Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts: applications in olefin metathesis and olefin epoxidation
Saved in:
| Main Author: | |
|---|---|
| Format: | Thesis Book |
| Language: | English |
| Published: |
München
Verl. Dr. Hut
2009
|
| Edition: | 1. Aufl. |
| Series: | Anorganische Chemie
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XII, 165 S. graph. Darst. 210 mm x 148 mm, 233 gr. |
| ISBN: | 9783868530667 |
Staff View
MARC
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| 245 | 1 | 0 | |a Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts |b applications in olefin metathesis and olefin epoxidation |c Draganco Veljanovski |
| 250 | |a 1. Aufl. | ||
| 264 | 1 | |a München |b Verl. Dr. Hut |c 2009 | |
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Record in the Search Index
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| adam_text | CONTENTS IX CONTENTS ABBREVIATIONS 1 1. INTRODUCTION 3 1.1. INDUSTRIAL
CATALYSIS 6 1.2. HETEROGENEOUS AND HOMOGENEOUS CATALYST 7 1.3. OUTLOOK
10 1. EPOXIDATION 11 2. INTRODUCTION 13 2.1. RHENIUM CATALYSTS IN THE
EPOXIDATION OF OLEFINS 16 2.1.1. DIRHENIUM HEPTAOXIDE AND DERIVATIVES 16
2.1.2. THE CARBOXYLATO RHENIUM COMPLEXES 17 2.1.3. MTO SYNTHESIS AND
USEAGE AS EPOXIDATION CATALYST 20 2.1.4. MTO AS A HETEROGENEOUS CATALYST
23 2.2. MOLYBDENUM CATALYSTS IN THE EPOXIDATION OF OLEFINS 26 2.2.1.
DIOXOMOLYBDENUM(VI) COMPLEXES WITH MO-C CR-BONDS 26 2.2.2.
DIOXOMOLYBDENUM(VI) COMPLEXES WITH CYCLOPENTADIENYL LIGANDS 27 2.2.3.
MECHANISTIC INSIGHTS INTO THE EPOXIDATION VNTH MOLYBDENUM CATALYSTS. . .
33 3. SYNTHESIS OF A NOVEL HETEROGENEOUS RHENIUM CATALYST FOR OLEFIN
EPOXIDATION 39 3.1. MOBIL CRYSTALLINE OF MATERIALS (MCM) 39 3.2. THE
GRAFTING OF ACYLPERRHENATE ON MESOPOROUS SIEVES 40 3.2.1. A MODEL OF THE
GRAFTING PROCESS 43 BIBLIOGRAFISCHE INFORMATIONEN
HTTP://D-NB.INFO/994584644 DIGITALISIERT DURCH X CONTENTS 3.2.2.
CATALYTIC APPLICATIONS 45 4. KINETIC STUDIES ON THE OXIDATION OF
CPMO(CO) 3 CH 3 49 4.1. REACTION OF CPMO(O 2 )OCH 3 WITH TBHP 54 4.2.
CATALYTIC EPOXIDATION 57 4.2.1. EPOXIDATION CATALYZED BY CPMO(CO) 3 CH 3
57 4.2.2. EPOXIDATION CATALYZED BY CPMO(O 2 )OCH 3 59 4.2.3. EPOXIDATION
CATALYZED BY CPMOO 2 CH 3 63 II. OLEFIN METATHESIS 65 5. INTRODUCTION 67
5.1. MECHANISTIC STUDIES AND THE DEVELOPMENT OF ORGANOMETALLIC CATALYSTS
72 5.1.1. THE ELUCIDATION OF THE OLEFIN METATHESIS MECHANISM 72 5.1.2.
