Hydrometallurgy: principles and applications
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English Slovak |
| Published: |
Cambridge [u.a.]
Cambridge Internat. Science Publ. [u.a.]
2008
|
| Series: | Woodhead publishing in materials
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Physical Description: | XIII, 536 S. Ill., zahlr. graph. Darst. |
| ISBN: | 9781420070446 9781845694074 |
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MARC
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| 245 | 1 | 0 | |a Hydrometallurgy |b principles and applications |c Tomáš Havlík |
| 264 | 1 | |a Cambridge [u.a.] |b Cambridge Internat. Science Publ. [u.a.] |c 2008 | |
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| 650 | 4 | |a Hidrometalurgia | |
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Record in the Search Index
| _version_ | 1804138831261204480 |
|---|---|
| adam_text | Contents
Introduction
.......................................................................................xi
1.
Current situation in copper production
...................................1
1.1.
Copper hydrometallurgy
........................................................................ 11
2.
Ore minerals
...........................................................................17
3.
Phase equilibrium of copper and
iron sulphides
..........................................................................29
3.1.
One-component systems
.......................................................................29
3.1.1.
Sulphur
....................................................................................................29
3.1.1.1.
Allotropie
modifications of solid sulphur
............................................32
3.1.1.2.
Phase diagram
.........................................................................................37
3.2.
Multi-component systems
.....................................................................38
3.2.1.
The copper-sulphur equilibrium phase system
...................................38
3.2.2.
The iron-sulphur equilibrium phase system
........................................43
3.2.3.
The copper-iron-sulphur equilibrium phase system
..........................48
4.
Equilibrium in aqueous solutions
..........................................60
4.1.
Ionic activities
........................................................................................65
4.1.1.
Debye-Hiickel theory
............................................................................65
4.1.1.1.
Extension to more concentrated solutions
...........................................69
4.1.1.2.
Extension to mixed electrolytes
.............................................................71
4.1.2.
Pitzer method
..........................................................................................72
4.1.2.1.
Calculation of
φ
for salts in mixed electrolytes
.....................................76
4.1.2.2.
Calculation of
γ
for salts in mixed electrolytes
.....................................78
4.1.2.3.
Calculation of
γ
for single ions
............................................................79
4.1.2.4.
Studies of complex systems
...................................................................80
4.2.
Formation of metallic complexes and equilibrium constant
................81
4.3.
Thermodynamics of equilibrium constants
..........................................85
4.3.1.
Selection of the values of equilibrium constants
.................................91
5.
Thermodynamic studies of heterogeneous systems
in an aqueous medium
...........................................................96
5.1.
Theoretical principle of the f-pH diagrams
....................................... 100
5.1.1. pH
and its principle
.............................................................................. 102
5.1.2.
Potential
E
and its principle
................................................................. 104
5.2.
Calculation and construction of
Е
-pH
diagrams
............................... 113
5.2.1.
Е
-pH
diagrams at elevated temperatures
........................................... 116
5.3. Potential-pH
diagrams in leaching of copper sulphides
................... 127
5.3.1.
S-H,0 equilibrium system
.................. ................................................. 129
5.3.2.
Cu-S-HjO equilibrium system
............................................................ 145
5.3.3.
Fe-S-HjO equilibrium system
............................................................. 153
5.3.4.
Cu-Fe-S-HjO equilibrium system
...................................................... 154
5.3.5.
Cu-S-Cl-HjO equilibrium system
....................................................... 157
5.3.6.
Fe-S-Cl-bip equilibrium system
....................................................... 159
5.3.7.
Equilibrium diagram of the Cu-Fe-S-Cl-Kp system
....................... 163
5.4.
Species diagrams
.................................................................................. 167
6.
Software and databases for thermodynamic calculations
173
7.
Kinetics of heterogeneous reactions of leaching
processes
..............................................................................184
7.1.
Effect of variables on the kinetics of a heterogeneous reaction
...... 190
7.2.
Elementary phenomena at the interface
..............................................211
7.2.1.
Intrinsic kinetics of heterogeneous reactions on solid surfaces
......216
7.2.1.1.
Kinetics of processes of leaching a single particle
...........................216
7.2.1.2.
Kinetics of leaching processes in multi-particle systems
.................228
8.
Leaching in chloride media
.................................................242
8.1.
Main aspects of leaching chalcopyrite in a chloride medium
...........243
9.
Extracting metals from solutions
.......................................255
9.1.
Cementation
..........................................................................................255
9.2.
Cementation of amalgams
....................................................................259
9.3.
Reduction with gaseous hydrogen
.....................................................261
9.4.
Liquid extraction
...................................................................................264
9.5.
Ion exchange
.........................................................................................268
9.6.
Precipitation of sparingly soluble compounds
..................................270
9.7.
