Mechanisms of inorganic reactions in solution: an introduction
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
London [u.a.]
McGraw-Hill
1968
|
| Series: | European chemistry series
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Mit Bibliogr |
| Physical Description: | XII, 218 S. graph. Darst. |
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| 100 | 1 | |a Benson, Denis |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a Mechanisms of inorganic reactions in solution |b an introduction |c D. Benson |
| 264 | 1 | |a London [u.a.] |b McGraw-Hill |c 1968 | |
| 300 | |a XII, 218 S. |b graph. Darst. | ||
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| 490 | 0 | |a European chemistry series | |
| 500 | |a Mit Bibliogr | ||
| 650 | 4 | |a Chemical reaction, Conditions and laws of | |
| 650 | 4 | |a Chemistry, Inorganic | |
| 650 | 4 | |a Solution (Chemistry) | |
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| adam_text | Mechanisms of
inorganic reactions in
solution
AN INTRODUCTION
D BENSON, B Sc , Ph D,ARIC
Widnes Technical College
amp;
McGRAW-HILL • LONDON
New York • Sydney Toronto • Mexico • Johannesburg • Panama
Contents
Preface vii
CHAPTER 1
1 Introduction 1
Theory of reaction rates 4
Rate laws and mechanism 7
Stationary-state approximation 13
The solvent and solvation of ions 16
Inert and labile complexes 17
References 17
Bibliography
2 Substitution reactions of metal complexes 19
A Octahedral complexes 22
Acid hydrolysis 25
Acid-catalysed aquation 32
Anation reactions 36
Base hydrolysis 40
Reactions without metal-ligand bond cleavage 45
Reactions of platinum(IV) complexes 47
Reactions in non-aqueous solvents 49
Fast reactions 52
B Square-planar complexes 60
Nucleophilic reactivity 62
Effect of non-labile group 67
Effect of solvent 71
Mechanism of substitution 72
Effect of leaving group 76
Electrophilic catalysis 77
Nickel(II) and palladium(II) complexes 79
ix
CONTENTS
CHAPTER
Gold(III) complexes 81
Rhodium(I) complexes 81
Substitution reactions of five-coordinated plati-
num(II) complexes 83
C Tetrahedral complexes 84
Substitution at silicon, germanium, and tin 84
Reactions of metal carbonyls 85
Substitution reactions of Co(NO)(CO)3 87
References 87
Bibliography 90
3 Oxidation-reduction reactions of metal ions 91
Inner- and outer-sphere reactions 92
Outer-sphere reactions 92
Inner-sphere reactions 95
Inorganic bridging ligands in inner-sphere reactions 100
Organic bridging groups in inner-sphere reactions 102
One-equivalent-one-equivalent reactions 104
Two-equivalent-one-equivalent reactions 110
Reactions of thallium(III) and thallium( I) ! 110
Reactions of mercury(I) and mercury(II) 116
Reactions of uranium(IV) 118
Reactions of plutonium(VI) 119
Reactions of lead(IV) in acetic acid 120
Reactions of tin(ll) 123
Summary 123
Two-equivalent-two-equivalent reactions 125
The oxidation of uranium(IV) by thallium(lll) 125
The oxidation of mercury(I) by thallium(lll) 126
The oxidation of tin(II) by plutonium(Vl) 128
Multi-equivalent reactions 128
Reactions of chromium(Vl) and chromium(IIl) 128
Metal-ion-catalysed reactions 132
Reactions, of molecular oxygen with metal ions 138
Catalysed reactions of molecular hydrogen and carbon
monoxide with metal ions 140
Reactions of the hydrated electron 142
References 150
Bibliography 152
CONTENTS xi
CHAPTER
4 Reactions of oxoanions 153
Exchange reactions of hypobromite and hypochlorite 153
Further reactions of hypochlorite 156
Oxygen exchanges of bromate and chlorate with water 158
Oxygen exchange of iodate and water 158
Oxygen exchange of periodate and water 161
The chlorite-iodide reaction 162
The reaction between iodate and iodide 164
The periodate-iodide reaction 165
Reactions of halogen oxoanions with sulphite 165
Reaction of sulphite with hydrogen peroxide 167
Nucleophilic displacements on sulphur 168
The oxidation of S(IV) by Cr( VI) 169
The chromium(VI)-chromium(III) exchange 171
Induced oxidations of Cr(VI) 173
Formation of peroxo complex of chromium(VI) 176
The oxidation of iodide by permanganate 177
The permanganate-oxalate reaction 178
The oxidation of cyanide by permanganate 179
Further reactions of alkaline permanganate 181
Reactions of manganate 182
References 183
Bibliography 185
5 Free radical reactions 186
The thermal decomposition of peroxodisulphate 186
The Fe(II)-peroxodisulphate reaction 188
The induced oxidation of As(lII) by Fe(H)-peroxo-
disulphate 189
The oxidation of oxalate by peroxodisulphate 191
The Ag(I)-catalysed oxidation of oxalate 193
The oxidation of thiosulphate by peroxodisulphate 194
The oxidation of methanol by peroxodisulphate 195
The hydrogen peroxide-peroxodisulphate reaction 198
The catalysed decomposition of hydrogen peroxide 200
Evidence for the existence of OH and H02 radicals 202
References 203
Bibliography 203
xii CONTENTS
CHAPTER
6 Protolytic reactions 204
The reaction between H+ and OH ions 204
Other reactions involving H+ and OH ions 207
The hydration of carbon dioxide 209
Hydrolysis of the halogens 209
References 210
Bibliography 211
Subject Index 212
|
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| indexdate | 2024-07-09T21:43:31Z |
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| language | English |
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| physical | XII, 218 S. graph. Darst. |
| publishDate | 1968 |
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| series2 | European chemistry series |
| spelling | Benson, Denis Verfasser aut Mechanisms of inorganic reactions in solution an introduction D. Benson London [u.a.] McGraw-Hill 1968 XII, 218 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier European chemistry series Mit Bibliogr Chemical reaction, Conditions and laws of Chemistry, Inorganic Solution (Chemistry) HEBIS Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017745507&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Benson, Denis Mechanisms of inorganic reactions in solution an introduction Chemical reaction, Conditions and laws of Chemistry, Inorganic Solution (Chemistry) |
| title | Mechanisms of inorganic reactions in solution an introduction |
| title_auth | Mechanisms of inorganic reactions in solution an introduction |
| title_exact_search | Mechanisms of inorganic reactions in solution an introduction |
| title_full | Mechanisms of inorganic reactions in solution an introduction D. Benson |
| title_fullStr | Mechanisms of inorganic reactions in solution an introduction D. Benson |
| title_full_unstemmed | Mechanisms of inorganic reactions in solution an introduction D. Benson |
| title_short | Mechanisms of inorganic reactions in solution |
| title_sort | mechanisms of inorganic reactions in solution an introduction |
| title_sub | an introduction |
| topic | Chemical reaction, Conditions and laws of Chemistry, Inorganic Solution (Chemistry) |
| topic_facet | Chemical reaction, Conditions and laws of Chemistry, Inorganic Solution (Chemistry) |
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