Carbon nanotube science: synthesis, properties and applications
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| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Cambridge [u.a.]
Cambridge Univ. Press
2009
|
| Edition: | 1. publ. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Frühere Ausg. u.d.T.: Harris, Peter J. F.: Carbon nanotubes and related structures. - Includes bibliographical references and indexes |
| Physical Description: | X, 301 S. Ill., graph. Darst. |
Staff View
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Record in the Search Index
| _version_ | 1804138820125327360 |
|---|---|
| adam_text | Contents
Preface
page
xi
Introduction
1
1.1
Buckminsterfullerene
2
1.2
Fullerene-related carbon nanotubes
3
1.3
Single- and double-walled nanotubes
5
1.4
Catalytically produced carbon nanotubes
6
1.5
Who discovered carbon nanotubes?
7
1.6
Carbon nanotube research
8
1.7
Scope of the book
10
References
11
Synthesis I: arc- and laser-vaporization, and heat treatment
methods
14
2.1
Production of multiwalled nanotubes by arc-evaporation
14
2.1.1
Early work
14
2.1.2
The arc-evaporation technique: further developments
16
2.1.3
Alternatives to graphite
18
2.1.4.
Safety considerations for the arc-evaporation method
18
2.2
Growth mechanisms of multiwalled nanotubes in the arc
19
2.2.1
General comments
19
2.2.2
Vapour phase growth
20
2.2.3
Liquid phase growth
21
2.2.4
Solid phase growth
22
2.2.5
The crystallization model
23
2.3
Production of multiwalled nanotubes by high-temperature
heat treatments
24
2.4
Production of single-walled nanotubes by arc-evaporation
27
2.5
Production of single-walled nanotubes by laser
vaporization
30
2.6
Growth mechanisms of SWNTs in the arc and laser methods
ЗІ
2.6.1
Vapour-liquid-solid models
32
2.6.2
Solid-state models
34
Contents
2.7
Arc-evaporation synthesis of double-walled
nanotubes 36
2.8
Discussion
37
References
3 8
Synthesis II: catalytic chemical vapour deposition and related
methods
43
3.1
Catalytic synthesis of multiwalled nanotubes: pre-1991 work
44
3.2
Catalytic synthesis of multiwalled nanotubes: post-
1991
work
46
3.2.1
Growth of aligned MWNTs on substrates
48
3.2.2
Direct spinning of nanotube yarns
51
3.3
Growth mechanisms of catalytically produced MWNTs
52
3.4
Catalytic synthesis of single-walled nanotubes
55
3.4.1
Conditions required to produce SWNTs
55
3.4.2
Large-scale catalytic synthesis of SWNTs
58
3.4.3
Preparation of SWNT strands
59
3.4.4
Directed growth of SWNTs
61
3.4.5
Synthesis of SWNTs with defined structures
63
3.5
Growth mechanisms of catalytically produced SWNTs
65
3.5.1
Vapour-liquid-solid mechanisms
65
3.5.2
A solid-state mechanism for CVD growth?
