Mössbauer spectroscopy and transition metal chemistry: fundamentals and applications ; with electronic supplementary material at extras.springer.com
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| Main Authors: | , , |
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| Format: | Kit Book |
| Language: | English |
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Heidelberg [u.a.]
Springer
2011
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| Online Access: | Inhaltsverzeichnis |
| Item Description: | Additional material to this book is abvailable on CD-ROM; in subsequent printings this material can be downloaded from http://extra.springer.com ... |
| Physical Description: | XV, 568 S. Ill., graph. Darst. |
| ISBN: | 9783540884279 9783540884286 |
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| 245 | 1 | 0 | |a Mössbauer spectroscopy and transition metal chemistry |b fundamentals and applications ; with electronic supplementary material at extras.springer.com |c Philipp Gütlich ; Eckhard Bill ; Alfred X. Trautwein |
| 264 | 1 | |a Heidelberg [u.a.] |b Springer |c 2011 | |
| 300 | |a XV, 568 S. |b Ill., graph. Darst. | ||
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| adam_text | IMAGE 1
CONTENTS
1 INTRODUCTION 1
REFERENCES 3
2 BASIC PHYSICAL CONCEPTS 7
2.1 NUCLEAR Y-RESONANCE 7
2.2 NATURAL LINE WIDTH AND SPECTRAL LINE SHAPE 9
2.3 RECOIL ENERGY LOSS IN FREE ATOMS AND THERMAL BROADENING OF
TRANSITION LINES 10
2.4 RECOIL-FREE EMISSION AND ABSORPTION 13
2.5 THE MOESSBAUER EXPERIMENT 17
2.6 THE MOESSBAUER TRANSMISSION SPECTRUM 18
2.6.1 THE LINE SHAPE FOR THIN ABSORBERS 21
2.6.2 SATURATION FOR THICK ABSORBERS 23
REFERENCES 24
3 EXPERIMENTAL 25
3.1 THE MOESSBAUER SPECTROMETER 25
3.1.1 THE MOESSBAUER DRIVE SYSTEM 27
3.1.2 RECORDING THE MOESSBAUER SPECTRUM 29
3.1.3 VELOCITY CALIBRATION 31
3.1.4 THE MOESSBAUER LIGHT SOURCE 34
3.1.5 PULSE HEIGHT ANALYSIS: DISCRIMINATION OF PHOTONS 35 3.1.6
MOESSBAUER DETECTORS 37
3.1.7 ACCESSORY CRYOSTATS AND MAGNETS 41
3.1.8 GEOMETRY EFFECTS AND SOURCE-ABSORBER DISTANCE 43 3.2 PREPARATION
OF MOESSBAUER SOURCES AND ABSORBERS 45
3.2.1 SAMPLE PREPARATION 46
3.2.2 ABSORBER OPTIMIZATION: MASS ABSORPTION AND THICKNESS 49 3.2.3
ABSORBER TEMPERATURE 52
BIBLIOGRAFISCHE INFORMATIONEN HTTP://D-NB.INFO/990358860
DIGITALISIERT DURCH
IMAGE 2
[ CONTENTS
3.3 THE MINIATURIZED SPECTROMETER MIMOS II 53
3.3.1 INTRODUCTION 53
3.3.2 DESIGN OVERVIEW 54
3.3.3 BACKSCATTER MEASUREMENT GEOMETRY 59
3.3.4 TEMPERATURE DEPENDENCE AND SAMPLING DEPTH 62 3.3.5 DATA STRUCTURE,
TEMPERATURE LOG, AND BACKUP STRATEGY 65 3.3.6 VELOCITY AND ENERGY
CALIBRATION 66
3.3.7 THE ADVANCED INSTRUMENT MIMOS ILA 67
REFERENCES 69
4 HYPERFLNE INTERACTIONS 73
