Handbook of stimuli-responsive materials:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH
2011
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XVII, 278 S. Ill., graph. Darst. |
| ISBN: | 9783527327003 3527327002 |
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Datensatz im Suchindex
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IMAGE 1
CONTENTS
PREFACE XI LIST OF CONTRIBUTORS XV
1 SYNTHETIC AND PHYSICOCHEMICAL ASPECTS OF ADVANCED STIMULI-RESPONSIVE
POLYMERS 1 DIRK RUCKLING AND MAREK W. URBAN 1.1 INTRODUCTION 1
1.2 CONTROLLED FREE RADICAL POLYMERIZATION OF STIMULI-RESPONSIVE
POLYMERS 3 1.3 SYNTHESIS OF STIMULI-RESPONSIVE COLLOIDAL DISPERSIONS 11
1.4 SUMMARY 21
REFERENCES 21
2 BIOLOGICAL- AND FIELD-RESPONSIVE POLYMERS: EXPANDING POTENTIAL IN
SMART MATERIALS 27 DEBASHISH ROY, JENNIFER N. CAMBRE, AND BRENT S.
SUMERLIN 2.1 INTRODUCTION 27
2.2 BIOLOGICALLY RESPONSIVE POLYMER SYSTEMS 28 2.2.1 GLUCOSE-RESPONSIVE
POLYMERS 28 2.2.1.1 GLUCOSE-RESPONSIVE SYSTEMS BASED ON GLUCOSE-GOX 28
2.2.1.2 GLUCOSE-RESPONSIVE SYSTEMS BASED ON CONA 29 2.2.1.3
GLUCOSE-RESPONSIVE SYSTEMS BASED ON BORONIC ACID-DIOL
COMPLEXATION 30
2.2.2 ENZYME-RESPONSIVE POLYMERS 32 2.2.3 ANTIGEN-RESPONSIVE POLYMERS 33
2.2.4 REDOX-/THIOL-RESPONSIVE POLYMERS 35 2.3 FIELD-RESPONSIVE POLYMERS
39 2.3.1 ELECTRORESPONSIVE POLYMERS 39 2.3.2 MAGNETORESPONSIVE POLYMERS
40 2.3.3 ULTRASOUND-RESPONSIVE POLYMERS 42 2.3.4 PHOTORESPONSIVE
POLYMERS 43 2.4 CONCLUSIONS 46
REFERENCES 47
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1007027681
DIGITALISIERT DURCH
IMAGE 2
VI CONTENTS
3 SELF-OSCILLATING GELS AS STIMULI-RESPONSIVE MATERIALS 59
ANNA C. BALAZS, PRATYUSH DAYAL, OLGA KUKSENOK, AND VICTOR V. YASHIN 3.1
INTRODUCTION 59
3.2 METHODOLOGY 61
3.2.1 CONTINUUM EQUATIONS 61 3.2.2 FORMULATION OF THE GEL LATTICE SPRING
MODEL (GLSM) 63 3.2.3 MODEL PARAMETERS AND CORRESPONDENCE BETWEEN
SIMULATIONS AND EXPERIMENTS 67 3.3 RESULTS AND DISCUSSIONS 69
3.3.1 EFFECT OF CONFINEMENT ON THE DYNAMICS OF THE BZ GELS 69 3.3.1.1
LINEAR STABILITY ANALYSIS IN LIMITING CASES 69 3.3.1.2 OSCILLATIONS
INDUCED BY THE RELEASE OF CONFINEMENT 72 3.3.1.3 BEHAVIOR OF PARTIALLY
CONFINED SAMPLES 74
3.3.2 RESPONSE OF THE BZ GELS TO NONUNIFORM ILLUMINATION 77 3.3.2.1
MODELING THE PHOTOSENSITIVITY OF THE BZ GELS 77 3.3.2.2 AUTONOMOUS
MOTION TOWARD THE DARK REGION 78 3.3.2.3 LIGHT-GUIDED MOTION ALONG
COMPLEX PATHS 81 3.4 CONCLUSIONS 87
