Combustion:
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| Main Authors: | , |
|---|---|
| Format: | Book |
| Language: | English |
| Published: |
Amsterdam [u.a.]
Elsevier
2008
|
| Edition: | 4. ed. |
| Subjects: | |
| Online Access: | Inhaltsverzeichnis |
| Item Description: | Includes bibliographical references and indexes |
| Physical Description: | XX, 773 S. Ill., graph. Darst. |
| ISBN: | 9780120885732 |
Staff View
MARC
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| 035 | |a (OCoLC)248001987 | ||
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| 040 | |a DE-604 |b ger |e aacr | ||
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| 100 | 1 | |a Glassman, Irvin |d 1923-2019 |e Verfasser |0 (DE-588)1026678560 |4 aut | |
| 245 | 1 | 0 | |a Combustion |c Irvin Glassman ; Richard A. Yetter |
| 250 | |a 4. ed. | ||
| 264 | 1 | |a Amsterdam [u.a.] |b Elsevier |c 2008 | |
| 300 | |a XX, 773 S. |b Ill., graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and indexes | ||
| 650 | 4 | |a Combustion | |
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| 999 | |a oai:aleph.bib-bvb.de:BVB01-017117722 | ||
Record in the Search Index
| _version_ | 1804138618073120768 |
|---|---|
| adam_text | Contents
Prologue
xvii
Preface
xix
CHAPTER
1.
CHEMICAL
THERMODYNAMICS AND
FLAME TEMPERATURES
1
A. Introduction I
B. Heats of reaction and formation
1
С
Free energy and the equilibrium constants
8
D. Flame temperature calculations
16
1.
Analysis
16
2.
Practical considerations
22
E. Sub-
and super sonic combustion thermodynamics
32
1.
Comparisons
32
2.
Stagnation pressure considerations
33
Problems
36
CHAPTER
2.
CHEMICAL KINETICS
43
A. Introduction
43
B. Rates of reactions and their temperature dependence
43
1.
The Arrhenius rate expression
45
2.
Transition state and recombination rate theories
47
С
Simultaneous interdependent reactions
52
D. Chain reactions
53
E. Pseudo-first-order reactions and the fall-off range
57
F. The partial equilibrium assumption
60
G. Pressure effect in fractional conversion
61
H. Chemical kinetics of large reaction mechanisms
62
1.
Sensitivity analysis
63
2.
Rate of production analysis
65
3.
Coupled thermal and chemical reacting systems
66
4.
Mechanism simplification
68
Problems
69
Contents
CHAPTER
3.
EXPLOSIVE AND GENERAL OXIDATIVE
CHARACTERISTICS OF FUELS
75
A. Introduction
75
B. Chain branching reactions and criteria for explosion
75
С
Explosion limits and oxidation characteristics of hydrogen
83
D. Explosion limits and oxidation characteristics of carbon
monoxide
91
E. Explosion limits and oxidation characteristics of hydrocarbons
98
1.
Organic nomenclature
99
2.
Explosion limits
103
3.
Low-temperature hydrocarbon oxidation mechanisms
106
F. The oxidation of aldehydes
110
G. The oxidation of methane
112
1.
Low-temperature mechanism
112
2.
High-temperature mechanism
113
H. The oxidation of higher-order hydrocarbons 1
17
1.
Aliphatic hydrocarbons
117
2.
Alcohols
127
3.
Aromatic hydrocarbons
129
4.
Supercritical effects
139
Problems
141
CHAPTER
4.
FLAME PHENOMENA IN PREMIXED
COMBUSTIBLE GASES
147
A. Introduction
147
B. Laminar flame structure
151
С
The laminar flame speed
153
1. The theory of Mallard and
Le Chatelier
156
2.
The theory of Zeldovich, Frank-Kamenetskii, and Semenov
161
3.
Comprehensive theory and laminar flame structure analysis
168
4.
The laminar flame and the energy equation
176
5.
Flame speed measurements
176
6.
Experimental results- physical and chemical effects
185
D. Stability limits of laminar flames
191
1.
Flammability limits
192
2.
Quenching distance
200
3.
Flame stabilization {low velocity)
201
4.
Stability limits and design
207
E. Flame propagation through stratified combustible mixtures
211
F. Turbulent reacting flows and turbulent flames
213
1.
The rate of reaction in a turbulent field
216
2.
Regimes of turbulent reacting flows
218
3.
The turbulent flame speed
231
Contents xi
G.
Stirred
reactor
theory
235
H.
Flame stabilization in high-velocity streams
240
I. Combustion in small volumes
250
Problems
254
CHAPTER
5.
DETONATION
261
A. Introduction
261
1.
Premixed and diffusion flames
261
2.
Explosion, deflagration, and detonation
261
3.
The onset of detonation
262
B. Detonation phenomena
264
С
Hugoniot relations and the hydrodynamic theory of
detonations
265
1.
Characterization of the Hugoniot curve and the uniqueness of the
С
-J
point
266
2.
Determination of the speed of sound in the burned gases for conditions
above the C-) point
276
3.
