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Thermodynamics: from concepts to applications

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Bibliographic Details
Main Authors:	Shavit, Arthur (Author), Gutfinger, Chaim (Author)
Format:	Book
Language:	English
Published:	Boca Raton, Fla. [u.a.] CRC Press 2009
Edition:	2. ed.
Subjects:	Teorias da termodinâmica Termodinâmica Thermodynamique - Manuels d'enseignement supérieur Thermodynamics Thermodynamik
Online Access:	Inhaltsverzeichnis
Physical Description:	XV, 649 S. Ill., graph. Darst.
ISBN:	9781420073683

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adam_text	Contents Preface for Students ..........................................................................................................xi Preface for Instructors ....................................................................................................xiii Authors .............................................................................................................................xv 1 Introduction ..............................................................................................................1 1.1 Historical Background ...............................................................................................1 1.2 Applications of Thermodynamics ............................................................................3 2 Basic Concepts ...........................................................................................................5 2.1 Thermodynamic System ............................................................................................6 2.2 Properties and States ..................................................................................................7 2.2.1 Identical States ...............................................................................................7 2.2.2 Path ..................................................................................................................7 2.2.3 Interaction ......................................................................................................7 2.2.4 Process ............................................................................................................8 2.2.5 Cycle ................................................................................................................8 2.2.6 General Definition of Property ...................................................................8 2.2.7 Derived Properties ........................................................................................9 2.2.8 Extensive and Intensive Properties ............................................................9 2.2.9 Quantity of Matter ........................................................................................9 2.2.10 Specific Property .........................................................................................10 2.2.11 Density ..........................................................................................................10 2.3 Some Characteristics of Properties ........................................................................11 2.4 Equilibrium ...............................................................................................................12 2.5 Stable Equilibrium ....................................................................................................13 2.5.1 Other Types of Equilibria ..........................................................................14 2.6 Mutual Equilibrium .................................................................................................15 2.7 Zeroth Law of Thermodynamics ...........................................................................15 Problems ...............................................................................................................................16 3 Work, Energy, and Heat: First Law of Thermodynamics ..................................21 3.1 Work in Mechanical Systems ..................................................................................21 3.2 Work in Thermodynamic Systems .........................................................................21 3.2.1 Example: Where Work Cannot Be Identified ..........................................23 3.3 Measure of Work .......................................................................................................24 3.4 Adiabatic Process ......................................................................................................24 3.5 Work in Nonadiabatic Processes ............................................................................25 3.6 Work at Moving Boundary ......................................................................................25 3.7 Work of Compressible System ................................................................................26 3.8 Quasistatic Process and Quasistatic Work ............................................................27 3.9 First Law of Thermodynamics ................................................................................29 3.10 Work, Heat, and Energy ...........................................................................................31 3.11 Temperature ..............................................................................................................32 3.12 Units and Dimensions .............................................................................................33 Problems ...............................................................................................................................35 vi Contents 4 Simple Systems.......................................................................................................43 4.1 Independent and Dependent Properties ...............................................................43 4.2 State Principle ............................................................................................................43 4.3 Simple Systems ..........................................................................................................44 4.4 Equations of State .....................................................................................................45 4.5 Internal Energy .........................................................................................................46 4.6 Basic Processes in Simple Systems .........................................................................48 4.6.1 Constant-Volume Process ...........................................................................48 4.6.2 Constant-Pressure Process .........................................................................50 4.7 Pure Substances ........................................................................................................54 4.8 Intensive State ...........................................................................................................54 4.9 Phases .........................................................................................................................54 4.10 Properties of Pure Substance ..................................................................................54 4.10.1 The Т -p Diagram .........................................................................................55 4.10.2 The p-v Diagram .........................................................................................56 4.11 Tables of Thermodynamic Properties ....................................................................58 4.11.1 Structure of the Steam Tables ....................................................................58 4.11.2 Using Steam Tables .....................................................................................59 4.11.3 Interpolation ................................................................................................60 4.11.4 Engineering Equation Solver Software ....................................................64 4.12 First Law of Thermodynamics for Simple Systems .............................................65 4.12.1 Methodology for Solving Problems .........................................................65 4.13 Summary of Equations for Simple Systems ..........................................................69 