Nanoscale devices: fabrication, functionalization, and accessibility from the macroscopic world
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Berlin [u.a.]
Springer
2009
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| Series: | Nanoscience and technology
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| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XVI, 205 S. Ill., graph. Darst. |
| ISBN: | 9783540927310 |
Staff View
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Record in the Search Index
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| adam_text | Titel: Nanoscale devices
Autor: Cerofolini, Gianfranco
Jahr: 2009
Contents
List of Acronyms................................................................... xv
Part I Basics
1 Matter on the Nanoscale...................................................... 3
1.1 Nanotechnology and the (N + 1) Problem............................ 4
1.2 Microelectronics is a Nanotechnology................................. 5
1.3 From Microlectronics to Molecular Electronics ...................... 6
2 Top-Down Paradigm to Miniaturization.................................... 9
2.1 The Path Toward Size Reduction ...................................... 10
2.2 Going Down with Device Size is a Hard Uphill Path................. 14
2.2.1 The Physical Limit............................................ 14
2.2.2 The Technological Limit...................................... 15
2.2.3 The Economic Limit........................................... 16
2.3 Going Beneath the Limiting Size....................................... 17
3 Physical Limits to Miniaturization.......................................... 19
3.1 A Case Study: The Limits of Computation............................ 19
3.2 The Basic Computational Unit......................................... 20
3.3 Programming............................................................ 24
3.3.1 Limits Imposed by the Uncertainty Principle................ 24
3.3.2 Limits Imposed by Ballistic Material Motion................ 25
3.3.3 Limits Imposed by the Thermal Embedding ................ 26
3.4 Computation and Irreversibility........................................ 29
3.4.1 Irreversible Computation...................................... 29
3.4.2 Reversible Computation....................................... 30
3.4.3 Minimum Dissipation......................................... 32
3.4.4 Computation and Measure.................................... 36
3.5 Reading.................................................................. 39
3.5.1 Coupling the Carrier with the External World............... 40
3.5.2 Physical Limits in READ Operation.......................... 40
3.5.3 A Little Step Toward Practical Implementation.............. 44
x;i Contents
4 The Crossbar Structure ...................................................... 45
4.1 The Crossbar Process................................................... 46
4.2 Process Integration ..................................................... 50
4.3 Why Molecules? ........................................................ 51
5 Crossbar Production ......................................................... 53
5.1 Imprint Lithography..................................................... 54
5.2 Spacer Patterning Technology.......................................... 56
5.3 Multispacer Patterning Technology.................................... 56
5.3.1 Multiplicative Route: S PTX.................................. 57
5.3.2 Additive Route: S PT+....................................... 61
5.4 Minimum Exploitable Bar Width....................................... 67
6 The Litho-to-Nano link....................................................... 69
6.1 The Horizontal Beveling Technique ................................... 71
6.2 Fusing Adjacent Lines in S PT+ ...................................... 72
6.3 Energetic Filtering ...................................................... 75
6.4 Technology and Architecture .......................................... 77
6.5 Not Only Crossbars..................................................... 79
6.5.1 Supercapacitors ............................................... 80
6.5.2 Photoluminescent Nanosheets................................ 80
6.5.3 Nanowire Arrays as Seebeck Generators..................... 81
7 Functional Molecules.......................................................... 83
7.1 The Molecule as a One-Dimensional Wire............................ 83
7.1.1 The Role of Contacts: Landauer Resistance ................. 84
7.1.2 Barrier Transparency.......................................... 84
7.2 Conduction Along Alkanes............................................. 87
7.3 Switchable n-Conjugated Molecules .................................. 88
7.4 Molecules Exhibiting Superexchange Conduction.................... 90
7.5 A Comparison of the Switching Mechanisms......................... 92
8 Grafting Functional Molecules .............................................. 95
8.1 Silicon and Its Surfaces................................................. 95
8.1.1 Silicon Chemistry.............................................. 97
8.1.2 The Role of Surfaces.......................................... 98
8.1.3 The Surface of Single-Crystalline Silicon.................... 99
8.1.4 The Surface of Polycrystalline Silicon.......................105
8.1.5 The Surface of Porous Silicon................................106
8.1.6 Inner Surfaces and the Fantastic Chemistry
in Nanocavities................................................107
8.2 Routes for Silicon Functionalization ..................................Ill
8.2.1 Hydrosilation..................................................113
