Diffusion-controlled solid state reactions: in alloys, thin-films, and nanosystems
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Weinheim, Bergstr
Wiley-VCH
2010
|
| Ausgabe: | 1., Auflage |
| Schlagworte: | |
| Online-Zugang: | Inhaltstext Inhaltsverzeichnis |
| Beschreibung: | XXI, 476 S. Ill., graph. Darst. |
| ISBN: | 9783527408849 |
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VII CONTENTS EDITOR'S PREFACE XVII LIST OF CONTRIBUTORS XIX 1
INTRODUCTION 1 ANDRIY M. GUSAK 2 NONEQUILIBRIUM VACANCIES AND
DIFFIISION-CONTROLLED PROCESSES AT NANOLEVEL 11 ANDRIY M. GUSAK 2.1
INTRODUCTION 11 2.2 BEYOND DARKEN'S APPROXIMATION 12 2.3 THE MODEL FOR
REGULAER CHAINS OF IDEAL VACANCIES SINKS/SOURCES 17 2.4 DESCRIPTION OF
INTERDIFFUSION IN ALLOYS AT RANDOM POWER OF DISTRIBUTED VACANCY SINKS 20
2.5 LINEAR PHASE GROWTH AND NONEQUILIBRIUM VACANCIES 22 2.6
INTERMETALLIC LAYER GROWTH AT IMPOSED CURRENT AND NONEQUILIBRIUM
VACANCIES DAMPING EFFECT 25 2.7 POSSIBLE ROLE OF NONEQUILIBRIUM
VACANCIES IN SPINODAL DECOMPOSITION 26 2.8 NANOSHELL COLLAPSE 29 2.9 THE
ROLE OF NONEQUILIBRIUM VACANCIES IN DIFFUSION COARSENING 32 2.10
CONCLUSIONS 34 REFERENCES 34 3 DIFFUSIVE PHASE COMPETITION: FUNDAMENTALS
37 ANDRIY M. GUSAK 3.1 INTRODUCTION 37 BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/1000249956 DIGITALISIERT DURCH VIII CONTENTS 3.6
SUPPRESSION OF AN INTERMEDIATE PHASE BY SOLID SOLUTIONS 52 3.6.1
UNLIMITED NUCLEATION 53 3.6.2 FINITE RATE OF NUCLEI FORMATION 54 3.7
PHASE COMPETITION IN A MODEL OF DIVIDED COUPLE 55 REFERENCES 59 4
NUCLEATION IN A CONCENTRATION GRADIENT 61 ANDRIY M. GUSAK 4.1
INTRODUCTION 61 4.2 NUCLEATION IN NONHOMOGENEOUS SYSTEMS: GENERAL
APPROACH 63 4.3 THERMODYNAMICS OF THE POLYMORPHIC MODE OF NUCLEATION IN
A CONCENTRATION GRADIENT 65 4.3.1 HOMOGENEOUS NUCLEATION: GENERAL
RELATIONS 65 4.3.2 SPHERICAL NUCLEI 66 4.3.3 ELLIPSOIDAL NUCLEI 68 4.3.4
MC SIMULATIONS OF THE SHAPE OF THE NUCLEUS 70 4.3.5 STRESS EFFECTS 71
4.4 THERMODYNAMICS OF THE TRANSVERSAL MODE OF NUCLEATION IN A
CONCENTRATION GRADIENT 74 4.4.1 HOMOGENEOUS NUCLEATION: GENERAL
RELATIONS 74 4.5 THERMODYNAMICS OF THE LONGITUDINAL MODE OF NUCLEATION
IN A CONCENTRATION GRADIENT 79 4.6 NUCLEATION IN SYSTEMS WITH LIMITED
METASTABLE SOLUBILITY 81 4.6. CONTENTS IX 5.3 KINETICS OF LATERAL GROWTH
OF INTERMEDIATE PHASE ISLANDS AT THE INITIAL STAGE OF REACTIVE DIFFUSION
112 5.3.1 PROBLEM FORMULATION 112 5.3.2 PHYSICAL MODEL 114 5.3.3
NUMERICAL RESULTS 116 5.3.4 ANALYTICAL SOLUTION FOR THE STEADY STATE 117
5.3.5 ASYMPTOTIC THICKNESS OF AN ISLAND 118 5.3.6 ESTIMATES 119 5.3.7
CONCLUSIONS 121 5.4 MC-SCHEMEOF REACTIVE DIFFUSION 121 5.4.1 FORMULATION
OF THE PROBLEM 121 5.4.2 THE MODEL 122 5.4.3 NUCLEATION OF PHASE A 2 B T
