Chemical thermodynamics: an introduction
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| Main Author: | |
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| Format: | Book |
| Language: | English |
| Published: |
Berlin [u.a.]
Springer
2012
|
| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | XI, 354 S. graph. Darst. |
| ISBN: | 9783642198632 |
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| 100 | 1 | |a Keszei, Ernő |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Chemical thermodynamics |b an introduction |c Ernő Keszei |
| 264 | 1 | |a Berlin [u.a.] |b Springer |c 2012 | |
| 300 | |a XI, 354 S. |b graph. Darst. | ||
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Record in the Search Index
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IMAGE 1
CONTENTS
1 INTRODUCTION 1
FURTHER READING 2
2 POSTULATES OF THERMODYNAMICS 3
2.1 THERMODYNAMIC SYSTEMS: POSTULATE 1 4
2.1.1 CONSTRAINED SYSTEMS AND THE MEASURABILITY OF ENERGY VIA MECHANICAL
WORK 6
2.2 THE CONDITIONS OF EQUILIBRIUM: POSTULATES 2, 3 AND 4 8
2.2.1 PROPERTIES OF THE ENTROPY FUNCTION 10
2.2.2 PROPERTIES OF THE DIFFERENTIAL FUNDAMENTAL EQUATION 13 2.2.3 THE
SCALE OF ENTROPY AND TEMPERATURE 15
2.2.4 EULER RELATION, GIBBS-DUHEM EQUATION AND EQUATIONS OF STATE 17
2.2.5 THE FUNDAMENTAL EQUATION OF AN IDEAL GAS 18
2.2.6 THE FUNDAMENTAL EQUATION OF AN IDEAL VAN DER WAALS FLUID 22
FURTHER READING 28
3 THERMODYNAMIC EQUILIBRIUM IN ISOLATED AND ISENTROPIC SYSTEMS . 29
3.1 THERMAL EQUILIBRIUM 32
3.2 THERMAL AND MECHANICAL EQUILIBRIUM 36
3.3 THERMAL AND CHEMICAL EQUILIBRIUM 37
FURTHER READING 41
4 THERMODYNAMIC EQUILIBRIUM IN SYSTEMS WITH OTHER CONSTRAINTS 43 4.1
EQUILIBRIUM IN CONSTANT PRESSURE SYSTEMS: THE ENTHALPY FUNCTION 44
4.2 EQUILIBRIUM IN CONSTANT TEMPERATURE AND CONSTANT VOLUME SYSTEMS: THE
FREE ENERGY FUNCTION 46
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1010119303
DIGITALISIERT DURCH
IMAGE 2
CONTENTS
4.3 EQUILIBRIUM IN CONSTANT TEMPERATURE AND CONSTANT PRESSURE SYSTEMS:
THE GIBBS POTENTIAL 48
4.4 SUMMARY OF THE EQUILIBRIUM CONDITIONS: PROPERTIES OF THE ENERGY-LIKE
POTENTIAL FUNCTIONS 50
4.4.1 CALCULATION OF HEAT AND WORK FROM THERMODYNAMIC POTENTIAL
FUNCTIONS 52
4.4.2 CALCULATION OF ENTROPY AND ENERGY-LIKE FUNCTIONS FROM MEASURABLE
QUANTITIES 53
4.4.3 CALCULATION OF THERMODYNAMIC QUANTITIES FROM THE FUNDAMENTAL
EQUATION 57
4.5 EQUATIONS OF STATE OF REAL GASES, FLUIDS AND SOLIDS 58
4.5.1 CHEMICAL POTENTIAL AND FUGACITY OF A REAL GAS 64
FURTHER READING 68
THERMODYNAMIC PROCESSES AND ENGINES 69
5.1 QUASISTATIC, REVERSIBLE AND IRREVERSIBLE PROCESSES 69
5.2 HEAT ENGINES: THE CARNOT CYCLE AND THE CARNOT ENGINE 72 5.3
REFRIGERATORS AND HEAT PUMPS: THE CARNOT REFRIGERATING AND HEAT-PUMP
CYCLE 75
5.4 HEAT ENGINES AND REFRIGERATORS USED IN PRACTICE 77
5.4.1 HEAT ENGINES BASED ON THE RANKINE CYCLE 77
5.4.2 REFRIGERATORS AND HEAT PUMPS BASED ON THE RANKINE CYCLE 79
5.4.3 ISENTHALPIC PROCESSES: THE JOULE-THOMPSON EFFECT 80 FURTHER
READING 85
THERMODYNAMICS OF MIXTURES (MULTICOMPONENT SYSTEMS) 87 6.1 PARTIAL MOLAR
QUANTITIES 87
6.1.1 CHEMICAL POTENTIAL AS A PARTIAL MOLAR QUANTITY 89 6.1.2
DETERMINATION OF PARTIAL MOLAR QUANTITIES FROM EXPERIMENTAL DATA 90
