Encyclopedia of polymer blends: 1 Fundamentals
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| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2010
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | XVI, 313 S. Ill., graph. Darst. |
| ISBN: | 9783527319299 |
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| 245 | 1 | 0 | |a Encyclopedia of polymer blends |n 1 |p Fundamentals |c ed. by Avraam I. Isayev |
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| adam_text | Contents
Preface
XI
List of Contributors XV
1
Molecular Simulation of Polymer Melts and Blends: Methods,
Phase Behavior, Interfaces, and Surfaces
1
Peter Virnau, Kurt Binder,
Hendrik Heinz, Torsten Kreer,
and Marcus
Müller
1.1
Introduction
1
1.2
Molecular Models for Polymers and Monte Carlo Simulations
6
1.2.1
Modeling Polymers in Molecular Simulations
6
1.2.2
Basics of Monte Carlo Simulations
8
1.2.3
Determination of Phase Behavior
9
1.3
Wetting and Phase Diagrams in Confined Geometries
14
1.3.1
Length and Energy Scales of Minimal, Coarse-Grained Models
for Polymer-Solid Contacts
14
1.3.2
Measuring the Surface Free Energy Difference,
Δγ,
by Computer
Simulation
18
1.3.3
Application to Polymer-Solvent Mixtures
20
1.4
Molecular Dynamics Method
21
1.4.1
Basic Molecular Dynamics
21
1.4.2
Non-equilibrium Molecular Dynamics Simulations
of Coarse-Grained Polymer Systems
23
1.5
Atomistic Simulation of Polymer Melts and Blends Using
Molecular Dynamics Techniques
28
1.5.1
Polymer Melts
28
1.5.2
Polymer Blends
30
1.5.3
Reversible Mapping between Atomistic, Coarse Grained,
and Field Models
33
1.5.4
Comparison to Experiment and Future Challenges
34
1.6
Concluding Remarks
35
Symbols
37
References
38
Encyclopedia of Polymer Blends, Volume I: Fundamentals. Edited by Avraam I. Isayev
Copyright
t
2010
WILEY-VCH
Verlag
GmbH
&
Co. KGaA,
Weinheim
ISBN:
978-3-527-31929-9
VI
Contents
2
Thermodynamics of Flexible and Rigid Rod Polymer Blends
45
Akihiko Matsuyama
2.1
Introduction
45
2.2
Fundamentals of a Nematic Phase
46
2.2.1
Scalar Orientational Order Parameter
46
2.2.2
Free Energy of Rigid Rod Solutions
47
2.2.3
Nematic-Isotropic Phase Separations
51
2.2.4
Entropy- and Energy-Driven Nematic Ordering
54
2.3
Mixtures of a Flexible Polymer and a Rigid Rod
56
2.3.1
Free Energy of Flexible and Rigid Rod Polymer Blends
59
2.3.2
Nematic-Isotropic Phase Transition
63
2.3.3
Landau-de Gennes Expansion of the Free Energy
64
2.3.4
Phase Separations
65
2.3.5
Phase Diagrams in Solutions of Rigid Rod-like Polymers
70
2.3.6
Smectic-Nematic-Isotropic Phase Separations
71
2.3.7
Conformation of a Polymer Dissolved in a Liquid Crystalline
Phase
76
2.4
Phase Separation Dynamics
78
2.4.1
Kinetic Equations
80
2.4.2
Linearized Analysis of Spinodal Decomposition
82
2.4.3
Morphologies
88
2.5
Summary
93
Symbols
94
References
96
3
Amorphous Polymer Blends: Recent Developments
103
Jeffery
L
White
3.1
Introduction
101
3.2
Miscible
Blend Dynamics and Length Scales of Mixing
102
3.3
Amorphous
Biopolymer
Blends
108
3.4
Conclusions
109
References
109
4
Phase Field Modeling on Polymer Crystallization and Phase Separation
in Crystalline Polymer Blends
113
Thein Kyu, Haijun Xu, Taiming Cuo, and Cuoxiang Wang
4.1
Phase Field Theory of Crystal Solidification of a Pure
Substance
113
4.2
Phase Field Modeling on Morphology Development
114
4.3
Application of Phase Field Approach to Crystallization
of a Homopolymer
122
4.4
Thermodynamics of Crystalline Polymer Solutions and Blends
129
4.4.1
Prigogine s Model
129
4.4.2
Flory
Diluent Theory
130
4.5
Phase Diagrams of Crystalline Polymer Blends
132
Contents
VII
4.5.1 Phase Diagram Calculation
of a Crystalline/Amorphous
Polymer Blend
132
4.5.2
Determination of Crystal-Amorphous Interaction
in Crystalline/Amorphous Blends
135
4.5.3
Phase Diagram Calculation for Binary Crystalline Polymer Blends
137
4.5.4
Morphology Development in Relation to Phase Diagram
of Crystalline/Amorphous Polymer Blends
139
4.5.5
Morphology Development in Relation to the Phase Diagram
of Crystalline/Crystalline Polymer Blends
142
4.5.6
Phase Field Modeling on Phase Separation and Morphology
Evolution
145
Symbols
148
References
149
5
Miscibility Criterion in Polymer Blends and its Determination
і
53
Valeria
Arrighi,
John M.C.
