The organometallic chemistry of the transition metals:
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Hoboken, NJ
Wiley
2009
|
| Edition: | 5. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | XIII, 505 S. Ill., graph. Darst. |
| ISBN: | 9780470257623 |
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| 100 | 1 | |a Crabtree, Robert H. |e Verfasser |4 aut | |
| 245 | 1 | 0 | |a The organometallic chemistry of the transition metals |c Robert H. Crabtree |
| 250 | |a 5. ed. | ||
| 264 | 1 | |a Hoboken, NJ |b Wiley |c 2009 | |
| 300 | |a XIII, 505 S. |b Ill., graph. Darst. | ||
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| 650 | 7 | |a Overgangsmetaalcomplexen |2 gtt | |
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Record in the Search Index
| _version_ | 1804139318763061248 |
|---|---|
| adam_text | CONTENTS
Acknowledgment
List of Abbreviations
1
Introduction
1.1
Why Study Organometallic Chemistry?,
1
1.2
Coordination Chemistry,
2
1.3
Werner Complexes,
3
1.4
The Trans Effect,
7
1.5
Soft versus Hard Ligands,
8
1.6
The Crystal Field,
9
1.7
The Ligand Field,
16
1.8
Back Bonding,
19
1.9
Electroneutrality,
23
1.10
Types of Ligand,
25
X
xi
2
General Properties of Organometallic Complexes
33
2.1
The le-Electron Rule,
33
2.2
Limitations of the lS-Electron Rule,
39
2.3
Electron Counting in Reactions,
41
2.4
Oxidation State,
42
2.5
Coordination Number and Geometry,
46
2.6
Effects of Complexation,
49
,¡
CONTENTS
2.7
Differences between Metals,
52
2.8
Supramolecular Chemistry,
54
3
Metal Alkyls, Aryls, and Hydrides and Related
σ
-Bonded
Ligands
58
3.1
Transition Metal Alkyls and Aryls,
58
3.2
Related
σ
-Bonded
Ligands,
73
3.3
Metal Hydride Complexes,
75
3.4
σ
Complexes,
78
3.5
Bond Strengths for Classical
σ
-Bonding
Ligands,
82
4
Carbonyls, Phosphine Complexes, and Ligand Substitution
Reactions
88
4.1
Metal Complexes of CO, RNC, CS, and NO,
88
4.2
Phosphines and Related Ligands,
99
4.3
Dissociative Substitution,
104
4.4
Associative Substitution,
108
4.5
Redox
Effects, The I Mechanism, and Rearrangements in
Substitution, 111
4.6
Photochemical Substitution,
114
4.7
Steric and Solvent Effects in Substitution,
117
5
Complexes of TT-Bound Ligands
122
5.1
Alkene and Alkyne Complexes,
122
5.2
Allyl Complexes,
128
5.3 Diene
Complexes,
132
5.4
Cyclopentadienyl Complexes,
136
5.5
Arenes
and Other Alicyclic Ligands,
143
5.6
Metalacycles and Isolobal Replacement,
148
5.7
Stability of Polyene and Polyenyl Complexes,
149
6
Oxidative Addition and Reductive Elimination
153
6.1
Concerted Additions,
156
6.2
SN2 Reactions,
158
6.3
Radical Mechanisms,
160
6.4
Ionic Mechanisms,
163
6.5
Reductive Elimination,
164
6.6
σ
-Bond
Metathesis,
170
6.7
Oxidative Coupling and Reductive Fragmentation,
172
7
Insertion and Elimination
177
7.1
Reactions Involving CO,
179
7.2
Insertions Involving Alkenes,
185
CONTENTS
vii
7.3
Other Insertions,
191
7.4
α, β, γ,
and
δ
Elimination,
192
8
Nucleophilic and Electrophilic Addition and Abstraction
199
8.1
Nucleophilic Addition to CO,
202
8.2
Nucleophilic Addition to Polyene and Polyenyl Ligands,
204
8.3
Nucleophilic Abstraction in Hydrides, Alkyls, and Acyls,
212
8.4
Electrophilic Addition,
213
8.5
Electrophilic Abstraction of
Alkyl
Groups,
216
8.6
Single-Electron Transfer Pathways,
218
8.7
Reactions of Organic Free Radicals with Metal
Complexes,
219
9
Homogeneous Catalysis
225
9.1
Alkene Isomerization,
229
9.2
Alkene
Hydrogénation,
231
9.3
Alkene Hydroformylation,
244
9.4
Hydrocyanation of Butadiene,
247
9.5
Alkene Hydrosilylation and Hydroboration,
250
9.6
Coupling Reactions,
252
9.7
Organometallic
Oxidase
Reactions,
254
9.8
Surface and Supported Organometallic Catalysis,
255
10
Physical Methods in Organometallic Chemistry
263
10.1
Isolation,
263
10.2
H NMR
Spectroscopy,
264
10.3
13C NMR Spectroscopy,
268
10.4
31P NMR Spectroscopy,
270
10.5
Dynamic NMR,
272
10.6
Spin Saturation Transfer,
276
10.7
Γι
and the Nuclear Overhauser Effect,
277
10.8
Isotopie
Perturbation of Resonance,
280
10.9
IR
Spectroscopy,
283
10.10
Crystallography,
286
10.11
Other Methods,
288
11
Metal-Ligand
Multiple Bonds
296
11.1
Carbenes,
296
11.2
Carbynes,
311
11.3
Bridging Carbenes and Carbynes,
313
11.4
N-Heterocyclic Carbenes,
315
11.5
Multiple Bonds to
Heteroatoms,
319
yiü CONTENTS
12
Applications
of Organometallic Chemistry
327
12.1
Alkene
Metathesis,
327
12.2
Dimerization, Oligomerization,
and Polymerization of
Alkenes,
334
12.3
Activation of
CO and CO2,
343
12.4
C
-Н
Activation,
348
12.5
Organometallic Materials
and Polymers,
354
13
Clusters,
Nanopartides, Materials,
and Surfaces
361
13.1
Cluster
Structures,
362
13.2
Structures,
362
13.3
The Isolobal Analogy,
374
13.4
Nanopartides,
378
13.5
