Solid oxide fuel cell technology: principles, performance and operations
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Boca Raton, FL [u.a.]
CRC Press
2009
Cambridge Woodhead |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XII, 328 S. Ill., graph. Darst. |
| ISBN: | 9781439813362 1439813361 9781845696283 184569628X |
Staff View
MARC
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Record in the Search Index
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Titel: Solid oxide fuel cell technology
Autor: Huang, Kevin
Jahr: 2009
Contents
Author contact details ix
Preface xi
1 Introduction to solid oxide fuel cells (SOFCs) 1
1.1 A brief history of the solid oxide fuel cell (SOFC) 1
1.2 Advantages of the solid oxide fuel cell 4
1.3 Applications of solid oxide fuel cells 5
1.4 Solid oxide fuel cell components and functionality 6
1.5 Solid oxide fuel cell designs 7
2 Thermodynamics of the solid oxide fuel cell (SOFC) 10
2.1 Electromotive force (EMF) and Gibbs free energy
change (aG) 10
2.2 Effect of concentration on electromotive force (EMF) 11
2.3 Heat effects in a galvanic cell 14
2.4 The temperature coefficient of electromotive force (EMF) 16
2.5 The pressure coefficient of electromotive force (EMF) 17
2.6 The thermal and chemical expansion coefficients 19
3 Electronic properties of solids for solid oxide fuel
cells (SOFCs) 23
3.1 General considerations 23
3.2 Redox 4f energies and polaronic conduction 25
3.3 Ligand-field d-electron energies 26
3.4 Localized versus itinerant d electrons 29
3.5 Applications 32
4 Transport of charged particles in a solid oxide fuel
cell (SOFC) 41
4.1 General bulk transport theory 41
4.2 Effect of electronic conduction in electrolyte on
electromotive force (EMF) 47
vi Contents
4.3 Application to electrolyte: steady-state P0l distribution 50
4.4 Application to electrolyte: electronic leakage current
density 55
4.5 Application to interconnect: steady-state Pq2 distribution 57
4.6 Application to interconnect: ionic leakage current density 62
4.7 Pressure effect on electronic leakage current density in
the electrolyte 63
5 Oxide-ion electrolytes in solid oxide fuel cells
(SOFCs) 67
5.1 Quality criteria 67
5.2 Phenomenology 69
5.3 Random-walk theory 73
5.4 Fluorites 74
5.5 Perovskites 79
5.6 Other oxides 82
6 Current, gas flow, utilization, and energy balance in
a solid oxide fuel cell (SOFC) 85
6.1 Introduction 85
6.2 Fuel flow, current, and fuel utilization 86
6.3 Air flow, current, and oxygen utilization 87
6.4 Fuel consumption 88
6.5 Calculating stack fuel composition of reformed natural
gas 90
6.6 Energy balance in a solid oxide fuel cell system 92
7 Voltage losses in a solid oxide fuel cell (SOFC) 98
7.1 Ohmic polarization 98
7.2 Activation polarization 101
7.3 Concentration polarization 110
7.4 A combined activation and concentration polarization of
the cathode 125
7.5 Distributions of electromotive force and current density 127
7.6 Effect of leakage flux on the voltage-current curve 136
8 Direct current (DC) electrical efficiency and power
of a solid oxide fuel cell (SOFC) 141
8.1 Direct current electrical efficiency 141
8.2 Efficiency, fuel utilization, and electrical power 148
8.3 The maximum direct current electrical efficiency 150
8.4 Effect of the system pressure on direct current electrical
efficiency 154
Contents vii
9 Performance characterization techniques for a solid
oxide fuel cell (SOFC) and its components 156
9.1 Electrochemical impedance spectroscopy 156
9.2 Galvanic current interruption 163
9.3 Voltage-current curve characterizations 165
9.4 'Helium-oxygen shift' 166
9.5 Fuel sensitivity 170
9.6 Determination of fuel loss 173
9.7 Electrical conductivity and sheet resistance measurements 177
9.8 Determination of porosity and density of a porous
ceramic body 179
9.9 Diffusivity and diffusion conductance measurements 180
