Complex metallic alloys: fundamentals and applications
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2011
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| Physical Description: | XXIV, 409 S. Ill., graph. Darst. 25 cm |
| ISBN: | 9783527325238 |
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| 245 | 1 | 0 | |a Complex metallic alloys |b fundamentals and applications |c ed. by Jean-Marie Dubois ... |
| 264 | 1 | |a Weinheim |b Wiley-VCH-Verl. |c 2011 | |
| 300 | |a XXIV, 409 S. |b Ill., graph. Darst. |c 25 cm | ||
| 336 | |b txt |2 rdacontent | ||
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IMAGE 1
XI
CONTENTS
FOREWORD V PREFACE XIX
LIST OFCONTRIBUTORS XXI
1 INTRODUCTION TO THE SCIENCE OF COMPLEX METALLIC ALLOYS 1 JEAN-MARIE
DUBOIS, ESTHER BELIN-FERRE, AND MICHAEL FEUERBACHER 1.1 INTRODUCTION 1
1.2 COMPLEX METALLIC ALLOY: WHAT IS IT? 2 1.2.1 COMPOSITION AND
VARIETIES 3 1.2.2 COMPLEXITY AT A GLANCE 4 1.2.3 DEFECTS 6
1.3 COMPLEX METALLIC ALLOY: WHY IS IT COMPLEX? 12 1.3.1 ELECTRONIC
DENSITIES OF STATES AND HUME-ROTHERY RULES 12 1.3.2 SELF-HYBRIDIZATION
IN AL-MG ALLOYS 15 1.4 A BRIEF SURVEY OF PROPERTIES 18
1.4.1 TRANSPORT PROPERTIES 18 1.4.2 SURFACE PHYSICS AND CHEMISTRY 20
1.4.3 SURFACE ENERGY 22
1.4.4 PLASTICITY 25
1.5 POTENTIAL APPLICATIONS 30
1.5.1 APPLICATIONS RELATED TO SURFACE ENERGY 30 1.5.2 APPLICATIONS
RELATED TO TRANSPORT PROPERTIES 33 1.5.3 APPLICATIONS RELATED TO
DISPERSION OF PARTICLES IN A MATRIX 35 1.6 CONDUSION AND INTRODUCTION OF
THE FOLLOWING CHAPTERS 36
REFERENCES 36
2 PROPERTIES OF CMAS: THEORY AND EXPERIMENTS 41 ENRIQUE MACIO AND MARE
DE BOISSIEU 2.1 INTRODUCTION 41
2.2 ELECTRONIC-STRUCTURE-RELATED PROPERTIES 43 2.2.1 TRANSPORT
PROPERTIES OF QUASICRYSTALS AND APPROXIMANTS 43
COMPLEX METALLIC ALLOYS: FUNDAMENTALS AND APPLICATIONS EDITED BY
JEAN-MARIE DUBOIS AND ESTHER BELIN-FERRE COPYRIGHT 2011 WILEY-VCH
VERLAG GMBH & CO. KGAA, WEINHEIM ISBN: 978-3-527-32523-8
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/998577979
DIGITALISIERT DURCH
IMAGE 2
XII CONTENTS
2.2.1.1 INVERSE MATTHIESSEN RULE 43
2.2.1.2 CURRENT-VOLTAGE CURVES 44 2.2.1.3 OPTICAL CONDUCTIVITY 45
2.2.1.4 SEEBECK COEFFICIENT 49 2.2.1.5 -WIEDEMANN-FRANZ LAW 49 2.2.2
CHEMICAL TRENDS 53
2.2.3 ELECTRONIC STRUCTURE 56 2.2.3.1 FERMI-LEVEL -PSEUDOGAP 56 2.2.3.2
FINE SPECTRAL FEATURES 57 2.2.3.3 SPECTRAL CONDUCTIVITY MODELS 59
2.2.3.4 THE ROLE OF CRITICAL STATES 60