Problems ...............................................................................................................................70 5 Ideal Gas ..................................................................................................................83 5.1 Definition of an Ideal Gas ........................................................................................83 5.2 Internal Energy and Enthalpy of an Ideal Gas .....................................................85 5.3 Ideal Gas with Constant Specific Heat ..................................................................86 5.4 Quasistatic Processes in an Ideal Gas ....................................................................88 5.5 Polytropic Process .....................................................................................................90 5.6 Applications of First Law to Ideal Gas Systems ...................................................92 5.7 Summary of Equations for an Ideal Gas ...............................................................95 Problems ...............................................................................................................................96 6 Control Volume .....................................................................................................107 6.1 Transition from System to Control Volume ........................................................107 6.2 Conservation of Mass for a Control Volume ......................................................109 6.3 First Law of Thermodynamics fora Control Volume .......................................110 6.4 Steady State Processes ............................................................................................112 6.4.1 Nozzles and Diffusers ..............................................................................114 6.4.2 Throttling Devices ....................................................................................115 6.4.3 Turbines, Compressors, and Pumps .......................................................117 6.4.4 Heat Exchangers ........................................................................................118 6.5 Unsteady State Processes in Control Volumes ...................................................120 6.6 One-Port Control Volumes ....................................................................................120 6.6.1 Charging a Vessel ......................................................................................121 6.6.2 Discharging a Vessel ................................................................................124 6.7 Summary of Equations for a Control Volume ......................................................126 Problems .............................................................................................................................127 Contents vii 7 Heat Engines and Second Law of Thermodynamics .......................................141 7.1 Heat Engines ...........................................................................................................141 7.2 Efficiency of Heat Engines .....................................................................................143 7.3 Second Law of Thermodynamics .........................................................................146 7.4 Reversibility .............................................................................................................147 7.5 Internally Reversible Process ................................................................................150 76 Carnot Cycle ............................................................................................................151 7.7 Efficiency and the Reversible Engine ..................................................................152 7.8 Thermodynamic Temperature Scale ....................................................................153 7.9 Summary of Equations for Heat Engines and Second Law .............................156 Problems .............................................................................................................................157 8 Entropy ...................................................................................................................163 8.1 Clausius Inequality ................................................................................................163 8.2 Entropy .....................................................................................................................165 8.3 Entropy Change for Any Process .........................................................................166 8.4 Principle of Increase of Entropy ...........................................................................167 8.5 Calculating Entropy Change in an Irreversible Process ...................................168 8.6 Entropy Equations ..................................................................................................170 8.7 Using Entropy Data from Tables ..........................................................................171 8.8 Entropy Change of an Ideal Gas ...........................................................................172 8.9 Entropy Change of an Incompressible Substance ..............................................175 8.10 Entropy Diagrams ..................................................................................................176 8.11 Second Law Analysis of Control Volumes ..........................................................180 Problems .............................................................................................................................181 9 Applications of Second Law of Thermodynamics ...........................................199 9.1 Work in Expansion and Compression Processes ...............................................201 9.2 Effectiveness of Adiabatic Processes ...................................................................206 9.3 Work and Heat in Isothermal Processes .............................................................208 9.4 Effectiveness of Heat Exchangers .........................................................................211 9.5 Test for the Impossibility of a Process .................................................................214 9.6 Summary of Equations ..........................................................................................216 Problems .............................................................................................................................218 10 Availability, Exergy, and Irreversibility ...........................................................237 10.1 Available Work ........................................................................................................237 10.2 Useful Work .............................................................................................................241 10.3 Irreversibility ...........................................................................................................242 10.4 Availability ..............................................................................................................244 10.5 Control Volume Analysis: Exergy ........................................................................248 Problems .............................................................................................................................256 11 Power and Refrigeration Cycles .........................................................................271 11.1 Rankine Cycle .........................................................................................................272 11.2 Rankine Cycle Modifications ................................................................................276 11.2.1 Reheat Cycle ...............................................................................................276 11.2.2 Regenerative Cycle ....................................................................................276 11.3 Brayton Cycle ...........................................................................................................281 11.3.1 Jet Engines ..................................................................................................286 11.3.2 Regenerative Brayton