66
3.6
Catalytic synthesis of double-walled nanotubes
68
3.7
Electrochemical synthesis of multiwalled nanotubes
70
3.8
Synthesis of MWNTs by heat treatment of metal-doped carbon
70
3.9
Discussion
71
References
72
Purification and processing
80
4.1
Purification of multiwalled tubes
80
4.1.1
MWNTs produced by arc-evaporation
80
4.1.2
Catalytically-produced MWNTs
81
4.2
Purification of single-walled tubes
83
4.2.1
Acid treatment and oxidation
83
4.2.2
Functionalization
85
4.2.3
Physical techniques
85
4.2.4
Assessing purity
86
4.3
Processing of multiwalled nanotubes
86
4.3.1
Multiwalled nanotube suspensions and assemblies of pure MWNTs
86
4.3.2
Alignment and arrangement of MWNTs
87
4.3.3
Pure MWNT fibres
89
4.3.4
MWNT sheets
91
4.3.5
Breaking and cutting of MWNTs
91
4.4
Processing of single-walled tubes
92
4.4.1
Alignment and arrangement of SWNTs
92
4.4.2
Pure SWNT strands
95
Contents
vii
4.4.3 SWNT
sheets
96
4.4.4
Length control of SWNTs
98
4.5
Separating metallic and semiconducting single-walled
nanotubes
99
4.5.1
Selective elimination
99
4.5.2
Dielectrophoresis
100
4.5.3
Selective functionalization
100
4.6
Discussion
101
References
102
Structure
107
5.1
Bonding in carbon materials
107
5.2
The structure of carbon nanotubes: theoretical discussion
109
5.2.1
Vector notation for carbon nanotubes
109
5.2.2
Unit cells of nanotubes
110
5.2.3
Symmetry classification of nanotubes
112
5.2.4
Defects in the hexagonal lattice
114
5.2.5
The layer structure of multiwalled nanotubes
116
5.2.6
Theory of nanotube capping
118
5.3
Experimental studies: multiwalled nanotubes produced
by arc-evaporation
121
5.3.1
The layer structure: experimental observations
121
5.3.2
Electron diffraction of MWNTs
124
5.3.3
The cross-sectional shape of multiwalled nanotubes
124
5.3.4
MWNT cap structure
126
5.3.5
Elbow connections and branching structures
127
5.4
Experimental studies: multiwalled nanotubes produced
by catalysis
130
5.5
Experimental studies: single-walled nanotubes
132
5.5.1
General features
132
5.5.2
Electron diffraction of SWNTs
133
5.5.3
HRTEM of SWNTs
136
5.5.4
Scanning tunnelling microscope of SWNTs
137
5.6
Neutron diffraction
140
5.7
Discussion
140
References
141
Physical properties I: electronic
146
6.1
Electronic properties of graphite
146
6.2
Electronic properties of nanotubes: theory
148
6.2.1
Band structure of single-walled tubes
148
6.2.2
Effect of curvature and of tube-tube interactions
151
6.2.3
Electron transport in nanotubes
152
6.2.4
Effect of a magnetic field
153
viii Contents
6.3
Electronic
properties of nanotubes: experimental
measurements
155
6.3.1
Early studies of multiwalled nanotubes
155
6.3.2
Correlation between electronic properties and structure
of single-walled nanotubes
156
6.3.3
Quantum conductance
159
6.3.4
Electronic properties of nanotubes in a magnetic field
163
6.3.5
Superconductivity
164
6.4
Nanoelectronic devices
164
6.4.1
Diodes
164
6.4.2
Field effect transistors
166
6.4.3
Logic circuits
167
6.5
Magnetic properties of nanotubes
168
6.6
Nanotube field emitters
170
6.7
Conclusions
172
References
173
Physical properties II: mechanical, optical and thermal
179
7.1
Mechanical properties of carbon nanotubes
179
7.1.1
Theoretical predictions
179
7.1.2
Experimental observations: multiwalled nanotubes
182
7.1.3
Experimental observations: single-walled
nanotubes
188
7.2
Optical properties of nanotubes
188
7.2.1
Optical absorption spectroscopy
189
7.2.2
Fluorescence spectroscopy
190
7.3
Raman spectroscopy
192
7.4
Thermal properties of nanotubes
196
7.5
The physical stability of nanotubes
197
7.6
Discussion
198
References
199
Chemistry and biology of nanotubes
204
8.1
Covalent functionalization
204
8.1.1
Functionalization of nanotube ends and defects
205
8.1.2
Functionalization of sidewalls
206
8.2
Non-covalent functionalization
211
8.3
Characterizing chemically ftinctionalized nanotubes
214
8.4
Biological functionalization
214
8.4.1
Proteins
214
8.4.2
Nucleic acids
217
8.5
Toxicity
of carbon nanotubes
218
8.6
Discussion
220
References
220
Contents
9 Carbon nanotube
composites
227
9.1
Preparation of
carbon
nanotube/polymer
composites
227
9.1.1
Solution
mixing
227
9.1.2
Melt processing
229
9.1.3
In situ polymerization
230
9.1.4
Effect of nanotubes on polymer structure
231
9.2
Properties of carbon nanotube/polymer composites