2.2.4 PHENOMENOLOGICAL APPROACHES 63 2.2.4.1 KUBO-GREENWOOD FORMALISM OF
TRANSPORT COEFFICIENTS 63 2.2.4.2 APPLICATION EXAMPLES 67 2.3 PHONONS 71
2.3.1 PHONONS: AN INTRODUCTION 71 2.3.2 MEASURING PHONONS: INELASTIC
NEUTRON AND X-RAY SCATTERING 75 2.3.2.1 COHERENT INELASTIC NEUTRON
SCATTERING 75 2.3.2.2 INCOHERENT INELASTIC NEUTRON SCATTERING 78 2.3.3
BEYOND THE HARMONIE APPROXIMATION 78 2.3.4 PHONONS IN QUASICRYSTALS AND
THEIR APPROXIMANTS 81 2.3.4.1 THE ZN 2 MG LAVES PHASE 81 2.3.4.2 THE
I-AL-PD-MN ICOSAHEDRAL QUASICRYSTAL 86 2.3.4.3 THE I-ZN-MG-SC
QUASICRYSTAL AND ITS 1/1 ZN-SC APPROXIMANT 88 2.3.5 PHONONS IN CAGE
COMPOUNDS AND THERMOELECTRICITY 95
2.3.5.1 CLATHRATES 96 2.3.5.2 SKUTTERUDITES 101 2.3.5.3 ZINC-ANTIMONY
ALLOY ZN 4 SB 3 103 2.3.6 PHONON AND TRANSPORT PROPERTIES: THE EXAMPLE
OF THERMOELECTRICITY 105 2.3.6.1 THERMAL CONDUCTIVITY 105 2.3.6.2
THERMOELECTRIC FIGURE OF MERIT 106 2.4 CONCLUSION 109
REFERENCES 109
3 ANISOTROPIC PHYSICAL PROPERTIES OF COMPLEX METALLIC ALLOYS 117 JANEZ
DOLINSEK AND ANA SMONTARA 3.1 INTRODUCTION 117
3.2 STRUCTURAL CONSIDERATIONS AND SAMPLE PREPARATION 118 3.2.1
Y-AL-NI-CO 118 3.2.2 O-AL, 3 CO 4 119
3.2.3 AL 4 (CR,FE) 129
3.3 ANISOTROPIC MAGNETIC PROPERTIES 120 3.3.1 Y-AL-NI-CO 120 3.3.2
0-AI13C04 120
IMAGE 3
CONTENTS XIII
3.3.3
3.4 3.4.1 3.4.2 3.4.3 3.5 3.5.1 3.5.2 3.5.3 3.6 3.6.1 3.6.2 3.6.3 3.7
3.7.1 3.7.2 3.7.3 3.8 3.8.1 3.8.2 3.8.3 3.9
3.9.1 3.9.2 3.9.2.1
3.9.2.2 3.9.2.3 3.10
AL 4 (CR,FE) 122 ANISOTROPIC ELECTRICAL RESISTIVITY 124 Y-AL-NI-CO 124
0-AI13C04 125
AL 4 (CR,FE) 126 ANISOTROPIC THERMOELECTRIC POWER 130 Y-AL-NI-CO 130
O-AL 13 CO 4 131
AL4(CR,FE) 132 ANISOTROPIC HALL COEFFICIENT 132 Y-AL-NI-CO 132 O-ALI 3
CO 4 134 AL 4 (CR,FE) 135 ANISOTROPIC THERMAL CONDUCTIVITY 136
Y-AL-NI-CO 136
0-AI13C04 136 AL,(CR,FE) 138 FERMI SURFACE AND THE ELECTRONIC DENSITY OF
STATES 140 Y-AL-NI-CO 140
O-ALI 3 CO 4 142 AL 4 (CR,FE) 142 THEORETICAL AB INITIO CALCULATION OF
THE ELECTRONIC TRANSPORT COEFFICIENTS 144
ANISOTROPIC HALL COEFFICIENT OF Y-AL-NI-CO 146 ANISOTROPIC TRANSPORT
COEFFICIENTS OF O-A1 13 CO 4 148 ELECTRICAL RESISTIVITY 148 ELECTRONIC
THERMAL CONDUCTIVITY 149
HALL COEFFICIENT 150 CONCLUSION 151 REFERENCES 152
4 SURFACE SCIENCE OF COMPLEX METALLIC ALLOYS 155 VINCENT FOURNEE, JULIAN
LEDIEU, ANDJEONG Y. PARK 4.1 INTRODUCTION 155
4.2 SURFACE-STRUCTURE DETERMINATION 156 4.2.1 SURFACE PREPARATION 156
