Bioinorganic photochemistry:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Chichester, UK
Wiley
2009
|
| Ausgabe: | 1. publ. |
| Schlagworte: | |
| Online-Zugang: | Cover Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | xvi, 382 p. ill. (some col.) 26 cm |
| ISBN: | 1405161728 9781405161725 |
Internformat
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| 245 | 1 | 0 | |a Bioinorganic photochemistry |c Grażyna Stochel ... [et al.] |
| 250 | |a 1. publ. | ||
| 264 | 1 | |a Chichester, UK |b Wiley |c 2009 | |
| 300 | |a xvi, 382 p. |b ill. (some col.) |c 26 cm | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 4 | |a Bioinorganic chemistry | |
| 650 | 4 | |a Photobiochemistry | |
| 650 | 0 | 7 | |a Fotochemie |0 (DE-588)4045873-8 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Bioanorganische Chemie |0 (DE-588)4126727-8 |2 gnd |9 rswk-swf |
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| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Stochel, Grażyna |e Sonstige |4 oth | |
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Datensatz im Suchindex
| _version_ | 1804140678512377856 |
|---|---|
| adam_text | Titel: Bioinorganic photochemistry
Autor: Stochel, Grażyna
Jahr: 2009
Contents
Preface Page xi
Abbreviations xiii
Part I Introduction 1
1 Philosophy of bioinorganic photochemistry 3
Part II Fundamentals 13
2 Light and matter 15
2.1 Nature of light 15
2.2 Accessible light sources 16
2.3 Interaction between light and matter 17
3 Formation and properties of electronic excited states 19
3.1 Wave mechanics and quantum numbers 20
3.2 Electronic excitation 21
4 Photophysical deactivation of electronic excited states 25
4.1 Spontaneous deactivation 25
4.2 Quenching 27
4.3 Coordination and organometallic compounds 29
5 Kinetics of the excited-state decay 35
6 Photochemical reactions 41
6.1 Photochemical reaction channels 42
6.2 Intramolecular photoreactions 43
6.2.1 Photodissociation and photoionization 44
6.2.2 Photoisomerization 46
6.3 Intermolecular photoreactions 47
6.4 The coordination compound specificity 49
viii Contents
6.4.1 Ligand field photochemistry 50
6.4.2 Photochemistry from LC or LLCT states 51
6.4.3 Inner-sphere charge transfer photochemistry 52
6.4.4 Outer-sphere charge transfer photochemistry 55
6.5 Photosensitized reactions 58
6.6 Homogeneous photocatalysis 63
7 Photochemistry and photophysics of supramolecular systems
and nanoassemblies 77
7.1 From molecules through clusters to crystals 77
7.2 Metallic nanoparticles: metals in the embryonic state 78
7.3 Formation and decay of the excited states of semiconductors 85
7.3.1 Optical excitation of semiconductors 85
7.3.2 Electrons and hole trapping 87
7.3.3 Radiative vs non-radiative decay 88
7.3.4 Surface-molecule interaction: general description 90
7.3.5 Heterogeneous photocatalysis 93
Part III Natural photoprocesses involving inorganic compounds 107
8 From interstellar space to planetary atmospheres 109
8.1 Homogeneous systems: from interstellar space to planetary
atmospheres and primitive soup models 110
8.2 Heterogeneous photochemistry in ice phases 121
9 Solar radiation and terrestrial environment 127
9.1 Solar radiation 127
9.2 Atmospheric photochemistry 129
9.3 Photochemistry in the hydrosphere and soil 138
9.3.1 Nitrate photochemistry 139
9.3.2 Role of humic substances 140
9.3.3 Photocatalysis by Fenl/Fen complexes 141
9.3.4 Photocatalysis by Cu VCu1 complexes 144
9.3.5 Photocatalysis by chromium compounds 145
9.4 Photochemical self-cleaning in the environment 148
10 Heterogeneous (photo)catalysis and biogenesis on Earth 157
10.1 (Photo)catalysis on chalcogenide semiconductors 157
10.2 Photocatalytic nitrogen fixation 159
10.3 Photocatalytic carbon dioxide reduction 160
10.4 Fossils of prebiotic catalysts: metal clusters in active centres
of metalloenzymes 161
11 Foundation and evolution of photosynthesis 169
11.1 Photosynthetic structures 172
11.2 Aerobic photosynthesis 174
11.2.1 Photosystem II (PSII) 176
11.2.2 Photosystem I (PSI) 177
Contents ix
11.3 Light harvesting antennae (LHC) 177
11.3.1 Chlorophyll 179
11.3.2 Bacteriochlorophyll 179
11.4 Electron transfer pathways in PSII and PSI 179
11.5 Oxygen-evolving complex (OEC) 183
11.5.1 Inorganic species in OEC 185
Part IV Photochemistry and photophysics in bioinspired systems:
studies and modelling 189
12 Photoenzymes 191
12.1 Natural photoenzymes 191
12.2 Modified natural proteins/enzymes 194
12.3 Artificial photoenzymes 197
12.4 Towards mimicking the photosynthetic processes 200
12.4.1 Light harvesting antennae 200
12.4.2 Charge-separation systems 202
12.4.3 Biomimetic reaction centres 203
