Membrane reactors: distributing reactants to improve selectivity and yield
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| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2010
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| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | XVIII, 274 S. Ill., graph. Darst. |
| ISBN: | 9783527320394 |
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Record in the Search Index
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CONTENTS PREFACE XI LIST OF CONTRIBUTORS XV 1 BASIC PROBLEMS OF CHEMICAL
REACTION ENGINEERING AND POTENTIAL OF MEMBRANE REACTORS 1 SASCHA THOMAS,
CHRISTOF HAMEL, AND ANDREAS SEIDEL-MORGENSTERN 1.1 CHALLENGES IN
CHEMICAL REACTION ENGINEERING 1 1.2 CONCEPTS OF MEMBRANE REACTORS 3 1.3
AVAILABLE MEMBRANES 6 1.4 ILLUSTRATION OF THE SELECTIVITY PROBLEM 8 1.5
REACTION RATE, CONVERSION, SELECTIVITY AND YIELD 9 1.5.1 REACTION RATES
9 1.5.2 CONVERSION 10 1.5.3 MASS BALANCE OF A PLUG FLOW TUBULAR REACTOR
10 1.5.4 SELECTIVITY AND YIELD 12 1.6 DISTRIBUTED DOSING IN PACKED-BED
AND MEMBRANE REACTORS 13 1.6.1 ADJUSTING LOCAL CONCENTRATIONS TO ENHANCE
SELECTIVITIES 15 1.6.2 OPTIMIZATION OF DOSING PROFILES 16 1.7 KINETIC
COMPATIBILITY IN MEMBRANE REACTORS 21 1.8 CURRENT STATUS OF MEMBRANE
REACTORS OF THE DISTRIBUTOR TYPE 22 NOTATION USED IN THIS CHAPTER 23
GREEK SYMBOLS 23 SUPERSCRIPTS AND SUBSCRIPTS 23 ABBREVIATION
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/994010443 DIGITALISIERT
DURCH VI CONTENTS 2.3.1.1 MOLECULAR TRANSPORT OF MOMENTUM 35 2.3.1.2
HEAT CONDUCTION 35 2.3.1.3 MOLECULAR DIFFUSION 36 2.3.2 POROUS DOMAINS
38 2.3.2.1 MOLECULAR DIFFUSION 39 2.3.2.2 KNUDSEN DIFFUSION 39 2.3.2.3
VISCOUS FLOW 40 2.3.2.4 MODELS FOR DESCRIPTION OF GAS PHASE TRANSPORT IN
POROUS MEDIA 40 2.4 REDUCED MODELS 42 2.5 SOLVABILITY, DISCRETIZATION
METHODS AND FAST SOLUTION 44 2.6 IMPLEMENTATION IN FLUENT, MOONMD,
COMSOL AND PROMOT 49 2.6.1 APPLICATION OF FLUENT 49 2.6.2 APPLICATION OF
MOONMD 50 2.6.3 APPLICATION OF PROMOT 51 2.7 CONCLUSION 56 NOTATION USED
IN THIS CHAPTER 56 LATIN NOTATION 56 GREEK NOTATION 57 SUPER- AND
SUBSCRIPTS 58 REFERENCES 59 3 CATALYSIS AND REACTION KINETICS OF A MODEL
REACTION 63 FRANK KLOSE, MILINDJOSHI, TANYA WOLFF, HENNING HAIDA,
ANDREAS SEIDEL- MORGENSTERN, YURI SUCHORSKI, AND H. WEISS 3. CONTENTS VII
4 TRANSPORT PHENOMENA IN POROUS MEMBRANES AND MEMBRANE REACTORS 85 KATYA
GEORGIEVA-ANGELOVA, VELISLAVA EDREVA, ARSHAD HUSSAIN, PIOTR SKRZYPACZ,
LUTZ TOBISKA, ANDREAS SEIDEL-MORGENSTERN, EVANGELOS TSOTSAS, AND JUERGEN
SCHMIDT 4.1 INTRODUCTION 85 4.2 ASPECTS OF DISCRETIZING
CONVECTION-DIFFUSION EQUATIONS 87 4.3 VELOCITY FIELDS IN MEMBRANE
REACTORS 89 4.4 DETERMINATION OF TRANSPORT COEFFICIENTS AND VALIDATION
OF MODELS 97 4.4.1 MASS TRANSPORT PARAMETERS OF MULTILAYER CERAMIC
MEMBRANES-PRE- CURSORS AVAILABLE 97 4.4.1.1 TASK AND TOOLS 97 4.4.1.2
IDENTIFICATION BY SINGLE GAS PERMEATION 100 4.4.1.3 VALIDATION BY