6.2 THERMODYNAMICS OF IDEAL MIXTURES 93
6.2.1 IDEAL GAS MIXTURES 93
6.2.2 PROPERTIES OF IDEAL MIXTURES 95
6.2.3 ALTERNATIVE REFERENCE STATES 98
6.2.4 ACTIVITY AND STANDARD STATE 101
6.3 THERMODYNAMICS OF REAL MIXTURES 103
6.3.1 MIXTURES OF REAL GASES 103
6.3.2 THE CHEMICAL POTENTIAL IN TERMS OF MOLE FRACTIONS 106 6.3.3 THE
CHEMICAL POTENTIAL IN TERMS OF SOLUTE CONCENTRATION . 108 6.3.4
ACTIVITY AND STANDARD STATE: AN OVERVIEW 109
6.3.5 THERMODYNAMIC PROPERTIES OF A REAL MIXTURE 115 6.4 IDEAL SOLUTIONS
AND IDEAL DILUTE SOLUTIONS 118
FURTHER READING 122
IMAGE 3
CONTENTS IX
7 PHASE EQUILIBRIA 125
7.1 STABILITY OF PHASES 127
7.2 PHASE EQUILIBRIA OF PURE SUBSTANCES 129
7.2.1 PHASE DIAGRAMS OF PURE SUBSTANCES 135
7.2.2 CALCULATION OF THE QUANTITY OF COEXISTING PHASES: THE LEVER RULE
139
7.2.3 CALCULATION OF EQUILIBRIUM TEMPERATURE AND PRESSURE; THE
CLAUSISUS-CLAPEYRON EQUATION 141
7.2.4 FIRST-ORDER AND SECOND-ORDER PHASE TRANSITIONS 144 7.3
LIQUID-VAPOR EQUILIBRIUM OF IDEAL BINARY MIXTURES 147 7.4 LIQUID-VAPOR
EQUILIBRIUM OF REAL BINARY MIXTURES 154 7.5 SOLID-LIQUID EQUILIBRIUM OF
IDEAL BINARY MIXTURES 158
7.6 EQUILIBRIUM OF PARTIALLY MISCIBLE BINARY MIXTURES 159 7.6.1
LIQUID-LIQUID PHASE DIAGRAMS 161
7.6.2 SOLID-LIQUID PHASE DIAGRAMS 163
7.6.3 COLLIGATIVE PROPERTIES: EQUILIBRIUM OF A BINARY MIXTURE PHASE AND
A PURE PHASE CONTAINING ONE OF THE MIXTURE COMPONENTS 178
7.7 PHASE DIAGRAMS OF MULTICOMPONENT SYSTEMS 185
7.8 SEPARATION OF COMPONENTS BASED ON DIFFERENT PHASE DIAGRAMS 190
FURTHER READING 200
8 EQUILIBRIA OF CHEMICAL REACTIONS 201
8.1 CONDITION OF A CHEMICAL EQUILIBRIUM AT CONSTANT TEMPERATURE AND
PRESSURE 202
8.1.1 RELATION OF THE EQUILIBRIUM CONSTANT AND THE STOICHIOMETRIC
EQUATION 205
8.1.2 AFFINITY: THE DRIVING FORCE OF CHEMICAL REACTIONS 206 8.2 THE
EQUILIBRIUM CONSTANT IN TERMS OF DIFFERENT ACTIVITIES 211 8.2.1
HETEROGENEOUS REACTION EQUILIBRIA OF IMMISCIBLE COMPONENTS 214
8.3 CALCULATION OF THE EQUILIBRIUM CONSTANT FROM THERMODYNAMIC DATA 218
8.4 TEMPERATURE AND PRESSURE DEPENDENCE OF THE EQUILIBRIUM CONSTANT 221
8.4.1 THE LE CHATELIER-BRAUN PRINCIPLE 223
FURTHER READING 226
9 EXTENSION OF THERMODYNAMICS FOR ADDITIONAL INTERACTIONS (NON-SIMPLE
SYSTEMS) 227
9.1 THERMODYNAMICS OF INTERFACES: TWO-DIMENSIONAL EQUATIONS OF STATE 231
9.1.1 THERMODYNAMIC PROPERTIES OF CURVED SURFACES 234
IMAGE 4
X CONTENTS
9.2 THERMODYNAMIC DESCRIPTION OF SYSTEMS CONTAINING ELECTRICALLY CHARGED
PARTICLES 241
9.2.1 THERMODYNAMIC CONSEQUENCES OF THE ELECTRONEUTRALITY PRINCIPLE: THE
CHEMICAL POTENTIAL OF ELECTROLYTES AND THE MEAN ACTIVITY COEFFICIENT 244
9.2.2 CHEMICAL POTENTIAL OF IONS IN AN ELECTRIC FIELD: THE
ELECTROCHEMICAL POTENTIAL 251
9.2.3 HETEROGENEOUS ELECTROCHEMICAL EQUILIBRIA: THE GALVANIC CELL 253
9.2.4 ELECTRODES AND ELECTRODE POTENTIALS 259
FURTHER READING 264
10 ELEMENTS OF EQUILIBRIUM STATISTICAL THERMODYNAMICS 265 10.1 THE
MICROCANONICAL ENSEMBLE 266
10.1.1 STATISTICAL THERMODYNAMICS OF THE EINSTEIN SOLID IN
MICROCANONICAL REPRESENTATION 269
10.1.2 STATISTICAL THERMODYNAMICS OF A SYSTEM OF TWO-STATE MOLECULES IN
MICROCANONICAL REPRESENTATION 272
10.2 THE CANONICAL ENSEMBLE 274
10.2.1 CALCULATION OF THE CANONICAL PARTITION FUNCTION FROM MOLECULAR
DATA 280
