Modern optical spectroscopy: with exercises and examples from biophysics and biochemistry
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Dordrecht [u.a.]
Springer
2009
|
| Edition: | 1. student ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Literaturverz. S. 465 - 504 |
| Physical Description: | XII, 530 S. Ill., graph. Darst. |
| ISBN: | 9783540958956 |
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MARC
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| 245 | 1 | 0 | |a Modern optical spectroscopy |b with exercises and examples from biophysics and biochemistry |c William W. Parson |
| 250 | |a 1. student ed. | ||
| 264 | 1 | |a Dordrecht [u.a.] |b Springer |c 2009 | |
| 300 | |a XII, 530 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
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Record in the Search Index
| _version_ | 1804139195652898816 |
|---|---|
| adam_text | Titel: Modern optical spectroscopy
Autor: Parson, William W.
Jahr: 2009
Contents
1 Introduction 1
1.1 Overview................................................................................ 1
1.2 The Beer-Lambert Law............................................................ 3
1.3 Regions of the Electromagnetic Spectrum................................... 4
1.4 Absorption Spectra of Proteins and Nucleic Acids........................ 6
1.5 Absorption Spectra of Mixtures................................................. 8
1.6 The Photoelectric Effect........................................................... 9
1.7 Techniques for Measuring Absorbance........................................ 10
1.8 Pump-Probe and Photon-Echo Experiments............................... 13
1.9 Linear and Circular Dichroism.................................................. 15
1.10 Distortions of Absorption Spectra by Light Scattering
or Nonuniform Distributions of the Absorbing Molecules............. 17
1.11 Fluorescence........................................................................... 19
1.12 IR and Raman Spectroscopy...................................................... 24
1.13 Lasers.................................................................................... 25
1.14 Nomenclature......................................................................... 26
2 Basic Concepts of Quantum Mechanics 29
2.1 Wavefunctions, Operators, and Expectation Values....................... 29
2.1.1 Wavefunctions ............................................................. 29
2.1.2 Operators and Expectation Values.................................... 30
2.2 The Time-Dependent
and Time-Independent Schrodinger Equations............................ 36
2.2.1 Superposition States...................................................... 41
2.3 Spatial Wavefunctions.............................................................. 42
2.3.1 A Free Particle.............................................................. 42
2.3.2 A Particle in a Box......................................................... 43
2.3.3 The Harmonic Oscillator ............................................... 46
2.3.4 Atomic Orbitals............................................................ 48
2.3.5 Molecular Orbitals......................................................... 51
2.3.6 Approximate Wavefunctions for Large Systems.................. 57
2.4 Spin Wavefunctions and Singlet and Triplet States........................ 57
2.5 Transitions Between States: Time-Dependent Perturbation Theory. 65
2.6 Lifetimes of States and the Uncertainty Principle.......................... 68
Contents
Light 73
3.1 Electromagnetic Fields............................................................. 73
3.1.1 Electrostatic Forces and Fields......................................... 73
3.1.2 Electrostatic Potentials................................................... 74
3.1.3 Electromagnetic Radiation............................................. 76
3.1.4 Energy Density and Irradiance........................................ 83
3.1.5 The Complex Electric Susceptibility and Refractive Index ... 90
3.1.6 Local-Field Correction Factors........................................ 94
3.2 The Black-Body Radiation Law.................................................. 96
3.3 Linear and Circular Polarization................................................ 98
3.4 Quantum Theory of Electromagnetic Radiation........................... 100
3.5 Superposition States and Interference Effects in Quantum Optics... 104
3.6 Distribution of Frequencies in Short Pulses of Light...................... 106
Electronic Absorption 109
4.1 Interactions of Electrons with Oscillating Electric Fields............... 109
4.2 The Rates of Absorption and Stimulated Emission........................ 113
4.3 Transition Dipoles and Dipole Strengths..................................... 118
4.4 Calculating Transition Dipoles for n Molecular Orbitals................ 126
4.5 Molecular Symmetry and Forbidden and Allowed Transitions....... 128
4.6 Linear Dichroism..................................................................... 142
4.7 Configuration Interactions........................................................ 148
4.8 Calculating Electric Transition Dipoles with the Gradient Operator 152
4.9 Transition Dipoles for Excitations to Singlet and Triplet States....... 161
4.10 The Born-Oppenheimer Approximation, Franck-Condon Factors,
and the Shapes of Electronic Absorption Bands........................... 163
4.11 Spectroscopic Hole-Burning...................................................... 171
4.12 Effects of the Surroundings on Molecular Transition Energies........ 174
4.13 The Electronic Stark Effect........................................................ 182
Fluorescence 189
5.1 The Einstein Coefficients.......................................................... 189
5.2 The Stokes Shift....................................................................... 192
5.3 The Mirror-Image Law............................................................. 195
5.4 The Strickler-Berg Equation and Other Relationships
Between Absorption and Fluorescence........................................ 197
5.5 Quantum Theory of Absorption and Emission............................. 203
5.6 Fluorescence Yields and Lifetimes.............................................. 208
5.7 Fluorescent Probes and Tags...................................................... 214
5.8 Photobleaching....................................................................... 218
5.9 Fluorescence Anisotropy........................................................... 219
5.10 Single-Molecule Fluorescence and High-Resolution Fluorescence
Microscopy............................................................................. 225
5.11 Fluorescence Correlation Spectroscopy....................................... 231
5.12 Intersystem Crossing, Phosphorescence, and Delayed Fluorescence 238
Contents XI
6 Vibrational Absorption 241
6.1 Vibrational Normal Modes and Wavefunctions............................ 241
6.2 Vibrational Excitation.............................................................. 247