232
9.2.1
Mechanical properties
232
9.2.2
Electrical properties
235
9.3
Carbon nanotube/ceramic composites
237
9.4
Carbon nanotube/carbon composites
239
9.5
Carbon nanotube/metal composites
239
9.6
Discussion
240
References
241
10
Filled and heterogeneous nanotubes
247
10.1
Filling by arc-evaporation
247
10.2
Opening and filling of multiwalled nanotubes using
chemical methods
248
10.2.1
Early work
248
10.2.2
Opening by treatment with acid
249
10.2.3
Filling opened tubes
251
10.3
Filling catalytically-grown multiwalled nanotubes
252
10.4
Water in multiwalled nanotubes
255
10.5
Filling single-and double-walled nanotubes
255
10.5.1
Filling with inorganic materials
255
10.5.2
Filling with
rullerenes:
nano-peapods*
257
10.6
Gases in nanotubes
263
10.6.1
Hydrogen
263
10.6.2
Other gases
264
10.7
Heterogeneous nanotubes
265
10.7.1
Boron-carbon-nitrogen tubes
265
10.7.2
Carbon-nitrogen tubes
267
10.7.3
Carbon-boron tubes
267
10.8
Discussion
268
References
269
11
Probes and sensors
275
1
1.1
Nanotube tips for atomic force microscopy
275
11.1.1
Preparing nanotube tips: mechanical assembly
275
11.1.2
Preparing nanotube tips: chemical vapour
deposition
277
11.1.3
Imaging using nanotube AFM tips 27S
11.2
Gassensors
280
Contents
11.3
Biosensors
282
11.4
Physical sensors
283
11.5
Discussion
285
References
285
12
Conclusions
289
12.1
Highlights of carbon nanotube research
289
12.2
Final thoughts
292
References
293
Name Index
296
Subject Index
299
|
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| id | DE-604.BV035395262 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:34:15Z |
| institution | BVB |
| language | English |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017315998 |
| oclc_num | 295002254 |
| open_access_boolean | |
| owner | DE-92 DE-29T DE-20 DE-703 DE-188 |
| owner_facet | DE-92 DE-29T DE-20 DE-703 DE-188 |
| physical | X, 301 S. Ill., graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Cambridge Univ. Press |
| record_format | marc |
| spelling | Harris, Peter J. F. 1957- Verfasser (DE-588)137108370 aut Carbon nanotube science synthesis, properties and applications Peter J. F. Harris 1. publ. Cambridge [u.a.] Cambridge Univ. Press 2009 X, 301 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Frühere Ausg. u.d.T.: Harris, Peter J. F.: Carbon nanotubes and related structures. - Includes bibliographical references and indexes Carbon Nanotubes Kohlenstoff (DE-588)4164538-8 gnd rswk-swf Kohlenstoff-Nanoröhre (DE-588)4581365-6 gnd rswk-swf Nanostrukturiertes Material (DE-588)4342626-8 gnd rswk-swf Kohlenstoff (DE-588)4164538-8 s Nanostrukturiertes Material (DE-588)4342626-8 s DE-604 Kohlenstoff-Nanoröhre (DE-588)4581365-6 s Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017315998&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Harris, Peter J. F. 1957- Carbon nanotube science synthesis, properties and applications Carbon Nanotubes Kohlenstoff (DE-588)4164538-8 gnd Kohlenstoff-Nanoröhre (DE-588)4581365-6 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd |
| subject_GND | (DE-588)4164538-8 (DE-588)4581365-6 (DE-588)4342626-8 |
| title | Carbon nanotube science synthesis, properties and applications |
| title_auth | Carbon nanotube science synthesis, properties and applications |
| title_exact_search | Carbon nanotube science synthesis, properties and applications |
| title_full | Carbon nanotube science synthesis, properties and applications Peter J. F. Harris |
| title_fullStr | Carbon nanotube science synthesis, properties and applications Peter J. F. Harris |
| title_full_unstemmed | Carbon nanotube science synthesis, properties and applications Peter J. F. Harris |
| title_short | Carbon nanotube science |
| title_sort | carbon nanotube science synthesis properties and applications |
| title_sub | synthesis, properties and applications |
| topic | Carbon Nanotubes Kohlenstoff (DE-588)4164538-8 gnd Kohlenstoff-Nanoröhre (DE-588)4581365-6 gnd Nanostrukturiertes Material (DE-588)4342626-8 gnd |
| topic_facet | Carbon Nanotubes Kohlenstoff Kohlenstoff-Nanoröhre Nanostrukturiertes Material |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017315998&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT harrispeterjf carbonnanotubesciencesynthesispropertiesandapplications |