AT THE INTERFACE A- A X B 2 124 5.4.4 COMPETITIVE NUCLEATION OF PHASES
AIB 2 AND A 2 BJ AT THE INTERFACE A-B 129 5.4.5 LATERAL COMPETITION 131
5.4.6 CONCLUSIONS 131 REFERENCES 132 FURTHER READING 133 6 FLUX-DRIVEN
MORPHOLOGY EVOLUTION 135 ANDRIY X CONTENTS 6.6.3 EXPERIMENTAL RESULTS
166 6.6.4 GENERAL INSTABILITY CRITERION 168 6.6.5 ESTIMATION OF
MARKERS'DISTRIBUTIONS NEAR THE VIRTUAL K-PLANE 169 6.6.6 SPATIAL
DISTRIBUTION OF MARKERS 170 6.6.7 POSSIBLE ALTERNATIVE TO THE MULTILAYER
METHOD 171 6.7 ELECTROMIGRATION-INDUCED GRAIN ROTATION IN ANISOTROPIE
CONDUCTING BETATIN 173 6.8 THERMOMIGRATION IN EUTECTIC TWO-PHASE
STRUCTURES 178 6.8.1 THERMOMIGRATION INDUCED BACK STRESS IN TWO-PHASE
MIXTURES 183 6.8.2 THERMOMIGRATION-DRIVEN KIRKENDALL EFFECT IN BINARY
MIXTURES 184 6.8.3 STOCHASTIK TENDENCIES IN THERMOMIGRATION 185
REFERENCES 186 7 NANOVOID EVOLUTION 189 TATYANA V. ZAPOROZHETS AND
ANDRIY M. GUSAK 7.1 INTRODUCTION 189 7.2 KINETIC ANALYSIS OF THE
INSTABILITY OF HOLLOW NANOPARTICLES 191 7.2.1 INTRODUCTION 191 7.2.2
MECHANISMOF NANOSHELL SHRINKAGE 192 7.2.3 MODELS OF NANOVOID SHRINKAGE
194 7.2.3.1 MODELL: SHRINKAGE OF PURE ELEMENT NANOSHELLS 195 7.2.3.2
MODEL 2: SHRINKAGE OF A BINARY COMPOUND NANOSHELL WITH STEADY STAT
CONTENTS XI 7.4.3 FORMATION OF A HOLLOW NANOSHELL FROM CORE-SHELL
STRUCTURE WITHOUT THE INFLUENCE OF AMBIENT ATMOSPHERE 233 7.4.4 RESULTS
OF THE PHENOMENOLOGICAL MODEL 234 7.4.5 MONTE CARLO SIMULATION OF THE
VACANCY SUBSYSTEM EVOLUTION IN THE STRUCTURE "CORE-SHELL" 238 7.4.5.1
FORMATION OF A NANOSHELL IN A MC SIMULATION 239 7.4.5.2 CROSSOVER FROM
FORMATION TO COLLAPSE 239 7.4.5.3 SHRINKAGE AND SEGREGATION KINETICS IN
AN MC SIMULATION 241 7.4.6 SUMMARY 241 7.5 VOID MIGRATION IN METALLIC
INTERCONNECTS 245 7.5.1 HYPOTHESES AND EXPERIMENTS 245 7.5.2 THE MODEL
248 7.5.3 RESULTS 249 7.5.3.1 MIGRATION OF VOIDS IN BULK CU AND
DETERMINATION OF THE CALIBRATION FACTOR BETWEEN MCS AND REAL TIME 249
7.5.3.2 VOID MIGRATION ALONG THE METAL/DIELECTRIC INTERFACE 250 7.5.4
SIMPLIFIED ANALYTICAL MODELS OF TRAPPING AT THE GBS AND AT THE GB
JUNCTIONS 253 7.5.5 SUMMARY 255 REFERENCES 256 8 PHASE FORMATION VIA
ELECTROMIGRATION 259 XII I CONTENTS 9 DIFFUSION PHASE COMPETITION IN
TERNARY SYSTEMS 289 SEMEN V. KORNIENKO, YURIY A. LYASHENKO, AND ANDRIY
M. GUSAK 9.1 INTRODUCTION 289 9.2 PHASE COMPETITION IN THE DIFFUSION
ZONE OFA TERNARY SYSTEM 289 9.2.1 PHASE COMPETITION IN THE DIFFUSION
ZONE OFA TERNARY SYSTEM WITH TWO INTERMEDIATE PHASES 290 9.2.2 INFLUENCE
OF PT ON PHASE COMPETITION IN THE DIFFUSION ZONE OF THE TERNARY
(NIPT)-SI SYSTEM 295 9.2.2.1 BASIC CONSIDERATIONS 295 9.2.2.2 EFFECT OF
PT ON PHASE COMPETITION IN THE DIFFUSION ZONE OFNI-SI 297 9.2.2.3