ACKNOWLEDGMENTS 89 REFERENCES 89
4 SELF-REPAIRING POLYMERIC MATERIALS 93 BISWAJIT GHOSH, CATHRIN C.
CORTEN, AND MAREK W. URBAN 4.1 INTRODUCTION 93
4.2 DAMAGE AND REPAIR MECHANISMS IN POLYMERS 97 4.2.1 DIMENSIONS OF
DAMAGES AND REPAIRS 99 4.2.1.1 ANGSTROM-LEVEL REPAIRS 99 4.2.1.2
NANOMETER-LEVEL REPAIRS 107 4.2.1.3 MICROMETER-LEVEL REPAIRS 110 4.2.1.4
MILLIMETER-LEVEL REPAIRS 112 4.3 SUMMARY 113
REFERENCES 114
5 STIMULI-DRIVEN ASSEMBLY OF CHROMOGENIC DYE MOLECULES: A VERSATILE
APPROACH FOR THE DESIGN OF RESPONSIVE POLYMERS 117 BRIAN MAKOWSKI, JILL
KUNZELMAN, AND CHRISTOPH WEDER
5.1 INTRODUCTION 117
5.2 EXCIMER-FORMING SENSOR MOLECULES 118 5.3 FLUORESCENT MECHANOCHROMIC
SENSORS 121 5.4 THERMOCHROMIC SENSORS 129
5.5 CHEMICAL SENSING WITH EXCIMER-FORMING DYES 133 5.6 SUMMARY AND
OUTLOOK 135
ACKNOWLEDGMENTS 136 REFERENCES 136
IMAGE 3
CONTENTS VII
6 SWITCHABLE SURFACE APPROACHES 139
AFIIN M. ROSS, HIMABINDU NANDIVADA, AND JOERG LAHANN 6.1 INTRODUCTION
139
6.2 ELECTROACTIVE MATERIALS 139 6.2.1 HIGH-DENSITY AND LOW-DENSITY
SELF-ASSEMBLED MONOLAYERS 139 6.2.2 SELF-ASSEMBLED MONOLAYERS WITH
HYDROQUINONE INCORPORATION 141 6.3 PHOTORESPONSIVE MATERIALS 142 6.3.1
MOLECULES CONTAINING AZOBENZENE UNITS 142 6.3.2 MOLECULES CONTAINING
SPIROPYRAN UNITS 143 6.3.3 PHOTORESPONSIVE SHAPE-MEMORY POLYMERS 144 6.4
PH-RESPONSIVE MATERIALS 145 6.4.1 PH-SWITCHABLE SURFACES BASED ON
SELF-ASSEMBLED MONOLAYERS
(SAMS) 146
6.4.2 PH-SWITCHABLE SURFACES BASED ON POLYMER BRUSHES 146 6.5
THERMORESPONSIVE MATERIALS 147 6.5.1 TEMPERATURE-DEPENDENT SWITCHING
BASED ON POLY(N-ISO-PROPYLACRYLAMIDE) (PNIPAAM) 147
6.5.2 TEMPERATURE-DEPENDENT SWITCHING IN POLYMER BRUSHES 149 6.5.3
THERMORESPONSIVE SHAPE-MEMORY POLYMERS 149 6.6 SWITCHABLE SURFACES BASED
ON SUPRAMOLECULAR SHUTTLES 150 6.6.1 ROTAXANE SHUTTLES 151 6.6.2
SWITCHES BASED ON CATENANES 152 6.7 SWITCHABLE SURFACES COMPRISING DNA
AND PEPTIDE MONOLAYERS 153 6.7.1 DNA-BASED SURFACE SWITCHES 153 6.7.2
SWITCHES BASED ON APTAMERS 154 6.7.3 SWITCHES BASED ON HELICAL PEPTIDES
155
6.7.4 SWITCHABLE SURFACES OF ELASTINLIKE POLYPEPTIDES (ELP) 155 6.8
SUMMARY 157
REFERENCES 157
7 LAYER-BY-LAYER SELF-ASSEMBLED MULTILAYER STIMULI-RESPONSIVE POLYMERIC
FILMS 165 LEI ZHAI
7.1 INTRODUCTION 165
7.2 FABRICATION OF MULTILAYER POLYMER COATINGS 367 7.3 RESPONSE OF
MULTILAYER POLYMER COATINGS TO EXTERNAL STIMULI 369 7.3.1 SALT
CONCENTRATION CHANGE 169 7.3.2 PH ALTERNATION 170
