Nanoparticles: from theory to application
Saved in:
| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2010
|
| Edition: | 2., completely rev. and updated ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIII, 522 S. Ill., graph. Darst. |
| ISBN: | 9783527325894 |
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| 264 | 1 | |a Weinheim |b Wiley-VCH |c 2010 | |
| 300 | |a XIII, 522 S. |b Ill., graph. Darst. | ||
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| adam_text | IMAGE 1
CONTENTS
LIST OF CONTRIBUTORS XI
1 GENERAL INTRODUCTION 1
GUENTER SCHMID
2 QUANTUM DOTS 3
WOLFGANGJOHANN PARAK, LIBERATO MANNA, FRIEDRICH C.
SIMMEL, DANIELE CERION, AND PAUL ALIVISATOS 2.1 INTRODUCTION AND OUTLINE
3
2.2 NANOSCALE MATERIALS AND QUANTUM MECHANICS 5 2.2.1 NANOSCALE
MATERIALS AS INTERMEDIATE BETWEEN ATOMIC AND BULK MATTER 5
2.2.2 QUANTUM MECHANICS 6 2.3 FROM ATOMS TO MOLECULES AND QUANTUM DOTS 7
2.4 SHRINKING BULK MATERIAL TO A QUANTUM DOT 10 2.4.1 THREE-DIMENSIONAL
SYSTEMS (BULK MATERIAL) 10 2.4.2 TWO-DIMENSIONAL SYSTEMS 13 2.4.3
ONE-DIMENSIONAL SYSTEMS (QUANTUM WIRES) 17 2.4.4 ZERO-DIMENSIONAL
SYSTEMS (QUANTUM DOTS) 18 2.5 ENERGY LEVELS OF A (SEMICONDUCTOR) QUANTUM
DOT 19
2.6 VARIETIES OF QUANTUM DOTS 22
2.6.1 LITHOGRAPHICALLY DEFINED QUANTUM DOTS 23 2.6.2 EPITAXIALLY
SELF-ASSEMBLED QUANTUM DOTS 25 2.6.3 COLLOIDAL QUANTUM DOTS 26
2.7 OPTICAL PROPERTIES OF QUANTUM DOTS 28 2.7.1 ABSORPTION AND EMISSION
SPECTRA 28 2.7.2 SPECTRAL DIFFUSION AND BLINKING 29 2.7.3 METAL
NANOPARTICLES 31 2.7 A OVERVIEW OF SOME SELECTED APPLICATIONS 32
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/1000249972
DIGITALISIERT DURCH
IMAGE 2
VI CONTENTS
2.8 SOME (ELECTRICAL) TRANSPORT PROPERTIES OF QUANTUM DOTS 33
2.8.1 COULOMB BLOCKADE: BASIC THEORY AND HISTORICAL SKETCH 33 2.8.2
SINGLE-ELECTRON TUNNELING 35 2.8.3 TUNNELING TRANSPORT: THE LINE SHAPE
OF CONDUCTANCE PEAKS 39 2.8.4 SOME APPLICATIONS 40
REFERENCES 42
3 SYNTHESES AND CHARACTERIZATIONS 49
3.1 ZINTL IONS 49
3.1.1 HOMOATOMIC AND INTERMETALLOID TETIEL CLUSTERS - SYNTHESIS,
CHARACTERIZATION, AND REACTIVITY 49 SANDRA SCHARFE AND THOMAS F. FAESSLER
3.1.1.1 INTRODUCTION 49 3.1.1.2 HOMOATOMIC CLUSTERS OF TETREL ELEMENTS
50 3.1.1.2.1 DISCRETE CLUSTERS IN NEAT SOLIDS AND FROM SOLUTIONS 50
3.1.1.2.2 CLUSTER SHAPES AND ION PACKING 52 3.1.1.2.3 LINKED E 9
CLUSTERS 55 3.1.1.3 INTERMETALLOID CLUSTERS OF TETREL ELEMENTS 56