4.2.2 STRUCRURE FROM REAL-SPACE METHODS 159 4.2.3 STRUCRURE FROM
RECIPROCAL-SPACE METHODS 165
4.2.4 STRUCRURE FROM AB INITIO METHODS 167 4.2.5 STABILITYOF ALLOY
SURFACES 169 4.3 ELECTRONIC STRUCRURE 170
4.3.1 THE PSEUDO-GAP FEATURE 170 4.3.2 NATURE OF THE ELECTRONIC STATES
175 4.4 THIN-FILM GROWTH ON CMA SURFACES 177 4.4.1 LOW-COVERAGE REGIME
178
IMAGE 4
XIV CONTENTS
4.4.1.1 NUCLEATION MECHANISM 278
4.4.1.2 IDENTIFICATION OF THE TRAP SITES 179 4.4.1.3 PSEUDOMORPHIC
LAYERS 181 4A.2 MULTILAYER REGIME 284 4.4.2.1 TWINNING OF NANOCRYSTALS
184 AA.2.2 INTERMIXING AND ALLOYING 185 4.4.2.3 ELECTRON CONFINEMENT 186
4.5 ADHESION, FRICTION AND WETTING PROPERTIES OF CMA SURFACES 188 4.5.1
WETTING PROPERTIES 188
4.5.2 ATOMIC-SCALE ADHESION PROPERTIES OF COMPLEX METALLIC ALLOYS 190
4.5.2.1 CONTINUUM-MECHANICS MODELS 290 4.5.2.2 ADHESION ON CLEAN AND
IN-SITU OXIDIZED QUASICRYSTAL SURFACES 191 4.5.2.3 ADHESION MEASURED IN
THE ELASTIC AND INELASTIC REGIME 192 4.5.2.4 ADHESION ON AIR-OXIDIZED
QUASICRYSTAL SURFACES 293
4.5.3 ATOMIC-SCALE FRICTION PROPERTIES 194 4.5.3.1 FRICTION-MEASUREMENT
APPARATUS - FFM AND TRIBOMETER 194 4.5.3.2 FRICTION ON ATOMICALLY CLEAN
AND IN-SITU OXIDIZED QUASICRYSTAL SURFACES 296 4.5.4 FRICTION ANISOTROPY
197 4.5.4.1 FRICTION ANISOTROPY OF CLEAN 2-FOLD AL-NI-CO SURFACE 198
4.5.4.2 FRICTION ANISOTROPY AFTER SURFACE MODIFICATION 200 4.5.4.3 LOW
FRICTION OF QUASICRYSTALS AND LTS RELATION WITH WETTING
AND ADHESION 200
4.6 CONCLUSION 201
REFERENCES 202
5 METALLURGY OF COMPLEX METALLIC ALLOYS 207 SASKIA GOTTLIEB-SCHOENMEYER,
WOLFASSMUS, NATHALIE PRUD'HOMME, AND CONSTANTIN VAHLAS 5.1 INTRODUCTION
207
5.2 BASIC CONCEPTS OF CRYS TAL GROWTH 208 5.2.1 BRIDGMAN METHOD 220
5.2.2 ZONE MELTING 222
5.2.3 CZOCHRALSKI TECHNIQUE 212 5.2.4 FLUX GROWTH TECHNIQUE 214 5.3
EXAMPLES OF SINGLE-CRYSTAL GROWTH OF CMAS 215 5.3.1 AL N CO 4 AND AL 13
FE 4 USING THE CZOCHRALSKI TECHNIQUE 215 5.3.2 SINGLE-CRYSTAL GROWTH OF
(3-AL-MG 217 5.3.2.1 BRIDGMAN GROWTH 218 5.3.2.2 CZOCHRALSKI GROWTH 218
5.3.2.3 SELF-FLUX GROWTH 218 5.3.3 SINGLE-CRYSTAL GROWTH OF MG 32
(AL,ZN) 49 219
5.3.3.1 BRIDGMAN GROWTH 219 5.3.3.2 CZOCHRALSKI GROWTH 220 5.3.4
SINGLE-CRYSTAL GROWTH OF AL-PD-MN APPROXIMANTS 221
IMAGE 5
CONTENTS XV
5.3.5 CRYSTAL GROWTH OF YB-CU SUPERSTRUCTURAL PHASES 222
5.3.6 SINGLE-CRYSTAL GROWTH OF MGZN 2 224 5.3.6.1 BRIDGMAN TECHNIQUE 224
5.3.6.2 LIQUID-ENCAPSULATED KYROPOULUS TECHNIQUE 224 5.4 INTRODUCTION TO
