Thermodynamics of materials:
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Heidelberg [u.a.]
Springer
2011
|
| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | X, 298 S. graph. Darst. |
| ISBN: | 9783642147173 |
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Record in the Search Index
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IMAGE 1
CONTENTS
CHAPTER 1 FUNDAMENTALS OF THERMODYNAMICS 1
1.1 THERMODYNAMICS OF MATERIALS SCIENCE, SCOPE AND SPECIAL FEATURES OF
THE BOOK 1
1.2 CONCEPTS OF THERMODYNAMICS 5
1.3 TEMPERATURE AND ZEROTH LAW OF THERMODYNAMICS 10
1.4 FIRST LAW OF THERMODYNAMICS 11
1.5 ENTROPY AND SECOND LAW OF THERMODYNAMICS 20
1.6 GENERAL THERMODYNAMIC RELATIONSHIPS 24
1.7 THIRD LAW OF THERMODYNAMICS 32
REFERENCES 34
CHAPTER 2 STATISTICAL THERMODYNAMICS 37
2.1 BASIC CONCEPTS 38
2.2 CLASSICAL STATISTIC THERMODYNAMICS OF INDEPENDENT PARTICLES 43
2.3 ENERGY MODE AND ENERGY LEVELS 47
2.4 BOSE-EINSTEIN AND FERMI-DIRAC STATISTICS 52
2.5 APPLICATION OF QUANTUM STATISTICS 54
2.5.1 SPATIAL CONFIGURATION OF LONG CHAIN POLYMERS 54 2.5.2 STATISTICAL
THERMODYNAMICS OF A PARAMAGNETIC CRYSTAL 58
2.5.3 NEGATIVE TEMPERATURE 63
REFERENCES 65
CHAPTER 3 HEAT CAPACITY, ENTROPY, AND NANOTHERMODYNAMICS 67
3.1 HEAT CAPACITY 67
3.1.1 RELATIONS OF PRINCIPAL HEAT CAPACITIES 67
3.1.2 MAGNETIC HEAT CAPACITY 69
3.1.3 HEAT CAPACITY OF LATTICE VIBRATION OF SOLIDS 71
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1004070780
DIGITALISIERT DURCH
IMAGE 2
VIII CONTENTS
3.1.4 ELECTRONIC HEAT CAPACITY OF METALS 75
3.2 ENTROPY 78
3.2.1 POSITIONAL PART OF MELTING ENTROPY AND ITS EVALUATION 83
3.2.2 CONTRIBUTION OF VIBRATIONAL PART OF MELTING ENTROPY OF
SEMICONDUCTORS 85
3.2.3 ELECTRONIC COMPONENT OF MELTING ENTROPY 87
3.3 NANOTHERMODYNAMICS 93
3.4 MELTING THERMODYNAMICS 95
3.4.1 A MELTING CRITERION 95
3.4.2 EXISTING MODELS FOR SIZE-DEPENDENT MELTING OF CRYSTALS * * * * 96
3.4.3 SIZE-DEPENDENT MELTING THERMODYNAMICS OF CRYSTALS 100
3.5 COHESIVE ENERGY 106
3.5.1 SIZE-DEPENDENT COHESIVE ENERGY OF CRYSTALS 106 3.5.2 VACANCY
FORMATION ENERGY AND COHESIVE ENERGY OF CLUSTERS 108
3.6 SIZE EFFECT ON BANDGAP OF II-VI SEMICONDUCTOR NANOCRYSTALS 114
REFERENCES 116
C H A P T ER 4 P H A SE DIAGRAMS 119
4.1 GIBBS PHASE RULE AND PHASE DIAGRAM OF UNARY SYSTEM 119 4.2 CLAPEYRON
EQUATION IN CONDENSED STATE EQUILIBRIA 121
4.3 SOLUTION, PARTIAL MOLAR PROPERTIES AND CHEMICAL POTENTIAL * * * 126
4.4 GRAPHICAL REPRESENTATION, IDEAL AND REGULAR SOLUTIONS 129 4.5
EQUILIBRIUM CONDITIONS OF PHASES AND PHASE DIAGRAM OF BINARY SYSTEMS 135
4.5.1 COMPLETE MISCIBILITY, CONTINUOUS BINARY SOLUTION PHASE DIAGRAM AND
RELATED SIZE DEPENDENCE 136 4.5.2 IMMISCIBILITY-TWO MECHANISMS OF PHASE
TRANSITIONS 140
4.6 ON APPROXIMATION OF GIBBS FREE ENERGY CHANGE OF CRYSTALLIZATION 144