Calculation of the detonation velocity
282
D. Comparison of detonation velocity calculations with
experimental results
286
E. The ZND structure of detonation waves
293
F. The structure of the cellular detonation front and other
detonation phenomena parameters
297
1.
The cellular detonation front
297
2.
The dynamic detonation parameters
301
3.
Detonation limits
302
G. Detonations in nongaseous media
306
Problems
307
CHAPTER
6.
DIFFUSION FLAMES
311
A. Introduction
311
B. Gaseous fuel jets
311
1.
Appearance
312
2.
Structure
316
3.
Theoretical considerations
318
4.
The Burke-Schumann development
322
5.
Turbulent fuel jets
329
С
Burning of condensed phases
331
1
.
General mass burning considerations and the evaporation coefficient
332
2.
Single fuel droplets in quiescent atmospheres
337
D. Burning of droplet clouds
364
E. Burning in convective atmospheres
365
Contents
1.
The stagnant film case
365
2.
The longitudinally burning
5Ηήαοβ
367
3.
The flowing droplet case
369
4.
Burning rates of plastics-. The small
В
assumption and radiation effects
372
Problems
374
CHAPTER?. IGNITION
379
A. Concepts
379
B. Chain spontaneous ignition
382
С
Thermal spontaneous ignition
384
1.
Semenov approach of thermal ignition
384
2.
Frank-Kamenetskii theory of thermal ignition
389
D. Forced ignition
395
1.
Spark ignition and minimum ignition energy
396
2.
ignition by adiabatic compression and shock waves
401
E. Other ignition concepts
402
1.
Hypergolicity and pyrophoridty
403
2.
Catalytic ignition
406
Problems
407
CHAPTER
8.
ENVIRONMENTAL COMBUSTION
CONSIDERATIONS
409
A. Introduction
409
B. The nature of photochemical smog
410
1.
Primary and secondary pollutants
411
2.
The effect of NO,
411
3.
The effect of SOX
415
С
Formation and reduction of nitrogen oxides
417
1.
The structure of the nitrogen oxides
418
2.
The effect of flame structure
419
3.
Reaction mechanisms of oxides of nitrogen
420
4.
The reduction of NOX
436
D. SOX emissions
441
1.
The product composition and structure of sulfur compounds
442
2.
Oxidative mechanisms of sulfur fuels
444
E. Paniculate formation
457
1.
Characteristics of soot
458
2.
Soot formation processes
459
3.
Experimental systems and soot formation
460
4.
Soot
/ид
tendencies
462
5.
Detailed structure of sooting flames
474
Contents
6. Chemical
mechanisms of soot
formation
478
7.
The influence of physical and chemical parameters on soot formation
482
F. Stratospheric ozone
485
1.
The HOt catalytic cycle
486
2.
The NOX catalytic cycle
487
3.
The ClOx catalytic cycle
489
Problems
491
CHAPTER
9.
COMBUSTION OF NONVOLATILE FUELS
495
A. Carbon char, soot, and metal combustion
495
B. Metal combustion thermodynamics
496
1.
The criterion for vapor-phase combustion
496
2.
Thermodynamics of metal-oxygen systems
496
3.
Thermodynamics of metal-air systems
509
4.
Combustion synthesis
513
С
Diffusional kinetics
520
D. Diffusion-controlled burning rate
522
1.
Burning of metals in nearly pure oxygen
524
2.
Burning of small particles
-
diffusion versus kinetic limits
527
3.
The burning of boron particles
530
4.
Carbon particle combustion (C. R. Shaddix)
531
E. Practical carbonaceous fuels (C. R. Shaddix)
534
1.
Devolatilization
534
2.
Char combustion
539
3.
Pulverized coal char oxidation
540
4.
Gasification and oxy-combustion
542
F. Soot oxidation
(C. R.
Shaddix)
545
Problems
548
APPENDIXES
551
APPENDIX A. THERMOCHEMICAL DATA AND
CONVERSION FACTORS
555
Table
Al.
Conversion factors and physical constants
556
Table A2. Thermochemical data for selected chemical
compounds
557
Table
A3.
Thermochemical data for species included in reaction
list of Appendix
С
646
APPENDIX B. ADIABATIC FLAME TEMPERATURES OF
HYDROCARBONS
653
Table Bl. Adiabatic flame temperatures
653
xlv
Contents
APPENDIX
С.
SPECIFIC
REACTION
RATE
CONSTANTS
659
Table Cl. H2/O2
mechanism
659
Table C2. CO/H2/O2
mechanism
661
Table C3.
СНјО/СО/Нз/Ој
mechanism
662
Table C4.
СНзОН/СНзО/СО/Нј/Ој
mechanism
663
Table C5.
СНуСНзОН/СНгО/СО/Нз/Оз
mechanism
665
Table
Сб. СгНб/СНд/СНзОН/СНзО/СО/Нз/Оз
mechanism
668
Table C7.