Сои
/ie,
Steven
Fuhrmann,
and Abdelsallam Youssef
5.1
Introduction
153
5.2
Thermodynamics
154
5.3
Glass Transition of Polymer Blends
358
5.3.1
Determination of the Glass Transition of Polymer Blends
160
5.4
Phase Equilibria Methods
162
5.4.1
Scattering Techniques
163
5.4.1.1
Turbidity Measurements and light Scattering
165
5.4.1.2
Small-Angle Neutron Scattering
168
5.4.1.3
Small-Angle and Wide-Angle
Х
-Ray Scattering
173
5.4.1.4
Neutron Reflectivity
175
5.4.2
Microscopy
176
5.4.2.1
Transmission Electron Microscopy
177
5.4.2.2
Scanning Electron Microscopy
177
5.4.2.3
Scanning Probe Microscopy
-
Atomic Force Microscopy (AFM)
and Scanning Tunneling Microscopy (STM)
178
5.5
Spectroscopic Methods
180
5.5.1
Dynamics above the Glass Transition
180
5.5.2
Sub-Tg Relaxations
185
5.5.3
Infrared and Raman Spectroscopy
386
5.6
Summary and Conclusions
189
Abbreviations and Symbols
189
References
192
6
Physical Aging of Polymer Blends
199
John M.C. Cowie and Valeria
Arrighi
6.1
Introduction to Physical Aging
199
6.2
Experimental Measurements
200
6.2.1
Enthalpy Relaxation
200
VIII Contents
6.2.2
Theoretical Approaches
202
6.2.2.1
Phenomenological Models
202
6.2.2.2
Petrie-Marshall and Cowie-Ferguson Models
204
6.2.2.3
Molecular Models
204
6.2.3 Enthalpie
Relaxation in Polymer Blends
205
6.2.4
Volume Relaxation
212
6.2.5
Mechanical Relaxation
214
6.2.6
Positron Annihilation Lifetime Spectroscopy
216
6.2.7
Other
Spectroscopie
Techniques
218
6.2.8
Scattering Techniques
219
6.3
Discussion of Physical Aging in Blends
220
6.3.1
Effect of Intermolecular Interactions
220
6.3.2
Phase Separated Blends
223
6.4
Concluding Comments
223
Abbreviations and Symbols
224
References
226
7
Nanoparticle/Polymer Blends: Theory and Modeling
233
Valeriy V. Ginzburg
7.1
Introduction
233
7.2
Morphology of Polymer Blends with Nanoparticles
235
7.2.1
Phase Behavior of Binary Polymer Blends
235
1 .2.2
Simple Arguments for Nanoparticles as Compatibilizers
237
7.2.3
Influence of Nanoparticles on the Dynamics of Phase Separation
in Polymer Blends
239
7.2.4
Thermodynamics of Binary Nanoparticle/Polymer Blends
242
7.2.5
Phase Behavior of Ternary Nanoparticle/Polymer/Polymer
Mixtures
245
7.2.6
Phase Behavior of Nanoparticle/Block-Copolymer Mixtures
248
7.2.7
Determination of Polymer-Particle Flory-Huggins Interaction
Parameters
254
7.3
Physical Properties of Filled Polymer Blends
255
7.3.1
Mechanical Properties (Modulus, Strength, and Toughness)
255
7.3.2
Electrical Conductivity
257
7.4
Summary and Outlook
260
Abbreviations and Symbols
261
References
263
8
Modeling the Self-Assembly of Ternary Blends that Encompass
Photosensitive Chemical Reactions: Creating Defect-Free, Hierarchically
Ordered Materials
269
Olga Kuksenok,
Rui D.
