Molecular materials:
Saved in:
| Other Authors: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Chichester
Wiley
2010
|
| Series: | Inorganic materials series
|
| Subjects: | |
| Online Access: | Publisher description Inhaltsverzeichnis |
| Item Description: | Literaturangaben |
| Physical Description: | X, 360 S. Ill., graph. Darst. |
| ISBN: | 9780470986776 |
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MARC
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| 245 | 1 | 0 | |a Molecular materials |c ed. by Duncan W. Bruce ... |
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| 490 | 0 | |a Inorganic materials series | |
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| 650 | 4 | |a Superconductors | |
| 650 | 4 | |a Organic conductors | |
| 650 | 4 | |a Magnetic materialsxOptical properties | |
| 650 | 4 | |a Inorganic compoundsxOptical peoperties | |
| 650 | 4 | |a Molecular dynamics | |
| 650 | 4 | |a Nonlinear optics | |
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Record in the Search Index
| _version_ | 1804143672575393792 |
|---|---|
| adam_text | IMAGE 1
MOLECULAR MATERIALS
EDITED BY
DUNCAN W. BRUCE UNIVERSITY OF YORK, UK
DERMOT O HARE UNIVERSITY OF OXFORD, UK
RICHARD I. WALTON UNIVERSITY OF WARWICK, UK
)WILEY
A JOHN WILEY AND SONS, LTD, PUBLICATION
IMAGE 2
CONTENTS
INORGANIC MATERIALS SERIES PREFACE IX
PREFACE XI
LIST OF CONTRIBUTORS XIII
1 METAL-BASED QUADRATIC NONLINEAR OPTICAL MATERIALS 1
OLIVIER MAURY AND HUBERT LE BOZEC
1.1 INTRODUCTION 1
1.2 BASIC CONCEPTS OF SECOND-ORDER NONLINEAR OPTICS 2
1.2.1 INTRODUCTION TO NONLINEAR MOLECULAR MATERIALS 2
1.2.2 MOLECULAR ENGINEERING OF QUADRATIC NLO CHROMOPHORES 4
1.2.3 EXPERIMENTAL MEASUREMENTS OF SECOND-ORDER NLO ACTIVITIES 7
1.3 DIPOLAR METAL COMPLEXES 9
1.3.1 METAL COMPLEXES AS DONOR GROUPS 9
1.3.2 METAL COMPLEXES AS ACCEPTOR GROUPS 17
1.3.3 BIMETALLIC PUSH-PULL COMPLEXES 22
1.3.4 METAL COMPLEXES AS ^-CONJUGATED BRIDGES 25
1.4 OCTUPOLAR METAL COMPLEXES 31
1.4.1 METAL AS PERIPHERAL DONOR (OR ACCEPTOR) SUBSTITUENT 31
1.4.2 METAL AS TEMPLATE 32
1.4.3 CONFORMATIONAL STUDIES USING SECOND-ORDER NLO ACTIVITY
MEASUREMENTS 39
1.5 SWITCHING OPTICAL NONLINEARITIES OF METAL COMPLEXES 40 1.5.1 REDOX
SWITCHING OF QUADRATIC NONLINEARITIES 41 1.5.2 ACID/BASE SWITCHING OF
QUADRATIC NONLINEARITIES 44 1.5.3 PHOTOSWITCHING OF QUADRATIC
NONLINEARITIES 46
1.6 TOWARDS THE DESIGN OF PRE-ORGANISED MATERIALS 48
1.6.1 SUPRAMOLECULAR OCTUPOLAR SELF-ORDERING WITHIN METALLODENDRIMERS 48
1.6.2 ENGINEERING OF NLO-ACTIVE CRYSTALS 50
1.7 CONCLUSIONS 52
REFERENCES 53
IMAGE 3
CONTENTS
PHYSICAL PROPERTIES OF METALLOMESOGENS 61
KOEN BINNEMANS
2.1 2.2 2.3
2.4
2.5
2.6
INTRODUCTION OVERVIEW OF MESOPHASES OPTICAL PROPERTIES 2.3.1
BIREFRINGENCE
2.3.2 LIGHT ABSORPTION AND COLOUR 2.3.3 LUMINESCENCE 2.3.4 NONLINEAR
OPTICAL PROPERTIES ELECTRICAL PROPERTIES 2.4.1 ELECTRICAL CONDUCTIVITY
2.4.2 PHOTOCONDUCTIVITY 2.4.3 ELECTROCHROMISM 2.4.4 FERROELECTRICITY
MAGNETIC PROPERTIES
2.5.1 MAGNETIC ANISOTROPY AND ALIGNMENT IN EXTERNAL MAGNETIC FIELDS