THE DISCOVERY AND DEVELOPMENT OF THE SCHROCK CATALYST 74 5.1.3. THE
DISCOVERY AND DEVELOPMENT OF THE GRUBBS CATALYST 78 5.2. HETEROGENEOUS
CATALYSTS IN THE OLEFIN METATHESE 82 5.2.1. OLEFIN METATHESIS CATALYSTST
ON SILICA SURFACES 83 5.2.2. MTO ON 7 - AL 2 0 3 . (5 OO) 86 5.2.3. THE
REACTION MECHANISM AND DEACTIVATION PATHWAYS 90 6.
CPMOICOJJCHJ/^-A^OJ.^OO). A HETEROGENEOUS CATALYST FOR OLEFIN METATHESIS
93 6.1. AN ESTIMATION OF THE PKA-VALUE OF CPMO(CO) 3 CH CONTENTS XI
7.1.1. IR SPECTROSCOPY 108 7.1.2. MASS BALANCE ANALYSIS 109 7.1.3. NMR
SPECTROSCOPY 109 7.2. PROPENE METATHESIS WITH (CH 3 ) 3 REO 2 ON 7-AL 2
0 3 .( 50 O) 109 7.3. PROPENE METATHESIS WITH (CH 3 ) 3 RE0 2 ON 7-AL 2
0 3 .(5OO) IN A FLOW REACTOR 110 III. EXPERIMENTAL PROCEDURES 117 8.
GENERAL PROCEDURES 119 8.1. IR SPECTROSCOPY 119 8.2. NMR SPECTROSCOPY
120 8.3. THE POWER X-RAY DIFFRACTION 120 8.4. THE LOW TEMPERATURE N 2
ADSORPTION/DESORPTION ISOTHERMS 120 9. THE SYNTHESIS OF THE CATALYST
PRECURSORS 123 9.1. PREPARATION OF CPMO(O) 2 OCH 3 123 9.2. SINGLE
CRYSTAL DETERMINATION OF CPMO(O 2 )OCH 3 123 9.3. PREPARATION OF CPMO(
13 CO) 3 CH 3 124 9.4. PREPARATION OF CPMO(CO) 313 CH 3 125 9.5.
PREPARATION OF TRIMETHYLSILYL PERRHENATE 125 9.6 XII CONTENTS 11.3.
REACTIVITY OF CPMO(CO) 3 CH 3 ON 7-AL 2 0 3 - (5 OO) AND 13 C DI -
LABELED ETHENE ... 132 11.4. REACTIVITY OF (CH 3 ) 3 RE0 2 ON 7-AL 2 0 3
.(5OO) WITH PROPENE 132 11.5. REACTIVITY OF (CH 3 ) 3 RE0 2 ON 7-AL 2 0
3 _(5OO) WITH PROPENE IN FLOW REACTOR 132 12. THE KINETIC STUDIES 133
12.1. H-D EXCHANGE IN CPMO(CO) 3 CH 3 134 IV. CONCLUSIONS AND
PERSPECTIVES 135 13. ACYLPERRHENATE ON MESOPOROUSE SILICA 137
14.CATALYTIC EPOXIDATION WITH CPMO(CO) 3 CH 3 139 15.CPMO(CO) 3 CH 3 ON
7-AI 2 0 3 .( 5 OO) AS A CATALYST FOR OLEFIN METATHESIS 143 16.(CH 3 ) 3
REO 2 ON 7-AI 2 0
|
| any_adam_object | 1 |
| author | Veljanovski, Draganco 1980- |
| author_GND | (DE-588)137997418 |
| author_facet | Veljanovski, Draganco 1980- |
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| building | Verbundindex |
| bvnumber | BV035556820 |
| classification_tum | CHE 330d CHE 658d CIT 325d |
| ctrlnum | (OCoLC)645094153 (DE-599)DNB994584644 |
| dewey-full | 547.215 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 547 - Organic chemistry |
| dewey-raw | 547.215 |
| dewey-search | 547.215 |
| dewey-sort | 3547.215 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie Chemie Chemie-Ingenieurwesen |
| edition | 1. Aufl. |
| format | Thesis Book |
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| id | DE-604.BV035556820 |
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| indexdate | 2024-07-09T21:40:22Z |
| institution | BVB |
| isbn | 9783868530667 |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017612622 |
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| physical | XII, 165 S. graph. Darst. 210 mm x 148 mm, 233 gr. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Verl. Dr. Hut |
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| series2 | Anorganische Chemie |
