Metal amide chemistry:
Gespeichert in:
| Format: | Buch |
|---|---|
| Sprache: | English |
| Veröffentlicht: |
Hoboken, NJ
Wiley
2009
|
| Schlagworte: | |
| Online-Zugang: | Inhaltsverzeichnis |
| Beschreibung: | Includes bibliographical references and index |
| Beschreibung: | XII, 355 S. graph. Darst. |
| ISBN: | 9780470721841 |
Internformat
MARC
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| 020 | |a 9780470721841 |c cloth : alk. paper |9 978-0-470-72184-1 | ||
| 035 | |a (OCoLC)299046793 | ||
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| 040 | |a DE-604 |b ger |e aacr | ||
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| 245 | 1 | 0 | |a Metal amide chemistry |c Michael Lappert ... [et al.] |
| 264 | 1 | |a Hoboken, NJ |b Wiley |c 2009 | |
| 300 | |a XII, 355 S. |b graph. Darst. | ||
| 336 | |b txt |2 rdacontent | ||
| 337 | |b n |2 rdamedia | ||
| 338 | |b nc |2 rdacarrier | ||
| 500 | |a Includes bibliographical references and index | ||
| 650 | 4 | |a Amides | |
| 650 | 4 | |a Alkaline earth metals | |
| 650 | 4 | |a Organometallic compounds | |
| 650 | 0 | 7 | |a Metallorganische Verbindungen |0 (DE-588)4038906-6 |2 gnd |9 rswk-swf |
| 650 | 0 | 7 | |a Metallamide |0 (DE-588)4289738-5 |2 gnd |9 rswk-swf |
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| 689 | 0 | |5 DE-604 | |
| 700 | 1 | |a Lappert, Michael F. |e Sonstige |4 oth | |
| 856 | 4 | 2 | |m HBZ Datenaustausch |q application/pdf |u http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017070268&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA |3 Inhaltsverzeichnis |
| 999 | |a oai:aleph.bib-bvb.de:BVB01-017070268 | ||
Datensatz im Suchindex
| _version_ | 1804138549392441344 |
|---|---|
| adam_text | Titel: Metal amide chemistry
Autor: Lappert, Michael F.
Jahr: 2009
Contents
Biographies xi
Preface xüi
1 Introduction 1
1.1 Scope and Organisation of Subject Matter 1
1.2 Developments and Perspectives 2
2 Alkali Metal Amides 7
2.1 Introduction 7
2.2 Lithium Amides 8
2.2.1 Introduction 8
2.2.2 Monomeric Lithium Amides 9
2.2.3 Dimeric Lithium Amides 11
2.2.4 Trimeric Lithium Amides 13
2.2.5 Tetrameric Lithium Amides 14
2.2.6 Higher Aggregate Lithium Amides 15
2.2.7 Laddering 17
2.2.8 Heterometallic Derivatives 18
2.3 Sodium Amides 20
2.3.1 Introduction 20
2.3.2 Monomeric and Dimeric Sodium Amides 21
2.3.3 Higher Aggregate Sodium Amides 22
2.3.4 Heterometallic Sodium Amides 23
2.4 Potassium Amides 25
2.4.1 Introduction 25
2.4.2 Potassium Parent Amides (~NH2 as Ligand) 25
2.4.3 Potassium Primary and Secondary Amides 26
2.4.4 Heterometallic Potassium Amides 26
2.5 Rubidium Amides 28
2.6 Caesium Amides 30
References 31
3 Beryllium and the Alkaline Earth Metal Amides 39
3.1 Introduction 39
3.2 Beryllium Amides 40
vi Contents
3.3 Magnesium Amides 43
3.3.1 Introduction 43
3.3.2 Monomeric Magnesium Amides 45
3.3.3 Dimeric Magnesium Amides 48
3.3.4 Higher Aggregates and Related Magnesium Amides 51
3.3.5 Heterometallic Magnesium Amides 52
3.3.6 Magnesium Inverse Crown Complexes 56
3.3.7 Magnesium Imides 59
3.4 Calcium Amides 60
3.4.1 Introduction 60
3.4.2 Monomeric Calcium Amides 60
3.4.3 Dimeric Calcium Amides and Higher Aggregates 63
3.4.4 Heterometallic Calcium Amide Derivatives 64
3.5 Strontium Amides 65
3.5.1 Introduction 65
3.5.2 Monomeric Strontium Amides 67
3.5.3 Higher Aggregate Strontium Amides 68
3.6 Barium Amides 69
3.6.1 Introduction 69
3.6.2 Monomeric Barium Amides 69
3.6.3 Dimeric Barium Amides 70
3.6.4 Heterometallic Barium Amides 70
References 72
Amides of the Group 3 and Lanthanide Metals 79
4.1 Introduction 79
4.2 The Pre-1996 Literature: Anwander s Review 81
4.2.1 Introduction 81
