DE-588)4113937-9 |
| title | Palladium complexes for cross-coupling reactions in aqueous media |
| title_auth | Palladium complexes for cross-coupling reactions in aqueous media |
| title_exact_search | Palladium complexes for cross-coupling reactions in aqueous media |
| title_full | Palladium complexes for cross-coupling reactions in aqueous media Alexander Marziale |
| title_fullStr | Palladium complexes for cross-coupling reactions in aqueous media Alexander Marziale |
| title_full_unstemmed | Palladium complexes for cross-coupling reactions in aqueous media Alexander Marziale |
| title_short | Palladium complexes for cross-coupling reactions in aqueous media |
| title_sort | palladium complexes for cross coupling reactions in aqueous media |
| topic | Wässrige Lösung (DE-588)4124928-8 gnd Katalysator (DE-588)4029919-3 gnd Palladiumkomplexe (DE-588)4223138-3 gnd Kupplungsreaktion (DE-588)4166199-0 gnd |
| topic_facet | Wässrige Lösung Katalysator Palladiumkomplexe Kupplungsreaktion Hochschulschrift |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3849791&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=024145922&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT marzialealexandernicandro palladiumcomplexesforcrosscouplingreactionsinaqueousmedia |