Giant Molecules,
381
13.6
Organometallic Materials,
381
14
Applications to Organic Synthesis
388
14.1
Catalyzed Carbon-Carbon and Carbon-Heteroatom Bond
Formation,
389
14.2
Metathesis,
396
14.3
Rhodium Carbenes in Cyclopropanation and
C—H
Insertion,
397
14.4
Hydrogénation
and Related Reactions,
399
14.5
Carbonylation,
401
14.6
Oxidation,
405
14.7
C
-Н
Activation,
408
14.8
Click Chemistry,
412
14.9
Noncatalytic Reactions,
413
15
Paramagnetic, High-Oxidation-State, and High-Coordination-
Number Complexes
421
15.1
Magnetism and Spin States,
422
15.2
Polyalkyls,
429
15.3
Polyhydrides,
434
15.4
Cyclopentadienyl Complexes,
437
15.5
/-Block Complexes,
439
16
Bioorganometallic Chemistry
448
16.1
Introduction,
448
16.2
Coenzyme B12,
454
16.3
Nitrogen Fixation,
460
CONTENTS ix
16.4 Nickel
Enzymes,
467
16.5
Biomedical Applications,
472
Useful Texts on Allied Topics
477
Major Reaction Types
479
Solutions to Problems
481
Index
4%
One impressive and
compressive
book.
. . .
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ІП
this Volume. —Journal of Metals Online
Fully updated and expanded to reflect recent advances, this Fifth Edition of
the classic text provides students and professional chemists with a compre¬
hensive introduction to the principles and general properties of organometallic
compounds, as well as including practical information on reaction mechanisms
and detailed descriptions of contemporary applications. With increased focus on
organic synthesis applications, nanoparticle science, and green chemistry, the
Fifth Edition brings this vital resource up to date.
New to the Fifth Edition·.
Chapters have been updated with relevant examples in the field, mod¬
ern trends, and new applications; the organic applications chapter has
been completely rewritten
New end-of-chapter problems, along with their solutions
Coverage enhanced with developments in nanoparticle science
Increased focus on green chemistry
An unparalleled pedagogic resource as well as a valuable working reference for
professional chemists, with comprehensive coverage and up-to-date information,
students and researchers in organic and organometallic chemistry will turn to
The Organometallic Chemistry of the Transition Metals, Fifth Edition for the
critical information they need on organometallic compounds, their preparation,
and their use in synthesis.
//,
ROBERT H. CRABTREE, PhD,
¡s a
professor in the Department of Chemistry
Yale University.
at
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| discipline | Chemie / Pharmazie Chemie |
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| spelling | Crabtree, Robert H. Verfasser aut The organometallic chemistry of the transition metals Robert H. Crabtree 5. ed. Hoboken, NJ Wiley 2009 XIII, 505 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Organometaalcomplexen gtt Overgangsmetaalcomplexen gtt Organotransition metal compounds Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 gnd rswk-swf Übergangsmetallkomplexe (DE-588)4131837-7 s Übergangsmetallorganische Verbindungen (DE-588)4417301-5 s 1\p DE-604 DE-604 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017693720&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017693720&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext 1\p cgwrk 20201028 DE-101 https://d-nb.info/provenance/plan#cgwrk |
| spellingShingle | Crabtree, Robert H. The organometallic chemistry of the transition metals Organometaalcomplexen gtt Overgangsmetaalcomplexen gtt Organotransition metal compounds Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| subject_GND | (DE-588)4417301-5 (DE-588)4131837-7 |
| title | The organometallic chemistry of the transition metals |
| title_auth | The organometallic chemistry of the transition metals |
| title_exact_search | The organometallic chemistry of the transition metals |
| title_full | The organometallic chemistry of the transition metals Robert H. Crabtree |
| title_fullStr | The organometallic chemistry of the transition metals Robert H. Crabtree |
| title_full_unstemmed | The organometallic chemistry of the transition metals Robert H. Crabtree |
| title_short | The organometallic chemistry of the transition metals |
| title_sort | the organometallic chemistry of the transition metals |
| topic | Organometaalcomplexen gtt Overgangsmetaalcomplexen gtt Organotransition metal compounds Übergangsmetallorganische Verbindungen (DE-588)4417301-5 gnd Übergangsmetallkomplexe (DE-588)4131837-7 gnd |
| topic_facet | Organometaalcomplexen Overgangsmetaalcomplexen Organotransition metal compounds Übergangsmetallorganische Verbindungen Übergangsmetallkomplexe |
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