CHEMICAL VAPOR DEPOSITION OF COATINGS
CONTAINING CMAS 225 5.5 MOCVD PROCESSING OF AL-CU-FE THIN FILMS 227
5.5.1 PRECURSORS SELECTION 229 5.5.2 DEPOSITION OF ALUMINUM 232 5.5.3
DEPOSITION OF COPPER 233 5.5.4 DEPOSITION OF THE AL 4 CU 9 APPROXIMANT
PHASE 235 5.5.5 DEPOSITION OF IRON 237
5.6 CONCLUDING REMARKS 239
REFERENCES 241
6 SURFACE CHEMISTRY OF CMAS 243
MARIE-CENEVIEVE BARTHES-LABROUSSE, ALESSANDRA BENI, AND PATRIK SCHMUTZ
6.1 INTRODUCTION 243
6.2 SURFACE CHEMISTRY OF CMAS UNDER UHV ENVIRONMENT 244 6.2.1
INTERACTION WITH OXYGEN 244 6.2.2 INTERACTION WITH OTHER MOLECULES 248
6.3 ATMOSPHERIC AGING 251
6.3.1 ATMOSPHERIC OXIDATION 251 6.3.2 SURFACE PROPERTIES IN ATMOSPHERIC
CONDITIONS 254 6.4 SURFACE CHEMISTRY AND REACTIONS IN AQUEOUS SOLUTIONS
255 6.4.1 THERMODYNAMIC STABILITY 255 6.4.2 OXIDE ELECTRONIC PROPERTIES
259 6.4.3 LOCALIZED DEGRADATION REACTIONS 262 6.4.4 SUMMARY: LOCALIZED
CORROSION MODEL FOR THE AL 4 (FE,CR)
COMPOUND 265
6.5 HIGH-TEMPERATURE CORROSION 266 6.5.1 BULK SAMPLES 266
6.5.2 POWDERS, THIN FILMS AND OXIDATION-INDUCED PHASE TRANSFORMATIONS
268 6.6 CONCLUSION 270
REFERENCES 270
7 MECHANICAL ENGINEERING PROPERTIES OF CMAS 273 JUERGEN ECKERT, SERGIO
SCUDINO, MIHAI STOICA, SAMUEL KENZARI, AND MURIEL SALES 7.1 INTRODUCTION
273
7.2 STRUCRURE AND MECHANICAL PROPERTIES OF CMAS 274 7.2.1 SINGLE-PHASE
INTERMETALLICS 274 7.2.2 MULTIPHASE INTERMETALLICS 280
IMAGE 6
XVI CONTENTS
7.3 METAL MATRIX COMPOSITES REINFORCED WITH CMAS 290
7.3.1 PROCESSING OF ALUMINUM MATRIX COMPOSITES REINFORCED WITH CMAS 291
7.3.1.1 THERMAL STABILITY OF CMAS IN AL-BASED MATRIX COMPOSITES 291
7.3.1.2 PRESERVING COMPLEX PHASES IN AL-BASED MATRIX COMPOSITES 292
7.3.2 MECHANICAL PROPERTIES OF AL-BASED COMPOSITES REINFORCED
WITH CMAS 294
7.4 SURFACE MECHANICAL TESTING AND POTENTIAL APPLICATIONS 299 7 AA
FRETTING TESTS (COLD WEIDING) OF CMAS 299 7.4.2 FRICTION PROPERTIES OF
COMPOSITES 306 7.4.2.1 CMA MATRIX COMPOSITES 306
7.4.2.2 AL-BASED COMPOSITES REINFORCED WITH CMAS 309 7.5 CONCLUSIONS 311
REFERENCES 312
8 CMA'S AS MAGNETOCALORIC MATERIALS 317 SPOMENKA KOBE, BENJAMIN
PODMILJSAK, PAUL JOHN MCGUINESS, AND MATE] KOMELJ 8.1 INTRODUCTION 327
8.2 MATERIALS 320
8.2.1 THEORETICAL INVESTIGATION OF THE MAGNETOCALORIC EFFECT 320 8.2.1.1
GD S SI 2 GE 2 322
8.2.1.2 LAFE 13 _ X SI X 321
8.2.2 ELEMENTAL MAGNETOCALORICS 322 8.2.3 INTERMETALLIC COMPOUNDS 323
8.2.3.1 LAVES PHASES 323 8.2.3.2 CMAS [GDSJSI, _ X GE X ) 4 ALLOYS AND
