Electropolymerization: concepts, materials and applications
Gespeichert in:
| Weitere Verfasser: | |
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| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim
Wiley-VCH-Verl.
2010
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| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | Literaturangaben |
| Beschreibung: | XV, 280 S. Ill., graph. Darst. 25 cm |
| ISBN: | 9783527324149 |
Internformat
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CONTENTS PREFACE XI LIST OF CONTRIBUTORS X1U 1 ELECTROPOLYMERIZED FILMS
OF JT-CONJUGATED POLYMERS. A TOOL FOR SURFACE FUNCTIONALIZATION: A BRIEF
HISTORICAL EVOLUTION AND RECENT TRENDS 1 GERARD BIDAN 1.1 INTRODUCTION 1
1.2 ELECTROPOLYMERIZATION: EPISTEMOLOGICAL ANALYSIS WITHIN THE ICP SAGA
2 1.3 ELECTROPOLYMERIZATION: FROM PRISTINE HETEROCYDIC TO SOPHISTICATED
FUNCTIONAL AND CONJUGATED ARCHITECTURES 4 1.3.1 ELECTROPOLYMERIZATION OF
PRISTINE AROMATIC HETEROCYDES 5 1.3.2 ELECTROPOLYMERIZATION OF
SUBSTITUTED HETEROCYDES 7 1.3.3 ELECTROPOLYMERIZATION AS A TOOL TO
ELABORATE FUNCTIONAL CONJUGATED ARCHITECTURES 10 1.4 CONCLUSION 12
REFERENCES 13 2 MECHANISMS OF ELECTROPOLYMERIZATION AND REDOX ACTIVITY:
FUNDAMENTAL ASPECTS 27 MIKHAIL A. VOROTYNTSEV, VERONIKA A. ZINOVYEVA,
AND DMITRY V. KONEV 2.1 ELECTROPOLYMERIZATION: GENERAL ASPECTS 27 2.2
REDOX ACTIVITY OF POLYMER FILMS 32 2.3 EFFECT OF POLYMERIZATION
PARAMETERS ON PROPERTIES OF DEPOSITED POLYMER FILMS 38 2.4 CONCLUSIONS
47 REFERENCES 47 BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/998577804 DIGITALISIERT DURCH VI CONTENTS 3.2
EXPERIMENTAL ARRANGEMENTS 53 3.3 IMPEDANCE SPECTRA OF POLYMER FILMS 55
3.3.1 EFFECT OF THE FILM THICKNESS AND THICKNESS DISTRIBUTION OF POLYMER
FILMS 56 3.3.2 CHARACTERISTIC QUANTITIES FOR MODIFIED ELECTRODES 57
3.3.3 IMPEDANCE ASSOCIATED WITH POLYMER FILMS IN CONTACT WITH MEDIA
ALLOWING BOTH IONIC AND ELECTRONIC INTERFACIAL EXCHANGE 60 3.4 ANALYSIS
OF THE IMPEDANCE SPECTRA 61 3.5 MODELS OF POLYMERIC LAYERS 63 3.5.1
"HOMOGENEOUS" OR "UNIFORM" MODELS 63 3.5.2 "HETEROGENEOUS" OR "POROUS
LAYER" MODEL 64 3.5.3 THEORIES DEALING WITH TWO OR THREE CHARGE CARRIERS
65 3.5.4 BRUSH MODEL 66 3.6 SUMMARY 70 ACKNOWLEDGMENT 70 REFERENCES 70 4
RECENT TRENDS IN POLYPYRROLE ELECTROCHEMISTRY, NANOSTRUCTURATION, AND
APPLICATIONS 77 PIERRE AUDEBERT 4.1 INTRODUCTION 77 4.2 ADVANCES IN
SYNTHETIC PROCEDURES - NEW POLYMERS 78 4.2.1 NEW MONOMERS AND POLYMERS
78 4.2.2 FUNDAMENTAL RESEARCH 78 4.2.3 NEW POLYMERIZATION METHODS 79 4.
