Catalysis without precious metals:
Gespeichert in:
| Weitere Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH-Verl.
2010
|
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XVIII, 290 S. Ill., graph. Darst. 25 cm |
| ISBN: | 9783527323548 |
Internformat
MARC
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Datensatz im Suchindex
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| adam_text |
VII CONTENTS PREFACE XIII LIST OF CONTRIBUTORS XVII 1 CATALYSIS
INVOLVING THE H' TRANSFER REACTIONS OF FIRST-ROW TRANSITION METALS 1
JOHN HAERTUNG AND JACK R. NORTON 1.1 H' TRANSFER BETWEEN M-H BONDS AND
ORGANIC RADICALS 2 1.2 H'TRANSFER BETWEEN LIGANDS AND ORGANIC RADICALS 4
1.3 H - TRANSFER BETWEEN M-H AND C-C BONDS 7 1.4 CHAIN TRANSFER
CATALYSIS 11 1.5 CATALYSIS OF RADICAL CYCLIZATIONS 15 1.6 COMPETING
METHODS FOR THE CYCLIZATION OF DIENES 19 1.7 SUMMARY AND CONCLUSIONS 20
REFERENCES 21 2 CATALYTIC REDUCTION OF DINITROGEN TO AMMONIA BY
MOLYBDENUM 25 RICHARD R. SCHROCK 2.1 INTRODUCTION 25 2.2 SOME
CHARACTERISTICS OF TRIAMIDOAMINE COMPLEXES 26 2.3 POSSIBLE [HIPTN 3 N]MO
INTERMEDIATES IN A CATALYTIC REDUCTION OF MOLECULAR NITROGEN 30 2.3.1
MON 2 ANDMON2 30 2.3.2 MO-N=NH 33 2.3.3 CONVERSION OF MO(N 2 ) INTO
MO-N=NH 33 BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1000973913
DIGITALISIERT DURCH VILI CONTENTS 3 MOLYBDENUM AND TUNGSTEN CATALYSTS
FOR HYDROGENATION, HYDROSILYLATION AND HYDROLYSIS 51 R. MORRIS BULLOCK
3.1 INTRODUCTION 51 3.2 PROTON TRANSFER REACTIONS OF METAL HYDRIDES 52
3.3 HYDRIDE TRANSFER REACTIONS OF METAL HYDRIDES 54 3.4 STOICHIOMETRIC
HYDRIDE TRANSFER REACTIVITY OF ANIONIC METAL HYDRIDE COMPLEXES 56 3.5
CATALYTIC HYDROGENATION OF KETONES WITH ANIONIC METAL HYDRIDES 58 3.6
IONIC HYDROGENATION OF KETONES USING METAL HYDRIDES AND ADDED ACID 59
3.7 IONIC HYDROGENATIONS FROM DIHYDRIDES: DELIVERY OF THE PROTON AND
HYDRIDE FROM ONE METAL 64 3.8 CATALYTIC IONIC HYDROGENATIONS WITH MO AND
W CATALYSTS 65 3.9 MO PHOSPHINE CATALYSTS WITH IMPROVED LIFETIMES 69
3.10 TUNGSTEN HYDROGENATION CATALYSTS WITH N-HETEROCYCLIC CARBENE
LIGANDS 70 3.11 CATALYSTS FOR HYDROSILYLATION OF KETONES 71 3.12 CP 2 MO
CATALYSTS FOR HYDROLYSIS, HYDROGENATIONS AND HYDRATIONS 73 3.13
CONCLUSION 78 ACKNOWLEDGEMENTS 78 REFERENCES 79 4 CONTENTS IX 5.2.1
LIGAND PREPARATION 112 5.2.2 COMPLEXATION WITH MX 2 (M = FE, CO) 3 13
5.3 PRECATALYST ACTIVATION AND CATALYSIS 115 5.3.1 OLEFIN POLYMERIZATION
135 5.3.1.1 CATALYTIC EVALUATION 3 36 5.3.1.2 STERIC VERSUS ELECTRONIC
