A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents:
Gespeichert in:
| Hauptverfasser: | , |
|---|---|
| Format: | Buch |
| Sprache: | English |
| Veröffentlicht: |
Düsseldorf
VDI-Verl.
2009
|
| Ausgabe: | Als Ms. gedr. |
| Schriftenreihe: | Fortschritt-Berichte VDI
Reihe 3, Verfahrenstechnik ; 906 |
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | XX, 222 S. Ill., graph. Darst. 21 cm |
| ISBN: | 9783183906031 |
Internformat
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| 245 | 1 | 0 | |a A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents |c Alfons Mersmann ; Ugur Akgün |
| 250 | |a Als Ms. gedr. | ||
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| 300 | |a XX, 222 S. |b Ill., graph. Darst. |c 21 cm | ||
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Datensatz im Suchindex
| _version_ | 1804140791537336320 |
|---|---|
| adam_text | Titel: A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents
Autor: Mersmann, Alfons
Jahr: 2009
Table of Contents
Notation and Abbreviations VIII
Abstract XX
Introduction 1
1. Objective of this Booklet 3
2. Fundamentals of the system Adsorbent-Adsorptive 5
2.1. Adsorbents 7
2.1.1. Activated Carbon 9
2.1.2. Zeolites and Silicalites 11
2.2. Adsorptives 16
3. Characterisation of the system Adsorbent/Adsorptive 18
3.1. Characterisation of Adsorbents 18
3.1.1. Chemical composition and structure 19
3.1.2. Specific Surface 22
3.1.3. Pore Volume Distribution 25
3.1.4. Density and Porosity 31
3.1.5. Refractive Index 35
3.1.6. Hamaker Constant 51
3.2. Characterisation of Adsorptives 61
3.2.1. Molar Mass and critical Data 61
3.2.2. Polarity and Polarisability 62
3.2.3. Dipole Moment 64
3.2.4. Quadrupole Moment 67
3.2.5. Adsorbate Density 68
VI
4. Adsorption Isotherms 78
4.1. Langmuir Isotherm 80
4.2. BET Isotherm 82
4.3. Toth Isotherm 86
4.4. Potential Theory Isotherms 87
4.4.1. Isotherms according to Polanyi, Dubinin and Astakow 87
4.4.2. Isotherms according to Monte-Carlo Simulations 89
4.4.3. Isotherms according to the Hamaker Energy of the Solid 91
5. Prediction of Isotherms for p -»0 (Henry) 93
5.1. Thermodynamic Consistency 95
5.2. Energetically homogeneous Adsorbents 98
5.2.1. The dimensionless Henry Curve 100
5.2.2. The van-der- Waa/s Diameter of Solids 110
5.3. Energetic heterogeneous Adsorbents 113
5.3.1 The Range of Polarities 113
5.3.2. Induced Oipole Gas - electrical Charge Solid Interaction
(indcha) 113
5.3.3. Permanent Dipole Gas - induced Dipole Solid Interaction
(dipind) 117
5.3.4. Permanent Dipole Gas - electrical Charge Solid Interaction
(dipcha) 118
5.3.5. Quadrupole Moment Gas - induced Dipole Solid Interaction
(quadind) 118
5.3.6. Quadrupole Moment Gas - electrical Charge Solid Interaction
(quadcha) 119
5.3.7. Overall Adsorption Potential 120
5.3.8. Henry Coefficient for energetically heterogeneous
Adsorbents 123
5.4 Calculation of Henry Coefficients 124
vn
6. Prediction of Isotherms for p -» ~ (Saturation) 126
6.1. Differential Form 127
6.2. Integrated Form with boundary Conditions 133
6.2.1. The dilute Region {Henry) 134
6.2.2. The Saturation Region 135
6.2.3. The general Case 135
7. Prediction of Isotherms 139
7.1. Henry coefficients 139
7.2. Dimensional Analysis Approach for He 148
7.3. Prediction of complete isotherms 154
7.4. Dependency on the Saturation Degree 168
7.5. Relative Importance of Interaction Energies 171
8. Loading Ranges 176
8.1. Number of Layers 177
8.2. Pore filling degree 179
8.3. Henry and Saturation Range 184
9. Experimental Methods 189
9.1. BET-surface, Micropore Volume 189
9.2. Microbalance measurements 194
9.3. Volumetric Method 199
9.4. Packed Colum Method 201
9.5. Zero Length Column Method 203
9.6. Concentration Pulse Chromatography Method 206
References 208
|
| any_adam_object | 1 |
| author | Mersmann, Alfons Akgün, Ugur 1972- |
| author_GND | (DE-588)132901579 |