| spelling | Veljanovski, Draganco 1980- Verfasser (DE-588)137997418 aut Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts applications in olefin metathesis and olefin epoxidation Draganco Veljanovski 1. Aufl. München Verl. Dr. Hut 2009 XII, 165 S. graph. Darst. 210 mm x 148 mm, 233 gr. txt rdacontent n rdamedia nc rdacarrier Anorganische Chemie Zugl.: München, Techn. Univ., Diss., 2009 Alkene (DE-588)4001207-4 gnd rswk-swf Trägerkatalysator (DE-588)4185817-7 gnd rswk-swf Epoxidation (DE-588)4152560-7 gnd rswk-swf Metathese Chemie (DE-588)4169656-6 gnd rswk-swf Molybdänkomplexe (DE-588)4223139-5 gnd rswk-swf Rheniumkomplexe (DE-588)4223129-2 gnd rswk-swf (DE-588)4113937-9 Hochschulschrift gnd-content Trägerkatalysator (DE-588)4185817-7 s Rheniumkomplexe (DE-588)4223129-2 s Molybdänkomplexe (DE-588)4223139-5 s Alkene (DE-588)4001207-4 s Metathese Chemie (DE-588)4169656-6 s Epoxidation (DE-588)4152560-7 s DE-604 DNB Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017612622&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Veljanovski, Draganco 1980- Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts applications in olefin metathesis and olefin epoxidation Alkene (DE-588)4001207-4 gnd Trägerkatalysator (DE-588)4185817-7 gnd Epoxidation (DE-588)4152560-7 gnd Metathese Chemie (DE-588)4169656-6 gnd Molybdänkomplexe (DE-588)4223139-5 gnd Rheniumkomplexe (DE-588)4223129-2 gnd |
| subject_GND | (DE-588)4001207-4 (DE-588)4185817-7 (DE-588)4152560-7 (DE-588)4169656-6 (DE-588)4223139-5 (DE-588)4223129-2 (DE-588)4113937-9 |
| title | Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts applications in olefin metathesis and olefin epoxidation |
| title_auth | Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts applications in olefin metathesis and olefin epoxidation |
| title_exact_search | Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts applications in olefin metathesis and olefin epoxidation |
| title_full | Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts applications in olefin metathesis and olefin epoxidation Draganco Veljanovski |
| title_fullStr | Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts applications in olefin metathesis and olefin epoxidation Draganco Veljanovski |
| title_full_unstemmed | Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts applications in olefin metathesis and olefin epoxidation Draganco Veljanovski |
| title_short | Synthesis and characterization of heterogeneous rhenium and molybdenum catalysts |
| title_sort | synthesis and characterization of heterogeneous rhenium and molybdenum catalysts applications in olefin metathesis and olefin epoxidation |
| title_sub | applications in olefin metathesis and olefin epoxidation |
| topic | Alkene (DE-588)4001207-4 gnd Trägerkatalysator (DE-588)4185817-7 gnd Epoxidation (DE-588)4152560-7 gnd Metathese Chemie (DE-588)4169656-6 gnd Molybdänkomplexe (DE-588)4223139-5 gnd Rheniumkomplexe (DE-588)4223129-2 gnd |
| topic_facet | Alkene Trägerkatalysator Epoxidation Metathese Chemie Molybdänkomplexe Rheniumkomplexe Hochschulschrift |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017612622&sequence=000001&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT veljanovskidraganco synthesisandcharacterizationofheterogeneousrheniumandmolybdenumcatalystsapplicationsinolefinmetathesisandolefinepoxidation |