ISOBARIC DIFFUSION AND BY TRANSIENT DIFFUSION 105 4.4.2 MASS TRANSPORT
PARAMETERS OF METALLIC MEMBRANES-PRECURSORS NOT AVAILABLE 207 4.4.2.1
DIAGNOSIS 107 4.4.2.2 IDENTIFICATION 110 4.4.2.3 VALIDATION 111 4.4.3
MASS TRANSPORT IN 2-D MODELS 114 4.5 ANALYSIS OF CONVECTIVE AND
DIFFUSIVE TRANSPORT PHENOMENA INACMR 235 4.6 PARAMETRIC STUDY OF A CMR
120 4.6.1 INFLUENCE OF CHARACTERISTIC GEOMETRICAL PARAMETERS 123 VILI
CONTENTS 5.4.3 REFERENCE CONCEPT - CONVENTIONAL FIXED-BED REACTOR 247
5.4.4 MULTI-STAGE MEMBRANE REACTOR CASCADE 247 5.4.5 ANALYTICS 247 5.4.6
EXPERIMENTAL CONDITIONS 248 5.5 RESULTS FOR THE OXIDATIVE
DEHYDROGENATION OF ETHANE TO ETHYLENE 248 5.5.1 COMPARISON BETWEEN PBR
AND PBMR USING CERAMIC MEMBRANES IN A SINGLE-STAGE OPERATION MODE 148
5.5.2 2-D SIMULATION RESULTS - COMPARISON BETWEEN PBR AND PBMR 152 5.5.3
APPLICATION OF SINTERED METAL MEMBRANES FOR THE ODH OF ETHANE 253 5.5.4
INVESTIGATION OF A MEMBRANE REACTOR CASCADE - IMPACT OF DOSING PROFILES
255 5.5.5 QUANTITATIVE COMPARISON OF THE INVESTIGATED REACTOR
CONFIGURATIONS 257 5.6 RESULTS FOR THE OXIDATIVE DEHYDROGENATION OF
PROPANE 258 5.6.1 COMPARISON BETWEEN PBR AND A SINGLE-STAGE PBMR USING
CERAMIC MEMBRANES 258 5.6.2 INVESTIGATION OF A THREE-STAGE MEMBRANE
REACTOR CASCADE 259 5.7 SUMMARY AND CONCLUSIONS 260 SPECIAL NOTATION NOT
MENTIONED IN CHAPTER 2 162 LATIN NOTATION 262 GREEK NOTATION 262
REFERENCES 262 6 FLUIDIZED-BED MEMBRANE REACTORS 167 DESISLAVA TOTA,
AKOS TATA, STEFAN HEINRICH, AND LOTHAR MORI 6.1 INTRODUCTION 167 6.2
MODELING OF THE DISTRIBUTED REACTANT DOSAGE IN FLUIDIZED BEDS 270 6.2.1
THEORY 270 6.2.2 PARAMETRIC SENSITIVITY OF THE MODEL 273 6.2.2. CONTENTS
IX LATIN NOTATION 189 GREEK NOTATION 290 SUBSCRIPTS AND SUPERSCRIPTS 290
REFERENCES 190 7 SOLID ELECTROLYTE MEMBRANE REACTORS 293 LIISA
RIHKO-STRUCKMANN, BARBARA MUNDER, LJUBOMIR CHALAKOV, AND KAI SUNDMACHER
7.1 INTRODUCTION 193 7.2 OPERATIONAL AND MATERIAL ASPECTS IN SOLID
ELECTROLYTE MEMBRANE REACTORS 294 7.2.1 CLASSIFICATION OF MEMBRANES 194
7.2.2 ION CONDUCTIVITY OF SELECTED MATERIALS 295 7.2.3
MEMBRANE-ELECTRODE-INTERFACE DESIGN IN SOLID ELECTROLYTE MEMBRANE
REACTOR 296 7.2.4 OPERATING MODI OF SOLID ELECTROLYTE MEMBRANE REACTORS
298 7.2.5 CELL VOLTAGE ANALYSIS 299 7.2.6 NON-FARADAIC EFFECTS 200 7.3
MODELING OF SOLID ELECTROLYTE MEMBRANE REACTORS 201 7.3.1 REACTOR MODEL
FOR SYSTEMS CONTAINING SOLID ELECTROLYTE MEMBRANES 202 7.3.2 KINETIC
EQUATIONS FOR CHARGE TRANSFER REACTIONS 206 7.3.3 PARAMETERS FOR CHARGE
TRANSFER AND SOLID ELECTROLYTE CONDUCTIVITY 206 7.3.4 ANALYSIS OF MALEIC
ANHYDRIDE SYNTHESIS IN SOLID ELECTROLYTE MEMBRANE REACTOR 209 7.3.5
ANALYSIS OF OXIDATIVE DEHYDROGENATION OF ETHANE IN A SOLID ELECTROLYTE
PACKED-BED MEMBRANE REACTOR 222 7.4 MEMBRANE REACTORS APPLYING
ION-CONDUCTING MATERIALS 226 7.4. X CONTENTS SUPERSCRIPTS 230 REFERENCES
230 8 NONLINEAR DYNAMICS OF MEMBRANE REACTORS 235 MICHAEL MANGOLD, FAN