4.1 INTRODUCTION TO ELECTRIC HYPERFINE INTERACTIONS 73
4.1.1 NUCLEAR MOMENTS 75
4.1.2 ELECTRIC MONOPOLE INTERACTION 75
4.1.3 ELECTRIC QUADRUPOLE INTERACTION 76
4.1.4 QUANTUM MECHANICAL FORMALISM FOR THE QUADRUPOLE INTERACTION 77
4.2 MOESSBAUER ISOMER SHIFT 79
4.2.1 RELATIVISTIC EFFECTS 81
4.2.2 ISOMER SHIFT REFERENCE SCALE 81
4.2.3 SECOND-ORDER DOPPLER SHIFT 81
4.2.4 CHEMICAL INFORMATION FROM ISOMER SHIFTS 83
4.3 ELECTRIC QUADRUPOLE INTERACTION 89
4.3.1 NUCLEAR QUADRUPOLE MOMENT 90
4.3.2 ELECTRIC FIELD GRADIENT 90
4.3.3 QUADRUPOLE SPLITTING 92
4.3.4 INTERPRETATION AND COMPUTATION OF ELECTRIC FIELD GRADIENTS 95
4.4 MAGNETIC DIPOLE INTERACTION AND MAGNETIC SPLITTING 102 4.5 COMBINED
ELECTRIC AND MAGNETIC HYPERFINE INTERACTIONS 103 4.5.1 PERTURBATION
TREATMENT 104
4.5.2 HIGH-FIELD CONDITION: G N P N B EQVJ2 104
4.5.3 LOW-FIELD CONDITION: EQVJL » G N I N FI 108
4.5.4 EFFECTIVE NUCLEAR G-FACTORS FOR EQVJL G^N^B I LL
4.5.5 REMARKS ON LOW-FIELD AND HIGH-FIELD MOESSBAUER SPECTRA 112
4.6 RELATIVE INTENSITIES OF RESONANCE LINES 113
4.6.1 TRANSITION PROBABILITIES 113
4.6.2 EFFECT OF CRYSTAL ANISOTROPY ON THE RELATIVE INTENSITIES OF
HYPERFINE SPLITTING COMPONENTS 118
4.7 57 FE-MOESSBAUER SPECTROSCOPY OF PARAMAGNETIC SYSTEMS 120 4.7.1 THE
SPIN-HAMILTONIAN CONCEPT 121
4.7.2 THE FORMALISM FOR ELECTRONIC SPINS 124
4.7.3 NUCLEAR HAMILTONIAN AND HYPERFINE COUPLING 125
IMAGE 3
CONTENTS XI
4.7.4 COMPUTATION OF MOESSBAUER SPECTRA IN SLOW AND FAST RELAXATION LIMIT
127
4.7.5 SPIN COUPLING 128
4.7.6 INTERPRETATION, REMARKS AND RELATION WITH OTHER TECHNIQUES 131
REFERENCES 132
5 QUANTUM CHEMISTRY AND MOESSBAUER SPECTROSCOPY 137 5.1 INTRODUCTION 137
5.2 ELECTRONIC STRUCTURE THEORY 138
5.2.1 THE MOLECULAR SCHROEDINGER EQUATION 138
5.2.2 HARTREE-FOCK THEORY 139
5.2.3 SPIN-POLARIZATION AND TOTAL SPIN 142
5.2.4 ELECTRON DENSITY AND SPIN-DENSITY 144
5.2.5 POST-HARTREE-FOCK THEORY 145
5.2.6 DENSITY FUNCTIONAL THEORY 146
5.2.7 RELATIVISTIC EFFECTS 148
5.2.8 LINEAR RESPONSE AND MOLECULAR PROPERTIES 149
5.3 MOESSBAUER PROPERTIES FROM DENSITY FUNCTIONAL THEORY 150 5.3.1
ISOMERSHIFTS 150
5.3.2 QUADRUPOLE SPLITTINGS 164
5.3.3 MAGNETIC HYPERFINE INTERACTION 178
5.3.4 ZERO-FIELD SPLITTING AND G-TENSORS 185
5.4 NUCLEAR INELASTIC SCATTERING 186
5.4.1 THE MS INTENSITY 187
5.4.2 EXAMPLE 1: NIS STUDIES OF AN FE(III)-AZIDE (CYCLAM-ACETATO)
COMPLEX 189
5.4.3 EXAMPLE 2: QUANTITATIVE VIBRATIONAL DYNAMICS OF IRON FERROUS
NITROSYL TETRAPHENYLPORPHYRIN 193 REFERENCES 196
6 MAGNETIC RELAXATION PHENOMENA 201
6.1 INTRODUCTION 201
6.2 MOESSBAUER SPECTRA OF SAMPLES WITH SLOW PARAMAGNETIC RELAXATION 202
6.3 MOESSBAUER RELAXATION SPECTRA 205
6.4 PARAMAGNETIC RELAXATION PROCESSES 210
6.4.1 SPIN-LATTICE RELAXATION 211
6.4.2 SPIN-SPIN RELAXATION 214
6.5 RELAXATION IN MAGNETIC NANOPARTICLES 220