10.2.2 STATISTICAL THERMODYNAMICS OF THE EINSTEIN SOLID AND THE SYSTEM
OF TWO-STATE MOLECULES IN CANONICAL REPRESENTATION 281
10.2.3 THE TRANSLATIONAL PARTITION FUNCTION. STATISTICAL THERMODYNAMICS
OF A MONATOMIC IDEAL GAS 283 10.2.4 CALCULATION OF THE ROTATIONAL,
VIBRATIONAL, AND ELECTRONIC PARTITION FUNCTIONS 287
10.2.5 STATISTICAL CHARACTERIZATION OF THE CANONICAL ENERGY 291 10.2.6
THE EQUIPARTITION THEOREM 294
10.3 GENERAL STATISTICAL DEFINITION AND INTERPRETATION OF ENTROPY 297
10.4 CALCULATION OF THE CHEMICAL EQUILIBRIUM CONSTANT FROM CANONICAL
PARTITION FUNCTIONS 300
FURTHER READING 306
11 TOWARD EQUILIBRIUM: ELEMENTS OF TRANSPORT PHENOMENA 307 11.1
TRANSPORT EQUATIONS FOR HEAT, ELECTRICITY, AND MOMENTUM 309 11.2
EQUATIONS FOR THE DIFFUSIVE MATERIAL TRANSPORT 311
11.2.1 FICK'S FIRST LAW: THE FLUX OF DIFFUSION 312
11.2.2 FICK'S SECOND LAW: THE RATE OF CHANGE OF THE CONCENTRATION
PROFILE 312
11.3 PRINCIPLE TRANSPORT PROCESSES AND COUPLED PROCESSES 316 FURTHER
READING 318
IMAGE 5
CONTENTS XI
APPENDIX 319
AL USEFUL RELATIONS OF MULTIVARIATE CALCULUS 319
A. 1.1 DIFFERENTIATION OF MULTIVARIATE FUNCTIONS 319
A. 1.2 DIFFERENTIATION OF COMPOSITE FUNCTIONS 322
A. 1.3 DIFFERENTIATION OF IMPLICIT FUNCTIONS 323
A. 1.4 INTEGRATION OF MULTIVARIATE FUNCTIONS 324
A. 1.5 THE EULER EQUATION FOR HOMOGENEOUS FIRST-ORDER FUNCTIONS 325
A2 CHANGING EXTENSIVE VARIABLES TO INTENSIVE ONES: LEGENDRE
TRANSFORMATION 326
A.2.1 LEGENDRE TRANSFORMATIONS 327
A.2.2 LEGENDRE TRANSFORMATION OF THE ENTROPY FUNCTION 329 A3 CLASSICAL
THERMODYNAMICS: THE LAWS 331
A.3.1 ZEROTH LAW AND TEMPERATURE 332
A.3.2 FIRST LAW AND ENERGY 334
A.3.3 SECOND LAW AND ENTROPY 336
A.3.4 THIRD LAW AND THE UNIQUENESS OF THE ENTROPY SCALE 341 FURTHER
READING 341
INDEX 343 |
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| discipline | Chemie / Pharmazie Physik Chemie |
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| spelling | Keszei, Ernő Verfasser aut Chemical thermodynamics an introduction Ernő Keszei Berlin [u.a.] Springer 2012 XI, 354 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Thermochemie (DE-588)4078260-8 gnd rswk-swf (DE-588)4123623-3 Lehrbuch gnd-content Thermochemie (DE-588)4078260-8 s 1\p DE-604 Erscheint auch als Online-Ausgabe 978-3-642-19864-9 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3672050&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=022482386&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Keszei, Ernő Chemical thermodynamics an introduction Thermochemie (DE-588)4078260-8 gnd |
| subject_GND | (DE-588)4078260-8 (DE-588)4123623-3 |
| title | Chemical thermodynamics an introduction |
| title_auth | Chemical thermodynamics an introduction |
| title_exact_search | Chemical thermodynamics an introduction |
| title_full | Chemical thermodynamics an introduction Ernő Keszei |
| title_fullStr | Chemical thermodynamics an introduction Ernő Keszei |
| title_full_unstemmed | Chemical thermodynamics an introduction Ernő Keszei |
| title_short | Chemical thermodynamics |
| title_sort | chemical thermodynamics an introduction |
| title_sub | an introduction |
| topic | Thermochemie (DE-588)4078260-8 gnd |
| topic_facet | Thermochemie Lehrbuch |
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