Surface and colloid chemistry: principles and applications
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Boca Raton [u.a.]
CRC Press
2010
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIV, 244 S. Ill., graph. Darst. |
| ISBN: | 9781420095036 |
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| 264 | 1 | |a Boca Raton [u.a.] |b CRC Press |c 2010 | |
| 300 | |a XIV, 244 S. |b Ill., graph. Darst. | ||
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Record in the Search Index
| _version_ | 1804141013410775040 |
|---|---|
| adam_text | Contents
Preface
.......................................................................................................................xi
The Author
.............................................................................................................xiii
Chapter
1
Introduction to Surfaces and Colloids
..................................................1
1.1
Introduction
...............................................................................1
1.2
Solid Phase-Liquid Phase-Gas Phase
......................................1
Chapter
2
Capillarity and Surface Forces (Liquids)
.............................................9
2.1
Introduction
...............................................................................9
2.2
Surface Forces (in Liquids)
.....................................................10
2.2.1
Surface Energy
...........................................................11
2.3
Laplace Equation (Liquid Curvature and Pressure)
................13
2.3.1
The Important Role of Laplace Equation in
Various Applications
..................................................16
2.4
Capillary Rise (or Fall) of Liquids
..........................................18
2.5
Bubble Formation,
...................................................................20
2.6
Measurement of Surface Tension of Liquids
...........................23
2.6.1
Liquid Drop Weight and Shape Method
.....................23
2.6.2
The Ring Method
.......................................................26
2.6.3
Wilhelmy Slide (or Plate) Method
..............................27
2.7
Surface Tension of Liquids
..........................................................29
2.7.1
Effect of Temperature and Pressure on Surface
Tension of Liquids
......................................................29
2.7.2
Different Aspects of Liquid Surfaces
.........................33
2.7.2.1
Heat of Surface Formation and
Evaporation
.................................................33
2.7.2.2
Other Surface Properties of Liquids
...........36
2.7.2.3
Interfacial
Tension of Liquid[-Liquid2
.......36
2.7.2.4
Measurement of
Interfacial
Tension
(between Two Immiscible Liquids)
............37
2.8
Applications
.............................................................................38
Chapter
3
Surfactants (Soaps and Detergents) and Physicochemical
Properties
...........................................................................................39
3.1
Introduction
.............................................................................39
3.2
Surface Tension of Aqueous Solutions
....................................41
3.2.1
Surface-Active Substances (Amphiphiles)
.................43
3.2.1.1
Aqueous Solution of Surfactants
................45
3.2.1.2
Micelle Formation (in Aqueous Media)
.....48
vi
Contents
3.3
Gibbs
Adsorption
Equation in Solutions
.................................53
3.3.1
GIBBS
Adsorption
Theory at Liquid Interfaces
........53
3.3.2
Kinetic Aspects of Surface Tension of Detergent
Aqueous Solutions
......................................................62
3.3.3
Solubilization (of Organic-Water-Insoluble
Molecules) in Micelles
...............................................63
3.3.4
Bile Salt Micelles
.......................................................66
3.4
Applications
.............................................................................67
3.4.1
Cleaning and Detergency
...........................................67
Chapter
4
Spread
Lipid
Films on Liquid Surfaces (Langmuir-Blodgett
Films)
..................................................................................................69
4.1
Introduction
.............................................................................69
4.1.1
Surface Film Balance
.................................................71
4.2
Monolayer Isotherms on Water Surfaces
.................................72
4.3
Self-Assembly Monolayer (SAM) Formation
..........................72
4.3.1
States of Monolayers Spread on Water Surface
.........72
4.3.1.1
Self-Assembly Monolayers (SAMs)
............73
4.3.1.2
Reaction in Monolayers at Liquid
Surfaces
......................................................79
4.3.1.3
Fluorescence Studies of Monolayer
Films
...........................................................80
4.3.2
Other Changes at Water Surfaces due to
Monolayers
.................................................................80
4.3.2.1
Surface Viscosity (r|s)
.................................80
4.3.2.2
Surface Potential (AV) of
Lipid
Monolayers
..................................................82
4.3.3
Charged
Lipid
monolayers
.........................................82
4.3.3.1
Transport of Ions in Biological Cell
Membranes
.................................................87
4.4
Effect of
Lipid
Monolayers on Evaporation Rates of
Liquids
.....................................................................................87
4.4.1
Mixed Monolayers of Lipids
......................................88
4.5
Monolayers of Macromolecules at the Water Surface
.............89
4.6
Langmuir-Blodgett (LB) Films (Transfer of
Lipid
Monolayers on Solids)
.............................................................89
4.6.1
Structure and Orientation of Organized
Monolayer Assemblies
...............................................92
4.6.2
Optical and Related Methods of Absorption
..............93
4.6.3
LB-Deposited Film Structure
.....................................94
4.6.3.1
Molecular Orientation in Mixed-Dye
Monolayers on Polymer Surfaces
...............95
4.6.4
Physical Properties of LB Films
................................99
4.6.5
Application of LB Films in Industry
........................100
4.6.6
Bilipid Membranes (BLMs)
.....................................101
Contents
vii
4.7
Vesicles and
Liposomes.........................................................
