Colloids and the depletion interaction:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Dordrecht [u.a.]
Springer
2011
|
| Series: | Lecture notes in physics
833 |
| Subjects: | |
| Online Access: | Klappentext Inhaltsverzeichnis |
| Physical Description: | XIV, 233 S. Ill., graph. Darst. |
| ISBN: | 9789400712225 |
Staff View
MARC
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| 100 | 1 | |a Lekkerkerker, Henk N. W. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Colloids and the depletion interaction |c Henk N. W. Lekkerkerker ; Remco Tuinier |
| 264 | 1 | |a Dordrecht [u.a.] |b Springer |c 2011 | |
| 300 | |a XIV, 233 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
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Record in the Search Index
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|---|---|
| adam_text |
Contents
1
Introduction
. 1
1.1
Colloids
. 1
1.2
Colloidal Interactions
. 4
1.2.1
Van
der Waals
Interaction
. 4
1.2.2
Double Layer Interaction
. 6
1.2.3
DLVO Interaction
. 8
1.2.4
Influence of Attached Polymers
. 9
1.2.5
Depletion Interaction
. 12
1.3
Historical Overview on Depletion
. 15
1.3.1
Early Interest in Unbalanced Forces
. 16
1.3.2
Experimental Observations on Depletion
Before the
1950s. 18
1.3.3 1950-1969. 23
1.3.4 1970-1982. 24
1.3.5 1983-1989. 30
1.3.6 1990-1999. 31
1.3.7 2000-2010. 35
1.4
Manifestations of Depletion Effects of Biological
and Technological Interest
. 38
1.4.1
Depletion Effects in Biological Systems:
Macromolecular Crowding
. 39
1.4.2
Depletion Interactions and Protein Crystallization
. 39
1.4.3
Shape and Size Selection
. 43
1.4.4
Directing Colloidal Self-assembly Using
Surface
Microstructures
. 45
1.4.5
Motion of a Sphere Through a Polymer Solution
. 48
1.5
Outline
. 49
References
. 50
ii
Contents
Depletion Interaction
. 57
2.1
Depletion Interaction Due to Penetrable Hard Spheres
. 57
2.1.1
Depletion Interaction Between Two Rat Plates
. 57
2.1.2
Depletion Interaction Between Two Spheres
. 61
2.1.3
Depletion Interaction Between a Sphere and a Plate
. 63
2.1.4
Derjaguin Approximation
. 64
2.2
Depletion Interaction Due to Ideal Polymers
. 67
2.2.1
Depletion Interaction Between Two Flat Plates
. 67
2.2.2
Interaction Between Two Spheres
. 74
2.3
Depletion Interaction Due to Colloid Hard Spheres
. 79
2.3.1
Concentration Profiles Near a Hard Wall and Between
Two Hard Walls
. 79
2.3.2
Depletion Interaction Between Two Flat Plates
. 82
2.3.3
Depletion Interaction Between Two (Big) Spheres
. 86
2.4
Depletion Interaction Due to Colloidal Hard Rods
. 88
2.4.1
Depletion Interaction Between Two Flat Plates
. 88
2.4.2
Interaction Between Two (Big) Colloidal Spheres
Using the Derjaguin Approximation
. 91
2.5
Depletion Interaction Due to Thin Colloidal Disks
. 92
2.5.1
Depletion Interaction Between Two Flat Plates
. 92
2.5.2
Interaction Between Two (Big) Colloidal Spheres
Using the Derjaguin Approximation
. 96
2.6
Measurements of Depletion Interactions
. 98
2.6.1
Atomic Force Microscopy
. 98
2.6.2
Total Internal Reflection Microscopy
. 100
2.6.3
Optical Tweezers
. 102
2.6.4
Scattering and Microscopy
. 104
References
. 106
Phase Transitions of Hard Spheres Plus Depletants; Basics
. 109
3.1
Introduction: Colloid/Atom Analogy
. 109
3.2
The Hard-Sphere Fluid-Crystal Transition
. 110
3.2.1
Hard-Sphere
Huid
.
