Concepts in transition metal chemistry:
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| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Cambridge
RSC Publ.
2010
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | 140 S. Ill., graph. Darst. 1 DVD-ROM (12 cm) u.d.T.: Periodic table |
| ISBN: | 9781849730600 9781849730624 |
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Record in the Search Index
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| adam_text | Titel: Concepts in transition metal chemistry
Autor: Crabb, Eleanor
Jahr: 2010
Contents
1 Introduction to the first-row transition elements I
1.1 Introduction I
1.2 Electronic configurations of the transition elements 3
1.3 The elemental state 4
1.4 Oxidation state +2 7
1.5 A survey of oxidation states greater than +2 10
1.6 A closer look at the +3 oxidation state 10
2 Thermodynamic stability 13
2.1 The standard redox potential 14
2.2 Thermodynamic stability and electronic configuration 17
2.3 Some further comments on the relative stabilities of the dipositive and
tripositive oxidation states 20
2.4 Lower oxidation states 21
2.5 Higher oxidation states 23
2.6 Summary of oxidation-state patterns in the first transition series 27
3 Coordination chemistry 29
3.1 Werner s theory 29
3.2 Ligands and their nomenclature 32
3.3 Stereochemistry and isomerism 36
3.4 Ligands and their bonding 41
4 The stability of coordination compounds 49
4.1 Relative stability of metal complexes with varying ligands 49
4.2 Variation in stability constants of complexes across the transition series 57
4.3 Hard and soft acids and bases 57
5 Crystal-field theory 59
5.1 Thedorbitals 60
5.2 The basis of crystal-field theory 61
5.3 Octahedral complexes 61
5.4 Electronic spectra of octahedral complexes 70
5.5 Distorted octahedral, square pyramidal and square-planar complexes 79
5.6 Tetrahedral complexes 84
5.7 The magnetic properties of transition-metal complexes 90
6 Molecular orbital theory of transition-metal complexes 99
6.1 cr-bonding 100
6.2 7i-bonding in strong-field complexes 105
6.3 Other jt-acceptor complexes 110
6.4 Oxidation states and the 18-electron rule 117
6.5 7i-bonding in weak-field complexes 119
6.6 Bonding and ligand field strength 121
6.7 Charge-transfer bands in the electronic spectra of transition-metal complexes 121
References 129
Acknowledgements 130
Appendix 131
Index 133
Periodic Table DVD-ROM information 142
|
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| bvnumber | BV035946011 |
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| dewey-full | 546/.6 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 546 - Inorganic chemistry |
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| dewey-search | 546/.6 |
| dewey-sort | 3546 16 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik Chemie |
| format | Book |
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| isbn | 9781849730600 9781849730624 |
| language | English |
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| physical | 140 S. Ill., graph. Darst. 1 DVD-ROM (12 cm) u.d.T.: Periodic table |
| publishDate | 2010 |
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| publishDateSort | 2010 |
| publisher | RSC Publ. |
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| spelling | Concepts in transition metal chemistry ed. by Eleanor Crabb ... Cambridge RSC Publ. 2010 140 S. Ill., graph. Darst. 1 DVD-ROM (12 cm) u.d.T.: Periodic table txt rdacontent n rdamedia nc rdacarrier Übergangsmetall (DE-588)4078494-0 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf Chemie (DE-588)4009816-3 gnd rswk-swf Koordinationslehre (DE-588)4133952-6 gnd rswk-swf Übergangsmetall (DE-588)4078494-0 s Chemie (DE-588)4009816-3 s DE-604 Übergangsmetallkomplexe (DE-588)4131837-7 s Koordinationslehre (DE-588)4133952-6 s Crabb, Eleanor Sonstige (DE-588)140092064 oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018803155&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Concepts in transition metal chemistry Übergangsmetall (DE-588)4078494-0 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd Chemie (DE-588)4009816-3 gnd Koordinationslehre (DE-588)4133952-6 gnd |
| subject_GND | (DE-588)4078494-0 (DE-588)4131837-7 (DE-588)4009816-3 (DE-588)4133952-6 |
| title | Concepts in transition metal chemistry |
| title_auth | Concepts in transition metal chemistry |
| title_exact_search | Concepts in transition metal chemistry |
| title_full | Concepts in transition metal chemistry ed. by Eleanor Crabb ... |
| title_fullStr | Concepts in transition metal chemistry ed. by Eleanor Crabb ... |
| title_full_unstemmed | Concepts in transition metal chemistry ed. by Eleanor Crabb ... |
| title_short | Concepts in transition metal chemistry |
| title_sort | concepts in transition metal chemistry |
| topic | Übergangsmetall (DE-588)4078494-0 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd Chemie (DE-588)4009816-3 gnd Koordinationslehre (DE-588)4133952-6 gnd |
| topic_facet | Übergangsmetall Übergangsmetallkomplexe Chemie Koordinationslehre |
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