Progress in corrosion science and engineering: 1
Gespeichert in:
| 1. Verfasser: | |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Dordrecht [u.a.]
Springer
(2009)
|
| Schriftenreihe: | Modern aspects of electrochemistry
46 Modern aspects of electrochemistry ... |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XIV, 319 S. Ill., graph. Darst. |
| ISBN: | 9780387922621 |
Internformat
MARC
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| 300 | |a XIV, 319 S. |b Ill., graph. Darst. | ||
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Datensatz im Suchindex
| _version_ | 1804140941502578688 |
|---|---|
| adam_text | Contents
Chapter
1
STRUCTURE, PASSIVATION AND LOCALIZED
CORROSION OF METAL SURFACES
Vincent Maurice and Philippe Marcus
I. Introduction
..........................................................................1
II. Nucleation and Growth of Passive Films
.............................3
1.
Hydroxide Ion Adsorption and Growth of 2D
Passive Layers
...............................................................3
(/)
Copper
..................................................................3
(//)
Silver
....................................................................7
(iii)
Nickel
.................................................................12
2.
Influence of 2D Passive Films on Dissolution
............16
(0
Silver
..................................................................16
00
Nickel
.................................................................19
III. Structure of
3D
Passive Films on Metals and Alloys
.........22
1.
Crystalline Passive Films
............................................22
(0
Copper
...................................................................22
(н)
Nickel
....................................................................25
(iii)
Iron
.....................................................................28
2.
Ageing Effects on Chromium-Rich Passive Films
......29
(/)
Chromium
.............................................................29
(¿7)
Stainless Steels
......................................................30
IV. Dissolution in the Passive State
..........................................31
V. Nanostructure of Passive Film and Passivity Breakdown
..34
1.
Effect of Chlorides on Coalescence and
Crystallization of the Passive Film
..............................34
2.
Breakdown at Oxide Grain Boundaries
.......................39
VI. Grain Boundary Model of Passivity Breakdown and Pit
Initiation
.............................................................................44
1.
Local Redistribution of the Potential Drop
.................44
2.
Local Thinning of the Passive Film
............................46
3.
Voiding at the Metal/Oxide Interface
..........................49
viii Contents
4.
Stress-Induced Fracture of the Passive Film
...............51
VII.
Conclusion
..........................................................................52
References
..........................................................................54
Chapter
2
ANODIC OXIDE FILMS ON ALUMINUM: THEIR
SIGNIFICANCE FOR CORROSION PROTECTION AND
MICRO- AND NANO-TECHNOLOGIES
Hideaki Takahashi, Masatoshi Sakairi, and Tatsuya Kikuchi
I. Applications of Anodic Oxide Films
.................................59
II. Structure and Properties of Oxide and Hydroxide Films..
..61
1.
Pretreated-Surface Film
..............................................62
2.
Thermal Oxide Film
....................................................64
3.
Hydroxide Film
...........................................................66
4.
Barrier-Type Anodic Oxide Film (BAOF)
..................72
5.
Porous Type Anodic Oxide Film (PAOF)
...................80
(0
Structure
.............................................................80
(¿7)
Growth under Steady Conditions
.......................89
(iii)
Growth under Transient Conditions
...................94
III. Changes in Film Structure by Combination of
Treatments
..........................................................................98
1.
Change of PAOF Structure by Heating, Boiling, and
Anodizing in a Neutral Solution
..................................98
2.
Change in BAOF Structure by Heating, Boiling, and
Anodizing in an Acid Solution
..................................107
3.
Change of the Structure of Thermal Oxide Films by
Boiling, and Anodizing in a Neutral solution and in
an Acid Solution
........................................................107
4.
Changes in the Structure of Hydroxide Films
by Heating and Anodizing in Acid and Neutral
Solutions
....................................................................111
5.
Other Combination of Treatments
.............................117
IV. Role of Anodic Oxide Films in Corrosion Protection of
Aluminum
.........................................................................117
1.
Immersion of BAOF-Covered Aluminum in a
Solution
.....................................................................118
Contents jx
2.
Role of Anodic Oxide Films in Pitting Corrosion
during Cathodic Polarization
.....................................119
3.
Role of Anodic Oxide Films in the Corrosion of
Aluminum Alloys in Alcohol at High Temperatures
127
V. Micro- and Nano-Technologies Based on Anodized
Aluminum
........................................................................130
1.
Micro-Technologies with Laser Irradiation
...............131
2.
Applications of Laser Irradiation Techniques
...........140
(/)
Printed Circuit Boards
......................................140
(/7)
Plastic Injection Molds
.....................................141
(iii)
Electrochemical Micro-Reactor
........................142
(ív)
Free-Standing Microstructures
.........................145
(v) Micro-Actuator
.................................................145
(vi)
Printing Roll
.....................................................150
3.
Micro- and Nano-Patterning with AFM Probe
Processing
.................................................................151
4.