| author_facet | Mersmann, Alfons Akgün, Ugur 1972- |
| author_role | aut aut |
| author_sort | Mersmann, Alfons |
| author_variant | a m am u a ua |
| building | Verbundindex |
| bvnumber | BV035829822 |
| classification_rvk | VN 7260 |
| classification_tum | CIT 220f WER 460f |
| ctrlnum | (OCoLC)541073588 (DE-599)DNB998463558 |
| dewey-full | 660.2935 660.284235 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 660 - Chemical engineering |
| dewey-raw | 660.2935 660.284235 |
| dewey-search | 660.2935 660.284235 |
| dewey-sort | 3660.2935 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Werkstoffwissenschaften Chemie-Ingenieurwesen |
| edition | Als Ms. gedr. |
| format | Book |
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| id | DE-604.BV035829822 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T22:05:36Z |
| institution | BVB |
| isbn | 9783183906031 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-018688384 |
| oclc_num | 541073588 |
| open_access_boolean | |
| owner | DE-91G DE-BY-TUM DE-83 DE-210 DE-92 |
| owner_facet | DE-91G DE-BY-TUM DE-83 DE-210 DE-92 |
| physical | XX, 222 S. Ill., graph. Darst. 21 cm |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | VDI-Verl. |
| record_format | marc |
| series | Fortschritt-Berichte VDI |
| series2 | Fortschritt-Berichte VDI : Reihe 3, Verfahrenstechnik |
| spelling | Mersmann, Alfons Verfasser aut A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents Alfons Mersmann ; Ugur Akgün Als Ms. gedr. Düsseldorf VDI-Verl. 2009 XX, 222 S. Ill., graph. Darst. 21 cm txt rdacontent n rdamedia nc rdacarrier Fortschritt-Berichte VDI : Reihe 3, Verfahrenstechnik 906 Gas (DE-588)4019320-2 gnd rswk-swf Adsorptionsisotherme (DE-588)4327003-7 gnd rswk-swf Zeolith (DE-588)4067660-2 gnd rswk-swf Adsorbens (DE-588)4141454-8 gnd rswk-swf Kohlenstoff (DE-588)4164538-8 gnd rswk-swf Gas (DE-588)4019320-2 s Adsorptionsisotherme (DE-588)4327003-7 s Zeolith (DE-588)4067660-2 s Adsorbens (DE-588)4141454-8 s DE-604 Kohlenstoff (DE-588)4164538-8 s Akgün, Ugur 1972- Verfasser (DE-588)132901579 aut Fortschritt-Berichte VDI Reihe 3, Verfahrenstechnik ; 906 (DE-604)BV001897067 906 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018688384&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Mersmann, Alfons Akgün, Ugur 1972- A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents Fortschritt-Berichte VDI Gas (DE-588)4019320-2 gnd Adsorptionsisotherme (DE-588)4327003-7 gnd Zeolith (DE-588)4067660-2 gnd Adsorbens (DE-588)4141454-8 gnd Kohlenstoff (DE-588)4164538-8 gnd |
| subject_GND | (DE-588)4019320-2 (DE-588)4327003-7 (DE-588)4067660-2 (DE-588)4141454-8 (DE-588)4164538-8 |
| title | A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents |
| title_auth | A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents |
| title_exact_search | A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents |
| title_full | A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents Alfons Mersmann ; Ugur Akgün |
| title_fullStr | A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents Alfons Mersmann ; Ugur Akgün |
| title_full_unstemmed | A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents Alfons Mersmann ; Ugur Akgün |
| title_short | A priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents |
| title_sort | a priori prediction of adsorption equilibria of arbitrary gases on microporous adsorbents |
| topic | Gas (DE-588)4019320-2 gnd Adsorptionsisotherme (DE-588)4327003-7 gnd Zeolith (DE-588)4067660-2 gnd Adsorbens (DE-588)4141454-8 gnd Kohlenstoff (DE-588)4164538-8 gnd |
| topic_facet | Gas Adsorptionsisotherme Zeolith Adsorbens Kohlenstoff |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018688384&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| volume_link | (DE-604)BV001897067 |
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