Properties of polymers: their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions
Saved in:
| Main Author: | |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Amsterdam [u.a.]
Elsevier
2009
|
| Edition: | 4., completely rev. ed. |
| Subjects: | |
| Online Access: | Publisher description Inhaltsverzeichnis |
| Item Description: | Hier auch später erschienene unveränderte Nachdrucke |
| Physical Description: | XXVI, 1004 S. graph. Darst. |
| ISBN: | 9780080548197 |
Staff View
MARC
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| 100 | 1 | |a Krevelen, Dirk W. van |d 1914-2001 |e Verfasser |0 (DE-588)136511147 |4 aut | |
| 245 | 1 | 0 | |a Properties of polymers |b their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions |c D. W. van Krevelen. Rev. by K. te Nijenhuis |
| 250 | |a 4., completely rev. ed. | ||
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 2009 | |
| 300 | |a XXVI, 1004 S. |b graph. Darst. | ||
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Record in the Search Index
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| adam_text | From the
preface
to the first
edrtion
0972)
vii
From the preface to the second edition
(1976) ix
Preface to the third edition
(1990) xi
Introduction of the present author xin
Preface to the fourth edition
(2008) xv
Acknowledgements
xix
L
General
introduction:
A birďs-eye
view of polymer science and angina« ing
Chapter
1
Polymer properties
ł
11
Approach and objective
3
Bibliography
5
Chapter
2
Typology of polymers
7
21
introduction
7
22
Polymer structure
8
23
Molar mass and molar mass distribution
17
24
Phase transitions in polymers
25
25
Morphology of solid polymers
29
26
Polymeric liquid crystals
34
27
Multiple component polymer systems
36
28
Relaxation phenomena
38
Appendix
L
Milestones in the history of polymer science
40
Appendix H. Chronological development of commercial polymers
44
Bibliography
45
jfpołogy
от
ргоретвв
щя
11
The concept polymer properties
49
12
Physical quantities and their units
52
33
Categories of physical quantities
54
14
Dimensionless groups of quantities
SS
15
Types of mobr properties
57
16 Additive
molar functions
60
Bibliography
66
H
tHL
■ ■■ ■
i i Ł
■
T
■ ■
I
ципи шшЪълът
nĚ
ийііміаи
n. i
tfffttopny lic w
propvrov»
от рочупмге
4.1
Introduction: mass and packing of matter
7)
42
Fundamental quantities of mass and volume
72
43
Standard molar volumes at room temperature
(298
K)
%
xxi
xxii Contents
4.4
Thermal expansion
89
4.5
Isothermal compression: Equations
of state
101
Bibliography
107
Chapters Calorimctrkproperties
109
5.1
Heat capacity
109
5.2
Latent heat of crystallization and fusion (melting)
118
53
Enthalpy and entropy
123
Bibliography
127
Chapter
6
Transition temperatures
129
6.1
Introduction
129
6.2
The glass transition temperature
130
6.3
The crystalline melting point
152
6.4
Relationship between glass transition temperature and melting point of polymers
167
6.5
Relationship between Tg, Tm and other transition temperatures
170
6.6
Transitions in thermotropic liquid crystal polymers
172
Appendix I. Rules of thumb for substituting an
H-atom
by a group X
182
Appendix II. Similarities and differences between Yg and Ym
183
Bibliography
187
Chapter
7
Cohesive properties and solubility
189
7.1
Introduction
189
7.2
Cohesive energy
190
7.3
Solubility
201
7.4
Internal pressure
222
Bibliography
225
Chapter
8
Interfacial
energy properties
229
8.1
Introduction
229
82
Surface energy of liquids and melts
230
83
Surface energy of solid polymers
234
8.4
General expression for the
interfacial
tension
239
8.5
Polymer adhesion
242
Bibliography
244
Chapter
9
Limiting viscosity number (mtrinsk viscosity)
and related properties of very dilute solutions
245
9.1
Introduction
245
9.2
Molecular dimensions of the conformational state
246
93
The limiting viscosity number (intrinsic viscosity)
249
9.4
Interrelationships of limiting diffusive transport quantities
280
Bibliography
283
Contents xxiii
Part III. Properties of polymers in fields of force
Chapter
10
Optical properties
287
10.1
Optical properties in general
287
10.2
Light refraction
290
10.3
Reflection and transmission
297
10.4
Birefringence (and optical rotation)
299
10.5
Light scattering
308
10.6
Absorption
313
10.7
Optical appearance properties
313
Bibliography
317
Chapter
11
Electrical properties
319
Tl.l Introduction
319
11.2
Dielectric polarisation
319
11.3
Static electrification and conductivity
333
11.4
Ultimate electrical properties
352
Bibliography
352
Chapter
12
Magnetic properties
355
12.1
Magnetic susceptibility (magnetic inductive capacity)
355
12.2
Magnetic resonance