2.5.2 SPIN-CROSSOVER PHENOMENA 2.5.3 SINGLE MOLECULE MAGNETS CONCLUSIONS
REFERENCES
61 62 68 68 69 76 96 100 100 106 106 108 110
110 124 130 132 133
MOLECULAR MAGNETIC MATERIALS 143
NEIL ROBERTSON AND GORDON T. YEE
3.1 INTRODUCTION 143
3.1.1 HISTORY OF MEASUREMENTS 146
3.2 BASIC CONCEPTS 147
3.2.1 MAGNETISATION AND SUSCEPTIBILITY 147
3.2.2 THE CURIE AND CURIE-WEISS LAWS 149
3.2.3 OTHER MEASUREMENTS 155
3.2.4 ORBITAL ANGULAR MOMENTUM 156
3.3 THE VAN VLECK EQUATION 163
3.3.1 APPLICATION OF THE VAN VLECK FORMULA TO AN ISOLATED, SPIN-ONLY
METAL COMPLEX 164
3.3.2 DEVIATIONS FROM THE CURIE LAW: ZERO-FIELD SPLITTING 165
3.3.3 EXCHANGE COUPLING 167
3.4 DIMENSIONALITY OF MAGNETIC SYSTEMS 172
3.4.1 LATTICE DIMENSIONALITY VS SINGLE ION ANISOTROPY 173
IMAGE 4
CONTENTS
VLL
3.4.2 MEAN OR MOLECULAR FIELD APPROXIMATION
IN ANY DIMENSION AND ANY VALUE OF S 173
3.4.3 ONE-DIMENSIONAL SYSTEMS 174
3.4.4 TWO-DIMENSIONAL MAGNETIC MATERIALS 180
3.4.5 THREE-DIMENSIONAL MAGNETIC MATERIALS 183
3.5 SWITCHABLE AND HYBRID SYSTEMS AND FUTURE PERSPECTIVES 189
3.5.1 BISTABLE AND SWITCHABLE MAGNETIC MATERIALS 189
3.5.2 MULTIFUNCTIONAL MAGNETIC MATERIALS 196
3.6 CONCLUSIONS 204
REFERENCES 205
MOLECULAR INORGANIC CONDUCTORS AND SUPERCONDUCTORS 211 LYDIE VALADE AND
HISASHI TANAKA
4.1 INTRODUCTION 211
4.2 FAMILIES OF MOLECULAR CONDUCTORS AND SUPERCONDUCTORS 213
4.2.1 FROM MOLECULES TO CONDUCTORS AND SUPERCONDUCTORS 213
4.2.2 ORGANIC METALS AND SUPERCONDUCTORS 216
4.2.3 TRANSITION METAL COMPLEX-BASED CONDUCTING SYSTEMS 225
4.3 SYSTEMS BASED ON METAL BIS-DITHIOLENE COMPLEXES 236
4.3.1 SYNTHESIS OF METAL BIS-DITHIOLENE COMPLEXES 236 4.3.2 SYNTHESIS OF
CONDUCTORS AND SUPERCONDUCTORS BASED ON METAL BIS-DITHIOLENE COMPLEXES
238
4.3.3 SUPERCONDUCTORS BASED ON [M(DMIT)2] COMPLEXES 243
4.3.4 CONDUCTORS BASED ON NEUTRAL METAL BIS-DITHIOLENE COMPLEXES 249
4.4 TOWARDS THE APPLICATION OF MOLECULAR INORGANIC CONDUCTORS AND
SUPERCONDUCTORS 252
4.4.1 PROCESSING METHODS 252
4.4.2 FILMS AND NANOWIRES OF MOLECULAR INORGANIC CONDUCTORS 256
4.5 CONCLUSIONS 267
ACKNOWLEDGEMENTS 269
REFERENCES 269
IMAGE 5
VLLL
CONTENTS
5 MOLECULAR NANOMAGNETS 281
RICHARD E. P. WINPENNY AND ERIC J. L. MCLNNES
5.1 5.2 5.3
5.4
5.5
REFE
INTRODUCTION A VERY BRIEF INTRODUCTION TO MAGNETOCHEMISTRY TECHNIQUES
5.3.1 MAGNETOMETRY
5.3.2 AC MAGNETOMETRY 5.3.3 MICRO-SQUIDS 5.3.4 SPECIFIC HEAT 5.3.5
TORQUE MAGNETOMETRY
5.3.6 ELECTRON PARAMAGNETIC RESONANCE (EPR) SPECTROSCOPY 5.3.7 INELASTIC
NEUTRON SCATTERING (INS) 5.3.8 NUCLEAR MAGNETIC RESONANCE (NMR)
SPECTROSCOPY
SINGLE MOLECULE MAGNETS 5.4.1 PHYSICS OF SINGLE MOLECULE MAGNETS 5.4.2
CHEMISTRY OF SINGLE MOLECULE MAGNETS EMERGING TRENDS
5.5.1 MONOMETALLIC SMMS 5.5.2 MOLECULAR SPINTRONICS 5.5.3 QUANTUM
INFORMATION PROCESSING 5.5.4 ANTIFERROMAGNETIC (AF) RINGS AND CHAINS
5.5.5 MAGNETOCALORIC EFFECT 5.5.6 HIGH SYMMETRY POLYHEDRA AND SPIN
FRUSTRATION 5.5.7 SINGLE CHAIN MAGNETS RENCES
281 283 288 288 291 292 292
294
295 297
299 300 300 315
322 322 325 328 332 334 336 340 342