4.2.2 Lnm Complexes with N-Hydrocarbyl-Amido Ligands 81
4.2.3 Lnln Complexes having Silylamido Ligands 81
4.2.4 Bis(Trimethylsilyl)Amido-Lnn Complexes and a
CeIV Analogue 82
4.2.5 Lnm Complexes having Donor-Functionalised
Amido Ligands 83
4.2.6 Ln Amides as Precursors for Ln Coordination
or Organometallic Compounds 85
4.2.7 Applications as Materials or Catalysts 85
4.3 The Recent (Post-1995) Literature 86
4.3.1 Introduction 86
4.3.2 Ln111 Complexes with N-Hydrocarbyl Substituted
Ligands 86
4.3.3 Ln111 Complexes having Silylamido Ligands 87
4.3.4 Ln and CeIV Amides 90
4.3.5 Ln Complexes having Donor-Functionalised
Amido Ligands 93
Contents v/7
4.3.6 Ln Amides as Precursors for Ln Coordination
or Organometallic Compounds 104
4.3.7 Applications as Materials or Catalysts 110
4.3.8 Ln Complexes having 1,4-Disubstituted-1,4-
Diazabutadiene Ligands, R2-DAD 111
References 113
Amides of the Actinide Metals 121
5.1 Introduction 121
5.2 Neutral Amidouranium(IV) and Thorium(IV) Complexes 122
5.2.1 Introduction 122
5.2.2 Hydrocarbylamido-AnIV Compounds Free of
i7-Centred Ligands 123
5.2.3 Silylamido-AnIV Compounds Free of Tr-Centred
Ligands 127
5.2.4 AnIV Amides Containing 7r-Centred Co-ligands 131
5.3 Neutral Um Amides 135
5.4 Neutral Mixed Valence (Um/UIV), Un, Uv and UVI Amides 136
5.5 Amidouranates 139
5.6 Amidouranium Tetraphenylborates 141
References 144
Amides of the Transition Metals 149
6.1 Introduction 149
6.2 Transition Metal Derivatives of Monodentate Amides 150
6.2.1 Overview 150
6.2.2 Synthesis 162
6.2.3 Structure and Bonding 164
6.2.4 Parent Amido (-NH2) Derivatives 167
6.2.5 Low-coordinate Transition Metal Amides 170
6.2.6 Two-sided Amido Ligands 173
6.3 Transition Metal Complexes of Polydentate Amido Ligands 178
6.3.1 Introduction 178
6.3.2 Amido Phosphine Ligands 179
6.3.3 Multidentate Podand Ligands 180
6.4 Other Chelating Amido Ligands 184
References 186
Amides of Zinc, Cadmium and Mercury 205
7.1 Introduction 205
7.2 Neutral Homoleptic Zinc, Cadmium and Mercury Amides 206
7.3 Ionic Metal Amides 208
7.3.1 Amidometallates 208
7.3.2 Zincation Mediated by Amidozinc Complexes 208
7.3.3 Other Ionic Group 12 Metal Amido Salts 211
viii Contents
7.4 Lewis Base Complexes, Chelated Metal Amides and Heteroleptic
Amido Complexes 212
References 214
Amides of the Group 13 Metals 219
8.1 Introduction 219
8.1.1 Synthesis 220
8.1.2 M-N Bonding (M = Al, Ga, In or Tl) 220
8.1.3 Multiple Character in M-N (M = Al - Tl) Bonds 221
8.2 Aluminium Amides 221
8.2.1 Aluminium Parent Amides (~NH2 as Ligand) 221
8.2.2 Monomeric Aluminium Amides 223
8.2.3 Dimeric Aluminium Amides 226
8.2.4 Higher Aggregate Aluminium Amides 228
8.2.5 Heterometallic Aluminium Amides 230
8.2.6 Aluminium Imides (Iminoalanes) 232
8.2.7 Aluminium© Amides 235
8.3 Gallium Amides 236
8.3.1 Introduction 236
8.3.2 Monomeric Gallium Amides 237
8.3.3 Associated Gallium Amides 238
8.3.4 Heterometallic Gallium Amides 239
8.3.5 Iminogallanes (Gallium Imides) 240
8.3.6 Gallium Amides in Low ( +3)
Oxidation States 242
8.4 Indium Amides 242
8.4.1 Introduction 242
8.4.2 Monomeric Indium(III) Amides 242
8.4.3 Associated Indium Amides 243
8.4.4 Heterometallic Indium Amides 245
8.4.5 Iminoindanes (Indium Imides) 245
8.4.6 Indium Amides in Oxidation States +3 247
8.5 Thallium Amides 248
8.5.1 Introduction 248
8.5.2 Thallium(I) Amides 248
8.5.3 Thallium(III) Derivatives 251
8.5.4 Thallium Amides in Mixed Oxidation States 251
8.5.5 Heterometallic Derivatives 252
References 253
Subvalent Amides of Silicon and the Group 14 Metals 263
9.1 Introduction 263
9.2 Subvalent Amidosilicon Compounds 264
9.2.1 Introduction 264
9.2.2 Bis(amino)silylenes: Pre-2001 265
