Chemistry versus physics: chemical reactions near critical points
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
New Jersey [u.a.]
World Scientific
2010
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturverz. S. 127 - 134 |
| Physical Description: | XI, 136 S. graph. Darst. |
| ISBN: | 981429120X 9789814291200 |
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Record in the Search Index
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| adam_text | Titel: Chemistry versus physics
Autor: Gitterman, Moshe
Jahr: 2010
Contents
Preface v
1. Criticality and Chemistry 1
1.1 Critical phenomena...................... 1
1.2 Chemical reactions...................... 8
1.3 Analogy between critical phenomena and the instability of
chemical reactions...................... 12
2. Effect of Criticality on Chemical Reaction 15
2.1 The effect of pressure on the equilibrium constant and rate
of reaction........................... 15
2.2 Effect of phase transformations on chemistry....... 17
2.3 Critical slowing-down of chemical reactions........ 19
2.4 Hydrodynamic equations of reactive binary mixture:
piston effect.......................... 25
2.4.1 Heterogeneous reactions in near-critical systems . 26
2.4.2 Dynamics of chemical reactions.......... 27
2.4.3 Relaxation time of reactions............ 29
2.4.4 Hydrodynamic equations of a reactive binary
mixtures....................... 32
2.4.5 Hydrodynamic equations with statistically
independent variables ............... 38
2.5 Critical anomalies of chemical equilibria.......... 46
2.6 Experiment .......................... 48
3. Effect of Chemistry on Critical Phenomena 53
x Chemistry versus Physics: Chemical Reactions near Critical Points
3.1 Change of critical parameters due to a chemical reaction . 53
3.2 Modification of the critical indices............. 55
3.3 Singularity in the degree of dissociation near a critical point 60
3.4 Isotope exchange reaction in near-critical systems..... 62
3.5 Singularities of transport coefficients in reactive systems . 63
3.5.1 Mode-coupling analysis............... 63
3.5.2 Renormalization group methods.......... 65
4. Phase Separation in Reactive Systems 67
4.1 Multiple solutions of the law of mass action........ 67
4.2 Phase equilibrium in reactive binary mixtures quenched
into a metastable state.................... 69
4.2.1 Thermodynamic analysis of reactive binary
mixtures....................... 69
4.2.2 Thermodynamic analysis of reactive ternary
mixtures....................... 72
4.2.3 Kinetics of phase separation............ 75
4.3 Phase equilibrium in reactive mixtures quenched into an
unstable state......................... 81
4.4 Thermodynamics of a three-component plasma with a
dissociative chemical reaction................ 89
5. Comments on the Geometry of the Phase Diagram of a
Reaction Mixture 93
5.1 Solubility in supercritical fluids............... 93
5.2 Azeotropic points in reactive many-component systems . . 100
5.3 Melting point of reactive binary mixtures......... 101
5.4 Double critical point..................... 105
6. Sound Propagation and Light Scattering in Chemically
Reactive Systems 111
6.1 Ultrasound attenuation in near-critical reactive mixtures . Ill
6.2 Hydrodynamic analysis of the dispersion relation for sound
waves............................. 113
6.3 Light scattering from reactive systems........... 118
6.4 Inhomogeneous structure of near-critical reactive systems 121
7. Conclusions 125
Contents
127
Bibliography
135
Index
|
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| author_GND | (DE-588)140080287 |
| author_facet | Gitterman, Moshe 1931- |
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| illustrated | Illustrated |
| indexdate | 2024-07-09T22:46:29Z |
| institution | BVB |
| isbn | 981429120X 9789814291200 |
| language | English |
| lccn | 2010278406 |
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| physical | XI, 136 S. graph. Darst. |
| publishDate | 2010 |
| publishDateSearch | 2010 |
| publishDateSort | 2010 |
| publisher | World Scientific |
| record_format | marc |
| spelling | Gitterman, Moshe 1931- Verfasser (DE-588)140080287 aut Chemistry versus physics chemical reactions near critical points Moshe Gitterman New Jersey [u.a.] World Scientific 2010 XI, 136 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturverz. S. 127 - 134 Chemische Reaktion (DE-588)4009853-9 gnd rswk-swf Kritischer Punkt (DE-588)4140476-2 gnd rswk-swf Kritisches Phänomen (DE-588)4165788-3 gnd rswk-swf Kritisches Phänomen (DE-588)4165788-3 s Kritischer Punkt (DE-588)4140476-2 s Chemische Reaktion (DE-588)4009853-9 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020634956&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gitterman, Moshe 1931- Chemistry versus physics chemical reactions near critical points Chemische Reaktion (DE-588)4009853-9 gnd Kritischer Punkt (DE-588)4140476-2 gnd Kritisches Phänomen (DE-588)4165788-3 gnd |
| subject_GND | (DE-588)4009853-9 (DE-588)4140476-2 (DE-588)4165788-3 |
| title | Chemistry versus physics chemical reactions near critical points |
| title_auth | Chemistry versus physics chemical reactions near critical points |
| title_exact_search | Chemistry versus physics chemical reactions near critical points |
| title_full | Chemistry versus physics chemical reactions near critical points Moshe Gitterman |
| title_fullStr | Chemistry versus physics chemical reactions near critical points Moshe Gitterman |
| title_full_unstemmed | Chemistry versus physics chemical reactions near critical points Moshe Gitterman |
| title_short | Chemistry versus physics |
| title_sort | chemistry versus physics chemical reactions near critical points |
| title_sub | chemical reactions near critical points |
| topic | Chemische Reaktion (DE-588)4009853-9 gnd Kritischer Punkt (DE-588)4140476-2 gnd Kritisches Phänomen (DE-588)4165788-3 gnd |
| topic_facet | Chemische Reaktion Kritischer Punkt Kritisches Phänomen |
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