6.5.1 SUPERPARAMAGNETIC RELAXATION 220
6.5.2 COLLECTIVE MAGNETIC EXCITATIONS 223
6.5.3 INTERPARTICLE INTERACTIONS 226
6.6 TRANSVERSE RELAXATION IN CANTED SPIN STRUCTURES 229
REFERENCES 232
IMAGE 4
CII CONTENTS
7 MOESSBAUER-ACTIVE TRANSITION METALS OTHER THAN IRON 235 7.1 NICKEL( 61
NI) 237
7.1.1 SOME PRACTICAL ASPECTS 237
7.1.2 HYPERFINE INTERACTIONS IN 61 NI 238
7.1.3 SELECTED 61 NI MOESSBAUER EFFECT STUDIES 246
7.2 ZINC( 67 ZN) 255
7.2.1 EXPERIMENTAL ASPECTS 255
7.2.2 SELECTED 67 ZN MOESSBAUER EFFECT STUDIES 262
7.3 RUTHENIUM ( RU, 101 RU) 270
7.3.1 EXPERIMENTAL ASPECTS 270
7.3.2 CHEMICAL INFORMATION FROM 99 RU MOESSBAUER PARAMETERS 270 7.3.3
FURTHER RU STUDIES 284
7.4 HAFNIUM ( 176 177 17SM80 HF) 285
7.4.1 PRACTICAL ASPECTS OF HAFNIUM MOESSBAUER SPECTROSCOPY 286 7.4.2
MAGNETIC DIPOLE AND ELECTRIC QUADRUPOLE INTERACTION 288 7.5 TANTALUM (
181 TA) 289
7.5.1 EXPERIMENTAL ASPECTS 290
7.5.2 ISOMER SHIFT STUDIES 292
7.5.3 HYPERFINE SPLITTING IN 181 TA (6.2 KEV) SPECTRA 296
7.5.4 METHODOLOGICAL ADVANCES AND SELECTED APPLICATIONS 300 7.6 TUNGSTEN
( 180 - 182 183 - 184 186 W) 301
7.6.1 PRACTICAL ASPECTS OF MOESSBAUER SPECTROSCOPY WITH TUNGSTEN 303
7.6.2 CHEMICAL INFORMATION FROM DEBYE-WALLER FACTOR MEASUREMENTS 305
7.6.3 CHEMICAL INFORMATION FROM HYPERFINE INTERACTION 306 7.6.4 FURTHER
183 W STUDIES 309
7.7 OSMIUM ( 186 188 - 189 190 OS) 310
7.7.1 PRACTICAL ASPECTS OF MOESSBAUER SPECTROSCOPY WITH OSMIUM 311
7.7.2 DETERMINATION OF NUCLEAR PARAMETERS OF OSMIUM MOESSBAUER ISOTOPES
313
7.7.3 INORGANIC OSMIUM COMPOUNDS 317
7.8 INDIUM ( 19U93 IR) 320
7.8.1 PRACTICAL ASPECTS OF 193 IR MOESSBAUER SPECTROSCOPY 321 7.8.2
COORDINATION COMPOUNDS OF IRIDIUM 322
7.8.3 INTERMETALLIC COMPOUNDS AND ALLOYS OF IRIDIUM 329 7.8.4 RECENT 193
IR MOESSBAUER STUDIES 337
7.9 PLATINUM ( 195 PT) 339
7.9.1 EXPERIMENTAL ASPECTS 339
7.9.2 PLATINUM COMPOUNDS 341
7.9.3 METALLIC SYSTEMS 344
7.10 GOLD( 197 AU) 348
7.10.1 PRACTICAL ASPECTS 349
IMAGE 5
CONTENTS XIII
7.10.2 INORGANIC AND METAL-ORGANIC COMPOUNDS OF GOLD 350 7.10.3 SPECIFIC
APPLICATIONS 361
7.11 MERCURY ( 199 201 HG) 373
REFERENCES 376
8 SOME SPECIAL APPLICATIONS 391
8.1 SPIN CROSSOVER PHENOMENA IN FE(II) COMPLEXES 392
8.1.1 INTRODUCTION 392
8.1.2 SPIN CROSSOVER IN [FE(2-PIC) 3 ]CL 2 -SOL 396
8.1.3 EFFECT OF LIGHT IRRADIATION (LIESST EFFECT) 399
8.1.4 SPIN CROSSOVER IN DINUCLEAR IRON(II) COMPLEXES 403 8.1.5 SPIN
CROSSOVER IN A TRINUCLEAR IRON(II) COMPLEX 408 8.1.6 SPIN CROSSOVER IN
METALLOMESOGENS 411
8.1.7 EFFECT OF NUCLEAR DECAY: MOESSBAUER EMISSION SPECTROSCOPY 413
8.2 57 FE MOESSBAUER SPECTROSCOPY: UNUSUAL SPIN AND VALENCE STATES 417
8.2.1 IRON(III) WITH INTERMEDIATE SPIN, S = 3/2 417
8.2.2 IRON(II) WITH INTERMEDIATE SPIN, S = 1 425