Ill
3.2.2
Hard-Sphere Crystal
. 113
3.2.3
Fluid-Crystal Coexistence
. 115
3.3
Free Volume Theory of Hard Spheres and Depletants
. 117
3.3.1
System
. 117
3.3.2
Thermodynamics
. 119
3.3.3
Scaled Particle Theory
. 120
3.3.4
Phase Diagrams
. 123
References
. 128
Contents
Stability of Colloid-Polymer Mixtures
. 131
4.1
Experimental State Diagrams of Model
Colloid-Polymer Mixtures
. 134
4.2
Phase Behaviour of Colloid
+
Ideal Polymer Mixtures
. 138
4.3
Mixtures of Spheres Plus Interacting Polymer Mixtures
. 141
4.3.1
Characteristic Length Scales in Polymer Solutions
. 141
4.3.2
Depletion Thickness
. 144
4.3.3
Osmotic Pressure of Polymer Solutions
. 147
4.3.4
Phase Diagrams
. 149
4.4
Effects of Polydispersity and Charges
. 154
4.4.1
Polydispersity Effects
. 155
4.4.2
The Interplay of Depletion and Charges
. 156
4.5
Phase Separation Kinetics and Long-Lived Metastable
and Nonequilibrium States
. 159
4.5.1
<7>0.3
. 160
4.5.2
q
< 0.3. 164
References
. 172
Phase Transitions of Hard Spheres Plus Colloids
. 177
5.1
Free Volume Theory for Big Plus Small Hard Spheres
. 177
5.2
Phase Behaviour of Mixed Suspensions of Large and Small
Spherical Colloids
. 181
5.2.1
Phase Separation in Binary Mixtures Differing only
in Diameter
. 181
5.2.2
Mixtures of Latex Particles and Micelles
. 182
5.2.3
Oil-in-Water Emulsion Droplets and Micelles of the
Stabilizing Surfactant
. 183
5.3
Free Volume Theory for Sphere-Rod Mixtures
. 184
5.3.1
Free Volume Fraction
. 185
5.3.2
Pressure of a Dispersion of Rods
. 187
5.4
Phase Behaviour of Colloidal Sphere-Rod
Mixtures: Experiment
. 192
References
. 194
Phase Transitions in Suspensions of Rod-Like Colloids
Plus Polymers
. 197
6.1
Onsager Theory of the Isotropic-Nematic Transition
. 198
6.2
Scaled Particle Theory of the Isotropic-Nematic Transition
. 203
6.3
Isotropic-Nematic Phase Behaviour of Rods Plus Penetrable
Hard Spheres
. 206
6.4
I-N Phase Behaviour of Rod-Like Colloids Plus Polymers
. 212
6.4.1
Rod-like Colloids Plus Ideal Polymers
. 212
6.4.2
Rod-like Colloids Plus Interacting Polymers
. 213
6.5
Experimental Phase Behaviour of Rod/Polymer Mixtures
. 217
6.5.1
Stiff Virus Particles
+
Polymer
. 217
χ
Contents
6.5.2
Cellulose Nanocrystals
+ Polymer. 221
6.5.3
Sterically
Stabilized Colloidal Boehmite
Rods
+
Polymer
. 222
6.6
Phase Diagrams of Rod/Polymer Mixtures Including Highly
Ordered Phases
. 224
6.7
Concluding Remarks
. 227
References
. 227
Appendix A Statistical Mechanical Derivation
of the Free Volume Theory
. 229
Index
. 231
Lecture Notes
in Physics
833
Henk
N.
W.
Lekkerkerker
·
Remco
Tuinier
Colloids and the Depletion Interaction
Colloids are
submicron
particles that are ubiquitous in nature (milk, clay, blood) and
industrial products (paints, drilling fluids, food). It has been known for a long time
that adding salt or polymer influences the characteristics of colloidal suspensions.
