Silicon nanocrystals: fundamentals, synthesis and applications
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| Other Authors: | |
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| Format: | Book |
| Language: | English |
| Published: |
Weinheim
Wiley-VCH
2010
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| Subjects: | |
| Online Access: | Inhaltstext Inhaltsverzeichnis |
| Physical Description: | XXI, 627 S. Ill., graph. Darst. |
| ISBN: | 9783527321605 |
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CONTENTS LIST OF CONTRIBUTORS XV7/ 1 INTRODUCTION 1 L PAVES! AND R.
TURAN REFERENCES 4 2 ELECTRONIC AND OPTICAL PROPERTIES OF SILICON
NANOCRYSTALS 5 CEYHUN BULUTAY AND STEFANO OSSICINI 2.1 INTRODUCTION 5
2.2 ELECTRONIC STRUCTURE AND OPTICAL PROPERTIES FOR SMALL NANOCRYSTALS:
AH NITIO CALCULATION 7 2.2.1 HYDROGENATED SILICON NANOCRYSTALS 9 2.2.2
OXIDIZED SILICON NANOCRYSTALS JI 2.2.3 DOPED SILICON NANOCRYSTALS 14
2.2.3.1 SINGLE-DOPED SILICON NANOCRYSTALS 14 2.2.3.2 CODOPED SILICON
NANOCRYSTALS 15 2.2.4 SILICON NANOCRYSTALS EMBEDDED IN A SIO 2 MATRIX 18
2.3 ELECTRONIC STRUCTURE AND OPTICAL PROPERTIES FOR LARGE NANOCRYSTALS:
ATOMISTIC SEMIEMPIRICAL PSEUODOPOTENTIAL CALCULATIONS 22 2.3.1 EFFECTIVE
OPTICAL GAP 24 2.3.2 RADIATIVE LIFETIME 25 2.3.3 LINEAR OPTICAL
ABSORPTION 26 2.3.3.1 INTERBAND ABSORPTION 28 2.3.3.2 INTRABAND
ABSORPTION 29 2.3.3.3 EXCITED STATE ABSORPTION 30 2.3.4 THIRD-ORDER
NONLINEAR OPTICAL PROPERTIES 30 2.3.5 QUANTUM-CONFINED STARK EFFECT IN
SI NANOCRYSTALS 35 REFERENCE BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/996919260 DIGITALISIERT DURCH VI CONTENTS 3 OPTICAL
PROPERTIES OF INTRINSIC AND SHALLOW IMPURITY-DOPED SILICON NANOCRYSTALS
43 MINORU FUJII 3.1 INTRODUCTION 43 3.2 PL PROPERTIES OF INTRINSIC
SILICON NANOCRYSTALS 45 3.2.1 FUNDAMENTAL PROPERTIES 45 3.2.2 EFFECT OF
SIZE AND SHAPE DISTRIBUTION ON THE PL BANDWIDTH 48 3.2.3 RESONANT
QUENCHING OF PL BAND DUE TO ENERGY TRANSFER 48 3.2.4 PL QUANTUM
EFFICIENCY OF INTRINSIC SI NANOCRYSTALS 51 3.3 SHALLOW IMPURITY-DOPED SI
NANOCRYSTALS 53 3.3.1 PREPARATION OF IMPURITY-DOPED SI NANOCRYSTALS 53
3.3.2 PL FROM B-DOPED SI NANOCRYSTALS 54 3.3.3 PL FROM P-DOPED SI
NANOCRYSTALS 55 3.3.4 ELECTRON SPIN RESONANCE STUDIES OF SHALLOW
IMPURITY-DOPED SI NANOCRYSTALS 55 3.3.5 LOCATION OF DOPANT ATOMS 57 3.4
P AND B CODOPED SI NANOCRYSTALS 58 3.4.1 PL PROPERTIES OF P AND B
CODOPED SI NANOCRYSTALS 59 3.4.2 PL LIFETIME OF P AND B CODOPED SI
NANOCRYSTALS 62 3.4.3 CODOPED BUT NOT COMPENSATED SI NANOCRYSTALS 63 3.5
