Polymer nanotube nanocomposites: synthesis, properties, and applications
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Hoboken, NJ [u.a.]
Wiley
2010
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | XIV, 460 S. Ill., graph. Darst. |
| ISBN: | 9780470625927 0470625929 |
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| 245 | 1 | 0 | |a Polymer nanotube nanocomposites |b synthesis, properties, and applications |c Vikas Mittal |
| 264 | 1 | |a Hoboken, NJ [u.a.] |b Wiley |c 2010 | |
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| adam_text | Contents
Preface
хш
1.
Carbon
Nanotubes: An
Introduction
1
V.
Mittal
1.1
Introduction
1
1.2
Properties
4
1.3
Synthesis
8
References
12
2.
Overview of Polymer Nanotube Nanocomposites
15
V. Mittal
2.1
Introduction
15
2.2
Methods of Nanotube Nanocomposites Synthesis
18
2.2.1
Solution Mixing
18
2.2.2
In-Situ Polymerization
20
2.2.3
Melt Mixing
22
2.3
Properties of Polymer Nanotube Nanocomposites
25
2.3.1
Mechanical Properties
25
2.3.2
Thermal and Electrical Properties
34
References
42
3.
New Microscopy Techniques for a Better Understanding
of the Polymer/Nanotube Composite Properties
45
K. Masenelli-Varlot, A. Bogner,
С
Gauthier,
L. Chazeau
and J.Y.
Cavatile
3.1
Introduction
46
3.2
Near Field Microscopy
47
3.2.1
Principles of STM and AFM
48
3.2.2
Near Field Microscopy for Nanotubes
50
3.2.3
AFM and CNT Composites
50
vi
Contents
3.3
Transmission Electron Microscopy
52
3.3.1
Principles
52
3.3.2
Characterisation of Carbon Nanotubes
56
3.3.3
Characterisation of Polymer/
Nanotube Composites
58
3.4
Scanning Electron Microscopy
67
3.4.1
Overview of the Technique
(SEI,
BEI, CCI)
67
3.4.2
Application to the Study of Nanotubes
68
3.4.3
For Polymer CNT/Nanocomposites
69
3.4.4
Development of New Imaging Modes
72
3.5
Conclusions
75
References
77
4.
Polymer Nanocomposites with Clay
and Carbon Nanotubes
83
Qiang
Fu, Changyu
Tang,
Hua
Deng and Qin Zhang
4.1
Introduction
83
4.2
Electrical Properties of Polymer
Composites with Clay and CNTs
86
4.3
Mechanical Properties of Polymer
Composites with Clay and CNTs
89
4.4
Thermal and Flame Properties of Polymer
Composites with Clay and CNTs
100
4.5
Conclusion and Future Outlook
106
Acknowledgement
108
References
109
5.
Polyethylene Nanotube Nanocomposites
113
S. Kanagaraj
5.1
Introduction
113
5.2
Surface Modification of Carbon Nanotubes
115
5.3
Dispersion of Nanotubes in Polyethylene Matrix
117
5.4
Method of Preparation of CNT-PE Composites
119
5.5
Interfacial
Bonding and Load Transfer
123
5.6
Material Characterization
126
5.7
Conclusions
135
Acknowledgement
136
References
136
Contents
vii
6.
Properties of
Polyurethane/Carbon
Nanotube Nanocomposites
141
Tianxi Liu and Shuzhong Guo
6.1
Introduction
141
6.2
Preparation of CNT-Based
Polyurethane
Nanocomposites
144
6.2.1
Melt-Mixing
144
6.2.2
Solution Casting
145
6.2.3
In-Situ Polymerization
146
6.2.4
Sol-Gel Approach
147
6.3
Functionalization, Dispersion
Morphology and Micro-/Nano-structures
148
6.4
Physical Properties
151
6.4.1
Mechanical Properties
151
6.4.2
Thermal Conductivity
154
6.4.3
Thermal Stability and Degradation
155
6.4.4
Fire Retardancy
156
6.4.5
Rheological Properties
157
6.4.6
Electrical Conductivity
158
6.4.7
Water Vapor Transport Properties
161
6.4.8
Shape Memory
162
6.4.9
Special Properties Related to Bio-Applications
165
6.4.10
Microwave Absorption
166
6.4.11
UV-Protection
167
6.5
Applications
168
6.6
Conclusions
170
Acknowledgements
171
References
171
7.