3.1.1.3.1 COMPLEXES OF ZINTL IONS 56 3.1.1.3.2 LIGAND-FREE HETEROATOMIC
CLUSTER: INTERMETALLOIDS 58 3.1.1.4 BEYOND DELTAHEDRAL CLUSTERS 63
REFERENCES 65 3.2 SEMICONDUCTOR NANOPARTICLES 69 3.2.1 SYNTHESIS AND
CHARACTERIZATION OF II-VI NANOPARTICLES 69
ALEXANDER EYCHMUELLER
3.2.1.1 HISTORICAL REVIEW 69 3.2.1.2 THIOL-STABILIZED NANOPARTICLES 76
3.2.1.3 THE HOT-INJECTION SYNTHESIS 81 3.2.1.4 CORE-SHELL NANOCRYSTALS
83 3.2.1.5 QUANTUM DOT QUANTUM WELLS 88
REFERENCES 92
3.2.2 SYNTHESIS AND CHARACTERIZATION OF III-V SEMICONDUCTOR
NANOPARTICLES 101 URI BANIN
3.2.2.1 INTRODUCTION 101 3.2.2.2 SYNTHETIC STRATEGY 103 3.2.2.3 INAS AND
INP NANOCRYSTALS I05 3.2.2.3.1 SYNTHESIS OF INAS AND INP NANOCRYSTALS
105
3.2.2.3.2 STRUCTURAL AND BASIC OPTICAL CHARACTERIZATION OF INAS AND INP
NANOCRYSTALS 107 3.2.2.4 GROUP III-V CORE-SHELL NANOCRYSTALS: SYNTHESIS
AND CHARACTERIZATION 111
3.2.2.4.1 SYNTHESIS OF CORE-SHELL NANOCRYSTALS WITH INAS CORES 113
3.2.2.4.2 OPTICAL CHARACTERIZATION OF THE CORE-SHELL NANOCRYSTALS 114
3.2.2.4.3 CHEMICAL AND STRUCTURAL CHARACTERIZATION 117
IMAGE 3
CONTENTS VII
3.2.2.4.4 MODEL CALCULATIONS FOR THE BAND GAP 122
3.2.2.4.5 STABILITY OF CORE-SHELL NANOCRYSTALS 124 REFERENCES 125 3.2.3
SYNTHESIS AND CHARACTERIZATION OF IB-VI NANOCLUSTERS 127 STEFANIE
DEHNEN, ANDREAS EICHHOEFER, JOHN F. CORRIGAN, OLAF FUHR,
AND DIETER FENSKE
3.2.3.1 INTRODUCTION 127 3.2.3.2 CHALCOGEN-BRIDGED COPPER CLUSTERS 128
3.2.3.2.1 SYNTHESIS ROUTES 128 3.2.3.2.2 SULFUR-BRIDGED COPPER CLUSTERS
129 3.2.3.2.3 SELENIUM-BRIDGED COPPER CLUSTERS 136 3.2.3.2.4
TELLURIUM-BRIDGED COPPER CLUSTERS 165 3.2.3.3 CHALCOGEN-BRIDGED SILVER
CLUSTERS 177 3.2.3.3.1 SULFUR-BRIDGED SILVER CLUSTERS 178 3.2.3.3.2
SELENIUM-BRIDGED SILVER CLUSTERS 186 3.2.3.3.3 TELLURIUM-BRIDGED SILVER
CLUSTERS 196 3.2.3.4 SELENIUM-BRIDGED GOLD CLUSTERS 208
REFERENCES 210
3.3 SYNTHESIS OF METAL NANOPARTICLES 214 3.3.1 NOBLE METAL NANOPARTICLES
214 GUENTER SCHMID
3.3.1.1 INTRODUCTION 214 3.3.1.2 HISTORY AND BACKGROUND 214 3.3.1.3
STABILIZATION OF METAL NANOPARTICLES 215 3.3.1.4 SYNTHETIC METHODS 218
3.3.1.4.1 SALT REDUCTION 219
3.3.1.4.2 CONTROLLED DECOMPOSITION 226 3.3.1.5 SHAPE CONTROL 228
REFERENCES 232
3.3.2 SYNTHESIS, PROPERTIES AND APPLICATIONS OF MAGNETIC NANOPARTICLES
239 GALYNA KRYLOVA, MARYNA I. BODNARCHUK, ULRICH I. TROMSDORF, ELENA V.
SHEVCHENKO, DMITRI V. TALAPIN, AND HORST WELLER 3.3.2.1 INTRODUCTION 239
3.3.2.1.1 REVERSE MICELLES TECHNIQUE 241 3.3.2.1.2 SONOCHEMICAL