CALCULATIONS AND DISCUSSION 300 9.3 AMBIGUITY AND THE PROBLEM OF
SELECTION OF THE DIFFUSION PATH 302 9.3.1 GENERAL REMARKS 302 9.3.2
ANALYTICAL SOLUTION OF THE SIMPLIFIED SYMMETRIE MODEL 304 9.3.3
NUMERICAL CALCULATIONS FOR A COMPLEX MODEL 309 9.3.4 CONCLUSIONS 320 9.4
NUCLEATION IN THE DIFFUSION ZONE OFA TERNARY SYSTEM 321 9.4.1 MODEL
DESCRIPTION 321 9.4.2 ALGORITHM AND RESULTS FOR THE MODEL SYSTEM 325
9.4.3 DISCUSSION 327 REFERENCE CONTENTS XIII 10.4.5 CONCLUSIONS 356
REFERENCES 356 FURTHER READING 358 11 THE PROBLEM OF CHOICE OF REACTION
PATH AND EXTREMUM PRINCIPLES 359 ANDRIY M. GUSAK AND YURIY A. LYASHENKO
11.1 INTRODUCTION 359 11.2 PRINCIPLE OF MAXIMAL ENTROPY PRODUCTION AT
CHOOSING THE EVOLUTION PATHOF DIFFUSION-INTERACTIVE SYSTEMS 359 11.3
NONEQUILIBRIUM THERMODYNAMICS: GENERAL RELATIONS 361 11.3.1 ISOLATED
SYSTEMS 361 11.3.2 SYSTEM IN A THERMOSTAT 363 11.3.3 INHOMOGENEOUS
SYSTEMS: POSTULATE OF QUASI-EQUILIBRIUM FOR PHYSICALLY SMALL VOLUMES 364
11.3.4 EXTREMUM PRINCIPLES 366 11.4 APPLICATION OF THE PRINCIPLES OF
THERMODYNAMICS OF IRREVERSIBLE PROCESSES: EXAMPLES 368 11.4.1 CRITERION
OF FIRST PHASE CHOICE AT REACTION-DIFFUSION PROCESSES 368 11.5
CONCLUSIONS 378 REFERENCES 379 12 CHOICE OF OPTIMAL REGIMES IN CELLULAR
DECOMPOSITION, DIFFUSION-INDUCED GRAIN BOUNDARY MIGRATION, AND THE
INVERSE DIFFUSION PROBLEM 381 YURIY A. LYASHENKO 12.1 INTRODUCTION 381
12. XIV CONTENTS 12.3.1.1 MASS CONSERVATION AND THERMODYNAMIC
DESCRIPTION 408 12.3.1.2 CALCULATION OF THE ENTROPY PRODUCTION RATE DUE
TO GRAIN BOUNDARY DIFFUSION 409 12.3.1.3 CALCULATION OF THE DRIVING
FORCE 410 12.3.2 RESULTS OF MODEL CALCULATIONS FOR THE CU-NI SYSTEM 411
12.3.2.1 DETERMINATION OF THE CURVATURE OF THE GIBBS POTENTIAL 411
12.3.2.2 DIFFUSION PARAMETERS OF THE SYSTEM 412 12.3.2.3 GRAIN BOUNDARY
MOBILITY 412 12.3.2.4 RESULTS OF THE MODEL CALCULATION FOR THE
CU/NI/CU-LIKE SYSTEM 412 12.4 ENTROPY PRODUCTION AS A REGULARIZATION
FACTOR IN SOLVING THE INVERSE DIFFUSION PROBLEM 416 12.4.1 DESCRIPTION
OF THE PROCEDURE OF THE INVERSE DIFFUSION PROBLEM SOLUTION FOR A BINARY
SYSTEM 416 12.4.2 RESULTS OF MODEL CALCULATIONS 418 12.5 CONCLUSIONS 421
REFERENCES 422 FURTHER READING 424 13 NUCLEATION AND PHASE SEPARATION IN
NANOVOLUMES 425 ARAM S. SHIRINYAN AND ANDRIY M. GUSAK 13.1 INTRODUCTION
425 13.2 PHYSICS OF SMALL PARTICLES AND DISPERSED SYSTEMS 427 CONTENTS
XV 13.3.2.4 VARYING C O 441 13.3.2.5 PHASE DIAGRAM 441 13.3.2.6
SIZE-DEPENDENT DIAGRAM AND SOLUBILITIES IN MULTICOMPONENT NANOMATERIALS
442 13.3.2.7 CRITICAL SUPERSATURATION 443 13.3.2.8 CONCLUDING REMARKS
444 13.4 DIAGRAM METHOD OF PHASE TRANSITION ANALYSIS IN NANOSYSTEMS 444
13.4.1 GIBBS'S METHOD OF GEOMETRICAL THERMODYNAMICS 445 13.4.2
NUCLEATION OF AN INTERMEDIATE PHASE 446 13.4.2.1 PHASE TRANSITION