EFFECTS 116 5.3.1.3 EFFECT OF MAO CONCENTRATION 339 5.3.1.4 EFFECTS OF
PRESSURE AND TEMPERATURE 120 5.3.1.5 A-OLEFIN MONOMERS 121 5.3.2 OLEFIN
OLIGOMERIZATION 322 5.3.2.1 CATALYTIC EVALUATION 122 5.3.2.2 SUBSTITUENT
EFFECTS 322 5.3.2.3 SCHULZ-FLORY DISTRIBUTIONS 324 5.3.2.4 POISSON
DISTRIBUTIONS 124 5.3.2.5 A-OLEFIN MONOMERS 325 5.4 THE ACTIVE CATALYST
AND MECHANISM 125 5.4.1 ACTIVE SPECIES 325 5.4.1.1 IRON CATALYST 126
5.4.1.2 COBALT CATALYST 127 5.4.2 PROPAGATION AND CHAIN TRANSFER
PATHWAYS/THEORETICAL STUDIES 327 5.4.3 WELL-DEFINED IRON AND COBALT
ALKYLS 129 5.5 OTHER APPLICATIONS 133 5.5.1 IMMOBILIZATION 133 5.5.2
REACTOR BLENDING AND TANDEM CATALYSIS 134 5. X I CONTENTS 7.5 USING THE
SECOND COORDINATION SPHERE TO CONTROL THE MOVEMENT OF PROTONS BETWEEN
THE METAL AND THE EXTERIOR OF THE MOLECULAR CATALYST 173 7.6 INTEGRATION
OF THE FIRST AND SECOND COORDINATION SPHERES 174 7.7 SUMMARY 178
ACKNOWLEDGEMENTS 179 REFERENCES 179 8 NICKEL-CATALYZED REDUCTIVE
COUPLINGS AND CYCLIZATIONS 181 HASNAIN A. MALIK, RYAN D. BAXTER, AND
JOHN MONTGOMERY 8.1 INTRODUCTION 181 8.2 COUPLINGS OF ALKYNES WITH
RX,SS-UNSATURATED CARBONYLS 382 8.2.1 THREE-COMPONENT COUPLINGS VIA ALKYL
GROUP TRANSFER-METHODS DEVELOPMENT 182 8.2.2 REDUCTIVE COUPLINGS VIA
HYDROGEN ATOM TRANSFER-METHODS DEVELOPMENT 184 8.2.3 MECHANISTIC
INSIGHTS 386 8.2.3.1 METALLACYCLE-BASED MECHANISTIC PATHWAY 186 8.2.4
USE IN NATURAL PRODUCT SYNTHESIS 389 8.3 COUPLINGS OF ALKYNES WITH
ALDEHYDES 393 8.3.1 THREE-COMPONENT COUPLINGS VIA ALKYL GROUP
TRANSFER-METHOD DEVELOPMENT 192 8.3.2 REDUCTIVE COUPLINGS VIA HYDROGEN
ATOM TRANSFER-METHOD DEVELOPMENT 193 8.3.2.1 SIMPLE ALDEHYDE AND ALKYNE
REDUCTIVE COUPLINGS 194 8.3.2.2 DIRECTED PROCESSES 396 8.3.2. CONTENTS
XI 9.2.2.1 COUPLING OF ARYL HALIDES AND N-HETEROCYCLES 217 9.2.2.2
COUPLING OF VINYL BROMIDES AND N-HETEROCYCLES 218 9.2.3 AROMATIC
AMIDATION 218 9.2.3.1 CROSS-COUPLING OF ARYL HALIDES WITH AMIDES AND
CARBAMATES 219 9.2.3.2 CROSS-COUPLING OF VINYL HALIDES WITH AMIDES OR
CARBAMATES 220 9.2.3.3 CROSS-COUPLING OF ALKYNL HALIDES WITH AMIDES OR
CARBAMATES 220 9.2.4 AZIDATION 221 9.3 C-O BOND FORMATION 222 9.3.1
SYNTHESIS OF DIARYL ETHERS 222 9.3.2 ARYLOXYLATION OF VINYL HALIDES 223
9.3.3 CROSS-COUPLING OF ARYL HALIDES WITH ALIPHATIC ALCOHOLS 223 9.4 C-C
BOND FORMATION 224 9.4.1 CROSS-COUPLING WITH TERMINAL ACETYLENE 224
9.4.2 THE ARYLATION OF ACTIVATED METHYLENE COMPOUNDS 225 9.4.3 CYANATION
227 9.5 C-S BOND FORMATION 228 9.5.1 THE FORMATION OF BISARYL-AND
ARYLALKYL-THIOETHERS 228 9.5.2 THE SYNTHESIS OF ALKENYLSULFIDES 229