SUMMARY 63 REFERENCE CONTENTS VIL 5.2.1 KINETIC THEORY: THERMAL
PROPERTIES AND HEAT FLOW 107 5.2.2 LATTICE THERMAL CONDUCTIVITY 108
5.2.3 ELECTRONIC THERMAL CONDUCTIVITY 112 5.3 MEASUREMENTS OF THERMAL
CONDUCTIVITY IN NANOSTRUCTURES 114 5.3.1 THE 3(0 METHOD 115 5.3.2
IN-PLANE THERMAL CONDUCTIVITY MEASUREMENTS 117 5.3.3 PUMP-PROBE AND
OTHER OPTICAL MEASUREMENTS 119 5.3.4 RAMAN SCATTERING AND THERMAL
CONDUCTIVITY 120 5.4 THERMAL PROPERTIES OF SI-BASED NANOSTRUCTURES 122
5.4.1 TWO- AND ONE-DIMENSIONAL SI NANOSTRUCTURES: SI-ON-INSULATOR AND SI
NANOWIRES 122 5.4.2 EPITAXIALLY GROWN SI/SIGE NANOSTRUCTURES:
SUPERLATTICES AND CLUSTER MULTILAYERS 125 5.4.3 ELECTROCHEMICALLY ETCHED
SI (POROUS SI) 131 5.4.4 NANOCRYSTALLINE SI/SIO 2 MULTILAYERS 134 5.5
CONCLUSIONS 143 REFERENCES 145 6 SURFACE PASSIVATION AND
FUNCTIONALIZATION OF SI NANOCRYSTALS 155 JONATHAN VEINOT 6.1
INTRODUCTION 155 6.2 FUNCTIONALIZING FREESTANDING PARTICLES 156 6. VIII
CONTENTS 8 SIZE-CONTROLLED SI NANOCRYSTALS USING THE SIO/SIO 2
SUPERLATTICE APPROACH: CRYSTALLIZATION, DEFECTS, AND OPTICAL PROPERTIES
195 MARGIT TACHARIAS 8.1 INTRODUCTION 195 8.2 SIZE CONTROL OF SI
NANOCRYSTALS BY THE SIO/SIO 2 SUPERLATTICE APPROACH 2 96 8.3
CRYSTALLIZATION BEHAVIOR 200 8.4 DEFECTS AND THEIR SIGNATURES IN ESR 206
8.5 OPTICAL PROPERTIES 225 8.6 APPLICATIONS OF SI NCS AND CONCLUDING
REMARKS 229 REFERENCES 220 9 THE SYNTHESIS OF SILICON NANOCRYSTALS BY
ION IMPLANTATION 223 ROBERT ELLIMAN 9.1 INTRODUCTION 223 9.2 ION
IMPLANTATION 224 9.3 SPATIAL DISTRIBUTION 226 9.3.1 ION RANGE
DISTRIBUTIONS 226 9.3.2 MULTIPLE ENERGY IMPLANTS 229 9.3.3 HIGH-FLUENCE
EFFECTS 230 9.3.4 LATERAL PATTERNING 232 9.4 SIZE DISTRIBUTION 231 9.4.1
ANNEALING TEMPERATURE AND TIME 232 9.4.1.1 NUCLEATION AND GROWTH OF
NANOCRYSTALS 232 9.4. CONTENTS IX 10 STRUCTURAL AND OPTICAL PROPERTIES
OF SILICON NANOCRYSTALS SYNTHESIZED BY PLASMA ENHANCED CHEMICAL VAPOR
DEPOSITION 247 FABIO LACONA, CIORGIA FRANZOE, ALESSIA IRRERA, SIMONA
BONINELLI, AND FRANCESCO PRIOLO 10.1 INTRODUCTION 247 10.2 SYNTHESIS,
STRUCTURE, AND THERMAL EVOLUTION OF SIO X FILMS 249 10.3 A DEEPER
INSIGHT INTO THE THERMAL EVOLUTION OF SIO X FILMS 253 10.4
ROOM-TEMPERATURE PL PROPERTIES OF SI-NCS 258 10.5 EXCITATION AND
DE-EXCITATION PROPERTIES OF SI-NCS 260 10.6 CORRELATION BETWEEN
STRUCTURAL AND OPTICAL PROPERTIES OF SI-NCS 264 10.7 ER-DOPED SI
NANOCLUSTERS 267 10.8 SUMMARY 271 REFERENCES 272 11 FORMATION OF SI-NC
BY REACTIVE MAGNETRON SPUTTERING 275 F. COURBILLEAU, C. LEMON, C.
