Solid state hydrogen storage: materials and chemistry
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| Format: | Book |
|---|---|
| Language: | English |
| Published: |
Boca Raton, FL [u.a.]
CRC Press
2008
Cambridge Woodhead Publ. |
| Series: | Woodhead publishing in materials
|
| Subjects: | |
| Online Access: | Inhaltsverzeichnis Klappentext |
| Physical Description: | XVIII, 580 S. Ill., graph. Darst. |
| ISBN: | 9781845694944 9781845692704 9781420077889 |
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| adam_text | Contents
Contributor contact details
xiii
Preface
xvii
Part I Introduction
1
Hydrogen storage technologies
G. Walker, University of Nottingham, UK
1.1
Introduction
1.2
High-pressure gas storage
1.3
Liquid hydrogen
1.4
Physically bound hydrogen
1.5
Chemically bound hydrogen
1.6
Hydrolytic evolution of hydrogen
1.7
Summary
1.8
References
3
6
7
8
10
14
15
15
2
Hydrogen futures: emerging technologies for
hydrogen storage and transport
18
P. Ekins, King s College London and P. Bellaby, University of
Salford, UK
2.1
Introduction
18
2.2
Hydrogen technologies
18
2.3
Hydrogen scenarios: from production to applications
19
2.4
Hydrogen economics
23
2.5
Hydrogen end-use applications
29
2.6
Public acceptability of hydrogen
35
2.7
Policy implications
41
2.8
Conclusions
44
2.9
References
48
VI
Contents
3
Hydrogen containment materials
51
B. P. Somerday and
С
San Marchi,
Sandia
National Laboratories,
USA
3.1
Introduction
51
3.2
Materials challenges in hydrogen containment
51
3.3
Hydrogen permeation
53
3.4
Hydrogen embrittlement
54
3.5
Service experience with hydrogen containment
64
3.6
Materials used in the design of hydrogen containment
structures
66
3.7
Future trends
75
3.8
Other sources
76
3.9
Acknowledgements
77
3.10
References
77
4
Solid-state hydrogen storage system design
82
D. E. Dedrick.
Sandia
National Laboratories, USA
4.1
Introduction
82
4.2
The behavior of solid-state hydrogen storage materials
in systems
84
4.3
Thermodynamic properties of hydrogen storage materials
85
4.4
Thermal properties of hydrogen storage materials
86
4.5
System heat exchange design
94
4.6
Safe systems design
96
4.7
Enabling safe systems based on hydrogen sorption
materials
101
4.8
Future trends
101
4.9
Sources of further information and advice
102
4.10
References
102
Part II Analysing hydrogen interactions
5
Structural characterisation of hydride materials
107
В. С
Hauback,
Institute for Energy Technology, Norway
5.1
Introduction
107
5.2
Principles of diffraction
108
5.3
X-ray and neutron diffraction
112
5.4
The use of powder diffraction data
119
5.5
Examples of structures and results from powder
diffraction studies
126
5.6
Future trends
131
Contents
vii
5.7
Sources
of further
information
and
advice
132
5.8
References
133
6
Neutron scattering studies for analysing
solid-state hydrogen storage
135
D. K. Ross, University of Salford, UK
6.1
Introduction
135
6.2
The neutron scattering method
136
6.3
Studies of light metal hydrides
137
6.4
Studies of molecular hydrogen trapping in porous
materials
138
6.5
The basic theory of neutron scattering
138
6.6
Theory of inelastic neutron scattering
142
6.7
Inelastic scattering measurements on solid-state
hydrides
154
6.8
Inelastic neutron scattering from molecular hydrogen
trapped on surfaces
159
6.9
Quasi-elastic scattering measurements on hydrogen
diffusing in hydrides
167
6.10
Conclusions
169
6.11
References
170
7
Reliably measuring hydrogen uptake in storage
materials
174
E. MacA. Gray, Griffith University, Australia
7.1
Introduction
174
7.2
Compressibilities of hydrogen and deuterium
175
7.3
Measurement regimes
177
7.4
Measurement techniques
179
7.5
System characterisation
189
7.6
The sample volume problem
195
7.7
The variable-volume hydrogenator
200
7.8
Summary and conclusions
202
7.9
Acknowledgements
203
7.10
References
203
8
Modelling of carbon-based materials for hydrogen
storage
205
J.