CRITERION 446 13.4.2.2 MODEL OF INTERMEDIATE PHASE 446 13.4.2.3
SEPARATION IN A MACROSCOPIC SAMPLE: EQUILIBRIUM STATE DIAGRAM 447
13.4.2.4 SEPARATION IN DSS: SIZE-DEPENDENT PHASE DIAGRAM 448 13.4.2.5
INFLUENCEOF SIZE ON LIMITING SOLUBILITY 449 13.4.2.6 INFLUENCE OF SIZE
OF AN ISOLATED PARTICLE ON THE PHASE TRANSITION TEMPERATURE 449 13.4.2.7
CONCLUDING REMARKS 450 13.5 COMPETITIVE NUCLEATION AND GROWTH OF TWO
INTERMEDIATE PHASES: BINARY SYSTEMS 451 CASE 1 454 CASE 2 454 CASE 3 OR
CROSSOVER REGIME 455 XVI CONTENTS 13.7.2.1 CONCLUDING REMARKS 468 13.A
APPENDIX: THE RULE OF PARALLEL TANGENT CONSTRUCTION FOR OPTIMAL POINTS
OF PHASE TRANSITIONS 469 13.A.1 RESUME 470 REFERENCES 471 INDEX 475 |
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| spelling | Gusak, Andriy M. Verfasser aut Diffusion-controlled solid state reactions in alloys, thin-films, and nanosystems Andriy M. Gusak 1., Auflage Weinheim, Bergstr Wiley-VCH 2010 XXI, 476 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Diffusion (DE-588)4012277-3 gnd rswk-swf Festkörperreaktion (DE-588)4154188-1 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Festkörperreaktion (DE-588)4154188-1 s Diffusion (DE-588)4012277-3 s DE-604 text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3428182&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020603130&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Gusak, Andriy M. Diffusion-controlled solid state reactions in alloys, thin-films, and nanosystems Diffusion (DE-588)4012277-3 gnd Festkörperreaktion (DE-588)4154188-1 gnd |
| subject_GND | (DE-588)4012277-3 (DE-588)4154188-1 (DE-588)4143413-4 |
| title | Diffusion-controlled solid state reactions in alloys, thin-films, and nanosystems |
| title_auth | Diffusion-controlled solid state reactions in alloys, thin-films, and nanosystems |
| title_exact_search | Diffusion-controlled solid state reactions in alloys, thin-films, and nanosystems |
| title_full | Diffusion-controlled solid state reactions in alloys, thin-films, and nanosystems Andriy M. Gusak |
| title_fullStr | Diffusion-controlled solid state reactions in alloys, thin-films, and nanosystems Andriy M. Gusak |
| title_full_unstemmed | Diffusion-controlled solid state reactions in alloys, thin-films, and nanosystems Andriy M. Gusak |
| title_short | Diffusion-controlled solid state reactions |
| title_sort | diffusion controlled solid state reactions in alloys thin films and nanosystems |
| title_sub | in alloys, thin-films, and nanosystems |
| topic | Diffusion (DE-588)4012277-3 gnd Festkörperreaktion (DE-588)4154188-1 gnd |
| topic_facet | Diffusion Festkörperreaktion Aufsatzsammlung |
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