DUFOUR, X. PORTIER, AND R. RIZK 11.1 INTRODUCTION 275 11.2 EXPERIMENTAL
276 11.3 RESULTS 276 11.3.1 SINGLE LAYER 277 11.3.2 COMPOSITE LAYER 279
11.3. X CONTENTS 13.3.2.1 TEM CHARACTERIZATION 320 13.3.2.2 PARTICLE
SIZE DISTRIBUTION 320 13.3.2.3 NANOCRYSTAL SURFACE CONDITIONS 322
13.3.2.4 OPTICAL PROPERTIES OF SURFACE-OXIDIZED SILICON NANOCRYSTALS 326
13 A SURFACE FUNCTIONALIZATION OF SILICON NANOCRYSTALS 327 13.4.1
LIQUID-PHASE FUNCTIONALIZATION 327 13.4.2 LIQUID-PHASE HYDROSILYLATION
PROCEDURE 328 13.4.3 PLASMA GRAFTING OF SILICON NANOCRYSTALS 330 13.5
OPTICAL PROPERTIES OF PLASMA-SYNTHESIZED AND SURFACE-FUNCTIONALIZED
SILICON NANOCRYSTALS 337 13.6 SUMMARY AND CONCLUSIONS 342 REFERENCES 342
14 SILICON NANOCRYSTALS IN POROUS SILICON AND APPLICATIONS 349 BERNARD
CELLOZ 14.1 INTRODUCTION 349 14.2 PREPARATION OF POROUS SI LAYERS 350
14.2.1 POROUS SI PREPARED BY ANODIZATION 350 14.2.1.1 CONDITIONS LEADING
TO POROUS SI FORMATION 350 14.2.1.2 POROUS SI FORMATION MECHANISM 352
14.2.1.2.1 ELECTROCHEMICAL ETCHING OF SI 352 14.2.1.2.2 PORE INITIATION
AND PROPAGATION IN MICROPOROUS SI 352 14.2.1. CONTENTS XI 14.4.2.2
PASSIVE PHOTONIC STRUCTURES 366 14.4.2.2.1 WAVEGUIDES 367 14.4.2.2.2
MANIPULATION OF LIGHT USING INDEX MODULATION 367 14.4.2.3 ACTIVE
PHOTONIC STRUCTURES: SWITCHING, SENSING 371 14.4.2.3.1 OPTICAL SWITCHING
371 14.4.2.3.2 OPTICAL GAS/LIQUID/BIOMOLECULE SENSING AND DRUG DELIVERY
371 14.4.2.3.3 NONLINEAR PROPERTIES 372 14.4.3 LUMINESCENCE 372 14.4.3.1
PHOTOLUMINESCENCE 372 14.4.3.1.1 CHARACTERISTICS OF THE S-BAND 372
14.4.3.1.2 PHOTOLUMINESCENCE EFFICIENCY 374 14.4.3.1.3 PHOTOLUMINESCENCE
STABILIZATION 376 14.4.3.2 ENERGY TRANSFER, SENSING, AND IMAGING USING
POROUS SI PHOTOLUMINESCENCE 376 14.4.3.3 ELECTROLUMINESCENCE 377 14.4.4
ACOUSTIC AND THERMAL PROPERTIES 379 14.4.4.1 ACOUSTIC PROPERTIES AND
ACOUSTIC BAND CRYSTALS 379 14.4.4.1.1 ACOUSTIC PROPERTIES OF POROUS SI
379 14.4.4.1.2 ACOUSTIC BAND CRYSTALS 379 14.4.4.2 THERMOACOUSTIC
EMISSION 380 14. XI! CONTENTS 15.4.3 RETENTION CHARACTERISTICS WITH
ELECTRON CHARGE, STORAGE, AND DISCHARGE 427 15.4.4 CHARACTERISTICS
IMPROVEMENTS OF THE NC-SI FLASH MEMORY 420 15.4.5 OPERATION SPEED AND
DEVICE RELIABILITY 431 15.4.6 SUMMARY 434 15.5 COMPARISONS OF EMERGING
NONVOLATILE MEMORY DEVICES 434 15.5.1 SILICON NANOCRYSTALS FLASH MEMORY
AND OTHER TYPES OF NONVOLATILE MEMORY 435 15.5.2 SILICON NANOCRYSTALS
MEMORY DEVICES AND OTHER QUANTUM DOT MEMORY DEVICES 436 15.5.3 SUMMARY
437 15.6 CONCLUDING REMARKS AND PROSPECTS 437 REFERENCES 438 16
PHOTONICS APPLICATION OF SILICON NANOCRYSTALS 445 A. ANOPCHENKO, N.