Íñiguez,
Institut de
Ciencia de Materials de Barcelona
(ICMAB-CSIC), Spain
8.1
Introduction
205
viii
Contents
8.2
Hydrogen interactions with carbons: physisorption and
chemisorption
207
8.3
Predictions for hydrogen storage in carbon nanostructures
coated with light transition metals
211
8.4
Conclusions and future trends
216
8.5
Sources of further information and advice
217
8.6
References
217
Part III Physically bound hydrogen storage
9
Storage of hydrogen in zeolites
223
P. A. Anderson, University of Birmingham, UK
9.1
Introduction
223
9.2
Hydrogen encapsulation at high temperatures
224
9.3
Low-temperature physisorption
227
9.4
Storage at room temperature: encapsulation, physisorption,
chemisorption and spillover
231
9.5
Spectroscopie
studies
234
9.6
Theoretical studies and modelling
243
9.7
Other potential applications of zeolites in a hydrogen
energy system
248
9.8
Prospects for the use of zeolites in a hydrogen energy
system
249
9.9
Acknowledgements
251
9.10
References
252
10
Carbon nanostructures for hydrogen storage
261
P.
Benard
and R. Chahine,
Institut
de
recherche
sur l hydrogène,
Canada
10.1
Introduction
261
10.2
Storage of hydrogen in solids
262
10.3
Carbon nanostructures and hydrogen storage
263
10.4
Supercritical adsorption in nanoporous materials
267
10.5
Theory
269
10.6
Adsorption of hydrogen on activated carbons and carbon
nanostructures
274
10.7
Beyond carbon nanostructures
283
10.8
Conclusions
284
10.9
Acknowledgments
284
10.10
References
284
Contents ix
11
Metal-organic framework materials for hydrogen
storage
288
X. Lin, J. Jia,
N.
R. Champness, P. Hubberstey and M.
Schröder,
University of Nottingham, UK
11.1
Introduction
288
11.2
Hydrogen storage in particular metal-organic framework
(MOF)
materials
291
11.3
Interactions of H2 with metal—organic frameworks:
experiments and modelling
303
11.4
Conclusions and future trends
308
11.5
References
308
Part IV Chemically bound hydrogen storage
12
Intermetallics for hydrogen storage
315
D. Chandra, University of Nevada, USA
12.1
Introduction
315
12.2
Metal hydrides
317
12.3
Long-term stability of metal hydrides
325
12.4
Intrinsic testing of intermetallic hydrides
329
12.5
Extrinsic testing of intermetallic hydrides
341
12.6
Extrinsic cycling of complex hydrides
345
12.7
Conclusions
346
12.8
Acknowledgements
348
12.9
References
348
13
Magnesium hydride for hydrogen storage
357
D. Grant, University of Nottingham, UK
13.1
Introduction
357
13.2
Background to magnesium and magnesium hydride
357
13.3
Thermodynamics and hydride mechanisms
362
13.4
Ball milling to improve hydrogen sorption behaviour
363
13.5
Metal and alloy additives
366
13.6
Metal oxide catalysts
368
13.7
Kinetic models of hydrogen absorption
372
13.8
Conclusions and future work
374
13.9
References
376
χ
Contents
14
Alanates
as hydrogen storage materials
381
C. Jensen, University of Hawaii at Manoa, Hawaii,
Y. Wang
and
M. Y. Chou,
Georgia Institute of Technology, USA
14.1
Introduction
381
14.2
Atomic structure of
alanates
382
14.3
Dehydrogenation and rehydrogenation reactions in
alanates
390
14.4
Density-functional calculations of alkali and alkaline-earth
alanates
404
14.5
Future trends
411
14.6
Conclusions
415
14.7
References
415
15
Borohydrides as hydrogen storage materials
420
Y. Nakamori and S.
Orimo, Tohoku
University, Japan
15.1
Introduction
420
15.2
Synthesis of borohydrides
420
15.3
Structure of borohydrides
425
15.4
Dehydrogenation and rehydrogenation reactions
435
15.5
Future trends
445
15.6
Acknowledgements
445
15.7
References
445
16
Imides and amides as hydrogen storage materials
450
D. H. Gregory, University of Glasgow, UK
16.1
Introduction
450
16.2
The lithium-nitrogen-hydrogen system
450
16.3
The imides and amides of the group
2
elements
464
16.4
Mixed metal imides and amides
466
16.5
Future trends and conclusions
472
16.6
Acknowledgements
473
16.7
References
474
17
Multicomponent hydrogen storage systems
478
G. Walker, University of Nottingham, UK
17.1
Introduction
478
17.2
Thermodynamic
déstabilisation
480
17.3
Complex hydride-metal hydride systems
482
17.4
Complex hydride-non-hydride systems
491
17.5
Complex hydride-complex hydride systems
493
17.6
Other
déstabilisation
multicomponent systems
495
Contents xi
17.7
Future trends
496
17.8
References
497
18
Organic liquid carriers for hydrogen storage
500
M. Ichikawa, Hokkaido University, Japan
18.1
Introduction
500
18.2
Organic hydrides: chemistry and reactions for hydrogen
storage and supply
501
18.3
Spray-pulsed reactors for efficient hydrogen supply by
organic hydrides
506
18.4
Hydrogen storage and supply by organic hydrides
512
18.5
Hydrogen delivery using organic hydrides for fuel-cell
cars and domestic power systems
518
18.6
High-density electric power delivery using organic
hydride carriers
521
18.7
Rechargeable direct fuel cells using organic hydrides
523
18.8
Hydrogen delivery networks using organic hydrides
528
18.9
References
531
19
Indirect hydrogen storage in metal ammines
533
T.
VÉGGÉ,
R. Z.
S0RENSEN,
A. KlERKE, J. S.
HUMMELSH0J,
T.
Johannessen,
J.
K. N0rskov and C. H. Christensen, Technical
University of Denmark, Denmark
19.1
Introduction
533
19.2
Indirect hydrogen storage in ammonia
534
19.3
Compact storage in solid metal ammine materials
537
19.4
Selecting metal ammine storage materials
541
19.5
Nano-
to macro-scale design of metal ammines
548
19.6
Commercial applications and future trends
553
19.7
References
561
20
Conclusion: technological challenges in hydrogen
storage
565
G. Walker, University of Nottingham, UK
20.1
Challenges in hydrogen applications
565
20.2
Challenges in materials for storage
566
20.3
Conclusions
569
20.4
References
569
Index
571
WOODHEAD PUBLISHING IN MATERIALS
Hydrogen fuel cells are emerging as a major alternative to conventional energy
systems for transportation and other applications. Central to the development of
the hydrogen economy is safe, efficient and viable storage of hydrogen. Solid-state
hydrogen storage: Materials and chemistry reviews the latest developments in solid-
state hydrogen storage.
Part I discusses hydrogen storage technologies, hydrogen futures, hydrogen
containment materials, and solid-state hydrogen storage system design. Part II
reviews the analysis of hydrogen interactions including structural characterisation
of hydride materials, neutron scattering techniques, reliably measuring hydrogen
uptake in storage materials, and modelling of carbon-based materials for hydrogen
storage. Part III analyses physically bound hydrogen storage with chapters on zeolites,
carbon nanostructures, and metal-organic framework materials. Part IV examines
chemically bound hydrogen storage including intermetallics, magnesium hydride,
alanates, borohydrides,
imides and amides, multicomponent hydrogen storage
systems, organic liquid carriers, indirect hydrogen storage in metal ammines, and
technological challenges in hydrogen storage.