SYNTHESIS 242 3.3.2.1.3 COLLOIDAL SYNTHESES 242 3.3.2.2 COLLOIDAL
SYNTHESIS OF MAGNETIC METAL NANOPARTICLES 242 3.3.2.2.1 GENERAL REMARKS
ON THE SYNTHESIS OF CO AND COPT 3 NANOCRYSTALS 243 3.3.2.2.2 SYNTHESIS
OF COBALT NANOPARTICLES WITH DIFFERENT CRYSTALLINE
MODIFICATION 244
3.3.2.2.3 SYNTHESIS OF COPT 3 MAGNETIC ALLOY NANOCRYSTALS 247 3.3.2.2.4
SHAPE-CONTROLLED SYNTHESIS OF MAGNETIC NANOPARTICLES 252 3.3.2.2.5 OTHER
METAL MAGNETIC NANOPARTICLES SYNTHESIZED BY METHODS OF COLLOIDAL
CHEMISTRY 255 3.3.2.3 IRON OXIDE-BASED MAGNETIC NANOCRYSTALS 259
IMAGE 4
VILL CONTENTS
3.3.2.3.1 MAGHERNI*E AND MAGNETITE NANOCRYSTALS 259
3.3.2.3.2 NANOCRYSTALS OF OTHER IRON OXIDES (HEMATITE, WUESTITE,
GOETHITE) 262 3.3.2.3.3 NANOCRYSTALS OF METAL FERRITES 263 3.3.2.4
MULTICOMPONENT MAGNETIC NANOCRYSTALS 264 3.3.2.4.1 MAGNETIC CORE-SHELL
NANOPARTICLES 265 3.3.2.4.2 DUMBBELL-LIKE NANOPARTICLES 266
3.3.2.4.3 HOLLOW MAGNETIC NANOCRYSTALS 268 3.3.2.5 SIZE- AND
SHAPE-DEPENDENT MAGNETIC PROPERTIES OF MAGNETIC METAL NANOPARTICLES 271
3.3.2.6 MAGNETIC NANOCRYSTALS FOR DATA STORAGE APPLICATIONS 281
3.3.2.7 BIOMEDICAL APPLICATIONS OF MAGNETIC NANOPARTICLES 282 3.3.2.7.1
DESIGN OF MAGNETIC PARTICLES FOR BIOMEDICAL APPLICATIONS 283 3.3.2.7.2
DRUG DELIVERY 285
3.3.2.7.3 GENE DELIVERY 290 3.3.2.7.4 MAGNETIC SEPARATION 291 3.3.2.7.5
MAGNETIC HYPERTHERMIA 292 3.3.2.7.6 MAGNETIC RESONANCE IMAGING 295
3.3.2.7.7 TOMOGRAPHIE IMAGING 297 3.3.2.7.8 THE ROLE OF MAGNETIC
NANOPARTICLE-BASED CONTRAST
AGENTS IN MRI 298 REFERENCES 302
4 ORGANIZATION OF NANOPARTICLES 311 4.1 SEMICONDUCTOR NANOPARTICLES 311
NIKOLAI GAPONIK AND ALEXANDER EYCHMUELLER 4.1.1 MOLECULAR CRYSTALS AND
SUPERLATTICES 311 4.1.2 LAYERS OF SEMICONDUCTOR NANOCRYSTALS 315 4.1.3
COUPLING OF SEMICONDUCTOR NANOCRYSTALS 322
REFERENCES 323
4.2 METAL NANOPARTICLES 328
GUENTER SCHMID, DMITRI V. TALAPIN, AND ELENA V. SHEVCHENKO 4.2.1
THREE-DIMENSIONAL ORGANIZATION OF METAL NANOPARTICLES 328 4.2.2 TWO-AND
ONE-DIMENSIONAL STRUCTURES OF METAL NANOPARTICLES 338 4.2.2.1
SELF-ASSEMBLY 338
4.2.2.2 GUIDED SELF-ASSEMBLY 348 4.2.2.3 AIMED STRUCTURES 357 REFERENCES
368
5 PROPERTIES 371
5.1 SEMICONDUCTOR NANOPARTICLES 371 5.1.1 OPTICAL AND ELECTRONIC
PROPERTIES OF SEMICONDUCTOR NANOCRYSTALS 371 URI BANIN AND ODED MILLO
5.1.1.1 INTRODUCTION 371
5.1.1.2 SEMICONDUCTOR NANOCRYSTALS AS ARTIFICIAL ATOMS 372 5.1.1.3
THEORETICAL DESCRIPTIONS OF THE ELECTRONIC STRUCTURE 3 79
IMAGE 5
CONTENTS IX