359
Bibliography
380
Chapter
13
Mechanical properties of solid polymers
383
13.1
Introduction
383
13.2
Elastic parameters
383
13.3
Rubber elasticity
401
13.4
Viscoelasticity
405
13.5
Ultimate mechanical properties
453
13.6
Mechanical properties of uniaxially oriented polymers (fibres)
478
Bibliography
500
Chapter
14
Acoustic properties
505
14.1
Introduction
505
H2 Sound propagation and absorption
506
14.3
Additive molar functions for sound propagation
513
14.4
Sonic absorption
517
Bibliography
521
Part IV. Transport properties of polymers
Chapter
15
Rheological properties of polymer melts
525
15.1
Introduction
525
15.2
Modes of deformation and definition of viscosity and normal stress coefficients
526
153
Newtonian shear viscosity of polymer melts
533
15.4
Non-Newtonian shear viscosity and first normal stress coefficient of polymer melts
545
XXIV
Contents
15.5 Extensional
viscosity of polymer melts
564
15.6
Elastic effects in polymer melts
573
15.7
Rheological properties of thermotropic liquid crystalline polymers
581
Appendix I. Flow of polymer melts through narrow tubes and capillaries
591
Appendix II. Analysis of flow in processing operations
592
Bibliography
595
Chapter
16
Rheological properties of polymer solutions
599
16.1
Introduction
599
16.2
Dilute polymer solutions
600
16.3
Concentrated polymer solutions
604
16.4
Viscoelastic properties of polymer solutions in simple shear flow
619
16.5
Extensional flow of polymer solutions
630
16.6
Solutions of lyotropic liquid crystalline polymers
634
Bibliography
643
Chapter
17
Transport of thermal energy
645
17.1
Thermal conductivity
645
17.2
Appendix
651
Bibliography
652
Chapter
18
Properties determining mass transfer in polymeric systems
655
18.1
Introduction
655
18.2
Permeation of simple gases
656
18.3
Permeations of a more complex nature
681
18.4
Dissolution of polymers as a case of permeation
696
Bibliography
701
Chapter
19
Crystallisation and recrystallisation
703
19.1
Crystallinity, nucleation and growth
703
19.2
Spherulitic crystallisation of polymers from the melt
706
193
Induced crystallisation of flexible polymeric molecules by pressure and stress
726
19.4
Crystallisation phenomena in
uniaxial
drawing: fibre spinning
728
Bibliography
743
Part V. Properties determining the chemical stability and breakdown
of polymers
Chapter
20
Thermochemical properties
749
20.1
Thermodynamics and kinetics
749
20.2
Calculation of the free enthalpy of reaction from group contributions
752
20.3
Thermodynamics of free radicals
758
Bibliography
761
Contents
XXV
Chapter
21
Thermal decomposition
763
21.1
Introduction
763
21.2
Thermal degradation
763
21.3
Char formation
772
21.4
Kinetics of thermal degradation
776
Bibliography
776
Chapter
22
Chemical degradation
779
22.1
Introduction
779
22.2
Degradation under the influence of light
779
22.3
Oxidative degradation
781
22.4
Photo-oxidation
781
22.5
Thermal oxidation
783
22.6
Effects of oxidation degradation
783
22.7
Stabilisation
783
22.8
Hydrolytic degradation
785
22.9
Stress relaxation as a measure of chemical degradation
785
Bibliography
786
Part VI. Polymer properties as an integral concept
Chapter
23
Intrinsic properties in retrospect
789
23.1
Introduction
789
23.2
Reference values of intrinsic properties expressed as a function of additive quantities
790
23.3
Effect of structural groups on properties
792
23.4
Dependence of intrinsic properties on process variables
792
23.5
Outlook
796
Chapter
24
Processing properties
799
24.1
Classification of processes
799
24.2
Some important processing properties
800
24.3
Implementation of processing research
816
Bibliography
817
Chapter
25
Product properties (I): Mechanical behaviour and failure
819
25.1
Introduction
819
25.2
Failure mechanisms in polymers
820
25.3
Deformation properties
824
25.4
Toughness and endurance
829
25.5
Hardness
836
25.6
Friction and wear
840
25.7
The mechanical shortcomings of homogeneous materials and the need for composites
841
Bibliography
844
xxvi Contents
Chapter
26
Product properties (II): Environmental behaviour and failure
847
26.1
Introduction
847
26.2
Thermal end use properties
847
26.3
Flammability and combustion of polymers
850
26.4
Environmental decay of polymers
864
Bibliography
872
Chapter
27
An illustrative example of end use properties:
Article properties of textile products
875
271
Introduction
875
27.2
Aesthetic properties
875
27.3
Use or performance properties
877
27.4
Maintenance or care properties
882
27.5
Integral evaluation of fibre polymers, fibres and yarns by the criteria mentioned (profile method)
884
Bibliography
885
Part
VII.