101
4.7.1
Applications in Drug Delivery
.................................104
4.8
Applications
...........................................................................104
4.8.1
Diagnostics (Immobilized Enzymes on Solid
Surfaces)
...................................................................104
Chapter
5
Solid Surfaces
—
Adsorption
.............................................................105
5.1
Introduction
...........................................................................105
5.2
Solid Surface Tension (Wetting Properties of Solid
Surfaces)
................................................................................106
5.2.1
Solid Surface Tension (ysolid)
.....................................110
5.3
Contact Angle
(Θ)
of Liquids on Solid Surfaces
....................110
5.4
Measurements of Contact Angles
..........................................
Ill
5.5
Adsorption of Gas on a Solid Surface
...................................114
5.5.1
Gas Adsorption Measurement Methods
...................115
5.5.1.1
Volumetric Change Methods
....................115
5.5.1.2
Gravimetric Gas Adsorption Methods
..... 117
5.5.1.3
Langmuir Gas Adsorption
........................117
5.5.1.4
Various Gas Adsorption Equations
..........118
5.5.1.5
Multilayer Gas Adsorption
.......................119
5.6
Adsorption from Solution on Solid Surfaces
.........................120
5.6.1
Thermodynamics of Adsorption
..............................120
5.6.1.1
Adsorption of Acetic Acid onto
Activated Charcoal
...................................121
5.6.2
Solid Surface Area Determination
...........................122
5.6.2.1
Experimental Method
...............................123
5.6.2.2
Adsorption in Binary Liquid Systems
......124
5.6.3
Heats of Adsorption (Different Substances) on
Solid Surfaces
...........................................................124
5.6.3.1
Solid Surface Roughness (Degree of
Roughness)
................................................125
5.6.3.2
Friction (between Solidl-Solid2)
.............126
5.7
Surface Tension of Solid Polymers
........................................126
5.8
Applications
...........................................................................127
5.8.1
Flotation of Solid Particles to Liquid Surface
..........127
5.8.2
Polishing of Solid Surfaces
......................................128
5.8.3
Powders (Surface Technology)
.................................128
5.8.4
Coal Slurry
...............................................................130
5.8.5
Earthquakes and Faults (Solid Surfaces)
..................130
Chapter
6
Wetting, Adsorption, and Cleaning Processes
.................................131
6.1
Introduction
...........................................................................131
6.2
Oil Recovery and Surface Forces
..........................................131
6.2.1
Oil Spills and Cleanup Processes in Oceans
............133
Contents
6.3 Applications in
Cleaning Processes (Surface and
Colloidal Aspects)
.................................................................135
6.3.1
Detergency
................................................................135
6.3.2
Water Repellency of Materials
.................................136
6.4
Evaporation Rates of Liquid Drops
.......................................137
6.5
Adhesion (Glues)
(Solidi-Solidi)
.........................................137
Chapter
7
Colloidal Systems
............................................................................. 141
7.1
Introduction
...........................................................................141
7.1.1
Van
der Waals
Forces
...............................................142
7.1.2
Colloids Stability (DLVO Theory)
...........................143
7.2
Attractive Forces-Repulsive Forces
......................................144
7.2.1
Charged Colloids (Electrical Charge Distribution
at Interfaces)
.............................................................146
7.2.2
Electrokinetic Processes
...........................................149
7.2.3
Stability of Lyophobic Suspensions
.........................150
7.3
Kinetics of Coagulation of Colloids
......................................153
7.3.1
Flocculation and Coagulation of Colloidal
Suspension
................................................................154
7.4
Dispersions of Solid Particles in Fluids
.................................154
7.5