Crystallisation
......................................................................................274
9.8.
Electrolysis and electrolytic refining
..................................................276
9.8.1.
Electrowinning of metals
......................................................................278
9.8.2.
Electrolytic refining
..............................................................................289
10.
Effect of the electronic structure on leaching of
sulphide semiconductors
.....................................................294
10.1.
Leaching kinetics and electrochemistry of sulphides
.......................300
10.1.1.
Leaching of chalcopyrite
.....................................................................301
11.
Experimental methods of investigating hydrometallurgical
processes
..............................................................................309
11.1.
Experimental methods of examination of leaching processes
...........315
vi
11.1.1.
Leaching equipment
.............................................................................318
11.1.2.
Experimental procedure
........................................................................ 324
11.2.
Changes of
pH
in relation to temperature
..........................................334
12.
Leaching of copper sulphides
.............................................341
12.1.
Copper sulphides of the CuxFeySz type
...............................................341
12.1.1.
Leaching of chalcopyrite by ferric sulphate
......................................361
12.1.2.
Leaching of chalcopyrite by ferric chloride
....................................... 364
12.1.3.
Leaching of chalcopyrite by ferric chloride with the addition of
carbon tetrachloride
............................................................................. 366
12.1.4.
Leaching of chalcopyrite in sulphuric acid using ozone as the
oxidation agent
.....................................................................................368
12.1.5.
Leaching of chalcopyrite in the high-frequency field
....................... 375
12.1.6.
Leaching of chalcopyrite in the microwave field
...............................378
12.1.7.
Leaching of chalcopyrite in the presence of deep nodules as an
oxidation agent
.....................................................................................384
12.2.
Copper sulphides of the CuxS type
.....................................................388
12.3.
Copper sulphides of the type CuxMeySz
...............................................................................398
13.
Morphology and behaviour of sulphur in the leaching
of sulphides
...........................................................................421
14.
Study of the fine structure
...................................................444
14.1.
Examples of the application of X-ray diffractometry in
hydrometallurgy
...................................................................................446
15.
Mechanism of leaching of copper sulphides in an acid
medium
..................................................................................468
16.
The current state and prospects of hydrometallurgical
processes
..............................................................................479
16.1.
History of hydrometallurgical processes
............................................484
Index
...............................................................................................535
vii
|
| any_adam_object | 1 |
| author | Havlík, Tomáš |
| author_facet | Havlík, Tomáš |
| author_role | aut |
| author_sort | Havlík, Tomáš |
| author_variant | t h th |
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| bvnumber | BV035402761 |
| callnumber-first | T - Technology |
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| ctrlnum | (OCoLC)297796471 (DE-599)HBZHT015587972 |
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| dewey-ones | 669 - Metallurgy |
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| dewey-search | 669.0283 |
| dewey-sort | 3669.0283 |
| dewey-tens | 660 - Chemical engineering |
| discipline | Chemie / Pharmazie Physik |
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| id | DE-604.BV035402761 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:34:26Z |
| institution | BVB |
| isbn | 9781420070446 9781845694074 |
| language | English Slovak |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017323374 |
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| physical | XIII, 536 S. Ill., zahlr. graph. Darst. |
| publishDate | 2008 |
| publishDateSearch | 2008 |
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| publisher | Cambridge Internat. Science Publ. [u.a.] |
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| series2 | Woodhead publishing in materials |
| spelling | Havlík, Tomáš Verfasser aut Hydrometallurgy principles and applications Tomáš Havlík Cambridge [u.a.] Cambridge Internat. Science Publ. [u.a.] 2008 XIII, 536 S. Ill., zahlr. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Woodhead publishing in materials Hidrometalurgia Hydrometallurgy Nassmetallurgie (DE-588)4123820-5 gnd rswk-swf Nassmetallurgie (DE-588)4123820-5 s DE-604 Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017323374&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Havlík, Tomáš Hydrometallurgy principles and applications Hidrometalurgia Hydrometallurgy Nassmetallurgie (DE-588)4123820-5 gnd |
| subject_GND | (DE-588)4123820-5 |
| title | Hydrometallurgy principles and applications |
| title_auth | Hydrometallurgy principles and applications |
| title_exact_search | Hydrometallurgy principles and applications |
| title_full | Hydrometallurgy principles and applications Tomáš Havlík |
| title_fullStr | Hydrometallurgy principles and applications Tomáš Havlík |
| title_full_unstemmed | Hydrometallurgy principles and applications Tomáš Havlík |
| title_short | Hydrometallurgy |
| title_sort | hydrometallurgy principles and applications |
| title_sub | principles and applications |
| topic | Hidrometalurgia Hydrometallurgy Nassmetallurgie (DE-588)4123820-5 gnd |
| topic_facet | Hidrometalurgia Hydrometallurgy Nassmetallurgie |
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