10 Steam methane reforming and carbon formation in
solid oxide fuel cells (SOFCs) 183
10.1 Introduction 183
10.2 Thermodynamics of steam methane reforming 184
10.3 Partial pressure of oxygen (Po2) and Nernst potential (E)
of the steam-reformed methane 189
10.4 Kinetics of steam methane reforming 191
10.5 Carbon formation: thermodynamics versus kinetics 193
11 Poisoning of solid oxide fuel cell (SOFC) electrodes 197
11.1 Sulfur poisoning of the anode 197
11.2 Silica poisoning of the anode 202
11.3 Phosphorus poisoning of the anode 207
11.4 Chromium poisoning of the cathode 213
12 Materials for solid oxide fuel cells (SOFCs) 220
12.1 Zr02-based solid oxide fuel cells 220
12.2 Ce02-based solid oxide fuel cells 233
12.3 LaGa03-based solid oxide fuel cells 242
12.4 Interconnects and cell-to-cell connectors 248
12.5 Fabrication techniques 257
12.6 Conclusions 265
References 269
Appendix 1: Thermodynamic data of selected
chemical reactions and substances 278
Appendix 2: The standard heat of combustion of
common fuels 280
viii Contents
Appendix 3: Gas diffusion properties of a cylindrical
tubular cathode substrate 289
Appendix 4: Molecular diffusivities of selected
binary gas systems 298
Commonly used physical constants 299
Nomenclature 300
Greek symbols 300
Roman symbols 304
Index 319 |
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| discipline | Elektrotechnik / Elektronik / Nachrichtentechnik |
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| illustrated | Illustrated |
| indexdate | 2025-02-04T17:00:39Z |
| institution | BVB |
| isbn | 9781439813362 1439813361 9781845696283 184569628X |
| language | English |
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| owner_facet | DE-29T DE-1102 |
| physical | XII, 328 S. Ill., graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | CRC Press Woodhead |
| record_format | marc |
| spelling | Huang, Kevin Verfasser (DE-588)121910194X aut Solid oxide fuel cell technology principles, performance and operations Kevin Huang and John B. Goodenough Boca Raton, FL [u.a.] CRC Press 2009 Cambridge Woodhead XII, 328 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Solid oxide fuel cells Brennstoffzelle (DE-588)4008195-3 gnd rswk-swf Oxide (DE-588)4126202-5 gnd rswk-swf Oxide (DE-588)4126202-5 s Brennstoffzelle (DE-588)4008195-3 s DE-604 Goodenough, John B. 1922-2023 Sonstige (DE-588)1196728704 oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018981215&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Huang, Kevin Solid oxide fuel cell technology principles, performance and operations Solid oxide fuel cells Brennstoffzelle (DE-588)4008195-3 gnd Oxide (DE-588)4126202-5 gnd |
| subject_GND | (DE-588)4008195-3 (DE-588)4126202-5 |
| title | Solid oxide fuel cell technology principles, performance and operations |
| title_auth | Solid oxide fuel cell technology principles, performance and operations |
| title_exact_search | Solid oxide fuel cell technology principles, performance and operations |
| title_full | Solid oxide fuel cell technology principles, performance and operations Kevin Huang and John B. Goodenough |
| title_fullStr | Solid oxide fuel cell technology principles, performance and operations Kevin Huang and John B. Goodenough |
| title_full_unstemmed | Solid oxide fuel cell technology principles, performance and operations Kevin Huang and John B. Goodenough |
| title_short | Solid oxide fuel cell technology |
| title_sort | solid oxide fuel cell technology principles performance and operations |
| title_sub | principles, performance and operations |
| topic | Solid oxide fuel cells Brennstoffzelle (DE-588)4008195-3 gnd Oxide (DE-588)4126202-5 gnd |
| topic_facet | Solid oxide fuel cells Brennstoffzelle Oxide |
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