Cycle .....................................................................288 viu Contents 11.4 Cycles for Internal Combustion Engines ...........................................................290 11.5 Otto Cycle ...............................................................................................................291 11.6 Diesel Cycle ............................................................................................................293 11.7 Dual Cycle ..............................................................................................................294 11.8 Ref rigeration Cycles ..............................................................................................295 11.9 Basic Refrigeration Cycle ......................................................................................295 11.10 Internal Heat Exchanger .......................................................................................299 11.11 Refrigeration with Two-Stage Compression ......................................................304 11.12 Exergy Analysis .....................................................................................................305 11.13 Summary of Equations .........................................................................................312 Problems .............................................................................................................................312 12 Ideal Gas Mixtures and Humid Air ...................................................................337 12.1 Basic Definitions for Gaseous Mixtures .............................................................337 12.2 Equation of State for a Mixture of Ideal Gases ..................................................338 12.2.1 Dalton s Model ........................................................................................339 12.2.2 Amagat s Model ......................................................................................340 12.3 Properties of Mixtures of Ideal Gases ................................................................341 12.4 Gaseous Mixtures Involving a Condensable Component ...............................344 12.5 Moist Air .................................................................................................................345 12.6 First Law for Moist Air .........................................................................................346 12.7 Adiabatic Saturation .............................................................................................347 12.8 Wet-Bulb Temperature ..........................................................................................349 12.9 Psychrometric Chart .............................................................................................349 12.10 Processes in Moist Air ..........................................................................................351 12.10.1 Heating ....................................................................................................351 12.10.2 Cooling and Dehumidification ............................................................351 12.10.3 Wetting Moist Air ..................................................................................353 12.10.4 Mixing of Moist Air Streams ................................................................355 12.11 Cooling Towers ......................................................................................................356 12.12 Exergy Analysis .....................................................................................................358 12.13 Summary of Equations .........................................................................................359 Problems .............................................................................................................................362 13 Thermodynamic Relations ..................................................................................373 13.1 Some Mathematical Relations .............................................................................373 13.2 Maxwell Relations .................................................................................................375 13.3 Clapeyron Equation ..............................................................................................378 13.4 Specific Heats .........................................................................................................380 13.5 Energy and Enthalpy Variations at Constant Temperature ............................382 13.6 Joule-Thomson Coefficient ..................................................................................383 13.7 Volume Change Coefficients ................................................................................384 13.8 Summary of Equations ........................................................................................386 Problems .............................................................................................................................387 14 Equations of State and Generalized Charts ......................................................393 14.1 van der Waals Equation ........................................................................................393 14.2 Dieterici Equation ..................................................................................................397 14.3 Empirical Equations of State ................................................................................398 14.4 VirialForm of Equation of State ..........................................................................399 Contents ix 14.5 Thermodynamic Data from Equations of State................................................399 14.6 Rule of Corresponding States ..............................................................................404 14.7 Generalized Compressibility Chart ....................................................................406 14.8 Generalized Enthalpy Chart ................................................................................407 14.9 Generalized Entropy Chart ..................................................................................410 14.10 Fugacity ...................................................................................................................415 14.11 Summary of Equations .........................................................................................418 Problems .............................................................................................................................420 15 Multicomponent Systems ....................................................................................429 15.1 Intensive State ........................................................................................................429 15.2 Phase .......................................................................................................................429 15.3 Components of a Phase ........................................................................................430 15.4 Partial Properties ...................................................................................................433 15.5 Gibbs Equation .......................................................................................................437 15.6 Gibbs-Duhem Equation .......................................................................................440 15.7 Fugacity of a Component in a Solution ..............................................................444 15.8 Standard State and Activity .................................................................................445 15.9 Fugacity Relations .................................................................................................446 15.10 Partial and Specific Properties for Binary Phase ..............................................447 15.11 Mixing .....................................................................................................................449 15.12 Summary of Equations .........................................................................................451 Problems .............................................................................................................................454 16 