5.1.1.4 ATOMIC-LIKE STATES IN CORE-SHELL NANOCRYSTALS: SPECTROSCOPY
AND IMAGING 381
5.1.1.5 LEVEL STRUCTURE OF CDSE QUANTUM RODS 385 5.1.1.6 LEVEL STRUCTURE
AND BAND-OFFSETS IN HETEROSTRUCTURED SEEDED QUANTUM RODS 385 5.1.1.7
OPTICAL GAIN AND LASING IN SEMICONDUCTOR NANOCRYSTALS 388
REFERENCES 390
5.1.2 OPTICAL AND THERMAL PROPERTIES OF IB-VI NANOPARTICLES 392 STEFANIE
DEHNEN, ANDREAS EICHHOEFER, JOHN F. CORRIGAN, OLAF FUHR, AND DIETER
FENSKE
5.1.2.1 OPTICAL SPECTRA OF SELENIUM-BRIDGED AND TELLURIUM-BRIDGED COPPER
CLUSTERS 392 5.1.2.2 THERMAL BEHAVIOR OF SELENIUM-BRIDGED COPPER
CLUSTERS 397 REFERENCES 400 5.2 ELECTRICAL PROPERTIES OF METAL
NANOPARTICLES 401
KERSTIN BLECH, MELANIE HORNBERGER, AND ULRICH SIMON 5.2.1 INTRODUCTION
401
5.2.2 PHYSICAL BACKGROUND AND QUANTUM SIZE EFFECT 402 5.2.2.1
SINGLE-ELECTRON TUNNELING 403 5.2.2.2 THE SINGLE-ELECTRON TRANSISTOR 406
5.2.3 THIN FILM STRUCTURES 408 5.2.4 SINGLE-ELECTRON TUNNELING IN METAL
NANOPARTICLES 409 5.2.4.1 STM CONFIGURATIONS 411 5.2.4.2 CHEMICAL
SWITCHING AND GATING OF CURRENT THROUGH NANOPARTICLES 417 5.2.4.3
INDIVIDUAL PARTICLES AND 1-D ASSEMBLIES IN NANOGAP
CONFIGURATIONS 421
5.2.5 COLLECTIVE CHARGE TRANSPORT IN NANOPARTICLE ASSEMBLIES 435 5.2.5.1
TWO-DIMENSIONAL ARRANGEMENTS 438 5.2.5.2 THREE-DIMENSIONAL ARRANGEMENTS
446
5.2.6 CONCLUDING REMARKS 450 REFERENCES 451
6 SEMICONDUCTOR QUANTUM DOTS FOR ANALYTICAL AND BIOANALYTICAL
APPLICATIONS 455 RONIT FREEMAN, JIAN-PING XU, AND ITAMAR WILLNER
6.1 INTRODUCTION 455
6.2 WATER SOLUBILIZATION AND FUNCTIONALIZATION OF QUANTUM DOTS WITH
BIOMOLECULES 458 6.3 QUANTUM DOT-BASED SENSORS 462 6.3.1 RECEPTOR- AND
LIGAND-FUNCTIONALIZED QDS FOR SENSING 462 6.3.2 FUNCTIONALIZATION OF QDS
WITH CHEMICALLY REACTIVE UNITS PARTICIPATING
IN THE SENSING 470
6.4 BIOSENSORS 472
6.4.1 APPLICATION OF QDS FOR PROBING BIORECOGNITION PROCESSES 475 6.4.2
PROBING BIOCATALYTIC TRANSFORMATIONS WITH QDS 485
IMAGE 6
CONTENTS
6.4.3 PROBING STRUCTURAL PERTURBATIONS OF PROTEINS WITH QDS 496
6.5 INTRACELLULAR APPLICATIONS OF QDS 499 6.6 CONCLUSIONS AND
PERSPECTIVES 503 REFERENCES 504
7 CONCLUSIONS AND PERSPECTIVES 513 GUENTER SCHMID, ON BEHALF OF ALL THE
AUTHORS
INDEX 517
|
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| discipline | Chemie / Pharmazie Technik Werkstoffwissenschaften Chemie Chemie-Ingenieurwesen Elektrotechnik / Elektronik / Nachrichtentechnik Maschinenbau |