4.7 BANDGAP ENERGY OF BINARY NANOSEMICONDUCTOR ALLOYS 148 REFERENCES 154
IMAGE 3
CONTENTS IX
CHAPTER 5 THERMODYNAMICS OF PHASE TRANSITIONS 157
5.1 THERMODYNAMIC CLASSIFICATION OF PHASE TRANSITIONS 157 5.2 LANDAU AND
ISING MODELS FOR THE SECOND-ORDER PHASE TRANSITIONS 160
5.2.1 LANDAU MODEL 160
5.2.2 ISING MODEL AND ITS APPLICATIONS 162
5.2.3 CRITICAL EXPONENT 164
5.3 THERMODYNAMICS OF MARTENSITIC AND BAINITE TRANSITIONS * * - * 166
5.4 GLASS TRANSITION 174
5.4.1 FREEZING INTO SOLID STATE: GLASS FORMATION VERSUS CRYSTALLIZATION
174
5.4.2 CHARACTERISTIC PROPERTIES OF GLASS TRANSITION 178 5.4.3 SIZE
EFFECT ON GLASS TRANSITION 180
5.5 FERROMAGNETIC AND ANTIFERROMAGNETIC PHASE TRANSITIONS OF
NANOCRYSTALS 184
5.5.1 SIZE-DEPENDENT ORDERING TEMPERATURES OF FERROMAGNETIC AND
ANTIFERROMAGNETIC NANOCRYSTALS * * * 184 5.5.2 THERMAL STABILITY IN
EXCHANGE-BIASED FM/AFM BILAYERS 191
5.5.3 FERROELECTRIC PHASE TRANSITION OF NANOCRYSTALS 197 5.5.4
SUPERCONDUCTIVE PHASE TRANSITION OF NANOCRYSTALS * * * * 202 REFERENCES
205
CHAPTER 6 THERMODYNAMICS OF INTERFACES 207
6.1 POINT DEFECT THERMODYNAMICS 208
6.2 LINE DEFECTS THERMODYNAMICS 211
6.3 THERMODYNAMICS OF INTERFACES 214
6.3.1 THERMODYNAMIC DESCRIPTION OF SURFACE FREE ENERGY OF LIQUIDS AND
SOLIDS 215
6.3.2 THERMODYNAMICS OF SURFACE STRESS AND INTRINSIC STRESS 216
6.3.3 REAL SURFACE: RECONSTRUCTION AND RELAXATION 221 6.3.4 EQUILIBRIUM
OF FLUID DROPLETS AND SOLID PARTICLES 225 6.3.5 WULFF CONSTRUCTION AND
ADSORPTION ON SOLID SURFACES 229
6.4 SOLID-LIQUID INTERFACE ENERGY 232
6.4.1 BULK SOLID-LIQUID INTERFACE ENERGY AND THAT AT MELTING POINTS 232
6.4.2 SIZE DEPENDENCE OF SOLID-LIQUID INTERFACE ENERGY 239
IMAGE 4
X CONTENTS
6.4.3 NUCLEUS-LIQUID INTERFACE ENERGY 242
6.5 SOLID-SOLID INTERFACE ENERGY 246
6.6 SOLID-VAPOR INTERFACE ENERGY OR SURFACE ENERGY 248
6.6.1 BULK SURFACE ENERGY OF ELEMENTARY SOLIDS 248
6.6.2 7SVO OF SEVERAL CERAMICS WITH NACL STRUCTURE 257 6.6.3
SIZE-DEPENDENT SURFACE ENERGY OF SOLIDS 261
6.7 LIQUID-VAPOR INTERFACE ENERGY OR SURFACE TENSION 264 6.7.1 BULK
SURFACE TENSION AND ITS TEMPERATURE COEFFICIENT 264
6.7.2 DETERMINATION OF 7LVO(T 1 M ) AND 7L V O(^M) VALUES AND 7LVO(T)
AND 7 L V 0 ( T) FUNCTIONS 267
6.7.3 SIZE DEPENDENCE OF LIQUID-VAPOR INTERFACE ENERGY * * * * 275 6.8
APPLICATIONS OF SIZE-DEPENDENT INTERFACE ENERGY 278 6.8.1 THERMODYNAMIC
PHASE STABILITY OF NANOCARBONS 278 6.8.2 STATIC HYSTERESIS OF SOLID
TRANSITION OF CDSE
NANOCRYSTALS 284
6.8.3 CRITICAL LAYER NUMBER AND CRITICAL MISFIT OF EPITAXIAL GROWN
METALLIC THIN FILMS 287
6.8.4 RECONSTRUCTION POSSIBILITY OF FEE METALLIC SURFACES AT ROOM
TEMPERATURE 291
REFERENCES 293
INDEX 295 |
| any_adam_object | 1 |
| author | Jiang, Qing Wen, Zi |
| author_facet | Jiang, Qing Wen, Zi |