DALDOSSO, R. GUIDER, D. NAVARRO-URRIOS, A. PITANTI, R. SPANO, ZHIZHONG
YUAN, AND L. PAVESI 16.1 INTRODUCTION TO SILICON NANOPHOTONICS 445 16.2
NANOSILICON WAVEGUIDES AND RESONATORS 447 16.2.1 GENERAL PROPERTIES 447
16.2.2 SI-NC SLOT WAVEGUIDES 450 16.2.3 RING RESONATORS BASED ON SLOT
WAVEGUIDES 452 16.3 NANOSILICON CAVITY-BASED DEVICES 453 16.3.1
SLOW-WAVE DEVICES 454 16.3.2 SI-NC ACTIVE MICRODISKS 456 16. CONTENTS
XIII 18 BIOMEDICAL AND SENSOR APPLICATIONS OF SILICON NANOPARTICLES 507
E. BORSELLA, M. FALCONIERI, N. HERLIN, V. LOSCHENOV, C. MISEROCCHI, Y.
NIE, I. RIVOLTA, A. RYABOVA, AND D. WANG 18.1 INTRODUCTION 507 18.2
SYNTHESIS AND SURFACE ENGINEERING OF SI NANOPARTICLES FOR
BIOAPPLICATIONS 509 18.2.1 SYNTHESIS AND OPTICAL PROPERTIES OF SI
NANOPARTICLES 509 18.2.2 SURFACE FUNCTIONALIZATION OF LUMINESCENT SI NPS
FOR BIOAPPLICATIONS 522 18.2.2.1 ALKALI-ACID ETCHING OF SI NPS 512
18.2.2.2 SURFACE MODIFICATION OF SI NPS BY SILANIZATION 513 18.2.2.3
SURFACE MODIFICATION OF SI NPS VIA HYDROSILYLATION 514 18.3
BIOINTERACTION OF SI-BASED NANOPARTICLES 526 18.3.1 CELL VIABILITY 517
18.3.2 GENOTOXICITY 518 18.3.3 OVERALL CELL MONOLAYER ELECTRICAL
RESISTANCE 519 18.3.4 EFFECT OF NP SIZE 529 18.3.5 IN VITRO AND IN VIVO
COMPARATIVE STUDIES 523 18.3.6 EXPOSURE RISKS 524 18.4 APPLICATIONS OF
SI NPS IN BIOMEDICINE 524 18.5 SI NANOPARTICLE-BASED SENSORS 530 XIV
CONTENTS 20.2.3 CARRIER TUNNELING TRANSPORT IN SI QD SUPERLATTICES 562
20.3 THE "ALL-SI" TANDEM CELL: SI NANOSTRUCTURE TANDEM CELLS 563 20.3.1
ALTERNATIVE MATRICES FOR SI QDS 564 20.3.1.1 SI QUANTUM DOTS IN A
SILICON NITRIDE MATRIX 564 20.3.1.2 SILICON QD NANOCRYSTALS EMBEDDED IN
SILICON CARBIDE MATRIX 566 20.3.2 DOPING OF SI QD ARRAYS 566 20.3.2.1
PHOSPHORUS DOPING OF SI NANOSTRUCTURES 567 20.3.2.2 BORON DOPING OF SI
NANOSTRUCTURES 568 20.3.2.3 DOPING MECHANISMS 569 20.3.3 FABRICATION OF
SI QD PV DEVICES 570 20.3.3.1 SI QDS IN SIO 2 SOLAR CELL 570 20.3.3.2 SI
QDS IN SIC SOLAR CELL 571 20.4 INTERMEDIATE LEVEL CELLS: INTERMEDIATE
BAND AND IMPURITY PHOTOVOLTAIC CELL 572 20.5 MULTIPLE CARRIER EXCITATION
USING SI QDS 573 20.6 HOT CARRIER CELLS 574 20.6.1 PHOTOLUMINESCENCE OF
SI QD ESCS 575 20.6.2 NEGATIVE DIFFERENTIAL RESISTANCE IN SI QD ESCS 577
20.6.3 A COMPLETE HOT CARRIER CELL 578 20.7 CONCLUSIONS 578 REFERENCES
579 2 CONTENTS XV 21.4.1 FOURIER TRANSFORM INFRARED SPECTROSCOPY 602
