Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization:
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Abschlussarbeit Buch |
| Sprache: | English |
| Veröffentlicht: |
München
Verl. Dr. Hut
2010
|
| Ausgabe: | 1. Aufl. |
| Schriftenreihe: | Anorganische Chemie
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| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | 155 S. graph. Darst. 210 mm x 148 mm, 226 gr. |
| ISBN: | 9783868535280 |
Internformat
MARC
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| 100 | 1 | |a Li, Yang |d 1981- |e Verfasser |0 (DE-588)142057649 |4 aut | |
| 245 | 1 | 0 | |a Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization |c Yang Li |
| 250 | |a 1. Aufl. | ||
| 264 | 1 | |a München |b Verl. Dr. Hut |c 2010 | |
| 300 | |a 155 S. |b graph. Darst. |c 210 mm x 148 mm, 226 gr. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 490 | 0 | |a Anorganische Chemie | |
| 502 | |a Zugl.: München, Techn. Univ., Diss., 2010 | ||
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Datensatz im Suchindex
| _version_ | 1804143222095609856 |
|---|---|
| adam_text | IMAGE 1
INDEX
1 INTRODUCTION 1
1.1 WEAKLY COORDINATING ANIONS 2
1.1.1 CANDIDATES 2
1.1.2 SYNTHETIC STRATEGIES TO INTRODUCE WCAS 3
1.1.3 APPLICATIONS OF WCAS 4
1.2 ISOBUTYLENE POLYMERIZATION CATALYZED BY SOLVENT LIGATED METAL
COMPLEXES WITH W C AS AS
COUNTERANIONS 5
1.2.1 POLYISOBUTYIENES 5
1.2.2 CATALYTIC POLYMERIZATION OF ISOBUTYLENE - STATE OF THE ART 7
1.2.3 POLYMERIZATION OF ISOBUTYLENE BY ACETONITRILE LIGATED METAL
COMPLEXES WITH WCAS AS
COUNTERANIONS 9
1.3 CATALYTIC OLEFINAZIRIDINATION 10
1.3.1 AZIRIDINES AND AZIRIDINATION VIA NITRENE TRANSFER TO OLEFINS 10
1.3.2 CU-CATALYZED OLEFIN AZIRIDINATION 12
1.4 IMMOBILIZATION OF ACETONITRILE LIGATED METAL COMPLEXES 14
1.4.1 OVERVIEW OF HETEROGENEOUS SINGLE-SITE CATALYSIS 14
1.4.2 IMMOBILIZATION OF SOLVENT LIGATED METAL COMPLEXES THROUGH CATION
COORDINATION 15
1.4.3 IMMOBILIZATION OF SOLVENT LIGATED METAL COMPLEXES THROUGH ANION
IMMOBILIZATION 17
1.4.4 OVERVIEW ON FUNCTIONALIZED POLYMERIC SUPPORTS 17
2 SOLVENT LIGATED COPPER(H) COMPLEXES FOR THE HOMOPOLYMERIZAT1ON OF
ISOBUTYLENE 21
2.1 INTRODUCTION 21
2.2 RESULTS AND DISCUSSION 22
2.2.1 SYNTHESIS AND CHARACTERIZATION 22
2.2.2 POLYMERIZATION OF ISOBUTYLENE WITH COPPER(LL)-BASED CATALYSTS 27
2.3 CONCLUSION 32
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1005500193
DIGITALISIERT DURCH
IMAGE 2
3 THE FACIAL PREPARATION AND CHARACTERIZATION OF ACETONITRILE LIGATED
SILVER SALTS OF
POLY/PERFLUOROALKOXYALUMINATES 33
3.1 INTRODUCTION 33
3.2 RESULTS AND DISCUSSION 35
3.2.1 SYNTHESIS OF SILVER PER/POLYFLUOROALKOXYALUMINATES 35
3.2.2 X-RAY CRYSTALLOGRAPHY 37
3.2.3 ATTEMPTED SYNTHESIS OF AG[AI(OCIC SF5L,LJ 40
3.3 CONCLUSIONS 41
4 SYNTHESIS AND CRYSTAL STRUCTURES OF THREE ACETONITRILE LI6ATED
COPPER(I) COMPLEXES
WITH PER/POLYFLUOROALKOXYALUMINATES AS COUNTERANIONS 43
4.1 INTRODUCTION 43