With its distinguished editor and international team of contributors, Solid-state
hydrogen storage: Materials and chemistry will be a standard reference work for
researchers and professionals interested in renewable energy, hydrogen fuel cells and
hydrogen storage.
Dr
Gavin Walker is a leading authority on hydrogen storage. He works at the
University of Nottingham, is a partner in the UK Research Councils
Supergen
UK
Sustainable Hydrogen Energy Consortium (UKSHEC) and is a UK expert for the
International Energy Agency s Task
22
on hydrogen storage materials.
Woodhead Publishing and Maney Publishing
on behalf of
The Institute of Materials, Minerals
&
Mining
Woodhead Publishing Ltd
Abington Hall,
Cranta
Park
Great Abington
Cambridge CB21 6AH
England
www.woodheadpublishing.com
CRC
Press LLC
6000
Broken Sound Parkway, NW
Suite
300,
Boca Raton
FL
33487
USA
CRC
order number WP7788
|
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| id | DE-604.BV035300210 |
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| indexdate | 2024-07-09T21:30:46Z |
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| record_format | marc |
| series2 | Woodhead publishing in materials |
| spelling | Solid state hydrogen storage materials and chemistry ed. by Gavin Walker Boca Raton, FL [u.a.] CRC Press 2008 Cambridge Woodhead Publ. XVIII, 580 S. Ill., graph. Darst. txt rdacontent n rdamedia nc rdacarrier Woodhead publishing in materials Hydrogen Storage Hydrogen Storage Materials Solid state chemistry Wasserstoffspeicherung (DE-588)4189283-5 gnd rswk-swf Wasserstoff-Speicher (DE-588)4480116-6 gnd rswk-swf Metall-Wasserstoff-System (DE-588)4169641-4 gnd rswk-swf Metall-Wasserstoff-System (DE-588)4169641-4 s DE-604 Wasserstoff-Speicher (DE-588)4480116-6 s Wasserstoffspeicherung (DE-588)4189283-5 s Walker, Gavin Sonstige oth Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017105086&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis Digitalisierung UB Bayreuth application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017105086&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA Klappentext |
| spellingShingle | Solid state hydrogen storage materials and chemistry Hydrogen Storage Hydrogen Storage Materials Solid state chemistry Wasserstoffspeicherung (DE-588)4189283-5 gnd Wasserstoff-Speicher (DE-588)4480116-6 gnd Metall-Wasserstoff-System (DE-588)4169641-4 gnd |
| subject_GND | (DE-588)4189283-5 (DE-588)4480116-6 (DE-588)4169641-4 |
| title | Solid state hydrogen storage materials and chemistry |
| title_auth | Solid state hydrogen storage materials and chemistry |
| title_exact_search | Solid state hydrogen storage materials and chemistry |
| title_full | Solid state hydrogen storage materials and chemistry ed. by Gavin Walker |
| title_fullStr | Solid state hydrogen storage materials and chemistry ed. by Gavin Walker |
| title_full_unstemmed | Solid state hydrogen storage materials and chemistry ed. by Gavin Walker |
| title_short | Solid state hydrogen storage |
| title_sort | solid state hydrogen storage materials and chemistry |
| title_sub | materials and chemistry |
| topic | Hydrogen Storage Hydrogen Storage Materials Solid state chemistry Wasserstoffspeicherung (DE-588)4189283-5 gnd Wasserstoff-Speicher (DE-588)4480116-6 gnd Metall-Wasserstoff-System (DE-588)4169641-4 gnd |
| topic_facet | Hydrogen Storage Hydrogen Storage Materials Solid state chemistry Wasserstoffspeicherung Wasserstoff-Speicher Metall-Wasserstoff-System |
| url | http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017105086&sequence=000003&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017105086&sequence=000004&line_number=0002&func_code=DB_RECORDS&service_type=MEDIA |
| work_keys_str_mv | AT walkergavin solidstatehydrogenstoragematerialsandchemistry |