Comprehensive tables
I International system of units (SI)
889
II Survey of conversion factors
891
III Values of some fundamental constants
903
IV Physical constants of the most important solvents
904
V Physical properties of the most important polymers
920
VI Published data of high performance polymers
934
VII Code
symbols for the most important polymers
938
VIII
Trade names and generic names
941
IX Survey of group contributions in additive molar quantities
946
Indexation
Symbol index
957
Author index
979
Subject index
989
|
| any_adam_object | 1 |
| author | Krevelen, Dirk W. van 1914-2001 |
| author_GND | (DE-588)136511147 |
| author_facet | Krevelen, Dirk W. van 1914-2001 |
| author_role | aut |
| author_sort | Krevelen, Dirk W. van 1914-2001 |
| author_variant | d w v k dwv dwvk |
| building | Verbundindex |
| bvnumber | BV035382469 |
| callnumber-first | T - Technology |
| callnumber-label | TA455 |
| callnumber-raw | TA455.P58 |
| callnumber-search | TA455.P58 |
| callnumber-sort | TA 3455 P58 |
| callnumber-subject | TA - General and Civil Engineering |
| classification_rvk | UV 2200 VE 8000 VK 8000 ZM 5100 ZM 5300 |
| classification_tum | CHE 720f WER 550b CHE 710f |
| ctrlnum | (OCoLC)262892599 (DE-599)BVBBV035382469 |
| dewey-full | 620.1/9204292 |
| dewey-hundreds | 600 - Technology (Applied sciences) |
| dewey-ones | 620 - Engineering and allied operations |
| dewey-raw | 620.1/9204292 |
| dewey-search | 620.1/9204292 |
| dewey-sort | 3620.1 79204292 |
| dewey-tens | 620 - Engineering and allied operations |
| discipline | Chemie / Pharmazie Physik Chemie Werkstoffwissenschaften Werkstoffwissenschaften / Fertigungstechnik |
| edition | 4., completely rev. ed. |
| format | Book |
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| id | DE-604.BV035382469 |
| illustrated | Illustrated |
| indexdate | 2025-02-20T06:41:48Z |
| institution | BVB |
| isbn | 9780080548197 |
| language | English |
| lccn | 2008044601 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017186703 |
| oclc_num | 262892599 |
| open_access_boolean | |
| owner | DE-703 DE-91G DE-BY-TUM DE-29T DE-83 DE-11 DE-526 DE-863 DE-BY-FWS |
| owner_facet | DE-703 DE-91G DE-BY-TUM DE-29T DE-83 DE-11 DE-526 DE-863 DE-BY-FWS |
| physical | XXVI, 1004 S. graph. Darst. |
| publishDate | 2009 |
| publishDateSearch | 2009 |
| publishDateSort | 2009 |
| publisher | Elsevier |
| record_format | marc |
| spellingShingle | Krevelen, Dirk W. van 1914-2001 Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions Materiaalkunde gtt Polymeren gtt Polymers Mechanical properties Eigenschaft (DE-588)4151179-7 gnd Chemische Struktur (DE-588)4009857-6 gnd Physikalische Eigenschaft (DE-588)4134738-9 gnd Polymere (DE-588)4046699-1 gnd |
| subject_GND | (DE-588)4151179-7 (DE-588)4009857-6 (DE-588)4134738-9 (DE-588)4046699-1 |
| title | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions |
| title_auth | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions |
| title_exact_search | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions |
| title_full | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions D. W. van Krevelen. Rev. by K. te Nijenhuis |
| title_fullStr | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions D. W. van Krevelen. Rev. by K. te Nijenhuis |
| title_full_unstemmed | Properties of polymers their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions D. W. van Krevelen. Rev. by K. te Nijenhuis |
| title_short | Properties of polymers |
| title_sort | properties of polymers their correlation with chemical structure their numerical estimation and prediction from additive group contributions |
| title_sub | their correlation with chemical structure ; their numerical estimation and prediction from additive group contributions |
| topic | Materiaalkunde gtt Polymeren gtt Polymers Mechanical properties Eigenschaft (DE-588)4151179-7 gnd Chemische Struktur (DE-588)4009857-6 gnd Physikalische Eigenschaft (DE-588)4134738-9 gnd Polymere (DE-588)4046699-1 gnd |
| topic_facet | Materiaalkunde Polymeren Polymers Mechanical properties Eigenschaft Chemische Struktur Physikalische Eigenschaft Polymere |
| url | http://www.loc.gov/catdir/enhancements/fy0902/2008044601-d.html http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017186703&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT krevelendirkwvan propertiesofpolymerstheircorrelationwithchemicalstructuretheirnumericalestimationandpredictionfromadditivegroupcontributions AT nijenhuisklaaste propertiesofpolymerstheircorrelationwithchemicalstructuretheirnumericalestimationandpredictionfromadditivegroupcontributions |
Indexes
THWS Würzburg Zentralbibliothek Lesesaal
| Call Number: |
1000 ZM 5100 K92(4) |
|---|---|
| Copy 1 | ausleihbar Available Place a Hold |