4.2 SYNTHESIS AND CHARACTERIZATION OF COPPER(I) COMPLEXES 44
4.2.1 SYNTHESIS 44
4.2.2 X-RAY CRYSTAL STRUCTURES OF COMPLEXES 1-3 45
4.3 CONCLUSIONS AND PERSPECTIVES 50
5 SYNTHESES OF ACETONITRILE LIGATED COPPER(II) COMPLEXES WITH
PER/POLYFLUOROALKOXYALUMINATES AS COUNTERANIONS AND THEIR CATALYTIC
APPLICATION FOR
OLEFIN AZIRIDINATION 51
5.1 INTRODUCTION 51
5.2 SYNTHESIS AND CHARACTERIZATION 53
5.2.1 SYNTHESIS 53
5.2.2 SOLID-STATE STRUCTURES 54
5.2.3 FT-IR SPECTROSCOPIC STUDIES 55
5.2.4 EPR SPECTROSCOPIC STUDIES 56
5.3 CATALYTIC OLEFIN AZIRIDINATION 57
5.3.1 COMPARISON OFLALLOCLCFJLJJJ AND OTHER WCAS 57
5.3.2 OLEFIN AZIRIDINATION CATALYZED BY LCU(NCCH 3)SHAI(OCLCF3)3I,]! 59
5.3.3 INFLUENCE OF SUBSTRATES, COUNTERANIONS AND SOLVENTS 61
IMAGE 3
5.3.4 MECHANISTIC CONSIDERATIONS 66
5.4 CONCLUSION 67
6 ACETONITRILE AND BENZONITRILE LIGATED ZINCOLL/COPPERFLL) COMPLEXES
INCORPORATING
PER/POLYFLUOROALKOXYALUMINATES AS CATALYSTS FOR ISOBUTYLENE
POLYMERIZATION 69
6.1 INTRODUCTION 69
6.2 RESULTS AND DISCUSSION 71
6.2.1 SYNTHESIS AND CHARACTERIZATION 71
6.2.2 CATALYTIC APPLICATION IN THE POLYMERIZATION OF ISOBUTYLENE 73
6.2.3 STABILITY OF THE COUNTERANIONS 78
6.3 CONCLUSION 82
7 SYNTHESIS OF NITRILE COORDINATED LEWIS ACIDS AL(OC(CFI)2R) 3 AND THEIR
APPLICATION IN
CATALYTIC EPOXIDE RING-OPENING REACTIONS 83
7.1 INTRODUCTION 83
7.2 RESULTS AND DISCUSSION 84
7.2.1 SYNTHESIS AND CHARACTERIZATION 84
7.2.2 STUDIES OF THE CATALYTIC ACTIVITY OF COMPOUNDS 1-4 87
7.3 CONCLUSIONS 92
8 IMMOBILIZATION OF [B(CSF S)4] ON MERRIFIELD RESIN 93
8.1 INTRODUCTION 93
8.2 RESULTS AND DISCUSSION 95
8.2.1 SYNTHESIS OF LIOCEFTBICSFSHLI 95
8.2.2 INVESTIGATION OF THE REACTION CONDITIONS FOR THE SYNTHESIS OF
COMPOUND 8 99
8.2.3 SYNTHESIS OF PHCH 2OC6FIB(CSFSL3TLI AND P T-PHCH
!OCSF4B(CEF5)3RLI P = MERRIFIELD RESIN
BACKBONE) 101
8.3 CONCLUSION 104
9 EXPERIMENTAL SECTION 105
9.1 GENERAL PROCEDURE 105
9.1.1 INERT GAS ATMOSPHERE 105
IMAGE 4
9.1.2 SOLVENTS 205
9.1.3 CHARACTERIZATION METHODS 105
9.2 CHAPTER 2 106
9.2.1 SYNTHESIS AND CHARACTERIZATION OF COMPLEXES 106
9.2.2 POLYMERIZATION REACTIONS 108
9.3 CHAPTER 3 109
9.3.1 SYNTHESES AND CHARACTERIZATION OF THE COMPLEXES 109
9.3.2 X-RAY CRYSTALLOGRAPHY I LL
9.4 CHAPTER 4 115
9.4.1 SYNTHESIS OF COMPLEXES 1-3 115
9.4.2 X-RAY CRYSTALLOGRAPHY 116
9.5 CHAPTER 5 126
9.5.1 SYNTHESES AND CHARACTERIZATION OF THE COMPLEXES 126
9.5.2 CATALYTIC OLEFIN AZIRIDINATION 132
9.6 CHAPTER 6 135
9.6.1 SYNTHESES AND CHARACTERIZATION OF THE COMPLEXES 135
9.6.2 NMR STUDIES OF THE STABILITY OF THE COUNTERANIONS 137
9.7 CHAPTER 7 137
9.7.1 SYNTHESIS AND CHARACTERIZATION OF THE CATALYSTS 137
9.7.2 EPOXIDES RING-OPENING REACTIONS 139
9.8 CHAPTER 8 141
10 SUMMARY 143
10.1 SYNTHESIS OF NITRILE LIGATED COMPLEXES 143
10.2 CATALYTIC APPLICATIONS 145
10.2.1 OLEFIN AZIRIDINATION 145
10.2.2 POLYMERIZATION OF ISOBUTYLENE 145
10.3 IMMOBILIZATION OF IBIQFS),] 146
10.4 SYNTHESIS OF ALUMINUM LEWIS ACIDS AND THEIR APPLICATION IN