CONTENTS VII 5.3.2 ELECTROPOLYMERIZED AZINES AS ADVANCED
ELECTROCATALYSTS FOR NAD+INADH REGENERATION 99 5.3.2.1 DEHYDROGENASE
ENZYMES AND ELECTROCATALYSIS OF NAD + |NADH REGENERATION 99 5.3.2.2
MIMETICS OF ENZYME CATALYSIS 100 5.3.2.3 ELECTROPOLYMERIZED AZINES AS
NADH TRANSDUCERS 101 5.3.2.4 ELECTROREDUCTION OF NAD+ TO ENZYMATICALLY
ACTIVE NADH AT POLY(NEUTRAL RED)-MODIFIED ELECTRODES 102 5.3.2.5
OBSERVATION OF THE EQUILIBRIUM NAD + |NADH POTENTIAL AT POLY (NEUTRAL
RED) ELECTRODES 103 5.4 ELECTROPOLYMERIZED AZINES AS PROMOTERS FOR
BIOELECTROCATALYSIS 105 5.4.1 ATTEMPTS TO INVOLVE GLUCOSE OXIDASE IN
MEDIATOR FREE BIOELECTROCATALYSIS 105 5.4.1.1 BIOELECTROCATALYSIS BY
HYDROGENASE AND PEROXIDASE 106 5.4.2 BIOELECTROCATALYSIS BY CELLOBIOSE
DEHYDROGENASE ON POLYAZINES 106 5.5 CONCLUSION IOS REFERENCES 108 6
ELECTROPOLYMERIZATION OF PHTHALOCYANINES 111 NINEL M. ALPATOVA AND ELENA
V. OVSYANNIKOVA 6.1 INTRODUCTION 111 6. VILI CONTENTS 7.6.1
PIEZOELECTRIC SENSORS 144 7.6.2 CAPACITIVE SENSORS 144 7.6.3
AMPEROMETRIC AND VOLTAMMETRIC/POTENTIOMETRIC SENSORS 145 7.6.4
MISCELLANEOUS SENSING SYSTEMS 146 7.7 CONCLUSION 147 REFERENCES 148 8
GAS SENSING WITH CONDUCTING POLYMERS 153 KARIN POTJE-KAMLOTH 8.1
INTRODUCTION 153 8.2 ELECTRONIC PROPERTIES OF CONDUCTING POLYMERS 153
8.3 PREPARATION OF POLYMER GAS-SENSING LAYERS 155 8.3.1 SOLVENT CASTING
155 8.3.2 IN SITU ELECTROCHEMICAL DEPOSITION 155 8.3.3 TUNING OF
ELECTRONIC PROPERTIES OF CONDUCTING POLYMERS 356 8.3.3.1 EFFECT OF
PRIMARY DOPING ON WORK FUNCTION 156 8.3.3.2 ELECTROCHEMICAL WORK
FUNCTION TUNING 156 8.4 MECHANISM OF GAS/POLYMER INTERACTIONS 157 8.4.1
SECONDARY DOPING BY DONOR/ACCEPTOR INTERACTIONS 157 8.4.2 WORK FUNCTION
MODULATION - MODULATION OF CARRIER DENSITY 357 8.4.3 BULK RESISTANCE
CHANGES 158 8.4.4 CONTACT RESISTANCE CHANGES (SCHOTTKY BARRIER) 358 8.