8.2.2 Hydrosilation at the Hydrogen-Terminated
(10 0) Si Surface..............................................114
Contents xjjj
8.3 Grafting in Restricted Geometries .....................................116
8.4 Three-Terminal Molecules..............................................123
8.5 Nanostructured Oxo-Bonded Silicon ..................................125
8.5.1 Hydrothermal Synthesis: Zeolites............................126
8.5.2 Hydrolysis and Polycondensation: Aerogels.................127
Concluding Remarks..............................................................131
Part II Advanced Topics: Self-Similar Structures, Molecular Motors,
and Nanobiosystems
9 Examples.......................................................................135
9.1 Hybrid Molecule-MOS-FET Combination ...........................135
9.2 Crossbar Functionalization.............................................137
10 Self-Similar Nanostructures..................................................141
10.1 Fractals...................................................................141
10.1.1 Queer Systems.................................................141
10.1.2 Fractals in Mathematics.......................................142
10.2 Fractals in Nature.......................................................143
10.2.1 Fractal Biological Systems....................................143
10.2.2 Fractal Surfaces................................................144
10.3 Fractals in Technology..................................................146
11 Molecular Motors.............................................................151
11.1 Molecular Building Blocks.............................................153
11.2 Controlling Movement with Electric Field ............................155
11.3 Combining Ballistic and Brownian Motions ..........................157
11.4 Brownian Motors........................................................16°
12 Nanobiosensing................................................................165
12.1 Reducing Cell Biology to Molecular Biology.........................165
12.2 From Molecular Biology to Systems Biology.........................I68
12.3 Sensing as a Key Tool for Systems Biology...........................169
12.4 From ICs to Nanobiosensors............................................170
12.4.1 The Incremental Increase of Complexity
of ICs and Sensors.............................................
12.4.2 The Shift of Paradigm.........................................172
12.5 A Roadmap for Nanobiosensing........................................
12.5.1 Nanobiosensing In Vitro......................................174
12.5.2 Nanobiosensing In Vivo.......................................177
xiv Contents
13 Abstract Technology ..........................................................179
13.1 Material Bodies and Surfaces...........................................180
13.2 Processes Controlled by Geometry.....................................181
13.2.1 Conformal Processes..........................................182
13.2.2 Directional Processes..........................................184
13.3 Processes Controlled by the Material ..................................186
13.4 Abstract Technology in Concrete.......................................188
References...........................................................................191
Index.................................................................................201
|
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| discipline | Maschinenbau / Maschinenwesen Elektrotechnik / Elektronik / Nachrichtentechnik |
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| isbn | 9783540927310 |
| language | English |
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| physical | XVI, 205 S. Ill., graph. Darst. |
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| spelling | Cerofolini, Gianfranco Verfasser aut Nanoscale devices fabrication, functionalization, and accessibility from the macroscopic world Gianfranco Cerofolini Berlin [u.a.] Springer 2009 XVI, 205 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Nanoscience and technology Nanotechnologie Nanotechnologie (DE-588)4327470-5 gnd rswk-swf Nanotechnologie (DE-588)4327470-5 s DE-604 HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017376337&sequence=000004&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Cerofolini, Gianfranco Nanoscale devices fabrication, functionalization, and accessibility from the macroscopic world Nanotechnologie Nanotechnologie (DE-588)4327470-5 gnd |
| subject_GND | (DE-588)4327470-5 |
| title | Nanoscale devices fabrication, functionalization, and accessibility from the macroscopic world |
| title_auth | Nanoscale devices fabrication, functionalization, and accessibility from the macroscopic world |
| title_exact_search | Nanoscale devices fabrication, functionalization, and accessibility from the macroscopic world |
| title_full | Nanoscale devices fabrication, functionalization, and accessibility from the macroscopic world Gianfranco Cerofolini |
| title_fullStr | Nanoscale devices fabrication, functionalization, and accessibility from the macroscopic world Gianfranco Cerofolini |
| title_full_unstemmed | Nanoscale devices fabrication, functionalization, and accessibility from the macroscopic world Gianfranco Cerofolini |
| title_short | Nanoscale devices |
| title_sort | nanoscale devices fabrication functionalization and accessibility from the macroscopic world |
| title_sub | fabrication, functionalization, and accessibility from the macroscopic world |
| topic | Nanotechnologie Nanotechnologie (DE-588)4327470-5 gnd |
| topic_facet | Nanotechnologie |
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