Equilibrium ...........................................................................................................459 16.1 Maximum Entropy Criterion ...............................................................................459 16.2 Minimum Energy Criterion .................................................................................461 16.3 Minimum Gibbs Free Energy ..............................................................................462 16.4 Chemical Potential ................................................................................................462 16.5 Gibbs Phase Rule ...................................................................................................464 16.6 Phase Equilibrium of Pure Substance ................................................................465 16.7 Equilibrium between Vapor Bubble and Liquid Phase ...................................467 16.8 Equilibrium of Multicomponent Phases ............................................................469 16.9 Summary of Equations .........................................................................................469 Problems .............................................................................................................................470 17 Ideal Solutions ......................................................................................................473 17.1 Mixing Volume ......................................................................................................473 17.2 Enthalpy of Mixing ...............................................................................................475 17.3 Entropy of Mixing .................................................................................................475 17.4 Binary Mixtures .....................................................................................................476 17.5 Ideal Gas Mixtures ................................................................................................481 17.6 Phase Equilibrium in Multicomponent Mixtures ............................................482 17.7 Equilibrium between Pure and Multicomponent Phase .................................487 17.8 Effect of Solute Concentration on Boiling Point ................................................489 17.9 Effect of Pressure on Solubility ...........................................................................491 17.10 Effect of Temperature on Solubility ....................................................................492 1711 Osmosis ...................................................................................................................493 17.12 Exergy Analysis .....................................................................................................495 Problems .............................................................................................................................496 χ Contents 18 Nonideal Solutions...............................................................................................503 18.1 Henry s Law........................................................................................................... 503 18.2 RaoulťsLaw ...........................................................................................................504 18.3 Dilute Solutions .....................................................................................................506 18.4 Binary Nonideal Solutions ...................................................................................506 18.5 Enthalpy of Mixing for Nonideal Binary Solutions .........................................508 18.6 Enthalpy Diagrams ...............................................................................................509 18.7 Absorption Refrigeration .....................................................................................513 18.8 Summary of Equations .........................................................................................520 Problems .............................................................................................................................521 19 Chemical Reactions ..............................................................................................525 19.1 Stoichiometry .........................................................................................................525 19.2 Fuel Combustion ...................................................................................................527 19.3 First Law for Chemical Reactions .......................................................................529 19.3.1 Heating Value of Fuel ..............................................................................536 19.4 Adiabatic Flame Temperature .............................................................................537 19.5 Enthalpy of Formation at Any Temperature .....................................................539 19.6 Free Energy of Formation at Any Temperature ................................................540 19.7 Chemical Equilibrium ..........................................................................................541 19.8 Exergy Considerations ..........................................................................................548 19.9 Summary of Equations .........................................................................................557 Problems .............................................................................................................................560 Appendix ........................................................................................................................575 Appendix A ........................................................................................................................575 Appendix В .........................................................................................................................612 AppendixC ........................................................................................................................619 Answers to Selected Problems ....................................................................................621 Bibliography ...................................................................................................................637 Index ................................................................................................................................643
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spelling	Shavit, Arthur Verfasser aut Thermodynamics from concepts to applications Arthur Shavit ; Chaim Gutfinger 2. ed. Boca Raton, Fla. [u.a.] CRC Press 2009 XV, 649 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Teorias da termodinâmica larpcal Termodinâmica larpcal Thermodynamique - Manuels d'enseignement supérieur Thermodynamics Thermodynamik (DE-588)4059827-5 gnd rswk-swf Thermodynamik (DE-588)4059827-5 s DE-604 Gutfinger, Chaim Verfasser aut Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017384910&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis
spellingShingle	Shavit, Arthur Gutfinger, Chaim Thermodynamics from concepts to applications Teorias da termodinâmica larpcal Termodinâmica larpcal Thermodynamique - Manuels d'enseignement supérieur Thermodynamics Thermodynamik (DE-588)4059827-5 gnd
subject_GND	(DE-588)4059827-5
title	Thermodynamics from concepts to applications
title_auth	Thermodynamics from concepts to applications
title_exact_search	Thermodynamics from concepts to applications
title_full	Thermodynamics from concepts to applications Arthur Shavit ; Chaim Gutfinger
title_fullStr	Thermodynamics from concepts to applications Arthur Shavit ; Chaim Gutfinger
title_full_unstemmed	Thermodynamics from concepts to applications Arthur Shavit ; Chaim Gutfinger
title_short	Thermodynamics
title_sort	thermodynamics from concepts to applications
title_sub	from concepts to applications
topic	Teorias da termodinâmica larpcal Termodinâmica larpcal Thermodynamique - Manuels d'enseignement supérieur Thermodynamics Thermodynamik (DE-588)4059827-5 gnd
topic_facet	Teorias da termodinâmica Termodinâmica Thermodynamique - Manuels d'enseignement supérieur Thermodynamics Thermodynamik
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