Applications of Colloid Systems
...........................................155
7.5.1
Wastewater Treatment and Control
(Zeta
Potential)
..................................................................155
7.5.2
Steric Stabilization of Solid or Liquid Colloids
.......157
7.5.2.1
Other Applications of the
Zeta
Potential
....................................................158
7.5.3
Industrial Applications
.............................................158
Chapter
8
Thin Liquid Films
............................................................................ 161
8.1
Introduction
...........................................................................161
8.2
Bubbles and Foams
................................................................161
8.2.1
Application of Bubbles in Technology
.....................162
8.3
Foams (Thin Liquid films)
....................................................162
8.3.1
Foams Stability
.........................................................165
8.3.2
Foam Structure
.........................................................167
8.3.2.1
Foam Formation of Beer and Surface
Viscosity
...................................................168
8.3.3
Antifoaming Agents
.................................................169
8.4
Applications of Foams
...........................................................169
8.4.1
Water Purification
....................................................169
8.4.2
Froth Flotation and Bubble Foam Purification
........170
Chapter
9
Emulsions, Microemulsions, and Lyotropic Liquid Crystals
...........173
9.1
Introduction
...........................................................................173
Contents ix
9.2
Emulsions (Oil and Water)
....................................................174
9.2.1
Oil-Water Emulsions
...............................................174
9.2.1.1
Oil-in-Water Emulsions
............................176
9.2.1.2
Water-in-Oil Emulsions
............................176
9.2.1.3
Hydrophilic-Lipophilic (HLB) Values
of Emulsifiers
............................................176
9.2.2
Methods of Emulsion Formation
..............................178
9.2.3
Emuslion Stability and Analyses
.............................180
9.2.3.1
Emulsion Stability
....................................181
9.2.3.2
Electrical Emulsion Stability
....................181
9.2.4
Orientation of Molecules at Oil-Water
Interfaces
..................................................................182
9.3
Microemulsions
.....................................................................183
9.3.1
Different Emulsion Recipes
.....................................185
9.3.1.1
Cleaning and Polishing Emulsions
...........185
9.3.1.2 Microemulsion
Detergent
.........................185
9.3.2
Characteristics and Stability of Emulsions
..............186
9.4
Liquid Crystals
......................................................................186
9.4.1
Liquid Crystal Phases
...............................................187
9.4.1.1
Thermotropic Liquid Crystals
..................188
9.4.1.2
Lyotropic Liquid Crystals
.........................189
9.4.1.3
Biological Liquid Crystals
........................191
9.5
Applications of Emulsions
.....................................................193
9.5.1
Personal Care Industry
.............................................193
9.5.1.1
Fundamentals of Skin Creams and
Recipes
......................................................194
9.5.1.2
Detergent-Based Antiseptics or
Alcohol
.....................................................196
9.5.2
The Paint Industry and Colloidal Aspects
...............198
9.5.3
Food Emulsions (Milk Industry)
..............................199
9.5.3.1
Milk
—
Composition and Emulsion
Chemistry
.................................................201
9.5.3.2
Milk Fat Structure—Fat Globules
............203
9.5.3.3
Milk Lipids
—
Functional Properties
........204
9.5.3.4
The Casein Micelle
...................................206
9.5.3.5
Colloids in the Food Industry
...................209
9.5.3.6
Emulsion Stability
....................................209
Chapter
10
Diverse Applications of Surface and Colloid Chemistry in
Science and Industry
........................................................................213
10.1
Introduction
...........................................................................213
10.2
Applications of Scanning Probe Microscopes (STM,