INDEX 349
|
| any_adam_object | 1 |
| author2 | Bruce, Duncan W. 1960- |
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| discipline | Chemie / Pharmazie |
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| id | DE-604.BV036951852 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:51:23Z |
| institution | BVB |
| isbn | 9780470986776 |
| language | English |
| lccn | 2009041767 |
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| physical | X, 360 S. Ill., graph. Darst. |
| publishDate | 2010 |
| publishDateSearch | 2010 |
| publishDateSort | 2010 |
| publisher | Wiley |
| record_format | marc |
| series2 | Inorganic materials series |
| spelling | Molecular materials ed. by Duncan W. Bruce ... Chichester Wiley 2010 X, 360 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Inorganic materials series Literaturangaben Superconductors Organic conductors Magnetic materialsxOptical properties Inorganic compoundsxOptical peoperties Molecular dynamics Nonlinear optics Optischer Werkstoff (DE-588)4172680-7 gnd rswk-swf Magnetwerkstoff (DE-588)4136920-8 gnd rswk-swf Halbleiterwerkstoff (DE-588)4158817-4 gnd rswk-swf Magnetwerkstoff (DE-588)4136920-8 s Optischer Werkstoff (DE-588)4172680-7 s Halbleiterwerkstoff (DE-588)4158817-4 s DE-604 Bruce, Duncan W. 1960- (DE-588)142375721 edt http://www.loc.gov/catdir/enhancements/fy1001/2009041767-d.html Publisher description GBV Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020866896&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Molecular materials Superconductors Organic conductors Magnetic materialsxOptical properties Inorganic compoundsxOptical peoperties Molecular dynamics Nonlinear optics Optischer Werkstoff (DE-588)4172680-7 gnd Magnetwerkstoff (DE-588)4136920-8 gnd Halbleiterwerkstoff (DE-588)4158817-4 gnd |
| subject_GND | (DE-588)4172680-7 (DE-588)4136920-8 (DE-588)4158817-4 |
| title | Molecular materials |
| title_auth | Molecular materials |
| title_exact_search | Molecular materials |
| title_full | Molecular materials ed. by Duncan W. Bruce ... |
| title_fullStr | Molecular materials ed. by Duncan W. Bruce ... |
| title_full_unstemmed | Molecular materials ed. by Duncan W. Bruce ... |
| title_short | Molecular materials |
| title_sort | molecular materials |
| topic | Superconductors Organic conductors Magnetic materialsxOptical properties Inorganic compoundsxOptical peoperties Molecular dynamics Nonlinear optics Optischer Werkstoff (DE-588)4172680-7 gnd Magnetwerkstoff (DE-588)4136920-8 gnd Halbleiterwerkstoff (DE-588)4158817-4 gnd |
| topic_facet | Superconductors Organic conductors Magnetic materialsxOptical properties Inorganic compoundsxOptical peoperties Molecular dynamics Nonlinear optics Optischer Werkstoff Magnetwerkstoff Halbleiterwerkstoff |
| url | http://www.loc.gov/catdir/enhancements/fy1001/2009041767-d.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020866896&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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