13 Photoinduced electron transfer in proteins 209
13.1 Photochemical methodology 210
13.1.1 Photoactive ruthenium complexes 210
13.1.2 Metal-substituted haemoproteins 215
13.1.3 Photoinduced ligand dissociation 216
13.2 Biochemical applications 217
13.2.1 Mechanisms of electron transfer 217
13.2.2 Cross-linking of proteins 218
13.2.3 Analyzing intermediates and testing new inhibitors 219
13.2.4 Folding of proteins 219
14 Nucleic acid photocleavage and charge transport 227
14.1 Mechanisms and strategies for advanced metallophotocleavers 227
14.1.1 Ruthenium complexes 228
14.1.2 Rhodium complexes 232
14.1.3 Other metal complexes 234
14.1.4 Di-and trinuclear complexes 237
14.2 Photoinduced DNA-mediated charge transport 238
Part V Towards applications 247
15 Light and biomatter 249
16 Fluorescent and chromogenic sensing and labelling 257
16.1 Cations as targets in biochemical sensing 259
16.1.1 Cations common in biological systems 262
16.1.2 Fluorescent detection of toxic cations 268
16.2 Fluorescent and chromogenic sensing of anions 270
16.2.1 Common anions 270
16.2.2 Toxic anions 274
x Contents
16.3 Optical detection of neutral molecules 278
16.4 Nanoparticles in biochemical sensing and labelling 283
17 Therapeutic strategies 293
17.1 Photobiostimulation 295
17.2 Photoactivation of drugs 297
17.3 Photodynamic therapy 303
17.3.1 Mechanisms of PDT and PTT 304
17.3.2 Photosensitizers 305
17.3.3 Inorganic photosensitizers 307
17.3.4 Supporting role of metal ions in photodynamic therapy 312
17.3.5 Combination of polypyrrolic photosensitizers and
metallopharmaceuticals 313
17.3.6 Recent PDT development 313
17.4 Nanomedical methods 316
18 Photodynamic inactivation of microorganisms 335
18.1 Bacteria 337
18.2 Viruses 338
18.3 Fungi 340
18.4 Parasites 340
18.5 Perspectives 341
19 Photodelivery and phototargeting 345
20 Phototoxicity and photoprotection 353
20.1 Chemical and physical photoprotection 353
20.2 Inorganic sunscreens 355
21 Photocatalysis in environmental protection 359
21.1 Development of homo- and heterogeneous methods 359
21.2 Homogeneous photocatalysis 360
21.3 Heterogeneous photocatalysis 363
21.3.1 Water and air detoxification 363
21.3.2 Photocatalytic CO2 reduction 365
21.3.3 Other applications of photocatalysis 366
21.4 New ideas in pollution abatement 367
21.4.1 New emerging techniques 367
21.4.2 Renewable energy resources 368
Index 377
|
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| indexdate | 2024-07-09T22:03:48Z |
| institution | BVB |
| isbn | 1405161728 9781405161725 |
| language | English |
| lccn | 2008044387 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-018616988 |
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| physical | xvi, 382 p. ill. (some col.) 26 cm |
| publishDate | 2009 |
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| publisher | Wiley |
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| spelling | Bioinorganic photochemistry Grażyna Stochel ... [et al.] 1. publ. Chichester, UK Wiley 2009 xvi, 382 p. ill. (some col.) 26 cm txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Bioinorganic chemistry Photobiochemistry Fotochemie (DE-588)4045873-8 gnd rswk-swf Bioanorganische Chemie (DE-588)4126727-8 gnd rswk-swf Bioanorganische Chemie (DE-588)4126727-8 s Fotochemie (DE-588)4045873-8 s DE-604 Stochel, Grażyna Sonstige oth DE-576;wiley image/jpeg http://swbplus.bsz-bw.de/bsz306277816cov.htm 20090506214511 Cover HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018616988&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Bioinorganic photochemistry Bioinorganic chemistry Photobiochemistry Fotochemie (DE-588)4045873-8 gnd Bioanorganische Chemie (DE-588)4126727-8 gnd |
| subject_GND | (DE-588)4045873-8 (DE-588)4126727-8 |
| title | Bioinorganic photochemistry |
| title_auth | Bioinorganic photochemistry |
| title_exact_search | Bioinorganic photochemistry |
| title_full | Bioinorganic photochemistry Grażyna Stochel ... [et al.] |
| title_fullStr | Bioinorganic photochemistry Grażyna Stochel ... [et al.] |
| title_full_unstemmed | Bioinorganic photochemistry Grażyna Stochel ... [et al.] |
| title_short | Bioinorganic photochemistry |
| title_sort | bioinorganic photochemistry |
| topic | Bioinorganic chemistry Photobiochemistry Fotochemie (DE-588)4045873-8 gnd Bioanorganische Chemie (DE-588)4126727-8 gnd |
| topic_facet | Bioinorganic chemistry Photobiochemistry Fotochemie Bioanorganische Chemie |
| url | http://swbplus.bsz-bw.de/bsz306277816cov.htm http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=018616988&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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