8.2.3 IRON IN THE HIGH OXIDATION STATES IV-VI 428
8.2.4 IRON IN LOW OXIDATION STATES 440
8.3 MOBILE MOESSBAUER SPECTROSCOPY WITH MIMOS IN SPACE AND ON EARTH 447
8.3.1 INTRODUCTION 447
8.3.2 THE INSTRUMENT MIMOS II 448
8.3.3 EXAMPLES 451
8.3.4 CONCLUSIONS AND OUTLOOK 464
REFERENCES 464
9 NUCLEAR RESONANCE SCATTERING USING SYNCHROTRON RADIATION (MOESSBAUER
SPECTROSCOPY IN THE TIME DOMAIN) 477
9.1 INTRODUCTION 477
9.2 INSTRUMENTATION 478
9.3 NUCLEAR FORWARD SCATTERING (NFS) 479
9.3.1 QUADRUPOLE SPLITTING: THEORETICAL BACKGROUND 480 9.3.2 EFFECTIVE
THICKNESS, LAMB-MOESSBAUER FACTOR 480 9.4 NFS APPLICATIONS 483
9.4.1 POLYCRYSTALLINE MATERIAL VERSUS FROZEN SOLUTION (EXAMPLE:
PICKET-FENCE PORPHYRIN AND DEOXYMYOGLOBIN) 483
9.4.2 TEMPERATURE-DEPENDENT QUADRUPOLE SPLITTING IN PARAMAGNETIC (S = 2)
IRON COMPOUNDS (EXAMPLE: DEOXYMYOGLOBIN) 486
IMAGE 6
CONTENTS
9.4.3 DYNAMICALLY INDUCED TEMPERATURE-DEPENDENCE OF QUADRUPOLE SPLITTING
(EXAMPLE: OXYMYOGLOBIN) 487 9.4.4 MOLECULAR DYNAMICS OF A SENSOR
MOLECULE IN VARIOUS HOSTS (EXAMPLE: FERROCENE (FC)) 490
9.4.5 TEMPERATURE-DEPENDENT QUADRUPOLE SPLITTING AND LAMB-MOESSBAUER
FACTOR IN SPIN-CROSSOVER COMPOUNDS (EXAMPLE: [FE N (TPA)(NCS) 2 ]) 491
9.4.6 COHERENT VERSUS INCOHERENT SUPERPOSITION OF FORWARD SCATTERED
RADIATION OF HIGH-SPIN AND LOW-SPIN DOMAINS (EXAMPLE: [FE N (TPA)(NCS) 2
]) 493
9.4.7 ORIENTATION-DEPENDENT LINE-INTENSITY RATIO AND LAMB-MOESSBAUER
FACTOR IN SINGLE CRYSTALS (EXAMPLE: (CN 3 H 6 ) 2 [FE(CN) 5 NO]) 495
9.5 ISOMER SHIFT DERIVED FROM NFS (INCLUDING A REFERENCE SCATTERER) 497
9.6 MAGNETIC INTERACTION VISUALIZED BY NFS 498
9.6.1 MAGNETIC INTERACTION IN A DIAMAGNETIC IRON COMPLEX (EXAMPLE: [FEO
2 (SC 6 HF 4 )(TP PIV P)]) 498 9.6.2 MAGNETIC HYPERFINE INTERACTION IN
PARAMAGNETIC IRON COMPLEXES (EXAMPLES: [FE(CH 3 COO)(TP PIV P)R
WITH S = 2 AND [TPPFE(NH 2 PZH) 2 ]CL WITH S = 1/2) 498 9.6.3 MAGNETIC
HYPERFINE INTERACTION AND SPIN-LATTICE RELAXATION IN PARAMAGNETIC IRON
COMPLEXES (EXAMPLES: FERRIC LOW-SPIN (FE M , S = 1/2) AND FERROUS
HIGH-SPIN (FE 11 , S = 2)) 503
9.6.4 SUPERPARAMAGNETIC RELAXATION (EXAMPLE: FERRITIN) 505 9.6.5
HIGH-PRESSURE INVESTIGATIONS OF MAGNETIC PROPERTIES (EXAMPLES: LAVES
PHASES AND IRON OXIDES) 508
9.7 NFS VISUALIZED BY THE NUCLEAR LIGHTHOUSE EFFECT (NLE) (EXAMPLE: IRON
FOIL) 511
9.8 SYNCHROTRON RADIATION BASED PERTURBED ANGULAR CORRELATION, SRPAC
(EXAMPLE: WHOLE-MOLECULE ROTATION OF FC) 512 9.9 NUCLEAR INELASTIC
SCATTERING 516
9.9.1 PHONON CREATION AND ANNIHILATION 516
9.9.2 DATA ANALYSIS AND DOS (EXAMPLE: HEXACYANOFERRATE) 518 9.9.3 DATA
ANALYSIS USING ABSORPTION PROBABILITY DENSITY (EXAMPLE: GUANIDIM UM
NITROPRUSSIDE) 520
9.9.4 IRON-LIGAND VIBRATIONS IN SPIN-CROSSOVER COMPLEXES 523 9.9.5 BOSON