Properties of PMMA/Carbon
Nanotubes Nanocomposites
177
R.B. Mathur, Shailaja
Pande
and B.P. Singh
7.1
Introduction
177
7.2
Fabrication/Processing of CNT-PMMA Composites
179
7.2.1
Solution Processing
181
7.2.2
Melt-Processing
183
7.2.3
In-Situ Polymerization Processing
185
viii
Contents
7.2.4
Coagulation Method
186
7.2.5
Surfactant, Compatibilizers and Co-Solvent
Assisted CNT-PMMA Composites
188
7.2.6
Chemical Modification of CNTs for Processing
of Nanocomposites
189
7.3
Mechanical Properties of CNT-PMMA Composites
190
7.4
Electrical Properties of CNT-PMMA Composites
198
7.4.1
Electrical Conductivity
198
7.4.2
Electromagnetic Interference (EMI) Shielding
200
7.5
Thermal Properties
204
7.6
Conclusion
216
References
216
8.
Synthesis of Vinyl Polymer/Carbon Nanotube
Nanocomposites Prepared by Suspension
Polymerization and Their Properties
221
P. Slobodtan
8.1
Introduction
221
8.2
Free Radical Polymerization
223
8.3
Suspension and Bulk Polymerization Techniques
225
8.4
In-situ Radical Polymerization in Presence of CNT
228
8.4.1
Polymer Matrix
228
8.4.2
Addition of Radicals onto CNT
229
8.4.3
CNT Degradation
232
8.4.4
Additional Analyses
233
8.5
Polymer/CNT Composite Microspheres
235
8.5.1
CNT Material Adsorbed onto
Polymer Microspheres
239
8.6
Electrorheology of Polymer/CNT Nanocomposites
Prepared by in-situ Suspension Polymerization
243
References
246
9.
Polylactide-Based Carbon Nanotube Nanocomposites
249
Srikanth
Pilla, Shaoqin
Gong and Lih-Sheng Turng
9.1
Introduction
249
9.2
Synthesis of
PLA
252
9.3
Carbon Nanotubes
254
Contents
ix
9.4
Preparation of PLA-CNT Nanocomposites
255
9.5
Viscoelastic Properties
264
9.6
Thermal Properties
268
9.7
Mechanical Properties
269
9.8
Thermal Degradation Properties
272
9.9
Electrical Conductivity Properties
273
9.10
Biodegradability
274
9.11
Applications
275
9.12
Conclusions
275
Acknowledgements
276
Note
276
References
276
10.
Synthesis and Properties of PEEK/Carbon
Nanotube Nanocomposites
281
A.M. Diez-Pascual, J.M.
González-Domínguez,
У.
Martínez-Rubt,
M.
Naffakh,
A.
Ansón,
М.Т.
Martínez,
В.
Simará ana M.A. Gómez
10.1
Introduction
281
10.2
Poly(ether
ether ketone)s: Structure, Synthesis
and Properties
283
10.3
Synthesis, Purification and Characterization
of the SWCNTs
285
10.3.1
Synthesis of Laser-Grown SWCNTs
285
10.3.2
Synthesis and Purification
of Arc-Grown SWCNTs
285
10.3.3
Characterization of the Single-Walled
Carbon Nanotubes
287
10.4
Integration of the Carbon Nanotubes
in the PEEK Matrix
290
10.4.1
Covalent Grafting in Carbon Nanotube/PEEK
Nanocomposites
291
10.4.2
Wrapping of the SWCNTs
in Compatibilizing Agents
292
10.4.3
Pre-Mixing Stage and Melt Blending Approach
294
10.5
Characterization of PEEK/Carbon
Nanotube Nanocomposites
295
χ
Contents
10.5.1
Morphology
295
10.5.2
Thermogravimetric Study
297
10.5.3
Differential Scanning Calorimetry
298
10.5.4
X-ray Diffraction Analysis
303
10.5.5
Mechanical Properties
304
10.5.6
Electrical and Thermal Conductivity
307
10.6
Concluding Remarks
309
Acknowledgements
310
Glossary of Abbreviations
310
References
311
11.