M.
Trovasse,
Pratyush Dayal, and Anna
С.
Balázs
8.1
Introduction
269
8.2
The Model
272
8.3
Results and Discussion
275
Contents IX
8.3.1
Combing with Light: Creating Patterned, Defect-Free Thin Films
275
8.3.2
Modeling the Bulk Behavior of Photosensitive Blends under
Non-uniform Illumination
278
8.3.3
Combing Out Defects in Bulk Binary Blends
286
8.3.4
Creating Order within the Ternary Mixtures
290
8.3.5
Relating the Dimensionless Simulation Parameters
to Physical Values
293
8.3.6
Using a Single Photomask to Create Multiple Patterns
in the Ternary Films
295
8.4
Conclusions
300
Abbreviations and Symbols
303
References
305
Index
307
A complete and timely overview of the topic, this Encyclopedia
imparts knowledge of fundamental principles and their applications for
academicians, scientists and researchers, while informing engineers,
industrialists and entrepreneurs of the current state of the technology
and its utilization.
Each article is uniformly structured for easy navigation, containing
the latest research
&
development and its basic principles and applica¬
tions, examples of case studies, laboratory and pilot plant experiments,
as well as due reference to the published and patented literature.
Volume i: Fundamentals
Volume
2:
Processing
Volume
3:
Structure
Volume
4:
Properties
Volume
5:
Materials
&
Applications
Avraam I. Isayev is a Distinguished Professor of Polymer Engi¬
neering at the University of Akron. He is a native of Azerbaijan.
He received M.Sc. degrees from the Azerbaijan Institute of
Oil and Chemistry in Chemical Engineering and the Moscow
Institute of Electronic Machine Building in Applied Mathematics
and a Ph.D. in Polymer Engineering and Science from the
Institute of Petrochemical Synthesis of the USSR Academy
of Sciences, Moscow. Before joining the University of Akron
in
1983
as an Associate Professor, he was a Senior Research
Associate at Cornell University, a Senior Research Fellow at
Technion and a Research Associate at the Institute of Petro¬
chemical Synthesis of the USSR Academy of Sciences. He has
edited
5
books, published
7
monograph and over
220
journal
papers, many book chapters and encyclopedia articles. He has
received numerous awards.
ISBN
978-3-527-31929-9
|
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| spelling | Encyclopedia of polymer blends 1 Fundamentals ed. by Avraam I. Isayev Weinheim Wiley-VCH 2010 XVI, 313 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Polymergemisch (DE-588)4175243-0 gnd rswk-swf (DE-588)4151278-9 Einführung gnd-content Polymergemisch (DE-588)4175243-0 s DE-604 Isayev, Avraam I. 1942- (DE-588)112425798 edt (DE-604)BV036731998 1 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020649659&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020649659&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Encyclopedia of polymer blends Polymergemisch (DE-588)4175243-0 gnd |
| subject_GND | (DE-588)4175243-0 (DE-588)4151278-9 |
| title | Encyclopedia of polymer blends |
| title_auth | Encyclopedia of polymer blends |
| title_exact_search | Encyclopedia of polymer blends |
| title_full | Encyclopedia of polymer blends 1 Fundamentals ed. by Avraam I. Isayev |
| title_fullStr | Encyclopedia of polymer blends 1 Fundamentals ed. by Avraam I. Isayev |
| title_full_unstemmed | Encyclopedia of polymer blends 1 Fundamentals ed. by Avraam I. Isayev |
| title_short | Encyclopedia of polymer blends |
| title_sort | encyclopedia of polymer blends fundamentals |
| topic | Polymergemisch (DE-588)4175243-0 gnd |
| topic_facet | Polymergemisch Einführung |
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