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| indexdate | 2024-07-09T22:12:29Z |
| institution | BVB |
| isbn | 9783527325894 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-019009284 |
| oclc_num | 620364647 |
| open_access_boolean | |
| owner | DE-29T DE-20 DE-83 DE-11 DE-703 DE-19 DE-BY-UBM DE-91G DE-BY-TUM |
| owner_facet | DE-29T DE-20 DE-83 DE-11 DE-703 DE-19 DE-BY-UBM DE-91G DE-BY-TUM |
| physical | XIII, 522 S. Ill., graph. Darst. |
| publishDate | 2010 |
| publishDateSearch | 2010 |
| publishDateSort | 2010 |
| publisher | Wiley-VCH |
| record_format | marc |
| spelling | Nanoparticles from theory to application ed. by Günter Schmid 2., completely rev. and updated ed. Weinheim Wiley-VCH 2010 XIII, 522 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Nanoparticles Umweltschutz (DE-588)4061644-7 gnd rswk-swf Nanotechnologie (DE-588)4327470-5 gnd rswk-swf Nanopartikel (DE-588)4333369-2 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Nanopartikel (DE-588)4333369-2 s DE-604 Nanotechnologie (DE-588)4327470-5 s Umweltschutz (DE-588)4061644-7 s Schmid, Günter 1937- Sonstige (DE-588)13573097X oth DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019009284&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Nanoparticles from theory to application Nanoparticles Umweltschutz (DE-588)4061644-7 gnd Nanotechnologie (DE-588)4327470-5 gnd Nanopartikel (DE-588)4333369-2 gnd |
| subject_GND | (DE-588)4061644-7 (DE-588)4327470-5 (DE-588)4333369-2 (DE-588)4143413-4 |
| title | Nanoparticles from theory to application |
| title_auth | Nanoparticles from theory to application |
| title_exact_search | Nanoparticles from theory to application |
| title_full | Nanoparticles from theory to application ed. by Günter Schmid |
| title_fullStr | Nanoparticles from theory to application ed. by Günter Schmid |
| title_full_unstemmed | Nanoparticles from theory to application ed. by Günter Schmid |
| title_short | Nanoparticles |
| title_sort | nanoparticles from theory to application |
| title_sub | from theory to application |
| topic | Nanoparticles Umweltschutz (DE-588)4061644-7 gnd Nanotechnologie (DE-588)4327470-5 gnd Nanopartikel (DE-588)4333369-2 gnd |
| topic_facet | Nanoparticles Umweltschutz Nanotechnologie Nanopartikel Aufsatzsammlung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=019009284&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT schmidgunter nanoparticlesfromtheorytoapplication |