PEAK, A SIGNATURE OF DELOCALIZED COLLECTIVE MOTIONS IN GLASSES (EXAMPLE:
FC AS SENSOR MOLECULE) 526 9.9.6 PROTEIN DYNAMICS VISUALIZED BY NIS 528
9.10 NUCLEAR RESONANCE SCATTERING WITH ISOTOPES OTHER THAN 57 FE ... 534
REFERENCES 536
IMAGE 7
CONTENTS XV
10 APPENDICES 541
APPENDIX A: OPTIMIZATION OF SAMPLE THICKNESS 541
APPENDIX B: MASS ABSORPTION COEFFICIENTS 543
APPENDIX C: THE ISOMER SHIFT CALIBRATION CONSTANT 544
APPENDIX D: RELATIVISTIC CORRECTIONS FOR THE MOESSBAUER ISOMER SHIFT 546
APPENDIX E: AN INTRODUCTION TO SECOND-ORDER DOPPLER SHIFT 547 APPENDIX
F: FORMAL AND SPECTROSCOPIC OXIDATION STATES 549 APPENDIX G:
SPIN-HAMILTONIAN OPERATOR WITH TERMS OF HIGHER ORDER IN S 550
APPENDIX H: REMARK ON SPIN-LATTICE RELAXATION 551
APPENDIX I: PHYSICAL CONSTANTS AND CONVERSION FACTORS 553
INDEX 557
TABLE 7.1 NUCLEAR DATA FOR MOESSBAUER TRANSITIONS USED IN TRANSITION
METAL CHEMISTRY 569
|
| any_adam_object | 1 |
| author | Gütlich, Philipp Bill, Eckhard Trautwein, Alfred 1940-2019 |
| author_GND | (DE-588)13219418X |
| author_facet | Gütlich, Philipp Bill, Eckhard Trautwein, Alfred 1940-2019 |
| author_role | aut aut aut |
| author_sort | Gütlich, Philipp |
| author_variant | p g pg e b eb a t at |
| building | Verbundindex |
| bvnumber | BV035649246 |
| classification_rvk | UP 9500 VG 8950 |
| ctrlnum | (OCoLC)635294603 (DE-599)DNB990358860 |
| dewey-full | 537.5352 546.6 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 537 - Electricity and electronics 546 - Inorganic chemistry |
| dewey-raw | 537.5352 546.6 |
| dewey-search | 537.5352 546.6 |
| dewey-sort | 3537.5352 |
| dewey-tens | 530 - Physics 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Physik |
| format | Kit Book |
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| genre | 1\p (DE-588)4151278-9 Einführung gnd-content |
| genre_facet | Einführung |
| id | DE-604.BV035649246 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:42:26Z |
| institution | BVB |
| isbn | 9783540884279 9783540884286 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017703875 |
| oclc_num | 635294603 |
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| owner_facet | DE-19 DE-BY-UBM DE-703 DE-11 DE-355 DE-BY-UBR DE-20 DE-91G DE-BY-TUM |
| physical | XV, 568 S. Ill., graph. Darst. |
| publishDate | 2011 |
| publishDateSearch | 2011 |
| publishDateSort | 2011 |
| publisher | Springer |
| record_format | marc |