7.3.3 TEMPERATURE VARIATION 175 7.3.4 LIGHT RADIATION 178
7.3.5 ELECTROCHEMICAL STIMULI 181 7.3.6 SPECIFIC MOLECULAR INTERACTION
183 7.4 CONCLUSION AND OUTLOOK 184
REFERENCES 185 FURTHER READING 390
IMAGE 4
VIII I CONTENTS
8 PHOTOREFRACTIVE POLYMERS 393
KISHORE V. CHELLAPAN, RANI JOSEPH, AND DHANYA RAMACHANDRAN 8.1
INTRODUCTION 191
8.2 THE PHOTOREFRACTIVE EFFECT IN POLYMERS 193 8.2.1 CHARGE GENERATION
AND TRANSPORT IN POLYMERS 193 8.2.2 ELECTRO-OPTIC RESPONSE IN POLYMERS
200 8.2.3 FORMATION OF PHOTOREFRACTIVE GRATINGS 204 8.3 THE TWO-BEAM
COUPLING EFFECT 205 8.4 HIGH-PERFORMANCE PHOTOREFRACTIVE POLYMERS 206
8.4.1 GUEST-HOST POLYMER SYSTEMS 206 8.4.2 FUNCTIONALIZED POLYMER
SYSTEMS 211 8.5 EXPERIMENTAL TECHNIQUES 213 8.5.1 PHOTOCONDUCTIVITY AND
ELECTRO-OPTIC RESPONSES 213 8.5.2 TWO-BEAM COUPLING 234 8.5.3
DIFFRACTION EFFICIENCY AND RESPONSE TIME 216 8.6 CONCLUSIONS 218
REFERENCES 238
9 PHOTOCHROMIC RESPONSES IN POLYMER MATRICES 223 DHANYA RAMACHANDRAN AND
MAREK W. URBAN 9.1 INTRODUCTION 223
9.2 PHOTOCHROMIC POLYMERIC SYSTEMS 224 9.2.1 INFLUENCE OF MOLECULAR
STRUCTURES 224 9.2.2 ENVIRONMENTAL EFFECTS 226 9.2.3 KINETICS OF
PHOTOREACTIONS 227 9.3 PHOTOCHROMIC SYSTEMS 229
9.3.1 AZOBENZENES 229
9.3.2 SPIROPYRANS 231
9.3.3 DIARYLETHENES 234
9.3.4 FULGIDES 237
9.4 OUTLOOK OF PHOTOCHROMIC MATERIALS 238 ACKNOWLEDGMENTS 240 REFERENCES
240
10 COVALENT BONDING OF FUNCTIONAL COATINGS ON CONDUCTIVE MATERIALS: THE
ELECTROCHEMICAL APPROACH 247 MICHAEL CECIUS AND CHRISTINE JEROME 10.1
INTRODUCTION 247
10.2 ELECTRODEPOSITED COATINGS 248 10.3 ELECTROGRAFTED COATINGS 249 10.4
COMPOUNDS REQUIRING AN ANODIC PROCESS 250 10.4.1 ALIPHATIC PRIMARY
AMINES 250
10.4.2 ARYLACETATES 252 10.4.3 PRIMARY ALCOHOLS 253 10.4.4
ARYLHYDRAZINES 254
IMAGE 5
CONTENTS IX
10.5 COMPOUNDS REQUIRING A CATHODIC PROCESS 254
10.5.1 ARYLDIAZONIUM SALTS 254 10.5.2 (METH)ACRYLIC MONOMERS 258 10.5.3
IODIDE DERIVATIVES 263 10.6 CONCLUSIONS 264
REFERENCES 265
INDEX 269 |
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| title_exact_search | Handbook of stimuli-responsive materials |
| title_full | Handbook of stimuli-responsive materials ed. by Marek W. Urban |
| title_fullStr | Handbook of stimuli-responsive materials ed. by Marek W. Urban |
| title_full_unstemmed | Handbook of stimuli-responsive materials ed. by Marek W. Urban |
| title_short | Handbook of stimuli-responsive materials |
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