9.5.3 ASSEMBLY OF ARYL SULFONES 229 9.6 C-P BOND FORMATION 230 9.7
CONCLUSION 230 XII CONTENTS 11.3 METAL-FREE CATALYTIC HYDROGENATION 267
11.4 FUTURE CONSIDERATIONS 273 ACKNOWLEDGEMENTS 273 REFERENCES 273 INDEX
277 |
| any_adam_object | 1 |
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| indexdate | 2024-07-20T10:49:58Z |
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| isbn | 9783527323548 |
| language | English |
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| spelling | Catalysis without precious metals ed. by R. Morris Bullock Weinheim Wiley-VCH-Verl. 2010 XVIII, 290 S. Ill., graph. Darst. 25 cm txt rdacontent n rdamedia nc rdacarrier Literaturangaben Organische Synthese (DE-588)4075695-6 gnd rswk-swf Katalyse (DE-588)4029921-1 gnd rswk-swf Homogene Katalyse (DE-588)4160579-2 gnd rswk-swf Übergangsmetall (DE-588)4078494-0 gnd rswk-swf Unedles Metall (DE-588)4583082-4 gnd rswk-swf Katalyse (DE-588)4029921-1 s Unedles Metall (DE-588)4583082-4 s DE-604 Organische Synthese (DE-588)4075695-6 s Homogene Katalyse (DE-588)4160579-2 s Übergangsmetall (DE-588)4078494-0 s b DE-604 Bullock, R. Morris edt X:MVB text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3443170&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020658374&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Catalysis without precious metals Organische Synthese (DE-588)4075695-6 gnd Katalyse (DE-588)4029921-1 gnd Homogene Katalyse (DE-588)4160579-2 gnd Übergangsmetall (DE-588)4078494-0 gnd Unedles Metall (DE-588)4583082-4 gnd |
| subject_GND | (DE-588)4075695-6 (DE-588)4029921-1 (DE-588)4160579-2 (DE-588)4078494-0 (DE-588)4583082-4 |
| title | Catalysis without precious metals |
| title_auth | Catalysis without precious metals |
| title_exact_search | Catalysis without precious metals |
| title_full | Catalysis without precious metals ed. by R. Morris Bullock |
| title_fullStr | Catalysis without precious metals ed. by R. Morris Bullock |
| title_full_unstemmed | Catalysis without precious metals ed. by R. Morris Bullock |
| title_short | Catalysis without precious metals |
| title_sort | catalysis without precious metals |
| topic | Organische Synthese (DE-588)4075695-6 gnd Katalyse (DE-588)4029921-1 gnd Homogene Katalyse (DE-588)4160579-2 gnd Übergangsmetall (DE-588)4078494-0 gnd Unedles Metall (DE-588)4583082-4 gnd |
| topic_facet | Organische Synthese Katalyse Homogene Katalyse Übergangsmetall Unedles Metall |
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