| spelling | Gütlich, Philipp Verfasser aut Mössbauer spectroscopy and transition metal chemistry fundamentals and applications ; with electronic supplementary material at extras.springer.com Philipp Gütlich ; Eckhard Bill ; Alfred X. Trautwein Heidelberg [u.a.] Springer 2011 XV, 568 S. Ill., graph. Darst. Additional material to this book is abvailable on CD-ROM; in subsequent printings this material can be downloaded from http://extra.springer.com ... Mößbauer-Spektroskopie (DE-588)4170352-2 gnd rswk-swf Übergangsmetall (DE-588)4078494-0 gnd rswk-swf 1\p (DE-588)4151278-9 Einführung gnd-content Mößbauer-Spektroskopie (DE-588)4170352-2 s Übergangsmetall (DE-588)4078494-0 s DE-604 Bill, Eckhard Verfasser aut Trautwein, Alfred 1940-2019 Verfasser (DE-588)13219418X aut DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017703875&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Gütlich, Philipp Bill, Eckhard Trautwein, Alfred 1940-2019 Mössbauer spectroscopy and transition metal chemistry fundamentals and applications ; with electronic supplementary material at extras.springer.com Mößbauer-Spektroskopie (DE-588)4170352-2 gnd Übergangsmetall (DE-588)4078494-0 gnd |
| subject_GND | (DE-588)4170352-2 (DE-588)4078494-0 (DE-588)4151278-9 |
| title | Mössbauer spectroscopy and transition metal chemistry fundamentals and applications ; with electronic supplementary material at extras.springer.com |
| title_auth | Mössbauer spectroscopy and transition metal chemistry fundamentals and applications ; with electronic supplementary material at extras.springer.com |
| title_exact_search | Mössbauer spectroscopy and transition metal chemistry fundamentals and applications ; with electronic supplementary material at extras.springer.com |
| title_full | Mössbauer spectroscopy and transition metal chemistry fundamentals and applications ; with electronic supplementary material at extras.springer.com Philipp Gütlich ; Eckhard Bill ; Alfred X. Trautwein |
| title_fullStr | Mössbauer spectroscopy and transition metal chemistry fundamentals and applications ; with electronic supplementary material at extras.springer.com Philipp Gütlich ; Eckhard Bill ; Alfred X. Trautwein |
| title_full_unstemmed | Mössbauer spectroscopy and transition metal chemistry fundamentals and applications ; with electronic supplementary material at extras.springer.com Philipp Gütlich ; Eckhard Bill ; Alfred X. Trautwein |
| title_short | Mössbauer spectroscopy and transition metal chemistry |
| title_sort | mossbauer spectroscopy and transition metal chemistry fundamentals and applications with electronic supplementary material at extras springer com |
| title_sub | fundamentals and applications ; with electronic supplementary material at extras.springer.com |
| topic | Mößbauer-Spektroskopie (DE-588)4170352-2 gnd Übergangsmetall (DE-588)4078494-0 gnd |
| topic_facet | Mößbauer-Spektroskopie Übergangsmetall Einführung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017703875&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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