Formation of Composite Oxide Films by the
Combination of Anodizing with Other Coating
Methods
.....................................................................157
(/)
Pore-Filling Method
.........................................159
(ii) Combination of Metal-Organic Chemical
Vapor Deposition with Anodizing
....................160
(Hi) Combination of Sol-Gel Dip Coating and
Anodizing
.........................................................161
(iv)
Combination of Electrophoretic Sol-Gel
Coating and Anodizing
.....................................163
(v) Combination of Liquid Phase Deposition with
Anodizing
.........................................................165
VI. Conclusions
......................................................................167
References
........................................................................168
x
Contents
Chapter
3
ELECTROCHEMICAL, MICROSCOPIC AND SURFACE
ANALYTICAL STUDIES OF AMORPHOUS AND
NANOCRYSTALLINE ALLOYS
Maria Janik-Czachor and
Marcin Pisarek
I. Introduction
......................................................................175
II. Stability of the Passive State of
ΑΙ
-Based Amorphous
Alloys
...............................................................................177
1.
Effect of Refractory Metals on the Stability of the
Passive State
..............................................................180
2.
AES Investigations of Depth Distribution of
Refractory Metals within the
Passivating
Film
.........182
III. Effect of Hydrostatic Extrusion Leading to Nano-
Structurization on the Stability of the Passive State of
Austenitic Stainless Steels
................................................192
1.
Anodic Behavior of As-Received and HE Processed
Materials in Cl Containing Solutions
.......................194
2.
Microstructure Examination and Image Analysis
.....198
3.
Local AES and SAM Analyses of the Inclusions in
303
Stainless Steel
.....................................................201
4.
AES Investigations of the Surface Oxide Film on
HE Materials
.............................................................205
IV. Catalytic Activity of Cu-Based Amorphous Alloys
Modified by Cathodic Hydrogen Charging
......................207
1.
Catalytic Activity, Porosity and Specific Surface
Area of Cu-Based Catalysts
......................................212
2.
Surface Characterization of Cu-Based Catalysts
.......216
3.
Modified Mechanism of Dehydrogenation of
Aliphatic Alcohol on Cu-Ti Catalysts
.......................220
V. Summary and Conclusions
...............................................224
Acknowledgments
............................................................224
References
........................................................................226
Contents xi
Chapter
4
PHYSICOCHEMICAL
CHARACTERIZATION OF
PASSIVE FILMS AND CORROSION LAYERS BY
DIFFERENTIAL ADMITTANCE AND PHOTOCURRENT
SPECTROSCOPY
Francesco
Di
Quarto,
Fabio La
Mantia,
and
Monica
Santamaría
I. Introduction
......................................................................231
II. Impedance Measuremets for Passive Films
......................234
1.
Semiconductor/Electrolyte Interface
.........................234
2.
Location of Characteristic Energy Level in
c-Semiconductor/Electrolyte Interface
......................239
3.
Differential Admittance in
Semiconductor/
Electrolyte Junction
...................................................244
4.
Static Differential Capacitance in a-Semiconductor
with Constant DOS
....................................................250
5.
AC Response of
a-Semiconductor
Schottky Barrier.
253
III. Photocurrent Spectroscopy in Passivity Studies
...............264
1.
Semiconductor/Electrolyte Junctions under
Illumination: the
Gärtner-Butler
Model
....................267
2.
PCS Location of UJb and Eg Determination in
c-Semiconductor/Electrolyte Junction
.......................270
3.
Passive Film/Electrolyte Interface under
Illumination
...............................................................272
(0
Electronic Properties of Disordered Passive
Films
.................................................................272
(//)
Amorphous Film/Electrolyte Junction under
Illumination
......................................................273
( 0
Optical Gap in Amorphous Materials
...............278
(ív)
Photoemission
Phenomena at the Metal/
Passive Film Interface
......................................282
4.
Band Gap and Oxide Film Composition
...................290
(ƒ)
Binary Crystalline Oxides
................................290
(/ О
Ternary Crystalline Oxides
..............................293
(ш)
Amorphous Oxide Films
..................................296
¡і
Contents
(ív)
Correlation for Hydroxides and Oxi-
Hydroxide Films
...............................................298
(v) PCS Analysis of Passive Films and Corrosion
Layers on Base Metals and Alloys
..................302
IV. Conclusions
......................................................................308
References
........................................................................310
Index
.................................................................................317
|
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| indexdate | 2024-07-09T22:07:59Z |
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| isbn | 9780387922621 |
| language | English |
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| spelling | Pyun, Su-Il Verfasser aut Progress in corrosion science and engineering 1 ed. by Su-Il Pyun ... Dordrecht [u.a.] Springer (2009) XIV, 319 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Modern aspects of electrochemistry 46 Modern aspects of electrochemistry ... (DE-604)BV035949384 1 Erscheint auch als Online-Ausgabe 978-0-387-92263-8 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018806492&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Pyun, Su-Il Progress in corrosion science and engineering |
| title | Progress in corrosion science and engineering |
| title_auth | Progress in corrosion science and engineering |
| title_exact_search | Progress in corrosion science and engineering |
| title_full | Progress in corrosion science and engineering 1 ed. by Su-Il Pyun ... |
| title_fullStr | Progress in corrosion science and engineering 1 ed. by Su-Il Pyun ... |
| title_full_unstemmed | Progress in corrosion science and engineering 1 ed. by Su-Il Pyun ... |
| title_short | Progress in corrosion science and engineering |
| title_sort | progress in corrosion science and engineering |
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