RELATED 5:4 MATERIALS] 324 8.2.4 MN-BASED COMPOUNDS 326 8.2.4.1 MN(AS,_
X SB X ) ALLOYS 326 8.2.4.2 MNFE(P^ X AS X ) ALLOYS 327 8.2.4.3 NI 2 MNX
(X = GA, IN, SN, SB) HEUSLER ALLOYS 328 8.2.4.4 MISCELLANEOUS COMPOUNDS
329
8.2.5 LA(FE 13 _ X M X )-BASED COMPOUNDS 330 8.2.6 MANGANITES 332
8.2.7 MISCELLANEOUS INTERMETALLIC COMPOUNDS 334 8.2.8 NANOCOMPOSITES 336
8.2.9 COMPARISONOF MCE MATERIALS 336 8.2.10 CONCLUSIONS 337 8.3
MAGNETOCALORIC EFFECT AND HYSTERESIS LOSSES OF CMAS 337 8.3.1
SUBSTITUTING GE AND SI WITH VARIOUS ELEMENTS TO REDUCE THE
HYSTERESIS LOSSES 339 8.3.2 PHASE FORMATION AND MAGNETIC PROPERTIES OF
GD 5 SI 2 GE 2 WITH FE SUBSTITUTIONS 339 8.3.3 X-RAY DIFFRACTION
MEASUREMENTS 344
8.3.4 MAGNETIC MEASUREMENTS 344
IMAGE 7
CONTENTS XVII
8.3.5 HYSTERESIS LOSSES 346
8.4 TEM INVESTIGATION OF CMAS 346 8.4.1 TEM RESEARCH ON - GD 5 SI 2 GE 2
ALLOYS 346 8.4.2 IMAGING IN THE TEM 349
8.4.2.1 MASS-THICKNESS CONTRAST 350 8.4.2.2 TEM IMAGES 350 8.4.2.3 STEM
IMAGES 351 8.4.2.4 TEM DIFFRACTION CONTRAST 351 8.4.2.5 STEM DIFFRACTION
CONTRAST 352 8.4.3 EXPERIMENTAL RESULTS OF TEM ANALYSES 353 8.4.4 TEM OF
LOW LOSS SAMPLES 354 8.5 CONCLUSIONS 358
REFERENCES 358
9 RECENT PROGRESS IN THE DEVELOPMENT OF THERMOELECTRIC MATERIALS WITH
COMPLEX CRYSTAL STRUCTURES 365 SILKE PASCHEN, CLAUDE CODART, AND YURI
CRIN
9.1 INTRODUCTION 365
9.2 THERMOELECTRIC FIGURE OF MERIT 365 9.3 DESIGN PRINCIPLES 368
9.3.1 PHONON ENGINEERING 368 9.3.2 ELECTRON ENGINEERING 372 9.4
THERMOELECTRIC MATERIALS 372 9.4.1 ZINTL PHASES 373
9.4.2 SKUTTERUDITES 373
9.4.3 CLATHRATES 376
9 AA ZN 4 SB 3 377
9.4.5 MGAGAS-TYPE (HALF-HEUSLER) PHASES 379 9.5 CONCLUDING REMARKS 380
REFERENCES 380
10 COMPLEX METALLIC PHASES IN CATALYSIS 385 MARE ARMBRUESTER, KIRILL
KOVNIR, YURI CRIN, AND ROBERT SCHLOEGL 10.1 INTRODUCTION 385
10.2 WHY USE INTERMETALLIC COMPOUNDS - THE GENERAL CONCEPT 387 10.2.1
CHEMICAL BONDING 388 10.2.2 INVESTIGATING THE STABILITY IN SITU 390
10.2.2.1 BULK STABILITY 390
10.2.2.2 SURFACE STABILITY 393 10.3 THE SEMIHYDROGENATION OF ACETYLENE
395 10.4 COMPLEX METALLIC PHASES AS PLATFORM MATERIALS FOR HETEROGENEOUS
CATALYSIS 397
REFERENCES 398
INDEX 402 |
| any_adam_object | 1 |
| author2 | Dubois, Jean-Marie |
| author2_role | edt |
| author2_variant | j m d jmd |
| author_facet | Dubois, Jean-Marie |
| building | Verbundindex |
| bvnumber | BV036962080 |
| classification_rvk | ZM 4300 |