Contents ix
9.2.3 Bis(amino)silylenes: 2001-2004 266
9.2.4 Bis(amino)silylenes: Post-2004 271
9.3 Amidometal(II) Chemistry [Ge(II), Sn(II), Pb(II)] 279
9.3.1 Introduction 279
9.3.2 Homoleptic Metal(II) Amides: Synthesis, Structures
and Physical Properties 279
9.3.3 Protonolyses of Homoleptic Metal(II) Amides 287
9.3.4 Heteroleptic Metal(II) Amides 290
9.3.5 Metathetical Exchange Reactions 295
9.3.6 Reactions with Heterocumulenes 297
9.3.7 Oligomeric Metal(II) Imides 298
9.3.8 Metal(II) Amides based on 1,4-Diazabutadienes
or a Related Compound 298
9.3.9 Oxidative Addition and Redox Reactions 299
9.3.10 Reactions with Transition Metal Complexes 306
9.4 Dimeric Metal(III) Imides: Biradicaloid Compounds 312
9.5 Higher-Nuclearity Group 14 Metalloid Clusters having
Amido Ligands 316
References 318
10 Amides of the Group 15 Metals (As, Sb, Bi) 327
10.1 Introduction 327
10.2 Mononuclear Group 15 Metal(III) Amides 329
10.2.1 Introduction 329
10.2.2 Synthesis, Structures and Protolyses of Metal(III) Amides 329
10.2.3 Synthesis, Structures and Reactions of Heteroleptic
Mononuclear Bis(amido) Metal(III) Compounds 330
10.2.4 Synthesis, Structures and Reactions of Heteroleptic
Mononuclear Amidometal(III) Compounds 333
10.2.5 Bis(amido)Metal(III) Salts 334
10.3 Oligomeric Group 15 Metal Imides 338
10.3.1 Binuclear and Oligomeric Group 15 Metal(III) Imides 339
10.3.2 Binuclear Group 15 Metal(V) Imides 342
10.4 Mononuclear Group 15 Metal(V) Amides 343
10.5 Group 15 Metal(III) Macrocyclic Imides 344
10.6 Miscellaneous Group 15 Metal-Nitrogen Compounds 345
References 347
Index 351
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| indexdate | 2024-07-09T21:29:57Z |
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| isbn | 9780470721841 |
| language | English |
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| physical | XII, 355 S. graph. Darst. |
| publishDate | 2009 |
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| spelling | Metal amide chemistry Michael Lappert ... [et al.] Hoboken, NJ Wiley 2009 XII, 355 S. graph. Darst. txt rdacontent n rdamedia nc rdacarrier Includes bibliographical references and index Amides Alkaline earth metals Organometallic compounds Metallorganische Verbindungen (DE-588)4038906-6 gnd rswk-swf Metallamide (DE-588)4289738-5 gnd rswk-swf Metallorganische Verbindungen (DE-588)4038906-6 s Metallamide (DE-588)4289738-5 s DE-604 Lappert, Michael F. Sonstige oth HBZ Datenaustausch application/pdf http://bvbr.bib-bvb.de:8991/F?func=service&doc_library=BVB01&local_base=BVB01&doc_number=017070268&sequence=000002&line_number=0001&func_code=DB_RECORDS&service_type=MEDIA Inhaltsverzeichnis |
| spellingShingle | Metal amide chemistry Amides Alkaline earth metals Organometallic compounds Metallorganische Verbindungen (DE-588)4038906-6 gnd Metallamide (DE-588)4289738-5 gnd |
| subject_GND | (DE-588)4038906-6 (DE-588)4289738-5 |
| title | Metal amide chemistry |
| title_auth | Metal amide chemistry |
| title_exact_search | Metal amide chemistry |
| title_full | Metal amide chemistry Michael Lappert ... [et al.] |
| title_fullStr | Metal amide chemistry Michael Lappert ... [et al.] |
| title_full_unstemmed | Metal amide chemistry Michael Lappert ... [et al.] |
| title_short | Metal amide chemistry |
| title_sort | metal amide chemistry |
| topic | Amides Alkaline earth metals Organometallic compounds Metallorganische Verbindungen (DE-588)4038906-6 gnd Metallamide (DE-588)4289738-5 gnd |
| topic_facet | Amides Alkaline earth metals Organometallic compounds Metallorganische Verbindungen Metallamide |
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