Selected reactions of a
C3H8
oxidation mechanism
673
Table C8. NxOy/CO/H2/O2
mechanism
677
Table C9. HCl/NxOy/CO/H2/O2
mechanism
683
Table
СЮ. Оз/^Оу/СО/Нз/Ог
mechanism
684
TableCll. SO/NA/CO/Hj/Oj
mechanism
685
APPENDIX D. BOND DISSOCIATION ENERGIES OF
HYDROCARBONS
693
Table Dl. Bond dissociation energies of alkanes
694
Table D2. Bond dissociation energies of alkenes, alkynes, and
aromatics
695
Table D3. Bond dissociation energies of C/H/O compounds
698
Table D4. Bond dissociation energies of sulfur-containing
compounds
699
Table D5. Bond dissociation energies of nitrogen-containing
compounds
700
Table D6. Bond dissociation energies of halocarbons
702
APPENDIXE.
FLAMMABILITY LIMITS IN AIR
703
Table
E
1.
Flammability limits of fuel gases and vapors in air at
25°C and
1
atm
704
APPENDIX F. LAMINAR FLAME SPEEDS
713
Table Fl
.
Burning velocities of various fuels at 25°C air-fuel
temperature
(0.31
mol% H2O in air). Burning velocity
S
as a function of equivalence ratio
φ
in cm/s
714
Table F2. Burning velocities of various fuels at 100°C air-fuel
temperature
(0.31
mol% H2O in air). Burning velocity
S
as a function of equivalence ratio
φ
in cm/s
719
Table F3. Burning velocities of various fuels in air as a function
of pressure for an equivalence ratio of
1
in cm/s
720
APPENDIX G. SPONTANEOUS IGNITION TEMPERATURE
DATA
721
Table
G
1.
Spontaneous ignition temperature data
722
Contents
APPENDIX
H.
MINIMUM
SPARK IGNITION ENERGIES AND
QUENCHING DISTANCES
743
Table
H
1.
Minimum spark ignition energy data for fuels in air at
1
atm pressure
744
APPENDIX I. PROGRAMS FOR COMBUSTION KINETICS
747
A. Thermochemical parameters
747
B. Kinetic parameters
747
С
Transport parameters
748
D. Reaction mechanisms
748
E. Thermodynamic equilibrium
750
F. Temporal kinetics (Static and flow reactors)
752
G. Stirred reactors
753
H. Shock tubes
754
I. Premixed flames
754
J. Diffusion flames
756
K. Boundary layer flow
756
L. Detonations
756
M. Model analysis and mechanism reduction
756
Author Index
759
Subject Index
769
|
| any_adam_object | 1 |
| author | Glassman, Irvin 1923-2019 Yetter, Richard A. 1952- |
| author_GND | (DE-588)1026678560 (DE-588)13666069X |
| author_facet | Glassman, Irvin 1923-2019 Yetter, Richard A. 1952- |
| author_role | aut aut |
| author_sort | Glassman, Irvin 1923-2019 |
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| ctrlnum | (OCoLC)248001987 (DE-599)BVBBV035313012 |
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| dewey-hundreds | 500 - Natural sciences and mathematics |
| dewey-ones | 541 - Physical chemistry |
| dewey-raw | 541/.361 541.361 |
| dewey-search | 541/.361 541.361 |
| dewey-sort | 3541 3361 |
| dewey-tens | 540 - Chemistry and allied sciences |
| discipline | Chemie / Pharmazie |
| edition | 4. ed. |
| format | Book |
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| id | DE-604.BV035313012 |
| illustrated | Illustrated |
| indexdate | 2024-07-09T21:31:03Z |
| institution | BVB |
| isbn | 9780120885732 |
| language | English |
| lccn | 2008274100 |
| oai_aleph_id | oai:aleph.bib-bvb.de:BVB01-017117722 |
| oclc_num | 248001987 |
| open_access_boolean | |
| owner | DE-703 DE-634 |
| owner_facet | DE-703 DE-634 |
| physical | XX, 773 S. Ill., graph. Darst. |
| publishDate | 2008 |
| publishDateSearch | 2008 |
| publishDateSort | 2008 |
| publisher | Elsevier |
| record_format | marc |
| spelling | Glassman, Irvin 1923-2019 Verfasser (DE-588)1026678560 aut Combustion Irvin Glassman ; Richard A. Yetter 4. ed. Amsterdam [u.a.] Elsevier 2008 XX, 773 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and indexes Combustion Verbrennung (DE-588)4062656-8 gnd rswk-swf Verbrennung (DE-588)4062656-8 s DE-604 Yetter, Richard A. 1952- Verfasser (DE-588)13666069X aut Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017117722&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Glassman, Irvin 1923-2019 Yetter, Richard A. 1952- Combustion Combustion Verbrennung (DE-588)4062656-8 gnd |
| subject_GND | (DE-588)4062656-8 |
| title | Combustion |
| title_auth | Combustion |
| title_exact_search | Combustion |
| title_full | Combustion Irvin Glassman ; Richard A. Yetter |
| title_fullStr | Combustion Irvin Glassman ; Richard A. Yetter |
| title_full_unstemmed | Combustion Irvin Glassman ; Richard A. Yetter |
| title_short | Combustion |
| title_sort | combustion |
| topic | Combustion Verbrennung (DE-588)4062656-8 gnd |
| topic_facet | Combustion Verbrennung |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017117722&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |
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