ZHANG, MALTE KASPEREIT, AND ACHIM KIENLE 8.1 INTRODUCTION 235 8.2 LIMIT
OF CHEMICAL EQUILIBRIUM 235 8.2.1 REFERENCE MODEL 235 8.2.2 ISOTHERMAL
OPERATION 237 8.2.2.1 NONREACTIVE MEMBRANE SEPARATION 237 8.2.2.2
MEMBRANE REACTOR 240 8.2.3 NONISOTHERMAL OPERATION 245 8.2.3.1 FORMATION
OF TRAVELING WAVES 245 8.2.3.2 FORMATION OF DISCONTINUOUS PATTERNS 246
8.3 PATTERN FORMATION 248 8.3.1 ANALYSIS OF A SIMPLE MEMBRANE REACTOR
MODEL 249 8.3.1.1 ANALYSIS OF STEADY-STATE REACTOR BEHAVIOR FOR
VANISHING HEAT DISPERSION 252 8.3.1.2 INFLUENCE OF HEAT DISPERSION 254
8.3.2 DETAILED MEMBRANE REACTOR MODEL 255 8.3.2.1 MAIN MODEL ASSUMPTIONS
256 8.3.2.2 MODEL EQUATIONS OF THE MEMBRANE 257 8.3.2.3 SIMULATION
RESULTS 259 8.4 CONCLUSIONS 259 REFERENCES 262 9 COMPARISON OF DIFFERENT
MEMBRANE REACTORS 263 FRANK |
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| spelling | Membrane reactors distributing reactants to improve selectivity and yield ed. by Andreas Seidel-Morgenstern Weinheim Wiley-VCH 2010 XVIII, 274 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Membrane reactors Membrane reactors Case studies Membranreaktor (DE-588)4555095-5 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content (DE-588)4522595-3 Fallstudiensammlung gnd-content Membranreaktor (DE-588)4555095-5 s b DE-604 Seidel-Morgenstern, Andreas 1956- (DE-588)114946582 edt text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3294449&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018965108&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Membrane reactors distributing reactants to improve selectivity and yield Membrane reactors Membrane reactors Case studies Membranreaktor (DE-588)4555095-5 gnd |
| subject_GND | (DE-588)4555095-5 (DE-588)4143413-4 (DE-588)4522595-3 |
| title | Membrane reactors distributing reactants to improve selectivity and yield |
| title_auth | Membrane reactors distributing reactants to improve selectivity and yield |
| title_exact_search | Membrane reactors distributing reactants to improve selectivity and yield |
| title_full | Membrane reactors distributing reactants to improve selectivity and yield ed. by Andreas Seidel-Morgenstern |
| title_fullStr | Membrane reactors distributing reactants to improve selectivity and yield ed. by Andreas Seidel-Morgenstern |
| title_full_unstemmed | Membrane reactors distributing reactants to improve selectivity and yield ed. by Andreas Seidel-Morgenstern |
| title_short | Membrane reactors |
| title_sort | membrane reactors distributing reactants to improve selectivity and yield |
| title_sub | distributing reactants to improve selectivity and yield |
| topic | Membrane reactors Membrane reactors Case studies Membranreaktor (DE-588)4555095-5 gnd |
| topic_facet | Membrane reactors Membrane reactors Case studies Membranreaktor Aufsatzsammlung Fallstudiensammlung |
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