6.3 IRSpectroscopy of Proteins....................................................... 253
6.4 Vibrational Stark Effects........................................................... 256
7 Resonance Energy Transfer 259
7.1 Introduction........................................................................... 259
7.2 The Forster Theory.................................................................. 261
7.3 Exchange Coupling.................................................................. 275
7.4 Energy Transfer to and from Carotenoids in Photosynthesis.......... 277
8 Exciton Interactions 281
8.1 Stationary States of Systems with Interacting Molecules................ 281
8.2 Effects of Exciton Interactions on the Absorption Spectra
ofOligomers........................................................................... 290
8.3 Transition-Monopole Treatments of Interaction Matrix Elements
and Mixing with Charge-Transfer Transitions.............................. 295
8.4 Exciton Absorption Band Shapes and Dynamic Localization
of Excitations.......................................................................... 298
8.5 Exciton States in Photosynthetic Antenna Complexes................... 301
8.6 Excimers and Exciplexes........................................................... 304
9 Circular Dichroism 307
9.1 Magnetic Transition Dipoles and n-n* Transitions....................... 307
9.2 The Origin of Circular Dichroism.............................................. 317
9.3 Circular Dichroism of Dimers and Higher Oligomers.................... 322
9.4 Circular Dichroism of Proteins and Nucleic Acids........................ 328
9.5 Magnetic Circular Dichroism.................................................... 332
10 Coherence and Dephasing 335
10.1 Oscillations Between Quantum States of an Isolated System........... 335
10.2 The Density Matrix.................................................................. 339
10.3 The Stochastic Liouville Equation.............................................. 344
10.4 Effects of Stochastic Relaxations on the Dynamics
of Quantum Transitions............................................................ 346
10.5 A Density-Matrix Treatment of Steady-State Absorption............... 352
10.6 The Relaxation Matrix.............................................................. 355
10.7 More General Relaxation Functions and Spectral Lineshapes......... 364
10.8 Anomalous Fluorescence Anisotropy.......................................... 370
11 Pump-Probe Spectroscopy, Photon Echoes,
and Vibrational Wavepackets 377
11.1 First-Order Optical Polarization................................................377
XII Contents
11.2 Third-Order Optical Polarization
and Nonlinear Response Functions............................................386
11.3 Pump-Probe Spectroscopy........................................................391
11.4 Photon Echoes........................................................................395
11.5 Transient Gratings................................................................... 401
11.6 Vibrational Wavepackets........................................................... 404
11.7 Wavepacket Pictures of Spectroscopic Transitions........................413
12 Raman Scattering and Other Multiphoton Processes 417
12.1 Types of Light Scattering........................................................... 417
12.2 The Kramers-Heisenberg-Dirac Theory..................................... 422
12.3 The Wavepacket Picture of Resonance Raman Scattering............... 430
12.4 Selection Rules for Raman Scattering......................................... 432
12.5 Surface-Enhanced Raman Scattering..........................................435
12.6 Biophysical Applications of Raman Spectroscopy.........................436
12.7 Coherent Raman Scattering.......................................................437
12.8 Multiphoton Absorption........................................................... 439
12.9 Quasielastic (Dynamic) Light Scattering
(Photon Correlation Spectroscopy)............................................442
Appendix 1 - Vectors 447
Appendix 2 - Matrices 451
Appendix 3 - Fourier Transforms 455
Appendix 4 - Fluorescence Phase Shift and Modulation 459
Appendix 5 - CGS and SI Units and Abbreviations 463
References 465
Exercises 505
Subject Index 523
|
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| author | Parson, William W. |
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| classification_tum | CHE 236f CHE 160f CHE 808f |
| ctrlnum | (OCoLC)403981945 (DE-599)DNB992498619 |
| dewey-full | 535.84 |
| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 535 - Light and related radiation |
| dewey-raw | 535.84 |
| dewey-search | 535.84 |
| dewey-sort | 3535.84 |
| dewey-tens | 530 - Physics |
| discipline | Chemie / Pharmazie Physik Biologie Chemie |
| edition | 1. student ed. |
| format | Book |
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| illustrated | Illustrated |
| indexdate | 2024-07-09T21:40:14Z |
| institution | BVB |
| isbn | 9783540958956 |
| language | English |
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| physical | XII, 530 S. Ill., graph. Darst. |
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| spelling | Parson, William W. Verfasser (DE-588)1141916215 aut Modern optical spectroscopy with exercises and examples from biophysics and biochemistry William W. Parson 1. student ed. Dordrecht [u.a.] Springer 2009 XII, 530 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Literaturverz. S. 465 - 504 Optical spectroscopy Optische Spektroskopie (DE-588)4043680-9 gnd rswk-swf Optische Spektroskopie (DE-588)4043680-9 s DE-604 Erscheint auch als Online-Ausgabe 978-3-540-37542-5 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017606787&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Parson, William W. Modern optical spectroscopy with exercises and examples from biophysics and biochemistry Optical spectroscopy Optische Spektroskopie (DE-588)4043680-9 gnd |
| subject_GND | (DE-588)4043680-9 |
| title | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry |
| title_auth | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry |
| title_exact_search | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry |
| title_full | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry William W. Parson |
| title_fullStr | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry William W. Parson |
| title_full_unstemmed | Modern optical spectroscopy with exercises and examples from biophysics and biochemistry William W. Parson |
| title_short | Modern optical spectroscopy |
| title_sort | modern optical spectroscopy with exercises and examples from biophysics and biochemistry |
| title_sub | with exercises and examples from biophysics and biochemistry |
| topic | Optical spectroscopy Optische Spektroskopie (DE-588)4043680-9 gnd |
| topic_facet | Optical spectroscopy Optische Spektroskopie |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017606787&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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