Synthesis and Properties of PVA/Carbon
Nanotube Nanocomposites
315
C.
Mercader,
P. Poulin and C. Zakri
11.1
Introduction
315
11.1.1
Mechanical and Electrical Properties
of Carbon Nanotubes
316
11.1.2
Why Use Nanotubes in Nanocomposites?
317
11.1.3
Poly(vinyl) Alcohol
319
11.2
Synthesis Methods and Structural Properties
of Nanotubes/PVA Composites
320
11.2.1
Films
320
11.2.2
Fibers
324
11.3
Mechanical Properties of the Composites
327
11.3.1
Reinforcement
328
11.3.2
Stress Transfer Efficiency
331
11.4
Electrical Properties
333
11.5
Other Original Properties of PVA/
Nanotube Composites
335
11.5.1
Energy Absorption
335
11.5.2
Shape Memory Effect
337
11.6
Conclusion
339
References
340
12.
Elastomers Filled with Carbon Nanotubes
345
Liliane
Bokobza
12.1
Introduction
345
12.2
Composite Processing
347
12.3
Electrical Properties
350
Contents
xi
12.4
Mechanical Properties
355
12.4.1
Tensile and Swelling Behaviors
355
12.4.2
Dynamic Mechanical Analysis (DMA) and
Differential Scanning Calorimetry (DSC)
361
12.5
Spectroscopie
Characterization
364
12.6
Thermal Stability
367
12.7
Conclusions
369
References
369
13.
Specific Interactions Induced Controlled Dispersion
of Multiwall Carbon Nanotubes in Co-Continuous
Polymer Blends
373
Suryasarathi
Bose,
Arup R. Bhattacharyya,
Rupesh A. Khare and Ajit R.
Kulkami
13.1
Introduction
373
13.2
Experimental
376
13.2.1
Materials
376
13.2.2
Preparation of the Modifiers
376
13.2.3
Melt Blending
377
13.2.4
Characterization
378
13.3
Results and Discussion
379
13.3.1
Specific Interactions:
Spectroscopie
and
Microscopic Evidences
379
13.3.2
AC Electrical Conductivity Measurements:
Assessing the State of Dispersion of MWNTs
381
13.3.3
Phase Morphology and Selective Localization
of MWNTs in the Blends
383
13.3.4
Melt-Interfacial Interactions
386
13.4
Summary
387
Acknowledgements
388
References
388
14.
Effect of Structure and Morphology on the Tensile
Properties of Polymer/Carbon Nanotube
Nanocomposites
391
Jingjing Qiu and Shiren Wang
14.1
Background
391
14.2
Structure and Morphology Characterization
392
14.2.1
Structure and Mechanical Properties of CNTs
392
xii
Contents
14.2.2
Characterization of CNTs/Polymer Composites
395
14.2.3
Structure and Tensile Properties of CNTs/
Polymer Composites
396
14.3
Concluding Remarks
417
References
418
15.
Polymer Nanotube Composites: Promises
and Current Challenges
423
Amai M.K.
Esawi and
Mahmoud M.