Think of the Egyptians who engineered ink by adding gum Arabic to soot particles a
few thousand years ago. Unknowingly, they were taking advantage of the anchoring of
the polysaccharides onto the colloids to provide the stabilization of the soot particles
that
eventuali)·
provided an ink to write on papyrus. The effect of charges and polymers
attached to the surface of colloidal particles on their
stabilit)·
has been understood and
studied extensively in the last century. But the more elusive, albeit ubiquitous, effects of
the addition of free polymers and small colloids as depletants to colloidal dispersions
have become in focus recently. In recent decades it has become clear that adding such
depletants allows one to tune the interactions between the colloids and in this way
control the stability, structure and rheological properties of colloidal dispersions. This
book offers a concise introduction to the fundamentals of depletion effects and their
influence on the phase behavior of colloidal dispersions. These fundamental principles
promote insight and the intuitive sense needed to isolate issues related to depletion
effects in technological problems and design critical experiments. In an introductory
chapter, the authors provide a historical perspective and the applications of depletion
effects not only in colloid science but also in biology, medicine and technology. In the
subsequent chapter they address the basics of depletion interactions, including the
effects of anisotropic depletants. The next chapter covers the basics of phase behavior
in colloidal dispersions, followed by extensions towards mixtures of spherical colloids
with polymers or small colloids inducing depletion forces. Finally, the authors consider
depletion effects in suspensions of rod-like colloids. Throughout the book, conceptual
explanations are accompanied by experimental and computer simulation results. This is
an ideal book tor advanced undergraduates and graduate students in physical chemistry,
chemical engineering and soft matter physics. It provides the basic knowledge ot
depletion interactions and phase behaviour in general. Experienced scientists and
engineers working on polymers, particles or colloidal dispersions, may also
ńnd
this
book useful. |
| any_adam_object | 1 |
| author | Lekkerkerker, Henk N. W. Tuinier, Remco 1971- |
| author_GND | (DE-588)1012538338 |
| author_facet | Lekkerkerker, Henk N. W. Tuinier, Remco 1971- |
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| author_sort | Lekkerkerker, Henk N. W. |
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| classification_rvk | UD 8220 |
| classification_tum | CHE 180f |
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| discipline | Physik Chemie |
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| id | DE-604.BV037428982 |
| illustrated | Illustrated |
| indexdate | 2024-12-11T13:03:15Z |
| institution | BVB |
| isbn | 9789400712225 |
| language | English |
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| spelling | Lekkerkerker, Henk N. W. Verfasser aut Colloids and the depletion interaction Henk N. W. Lekkerkerker ; Remco Tuinier Dordrecht [u.a.] Springer 2011 XIV, 233 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Lecture notes in physics 833 Phasenumwandlung (DE-588)4132140-6 gnd rswk-swf Kolloid (DE-588)4164695-2 gnd rswk-swf Kolloid (DE-588)4164695-2 s Phasenumwandlung (DE-588)4132140-6 s DE-604 Tuinier, Remco 1971- Verfasser (DE-588)1012538338 aut Erscheint auch als Online-Ausgabe 978-94-007-1223-2 Lecture notes in physics 833 (DE-604)BV000003166 833 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022581098&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Klappentext Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022581098&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Lekkerkerker, Henk N. W. Tuinier, Remco 1971- Colloids and the depletion interaction Lecture notes in physics Phasenumwandlung (DE-588)4132140-6 gnd Kolloid (DE-588)4164695-2 gnd |
| subject_GND | (DE-588)4132140-6 (DE-588)4164695-2 |
| title | Colloids and the depletion interaction |
| title_auth | Colloids and the depletion interaction |
| title_exact_search | Colloids and the depletion interaction |
| title_full | Colloids and the depletion interaction Henk N. W. Lekkerkerker ; Remco Tuinier |
| title_fullStr | Colloids and the depletion interaction Henk N. W. Lekkerkerker ; Remco Tuinier |
| title_full_unstemmed | Colloids and the depletion interaction Henk N. W. Lekkerkerker ; Remco Tuinier |
| title_short | Colloids and the depletion interaction |
| title_sort | colloids and the depletion interaction |
| topic | Phasenumwandlung (DE-588)4132140-6 gnd Kolloid (DE-588)4164695-2 gnd |
| topic_facet | Phasenumwandlung Kolloid |
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