| author_role | aut aut |
| author_sort | Jiang, Qing |
| author_variant | q j qj z w zw |
| building | Verbundindex |
| bvnumber | BV036752165 |
| classification_rvk | UG 1000 ZM 3400 |
| ctrlnum | (OCoLC)705941591 (DE-599)DNB1004070780 |
| dewey-full | 620.11296 621.4021 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
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| dewey-raw | 620.11296 621.4021 |
| dewey-search | 620.11296 621.4021 |
| dewey-sort | 3620.11296 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Maschinenbau / Maschinenwesen Physik Energietechnik Werkstoffwissenschaften / Fertigungstechnik |
| format | Book |
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| indexdate | 2024-07-20T10:50:35Z |
| institution | BVB |
| isbn | 9783642147173 |
| language | English |
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| spelling | Jiang, Qing Verfasser aut Thermodynamics of materials Qing Jiang ; Zi Wen Heidelberg [u.a.] Springer 2011 X, 298 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Werkstoff (DE-588)4065579-9 gnd rswk-swf Thermodynamik (DE-588)4059827-5 gnd rswk-swf Werkstoffkunde (DE-588)4079184-1 gnd rswk-swf Thermodynamische Eigenschaft (DE-588)4126056-9 gnd rswk-swf Thermodynamik (DE-588)4059827-5 s Werkstoffkunde (DE-588)4079184-1 s DE-604 Werkstoff (DE-588)4065579-9 s Thermodynamische Eigenschaft (DE-588)4126056-9 s Wen, Zi Verfasser aut Erscheint auch als Online-Ausgabe 978-3-642-14718-0 X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3499265&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020669401&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Jiang, Qing Wen, Zi Thermodynamics of materials Werkstoff (DE-588)4065579-9 gnd Thermodynamik (DE-588)4059827-5 gnd Werkstoffkunde (DE-588)4079184-1 gnd Thermodynamische Eigenschaft (DE-588)4126056-9 gnd |
| subject_GND | (DE-588)4065579-9 (DE-588)4059827-5 (DE-588)4079184-1 (DE-588)4126056-9 |
| title | Thermodynamics of materials |
| title_auth | Thermodynamics of materials |
| title_exact_search | Thermodynamics of materials |
| title_full | Thermodynamics of materials Qing Jiang ; Zi Wen |
| title_fullStr | Thermodynamics of materials Qing Jiang ; Zi Wen |
| title_full_unstemmed | Thermodynamics of materials Qing Jiang ; Zi Wen |
| title_short | Thermodynamics of materials |
| title_sort | thermodynamics of materials |
| topic | Werkstoff (DE-588)4065579-9 gnd Thermodynamik (DE-588)4059827-5 gnd Werkstoffkunde (DE-588)4079184-1 gnd Thermodynamische Eigenschaft (DE-588)4126056-9 gnd |
| topic_facet | Werkstoff Thermodynamik Werkstoffkunde Thermodynamische Eigenschaft |
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| work_keys_str_mv | AT jiangqing thermodynamicsofmaterials AT wenzi thermodynamicsofmaterials |