CONTENTS IX 9.4 CONCLUSIONS 384 ACKNOWLEDGMENTS 185 REFERENCES 185 10
BIOSENSORS BASED ON ELECTROPOLYMERIZED FILMS 389 SERGE COSNIER AND
MICHAEL HOLZINGER 10.1 INTRODUCTION 189 10.2 CHRONOLOGICAL EVOLUTION OF
THE CONCEPT OF BIOSENSORS BASED ON ELECTROPOLYMERIZED FILMS: PRINCIPAL
STAGES 390 10.3 FORMATION OF POLYMER FILMS BY DIRECT
ELECTROPOLYMERIZATION OF THE BIOMOLECULE 191 10.4 ADSORPTION ON
ELECTROGENERATED POLYMERS 194 10.5 MECHANICAL ENTRAPMENT WITHIN
ELECTROPOLYMERIZED FILMS 195 10.6 COVALENT BINDING AT THE SURFACE OF
ELECTROPOLYMERIZED FILMS 200 10.7 NONCOVALENT BINDING BY AFFINITY
INTERACTIONS WITH THE ELECTROPOLYMERIZED FILMS 203 10.8 OUTLOOK 205
REFERENCES 206 11 INHERENTLY CONDUCTING POLYMERS VIA
ELECTROPOLYMERIZATION FOR ENERGY CONVERSION AND STORAGE 235 GORDON G.
WALLACE, GEORGE TSEKOURAS, AND CAIYUN WANG 11.1 INTRODUCTION 215 11.1.1
ELECTROCHEMICAL TECHNIQUES 236 11.1.2 SUBSTRATES 237 11.1.3 THE
ELECTROLYTE 217 11.2 ENERGY CONVERSION 218 11.2.1 POLYTHIOPHENES VIA
ELECTROPOLYMERIZATION OF SIMPLE PRECURSORS 219 X CONTENTS 11.7
CONCLUSIONS 236 REFERENCES 236 12 ELECTROCHEMOMECHANICAL DEVICES:
ARTIFICIAL MUSCLES 243 TORIBIO F. OTERO AND JOAQUIN ARIAS-PARDILLA 12.1
INTRODUCTION 241 12.2 CONDUCTING POLYMERS AS REACTIVE MATERIALS:
ELECTROCHEMICAL REACTIONS 242 12.2.1 OXIDATION 242 12.2.1.1 PREVAILING
ANION INTERCHANGE 243 12.2.1.2 PREVAILING CATION INTERCHANGE 243 12.2.2
REDUCTION OF NEUTRAL CHAINS 244 12.2.3 COMPLEX ACTUAL IONIC INTERCHANGES
AND POLYMERIC STRUCTURE 244 12.2.4 GIANT NONSTOICHIOMETRY 245 12.3
ELECTROCHEMICAL PROPERTIES: MULTIFUNCTIONALITY AND BIOMIMETISM 246
12.3.1 ELECTROCHEMOMECHANICAL PROPERTIES AND ARTIFICIAL MUSCLES 246
12.3.2 BASIC MOLECULAR MOTOR 247 12.4 MACROSCOPIC DIMENSIONAL CHANGES
AND MECHANICAL PROPERTIES 248 12.5 ANISOTROPY OBTAINED FROM ISOTROPIE
CHANGES: MACROSCOPIC DEVICES 248 12.5.1 ELECTROCHEMICAL TRANSDUCER 249
12.5.2 EFFICIENCY 253 12.5.3 BENDING STRUCTURES 252 12.5.3. |
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| spellingShingle | Electropolymerization concepts, materials and applications Elektrochemische Polymerisation (DE-588)4534773-6 gnd Sensortechnik (DE-588)4121663-5 gnd |
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| title | Electropolymerization concepts, materials and applications |
| title_auth | Electropolymerization concepts, materials and applications |
| title_exact_search | Electropolymerization concepts, materials and applications |
| title_full | Electropolymerization concepts, materials and applications ed. by Serge Cosnier ... |
| title_fullStr | Electropolymerization concepts, materials and applications ed. by Serge Cosnier ... |
| title_full_unstemmed | Electropolymerization concepts, materials and applications ed. by Serge Cosnier ... |
| title_short | Electropolymerization |
| title_sort | electropolymerization concepts materials and applications |
| title_sub | concepts, materials and applications |
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