RING-OPENING REACTION OF EPOXIDES 147
10.5 CONCLUSION 147
IMAGE 5
10 REFERENCE 149
|
| any_adam_object | 1 |
| author | Li, Yang 1981- |
| author_GND | (DE-588)142057649 |
| author_facet | Li, Yang 1981- |
| author_role | aut |
| author_sort | Li, Yang 1981- |
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| building | Verbundindex |
| bvnumber | BV036614888 |
| classification_tum | CHE 731d CHE 658d CHE 334d CHE 366d |
| ctrlnum | (OCoLC)705732470 (DE-599)DNB1005500193 |
| dewey-full | 541.2242 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541.2242 |
| dewey-search | 541.2242 |
| dewey-sort | 3541.2242 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie |
| edition | 1. Aufl. |
| format | Thesis Book |
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| id | DE-604.BV036614888 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:44:13Z |
| institution | BVB |
| isbn | 9783868535280 |
| language | English |
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| physical | 155 S. graph. Darst. 210 mm x 148 mm, 226 gr. |
| publishDate | 2010 |
| publishDateSearch | 2010 |
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| spelling | Li, Yang 1981- Verfasser (DE-588)142057649 aut Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization Yang Li 1. Aufl. München Verl. Dr. Hut 2010 155 S. graph. Darst. 210 mm x 148 mm, 226 gr. txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2010 Metallkomplexe (DE-588)4038898-0 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Metallkomplexe (DE-588)4038898-0 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020535049&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Li, Yang 1981- Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization Metallkomplexe (DE-588)4038898-0 gnd |
| subject_GND | (DE-588)4038898-0 (DE-588)4113937-9 |
| title | Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization |
| title_auth | Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization |
| title_exact_search | Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization |
| title_full | Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization Yang Li |
| title_fullStr | Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization Yang Li |
| title_full_unstemmed | Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization Yang Li |
| title_short | Synthesis of nitrile ligated metal complexes with poly/perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization |
| title_sort | synthesis of nitrile ligated metal complexes with poly perfluoroalkoxyaluminates as counteranions and their applications in olefin aziridination and isobutylene polymerization |
| topic | Metallkomplexe (DE-588)4038898-0 gnd |
| topic_facet | Metallkomplexe Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=020535049&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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