| ctrlnum | (OCoLC)693889324 (DE-599)DNB998577979 |
| dewey-full | 546.3 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
| dewey-raw | 546.3 |
| dewey-search | 546.3 |
| dewey-sort | 3546.3 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Werkstoffwissenschaften / Fertigungstechnik |
| format | Book |
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| id | DE-604.BV036962080 |
| illustrated | Illustrated |
| indexdate | 2024-07-20T10:55:46Z |
| institution | BVB |
| isbn | 9783527325238 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-020876951 |
| oclc_num | 693889324 |
| open_access_boolean | |
| owner | DE-92 |
| owner_facet | DE-92 |
| physical | XXIV, 409 S. Ill., graph. Darst. 25 cm |
| publishDate | 2011 |
| publishDateSearch | 2011 |
| publishDateSort | 2011 |
| publisher | Wiley-VCH-Verl. |
| record_format | marc |
| spelling | Complex metallic alloys fundamentals and applications ed. by Jean-Marie Dubois ... Weinheim Wiley-VCH-Verl. 2011 XXIV, 409 S. Ill., graph. Darst. 25 cm txt rdacontent n rdamedia nc rdacarrier Literaturangaben Intermetallische Verbindungen (DE-588)4162028-8 gnd rswk-swf Intermetallische Verbindungen (DE-588)4162028-8 s DE-604 Dubois, Jean-Marie edt X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3385140&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020876951&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Complex metallic alloys fundamentals and applications Intermetallische Verbindungen (DE-588)4162028-8 gnd |
| subject_GND | (DE-588)4162028-8 |
| title | Complex metallic alloys fundamentals and applications |
| title_auth | Complex metallic alloys fundamentals and applications |
| title_exact_search | Complex metallic alloys fundamentals and applications |
| title_full | Complex metallic alloys fundamentals and applications ed. by Jean-Marie Dubois ... |
| title_fullStr | Complex metallic alloys fundamentals and applications ed. by Jean-Marie Dubois ... |
| title_full_unstemmed | Complex metallic alloys fundamentals and applications ed. by Jean-Marie Dubois ... |
| title_short | Complex metallic alloys |
| title_sort | complex metallic alloys fundamentals and applications |
| title_sub | fundamentals and applications |
| topic | Intermetallische Verbindungen (DE-588)4162028-8 gnd |
| topic_facet | Intermetallische Verbindungen |
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