21.5 OPTICAL TECHNIQUES 606 21.5.1 PHOTOLUMINESCENCE SPECTROSCOPY 606
REFERENCES 609 INDEX 613 |
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| publisher | Wiley-VCH |
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| spelling | Silicon nanocrystals fundamentals, synthesis and applications Ed. by Lorenzo Pavesi ... Weinheim Wiley-VCH 2010 XXI, 627 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Nanocrystals Nanosilicon Silicon crystals Silicium (DE-588)4077445-4 gnd rswk-swf Nanokristall (DE-588)7574326-7 gnd rswk-swf (DE-588)4143413-4 Aufsatzsammlung gnd-content Silicium (DE-588)4077445-4 s Nanokristall (DE-588)7574326-7 s DE-604 Pavesi, Lorenzo 1961- (DE-588)131368591 edt text/html http://deposit.dnb.de/cgi-bin/dokserv?id=3357024&prov=M&dok_var=1&dok_ext=htm Inhaltstext DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018662557&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Silicon nanocrystals fundamentals, synthesis and applications Nanocrystals Nanosilicon Silicon crystals Silicium (DE-588)4077445-4 gnd Nanokristall (DE-588)7574326-7 gnd |
| subject_GND | (DE-588)4077445-4 (DE-588)7574326-7 (DE-588)4143413-4 |
| title | Silicon nanocrystals fundamentals, synthesis and applications |
| title_auth | Silicon nanocrystals fundamentals, synthesis and applications |
| title_exact_search | Silicon nanocrystals fundamentals, synthesis and applications |
| title_full | Silicon nanocrystals fundamentals, synthesis and applications Ed. by Lorenzo Pavesi ... |
| title_fullStr | Silicon nanocrystals fundamentals, synthesis and applications Ed. by Lorenzo Pavesi ... |
| title_full_unstemmed | Silicon nanocrystals fundamentals, synthesis and applications Ed. by Lorenzo Pavesi ... |
| title_short | Silicon nanocrystals |
| title_sort | silicon nanocrystals fundamentals synthesis and applications |
| title_sub | fundamentals, synthesis and applications |
| topic | Nanocrystals Nanosilicon Silicon crystals Silicium (DE-588)4077445-4 gnd Nanokristall (DE-588)7574326-7 gnd |
| topic_facet | Nanocrystals Nanosilicon Silicon crystals Silicium Nanokristall Aufsatzsammlung |
| url | http://deposit.dnb.de/cgi-bin/dokserv?id=3357024&prov=M&dok_var=1&dok_ext=htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018662557&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT pavesilorenzo siliconnanocrystalsfundamentalssynthesisandapplications |