Farag
15.1
Carbon Nanotubes
424
15.1.1
Background
424
15.1.2
Synthesis of CNTs
425
15.1.3
Fabrication of CNT Polymer Composites
426
15.1.4
Electrical Properties of CNT Polymer
Composites
429
15.1.5
Mechanical Properties of CNT
Polymer Composites
432
15.2
CaseStudies
435
15.2.1
Case Study: CNT-Based Strain Sensor
435
15.2.2
Case Study: Technical and Economic
Feasibility of Using CNT-Based Composites
in Aerospace Applications
440
15.3
Conclusions
445
References
446
Index
449
Provides a one-stop source for information on synthesis, properties, and
potential applications of nanotube reinforced polymer nanocomposites
Research on polymer nanotube composites is a relatively new field, and
a lot of development is required to achieve a very large-scale commercial
application. Although a number of developments have taken place in terms
of the dispersion of nanotubes in the polymer matrices and corresponding
improvements in the various physical properties of the composites, a
meaningful text on the subject, which can assimilate these advancements
in one place to provide an overall potential of the technology, is missing.
This edited volume brings together contributions from a variety of senior
scientists in the field of polymer nanotube composites technology to shed
light on the recent advances in these commercially important areas of
polymer technology. The book provides the following features:
•
A summary of recent advances in nanotube composite
synthesis technology
•
A basic introduction to polymer nanotube nanocomposite technology
for readers who are new to the field
•
Valuable insights for the use of technologies for polymer
nanocomposites for commercial application
•
Reviews of current polymer nanotube systems to underscore the high
potential of nanotubes as fillers
•
Pathways for large-scale commercial applications of
nanotube nanocomposites
Vikas
Mittal
is a Polymer Engineer at BASF Polymer Research in
Ludwigshafen,
Germany. He obtained his Ph.D. in
2006
in Polymer and
Materials Engineering from the Swiss Federal Institute of Technology in
Zurich, Switzerland. He then worked as a Materials Scientist in the Active
and Intelligent Coatings section of Sun Chemical in London, UK. His
research interests include polymer nanocomposites, novel filler surface
modifications, thermal stability enhancements, and polymer latexes
with functionalized surfaces. He has authored more than
30
scientific
publications, book chapters, and patents.
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| indexdate | 2024-07-09T22:46:50Z |
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| language | English |
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| spelling | Polymer nanotube nanocomposites synthesis, properties, and applications Vikas Mittal Hoboken, NJ [u.a.] Wiley 2010 XIV, 460 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Polymere (DE-588)4046699-1 gnd rswk-swf Nanoröhre (DE-588)4844582-4 gnd rswk-swf Nanokomposit (DE-588)4768127-5 gnd rswk-swf Polymere (DE-588)4046699-1 s Nanoröhre (DE-588)4844582-4 s Nanokomposit (DE-588)4768127-5 s DE-604 Mittal, Vikas Sonstige (DE-588)140061096 oth Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020650154&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020650154&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Polymer nanotube nanocomposites synthesis, properties, and applications Polymere (DE-588)4046699-1 gnd Nanoröhre (DE-588)4844582-4 gnd Nanokomposit (DE-588)4768127-5 gnd |
| subject_GND | (DE-588)4046699-1 (DE-588)4844582-4 (DE-588)4768127-5 |
| title | Polymer nanotube nanocomposites synthesis, properties, and applications |
| title_auth | Polymer nanotube nanocomposites synthesis, properties, and applications |
| title_exact_search | Polymer nanotube nanocomposites synthesis, properties, and applications |
| title_full | Polymer nanotube nanocomposites synthesis, properties, and applications Vikas Mittal |
| title_fullStr | Polymer nanotube nanocomposites synthesis, properties, and applications Vikas Mittal |
| title_full_unstemmed | Polymer nanotube nanocomposites synthesis, properties, and applications Vikas Mittal |
| title_short | Polymer nanotube nanocomposites |
| title_sort | polymer nanotube nanocomposites synthesis properties and applications |
| title_sub | synthesis, properties, and applications |
| topic | Polymere (DE-588)4046699-1 gnd Nanoröhre (DE-588)4844582-4 gnd Nanokomposit (DE-588)4768127-5 gnd |
| topic_facet | Polymere Nanoröhre Nanokomposit |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020650154&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020650154&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT mittalvikas polymernanotubenanocompositessynthesispropertiesandapplications |