AFM, FFM) to Surface and Colloidal Chemistry
.................214
10.2.1
Domain Patterns in Monomolecular Film
Assemblies
................................................................217
x
Contents
10.3
Drug Delivery Design (DDD)
...............................................219
10.4
Surface and Colloidal Aspects of Cement Industry
..............219
10.5
Diverse Industrial Applications
.............................................222
10.5.1
Paper Industry (Surface and Colloidal Aspects)
......222
10.5.1.1
Inks and Printers (Colloidal
Chemistry)
................................................223
10.5.1.2
Theory of Adhesives and Adhesion
..........223
10.5.1.3
Surface Coatings of Solids
........................224
10.5.2
Emulsion Polymerization
.........................................224
10.5.2.1
Polymer Colloidal Systems
.......................224
10.5.2.2
Medical Care and Surface Chemistry
......225
References
.............................................................................................................229
Appendix A: Effect of Temperature and Pressure on Surface Tension of
Liquids (Corresponding States Theory)
............................................................231
Appendix B: Solubility of Organic Molecules in Water Using a Surface
Tension-Cavity Model System
..............................................................................235
Appendix C: Gas Adsorption on Solid Surface
—
Theory
................................237
Appendix D: Common Fundamental Constants
..............................................239
Index
......................................................................................................................241
|
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| dewey-search | 541/.33 |
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| id | DE-604.BV035989664 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:09:07Z |
| institution | BVB |
| isbn | 9781420095036 |
| language | English |
| lccn | 2009028978 |
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| oclc_num | 237886104 |
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| physical | XIV, 244 S. Ill., graph. Darst. |
| publishDate | 2010 |
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| publishDateSort | 2010 |
| publisher | CRC Press |
| record_format | marc |
| spelling | Birdi, K. S. 1934- Verfasser (DE-588)171978234 aut Surface and colloid chemistry principles and applications K. S. Birdi Boca Raton [u.a.] CRC Press 2010 XIV, 244 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Surface chemistry Colloids Oberflächenchemie (DE-588)4126166-5 gnd rswk-swf Grenzflächenchemie (DE-588)4246080-3 gnd rswk-swf Kolloidchemie (DE-588)4134420-0 gnd rswk-swf Oberflächenchemie (DE-588)4126166-5 s DE-604 Grenzflächenchemie (DE-588)4246080-3 s Kolloidchemie (DE-588)4134420-0 s 1\p DE-604 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018882401&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Birdi, K. S. 1934- Surface and colloid chemistry principles and applications Surface chemistry Colloids Oberflächenchemie (DE-588)4126166-5 gnd Grenzflächenchemie (DE-588)4246080-3 gnd Kolloidchemie (DE-588)4134420-0 gnd |
| subject_GND | (DE-588)4126166-5 (DE-588)4246080-3 (DE-588)4134420-0 |
| title | Surface and colloid chemistry principles and applications |
| title_auth | Surface and colloid chemistry principles and applications |
| title_exact_search | Surface and colloid chemistry principles and applications |
| title_full | Surface and colloid chemistry principles and applications K. S. Birdi |
| title_fullStr | Surface and colloid chemistry principles and applications K. S. Birdi |
| title_full_unstemmed | Surface and colloid chemistry principles and applications K. S. Birdi |
| title_short | Surface and colloid chemistry |
| title_sort | surface and colloid chemistry principles and applications |
| title_sub | principles and applications |
| topic | Surface chemistry Colloids Oberflächenchemie (DE-588)4126166-5 gnd Grenzflächenchemie (DE-588)4246080-3 gnd Kolloidchemie (DE-588)4134420-0 gnd |
| topic_facet | Surface chemistry Colloids Oberflächenchemie Grenzflächenchemie Kolloidchemie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018882401&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT birdiks surfaceandcolloidchemistryprinciplesandapplications |